Perbromyl Fluoride
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Perbromyl Fluoride
Perbromyl fluoride is an inorganic compound of bromine, fluorine, and oxygen with the chemical formula . Synthesis Synthesis of perbromyl fluoride is by the effect of antimony pentafluoride on a solution of potassium perbromate in hydrofluoric acid: : Physical properties Perbromyl fluoride is a colorless gas at room temperature that is stable in the absence of moisture. Chemical properties Perbromyl fluoride reacts with water to produce perbromic acid and hydrogen fluoride Hydrogen fluoride (fluorane) is an Inorganic chemistry, inorganic compound with chemical formula . It is a very poisonous, colorless gas or liquid that dissolves in water to yield hydrofluoric acid. It is the principal industrial source of fluori ...: : References {{Authority control Oxyfluorides Bromine compounds ...
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Periodyl Fluoride
Periodyl fluoride is an inorganic compound of iodine, fluorine, and oxygen with the chemical formula . The compound has been initially synthesized around 1950. Synthesis Synthesis of periodyl fluoride is by fluorination In chemistry, halogenation is a chemical reaction which introduces one or more halogens into a chemical compound. Halide-containing compounds are pervasive, making this type of transformation important, e.g. in the production of polymers, drugs. ... of in liquid HF: : Physical properties Periodyl fluoride forms colorless crystals. Decomposes at 90 to 100 °C. References {{Fluorine compounds Oxyfluorides Iodine compounds ...
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Perchloryl Fluoride
Perchloryl fluoride is a reactive gas with the chemical formula . It has a characteristic sweet odor that resembles gasoline and kerosene. It is toxic and is a powerful oxidizing and fluorinating agent. It is the acid fluoride of perchloric acid. In spite of its small enthalpy of formation (Δf''H''° = ), it is kinetically stable, decomposing only at 400 °C. It is quite reactive towards reducing agents and anions, however, with the chlorine atom acting as an electrophile. It reacts explosively with reducing agents such as metal amides, metals, hydrides, etc. Its hydrolysis in water occurs very slowly, unlike that of chloryl fluoride. Synthesis and chemistry Perchloryl fluoride is produced primarily by the fluorination of perchlorates. The initial syntheses in the early 1950s used fluorine gas or fluorides and anodic oxidation as the fluorinating agents, but these give explosive gaseous mixtures. A common fluorinator in modern syntheses is antimony pentafluoride: : Alt ...
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Inorganic Compound
An inorganic compound is typically a chemical compound that lacks carbon–hydrogen bonds⁠that is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as ''inorganic chemistry''. Inorganic compounds comprise most of the Earth's crust, although the compositions of the deep Mantle (geology), mantle remain active areas of investigation. All allotropes (structurally different pure forms of an element) and some simple carbon compounds are often considered inorganic. Examples include the allotropes of carbon (graphite, diamond, buckminsterfullerene, graphene, etc.), carbon monoxide , carbon dioxide , carbides, and salt (chemistry), salts of inorganic anions such as carbonates, cyanides, cyanates, thiocyanates, isothiocyanates, etc. Many of these are normal parts of mostly organic systems, including organisms; describing a chemical as inorganic does not necessarily mean that it cannot occur within life, living things. History ...
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Bromine
Bromine is a chemical element; it has chemical symbol, symbol Br and atomic number 35. It is a volatile red-brown liquid at room temperature that evaporates readily to form a similarly coloured vapour. Its properties are intermediate between those of chlorine and iodine. Isolated independently by two chemists, Carl Jacob Löwig (in 1825) and Antoine Jérôme Balard (in 1826), its name was derived , referring to its sharp and pungent smell. Elemental bromine is very reactive and thus does not occur as a free element in nature. Instead, it can be isolated from colourless soluble crystalline mineral halide Ionic salt, salts analogous to table salt, a property it shares with the other halogens. While it is rather rare in the Earth's crust, the high solubility of the bromide ion (Br) has caused its Bromine cycle, accumulation in the oceans. Commercially the element is easily extracted from brine evaporation ponds, mostly in the United States and Israel. The mass of bromine in the oce ...
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Fluorine
Fluorine is a chemical element; it has Chemical symbol, symbol F and atomic number 9. It is the lightest halogen and exists at Standard temperature and pressure, standard conditions as pale yellow Diatomic molecule, diatomic gas. Fluorine is extremely Reactivity (chemistry), reactive as it reacts with all other Periodic table, elements except for the light Noble gas, noble gases. It is highly toxicity, toxic. Among the elements, fluorine ranks Abundance of the chemical elements, 24th in cosmic abundance and 13th in crustal abundance. Fluorite, the primary mineral source of fluorine, which gave the element its name, was first described in 1529; as it was added to metal ores to lower their melting points for smelting, the Latin verb meaning gave the mineral its name. Proposed as an element in 1810, fluorine proved difficult and dangerous to separate from its compounds, and several early experimenters died or sustained injuries from their attempts. Only in 1886 did French chemist He ...
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Oxygen
Oxygen is a chemical element; it has chemical symbol, symbol O and atomic number 8. It is a member of the chalcogen group (periodic table), group in the periodic table, a highly reactivity (chemistry), reactive nonmetal (chemistry), nonmetal, and a potent oxidizing agent that readily forms oxides with most elements as well as with other chemical compound, compounds. Oxygen is abundance of elements in Earth's crust, the most abundant element in Earth's crust, making up almost half of the Earth's crust in the form of various oxides such as water, carbon dioxide, iron oxides and silicates.Atkins, P.; Jones, L.; Laverman, L. (2016).''Chemical Principles'', 7th edition. Freeman. It is abundance of chemical elements, the third-most abundant element in the universe after hydrogen and helium. At standard temperature and pressure, two oxygen atoms will chemical bond, bind covalent bond, covalently to form dioxygen, a colorless and odorless diatomic gas with the chemical formula ...
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Journal Of The American Chemical Society
The ''Journal of the American Chemical Society'' (also known as JACS) is a weekly peer-reviewed scientific journal that was established in 1879 by the American Chemical Society. The journal has absorbed two other publications in its history, the ''Journal of Analytical and Applied Chemistry'' (July 1893) and the ''American Chemical Journal'' (January 1914). It covers all fields of chemistry. Since 2021, the editor-in-chief is Erick M. Carreira (ETH Zurich). In 2014, the journal moved to a hybrid open access publishing model. Abstracting and indexing The journal is abstracted and indexed in: According to the ''Journal Citation Reports'', the journal has a 2023 impact factor The impact factor (IF) or journal impact factor (JIF) of an academic journal is a type of journal ranking. Journals with higher impact factor values are considered more prestigious or important within their field. The Impact Factor of a journa ... of 14.4. Editors-in-chief The following people are or ...
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Antimony Pentafluoride
Antimony pentafluoride is the inorganic compound with the formula Sb F5. This colorless, viscous liquid is a strong Lewis acid and a component of the superacid fluoroantimonic acid, formed upon mixing liquid HF with liquid SbF5 in 1:1 ratio. It is notable for its strong Lewis acidity and the ability to react with almost all known compounds. Preparation Antimony pentafluoride is prepared by the reaction of antimony pentachloride with anhydrous hydrogen fluoride:Sabina C. Grund, Kunibert Hanusch, Hans J. Breunig, Hans Uwe Wolf "Antimony and Antimony Compounds" in Ullmann's Encyclopedia of Industrial Chemistry 2006, Wiley-VCH, Weinheim :SbCl5 + 5 HF → SbF5 + 5 HCl It can also be prepared from antimony trifluoride and fluorine. Structure and chemical reactions In the gas phase, SbF5 adopts a trigonal bipyramidal structure of D3h point group symmetry (see picture). The material adopts a more complicated structure in the liquid and solid states. The liquid contains polymers whe ...
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Potassium Perbromate
Potassium perbromate is the chemical compound composed of the potassium ion and the perbromate ion, with the chemical formula KBrO4. Preparation Potassium perbromate can be prepared by reacting perbromic acid with potassium hydroxide:Georg Brauer (Hrsg.), with the collaboration of Marianne Baudler Marianne Baudler (27 April 1921 – 5 March 2003) was a German chemist. She is known for her research on phosphorus. Life Marianne Baudler was born in Stettin. She started studying Chemistry at the Technische Hochschule Dresden in April 1940 and ... and others: ''Handbook of Preparative Inorganic Chemistry.'' 3rd, revised edition. Volume I, Ferdinand Enke, Stuttgart 1975, , S. 333. : References Potassium compounds Perbromates {{inorganic-compound-stub ...
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Hydrofluoric Acid
Hydrofluoric acid is a solution of hydrogen fluoride (HF) in water. Solutions of HF are colorless, acidic and highly corrosive. A common concentration is 49% (48–52%) but there are also stronger solutions (e.g. 70%) and pure HF has a boiling point near room temperature. It is used to make most organofluorine compounds; examples include the commonly used pharmaceutical antidepressant medication fluoxetine (Prozac) and the material PTFE (Teflon). Elemental fluorine is produced from it. It is commonly used to etch glass and silicon wafers. Uses Production of organofluorine compounds The principal use of hydrofluoric acid is in organofluorine chemistry. Many organofluorine compounds are prepared using HF as the fluorine source, including Teflon, fluoropolymers, fluorocarbons, and refrigerants such as freon. Many pharmaceuticals contain fluorine. Production of inorganic fluorides Most high-volume inorganic fluoride compounds are prepared from hydrofluoric acid. Foremost ...
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Walter De Gruyter
Walter de Gruyter GmbH, known as De Gruyter (), is a German scholarly publishing house specializing in academic literature. History The roots of the company go back to 1749 when Frederick the Great granted the Königliche Realschule in Berlin the royal privilege to open a bookstore and "to publish good and useful books". In 1800, the store was taken over by Georg Reimer (1776–1842), operating as the ''Reimer'sche Buchhandlung'' from 1817, while the school's press eventually became the ''Georg Reimer Verlag''. From 1816, Reimer used a representative palace at Wilhelmstraße 73 in Berlin for his family and the publishing house, whereby the wings contained his print shop and press. The building later served as the Palace of the Reich President. Born in Ruhrort in 1862, Walter de Gruyter took a position with Reimer Verlag in 1894. By 1897, at the age of 35, he had become sole proprietor of the hundred-year-old company then known for publishing the works of German romantic ...
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Perbromic Acid
Perbromic acid is the inorganic compound with the formula . Perbromic acid is characterized as a colorless liquid which has no characteristic scent. It is an oxoacid of bromine, with an oxidation state of +7. Perbromic acid is a strong acid and strongly oxidizing, though dilute perbromic acid solutions are slow oxidizing agents. It is the most unstable of the halogen(VII) oxoacids. It decomposes rapidly on standing to bromic acid and oxygen, which releases toxic brown bromine vapors. It can be used in the synthesis of perbromate salts, by reacting with a base. Perbromic acid is unstable and cannot be formed by displacement of chlorine from perchloric acid, as periodic acid is prepared; it can only be made by protonation of the perbromate ion. Perbromic acid is stable in aqueous solutions no greater than 6M. Perbromic acid solutions greater than 6M are unstable in air, where an autocatalytic decomposition of the compound will occur. Metals such as and can also catalyze the compou ...
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