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Stabilized Liquid Membrane Devices
A stabilized liquid membrane device or SLMD is a type of passive sampling device which allows for the in situ, integrative collection of waterborne, labile ionic metal contaminants.Brumbaugh, W.G., Petty, J.D., Huckins, J.N., Manahan, S.E. 2002. Stabilized liquid membrane device (SLMD) for the passive, integrative sampling of labile metals in water. Water, Air, Soil Pollut. 133, 109–119. By capturing and sequestering metal ions onto its surface continuously over a period of days to weeks, an SLMD can provide an integrative measurement of bioavailable toxic metal ions present in the aqueous environment.Petty, J.D., Brumbaugh, W.G., Huckins, T.W.M., Wiedmeyer, R. 2001. US Patent No. US006296760B1. https://patents.google.com/patent/US6296760?oq=ininventor:Petty+ininventor:Brumbaugh+ininventor:Huckins+ininventor:Wiedmeyer As such, they have been used in conjunction with other passive samplers in ecological field studies.2012. Potential Causes for Impairment of Rainbow Trout Earl ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Atomic Absorption Spectroscopy
Atomic absorption spectroscopy (AAS) and atomic emission spectroscopy (AES) is a spectroanalytical procedure for the quantitative determination of chemical elemlight) by free atoms in the gaseous state. Atomic absorption spectroscopy is based on absorption of light by free metallic ions. In analytical chemistry the technique is used for determining the concentration of a particular element (the analyte) in a sample to be analyzed. AAS can be used to determine over 70 different elements in solution, or directly in solid samples via electrothermal vaporization, and is used in pharmacology, biophysics, archaeology and toxicology research. Atomic emission spectroscopy was first used as an analytical technique, and the underlying principles were established in the second half of the 19th century by Robert Wilhelm Bunsen and Gustav Robert Kirchhoff, both professors at the University of Heidelberg, Germany. The modern form of AAS was largely developed during the 1950s by a team of ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chemcatcher
Chemcatcher is a passive sampling device for monitoring a variety of pollutants (including trace metals, polycyclic aromatic hydrocarbons, pesticides and pharmaceutical residues) in water. It is a reusable three component, water-tight PTFE body. Two different designs are available to accommodate different types of commercially available 47 mm diameter receiving phase disks. Background Most monitoring programmes involve the periodic collection of low volume spot samples (bottle or grab) of water, which is challenging, particularly where levels fluctuate over time and when chemicals are only present at trace, yet toxicologically relevant concentrations. Chemcatcher is used to measure time-weighted average (TWA) or equilibrium concentrations of a wide range of pollutants in water. This allows the end user to obtain a more representative picture of the chemicals that may be present in the aquatic environment. Development The Chemcatcher concept was developed by Professors Ric ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Diffusive Gradients In Thin Films
The diffusive gradients in thin films (DGT) technique is an environmental chemistry technique for the detection of Chemical element, elements and Chemical compound, compounds in aqueous Ecology#Physical environment, environments, including Hydrosphere, natural waters, sediments and soils. It is well suited to ''in situ'' detection of bioavailable toxic trace metal contaminants. The technique involves using a specially-designed Environmental monitoring#Passive sampling, passive sampler that houses a binding gel, Diffusion, diffusive gel and Membrane technology, membrane filter. The element or compound passes through the membrane filter and diffusive gel and is assimilated by the binding gel in a rate-controlled manner. Post-deployment analysis of the binding gel can be used to determine the time-weighted-average bulk solution concentration of the element or compound via a simple equation. History The DGT technique was developed in 1994 by Hao Zhang and William Davison at the Lancas ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Polar Organic Chemical Integrative Sampler
A polar organic chemical integrative sampler (POCIS) is a passive sampling device which allows for the in situ collection of a time-integrated average of hydrophilic organic contaminants developed by researchers with the United States Geological Survey in Columbia, Missouri. POCIS provides a means for estimating the toxicological significance of waterborne contaminants. The POCIS sampler mimics the respiratory exposure of organisms living in the aquatic environment and can provide an understanding of bioavailable contaminants present in the system. POCIS can be deployed in a wide range of aquatic environments and is commonly used to assist in environmental monitoring studies. __TOC__ Background The first passive sampling devices were developed in the 1970s to determine concentrations of contaminants in the air. In 1980 this technology was first adapted for the monitoring of organic contaminants in water. The initial type of passive sampler developed for aquatic monitoring purpose ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Organic Compound
In chemistry, organic compounds are generally any chemical compounds that contain carbon- hydrogen or carbon-carbon bonds. Due to carbon's ability to catenate (form chains with other carbon atoms), millions of organic compounds are known. The study of the properties, reactions, and syntheses of organic compounds comprise the discipline known as organic chemistry. For historical reasons, a few classes of carbon-containing compounds (e.g., carbonate salts and cyanide salts), along with a few other exceptions (e.g., carbon dioxide, hydrogen cyanide), are not classified as organic compounds and are considered inorganic. Other than those just named, little consensus exists among chemists on precisely which carbon-containing compounds are excluded, making any rigorous definition of an organic compound elusive. Although organic compounds make up only a small percentage of Earth's crust, they are of central importance because all known life is based on organic compounds. Livin ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Grab Sample
Convenience sampling (also known as grab sampling, accidental sampling, or opportunity sampling) is a type of non-probability sampling that involves the sample being drawn from that part of the population that is close to hand. This type of sampling is most useful for pilot testing. Definition A convenience sample is a type of non-probability sampling method where the sample is taken from a group of people easy to contact or to reach; for example, standing at a mall or a grocery store and asking people to answer questions. This type of sampling is also known as grab sampling or availability sampling. There are no other criteria to the sampling method except that people be available and willing to participate. In addition, this type of sampling method does not require that a simple random sample is generated since the only criterion is whether the participants agree to participate. Applications Convenience sampling is not often recommended for research due to the possibility o ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Detection Limit
The limit of detection (LOD or LoD) is the lowest signal, or the lowest corresponding quantity to be determined (or extracted) from the signal, that can be observed with a sufficient degree of confidence or statistical significance. However, the exact threshold (level of decision) used to decide when a signal significantly emerges above the continuously fluctuating background noise remains arbitrary and is a matter of policy and often of debate among scientists, statisticians and regulators depending on the stakes in different fields. Significance in analytical chemistry In analytical chemistry, the detection limit, lower limit of detection, or LOD (limit of detection), often mistakenly confused with the analytical sensitivity, is the lowest quantity of a substance that can be distinguished from the absence of that substance (a '' blank value'') with a stated confidence level (generally 99%). The detection limit is estimated from the mean of the blank, the standard deviation o ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Trace Element
__NOTOC__ A trace element, also called minor element, is a chemical element whose concentration (or other measure of amount) is very low (a "trace amount"). They are classified into two groups: essential and non-essential. Essential trace elements are needed for many physiological and biochemical processes in both plants and animals. Not only do trace elements play a role in biological processes but they also serve as catalysts to engage in oxidation and reduction mechanisms. The exact definition depends on the field of science: * In analytical chemistry, a trace element is one whose average concentration is less than 100 parts per million (ppm) measured in the atomic count or less than 100 micrograms per gram. * In biochemistry, an essential trace element is a dietary element that is needed in very minute quantities for the proper growth, development, and physiology of the organism. The dietary elements or essential trace elements are those that are required to perform v ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Zinc
Zinc is a chemical element with the symbol Zn and atomic number 30. Zinc is a slightly brittle metal at room temperature and has a shiny-greyish appearance when oxidation is removed. It is the first element in group 12 (IIB) of the periodic table. In some respects, zinc is chemically similar to magnesium: both elements exhibit only one normal oxidation state (+2), and the Zn2+ and Mg2+ ions are of similar size.The elements are from different metal groups. See periodic table. Zinc is the 24th most abundant element in Earth's crust and has five stable isotopes. The most common zinc ore is sphalerite (zinc blende), a zinc sulfide mineral. The largest workable lodes are in Australia, Asia, and the United States. Zinc is refined by froth flotation of the ore, roasting, and final extraction using electricity ( electrowinning). Zinc is an essential trace element for humans, animals, plants and for microorganisms and is necessary for prenatal and postnatal development. It ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Lead
Lead is a chemical element with the Symbol (chemistry), symbol Pb (from the Latin ) and atomic number 82. It is a heavy metals, heavy metal that is density, denser than most common materials. Lead is Mohs scale of mineral hardness#Intermediate hardness, soft and malleable, and also has a relatively low melting point. When freshly cut, lead is a shiny gray with a hint of blue. It tarnishes to a dull gray color when exposed to air. Lead has the highest atomic number of any stable nuclide, stable element and three of its isotopes are endpoints of major nuclear decay chains of heavier elements. Lead is toxic, even in small amounts, especially to children. Lead is a relatively unreactive post-transition metal. Its weak metallic character is illustrated by its amphoteric nature; lead and lead oxides react with acids and base (chemistry), bases, and it tends to form covalent bonds. Compounds of lead are usually found in the +2 oxidation state rather than the +4 state common with lighte ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Nickel
Nickel is a chemical element with symbol Ni and atomic number 28. It is a silvery-white lustrous metal with a slight golden tinge. Nickel is a hard and ductile transition metal. Pure nickel is chemically reactive but large pieces are slow to react with air under standard conditions because a passivation layer of nickel oxide forms on the surface that prevents further corrosion. Even so, pure native nickel is found in Earth's crust only in tiny amounts, usually in ultramafic rocks, and in the interiors of larger nickel–iron meteorites that were not exposed to oxygen when outside Earth's atmosphere. Meteoric nickel is found in combination with iron, a reflection of the origin of those elements as major end products of supernova nucleosynthesis. An iron–nickel mixture is thought to compose Earth's outer and inner cores. Use of nickel (as natural meteoric nickel–iron alloy) has been traced as far back as 3500 BCE. Nickel was first isolated and classified a ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
