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Oxygen Transmission Rate
Oxygen transmission rate (OTR) is the measurement of the amount of oxygen gas that passes through a substance over a given period. It is mostly carried out on non-porous materials, where the mode of transport is diffusion, but there are a growing number of applications where the transmission rate also depends on flow through apertures of some description. It relates to the permeation of oxygen through packaging to sensitive foods and pharmaceuticals. Measurement Standard test methods are available for measuring the oxygen transmission rate of packaging materials. Completed packages, however, involve heat seals, creases, joints, and closures which often reduce the effective barrier of the package. For example, the glass of a glass bottle may have an effective total barrier but the screw cap closure and the closure liner might not. ASTM standard test methods include: * F3136 Standard Test Method for Oxygen Gas Transmission Rate through Plastic Film and Sheeting using a Dynamic A ...
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Oxygen
Oxygen is a chemical element; it has chemical symbol, symbol O and atomic number 8. It is a member of the chalcogen group (periodic table), group in the periodic table, a highly reactivity (chemistry), reactive nonmetal (chemistry), nonmetal, and a potent oxidizing agent that readily forms oxides with most elements as well as with other chemical compound, compounds. Oxygen is abundance of elements in Earth's crust, the most abundant element in Earth's crust, making up almost half of the Earth's crust in the form of various oxides such as water, carbon dioxide, iron oxides and silicates.Atkins, P.; Jones, L.; Laverman, L. (2016).''Chemical Principles'', 7th edition. Freeman. It is abundance of chemical elements, the third-most abundant element in the universe after hydrogen and helium. At standard temperature and pressure, two oxygen atoms will chemical bond, bind covalent bond, covalently to form dioxygen, a colorless and odorless diatomic gas with the chemical formula ...
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Wine
Wine is an alcoholic drink made from Fermentation in winemaking, fermented fruit. Yeast in winemaking, Yeast consumes the sugar in the fruit and converts it to ethanol and carbon dioxide, releasing heat in the process. Wine is most often made from grapes, and the term "wine" generally refers to grape wine when used without any qualification. Even so, wine can be made fruit wine, from a variety of fruit crops, including plum, cherry, pomegranate, blueberry, Ribes, currant, and Sambucus, elderberry. Different varieties of grapes and Strain (biology), strains of yeasts are major factors in different styles of wine. These differences result from the complex interactions between the Biochemistry, biochemical development of the grape, the reactions involved in fermentation, the grape's growing environment (terroir), and the wine production process. Many countries enact legal appellations intended to define styles and qualities of wine. These typically restrict the geographical origin ...
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Oxygen Scavenger
Oxygen scavengers or oxygen absorbers are added to enclosed packaging to help remove or decrease the level of oxygen in the package. They are used to help maintain product safety and extend shelf life. There are many types of oxygen absorbers available to cover a wide array of applications. The components of an oxygen absorber vary according to intended use, the water activity of the product being preserved, and other factors. Often the oxygen absorber or scavenger is enclosed in a porous sachet or packet but it can also be part of packaging films and structures. Others are part of a polymer structure. Oxygen absorbing chemicals are also commonly added to boiler feedwater used in boiler systems, to reduce corrosion of components within the system. Mechanism The first patent for an oxygen scavenger used an alkaline solution of pyrogallic acid in an air-tight vessel. Modern scavenger sachets use a mixture of iron powder and sodium chloride. Often activated carbon is also incl ...
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Shelf Life
Shelf life is the length of time that a commodity may be stored without becoming unfit for use, consumption, or sale. In other words, it might refer to whether a commodity should no longer be on a pantry shelf (unfit for use), or no longer on a supermarket shelf (unfit for sale, but not yet unfit for use). It applies to cosmetics, foods and beverages, medical devices, medicines, explosives, pharmaceutical drugs, chemicals, tyres, batteries, and many other perishable items. In some regions, an advisory ''best before'', mandatory ''use by'' or ''freshness date'' is required on packaged perishable foods. The concept of expiration date is related but legally distinct in some jurisdictions. Background Shelf life is the recommended maximum time for which products or fresh (harvested) produce can be stored, during which the defined quality of a specified proportion of the goods remains acceptable under expected (or specified) conditions of distribution, storage and display. Accordi ...
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Permeation
In physics and engineering, permeation (also called imbuing) is the penetration of a wikt:permeate#English, permeate (a fluid such as a liquid, gas, or vapor) through a solid. It is directly related to the concentration gradient of the permeate, a material's intrinsic permeability, and the materials' mass diffusivity. Permeation is modeled by equations such as Fick's laws of diffusion, and can be measured using tools such as a minipermeameter. Description The process of permeation involves the diffusion of molecules, called the permeant, through a membrane or interface. Permeation works through diffusion; the permeant will move from high concentration to low concentration across the interface. A material can be semipermeable, with the presence of a semipermeable membrane. Only molecules or ions with certain properties will be able to diffuse across such a membrane. This is a very important mechanism in biology where fluids inside a blood vessel need to be regulated and controlle ...
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Moisture Vapor Transmission Rate
Moisture vapor transmission rate (MVTR), also water vapor transmission rate (WVTR), is a measure of the passage of water vapor through a substance. It is a measure of the permeability for vapor barriers. There are many industries where moisture control is critical. Moisture sensitive foods and pharmaceuticals are put in packaging with controlled MVTR to achieve the required quality, safety, and shelf life. In clothing, MVTR as a measure of breathability has contributed to greater comfort for wearers of clothing for outdoor activity. The building materials industry also manages the moisture barrier properties in architectural components to ensure the correct moisture levels in the internal spaces of buildings. Optoelectronic devices based on organic material, generally named OLEDs, need an encapsulation with low values of WVTR to guarantee the same performances over the lifetime of the device. MVTR generally decreases with increasing thickness of the film/barrier, and increases ...
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Bottle Variation
Bottle variation is the degree to which different bottles, nominally of the same product, can have different taste, smell, etc. There are many possible causes of bottle variation: * variation in the contents prior to packaging * variation in the packaging components * variation in the product and packaging processes * variation in storage, distribution, cold chain, etc. * variation in the quantity of contents Wine Different bottles, nominally of the same wine, can taste and smell different. One factor is found in the variable oxygen transmission rate (OTR) of cork stoppers, which translates to a degree of bottle variation. Before the advent of inexpensive stainless steel tanks, it was not customary to blend all the wine together and bottle it at once, a process called ''assemblage''. Instead, the winemaker would take his or her siphon from barrel to barrel and fill the bottles from a single barrel at a time. Some traditional and/or idiosyncratic wineries still do this, i ...
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Cork (material)
Cork is an impermeable buoyant material. It is the phellem layer of bark tissue which is harvested for commercial use primarily from '' Quercus suber'' (the cork oak), which is native to southwest Europe and northwest Africa. Cork is composed of suberin, a hydrophobic substance. Because of its impermeable, buoyant, elastic, and fire retardant properties, it is used in a variety of products, the most common of which is wine stoppers. The montado landscape of Portugal produces approximately half of the cork harvested annually worldwide, with Corticeira Amorim being the leading company in the industry. Cork was examined microscopically by Robert Hooke, which led to his discovery and naming of the cell. Cork composition varies depending on geographic origin, climate and soil conditions, genetic origin, tree dimensions, age (virgin or reproduction), and growth conditions. However, in general, cork is made up of suberin (average of about 40%), lignin (22%), polysaccharid ...
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Closure (bottle)
A closure is a device used to close or seal a container such as a bottle, Jug (container), jug, jar, Tube (container), tube, or can (other)#Container, can. A closure may be a cap, cover, Lid (container), lid, plug, liner, or the like. The part of the container to which the closure is applied is called the finish. Other types of containers such as boxes and drum (container), drums may also have closures but are not discussed in this article. Many containers and packages require a means of closing, which can be a separate device or seal or sometimes an integral latch or lock. Purpose of closures The closure is often the most critical part of a package, and must fulfill all of the food packaging#Functions, basic functions of packaging in addition to being easy to open and (if applicable) reclose. Depending on the contents and container, closures have several functions: * Keep the container closed and the contents contained for the specified shelf life until time of open ...
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ASTM
ASTM International, formerly known as American Society for Testing and Materials, is a standards organization that develops and publishes voluntary consensus technical international standards for a wide range of materials, products, systems and services. Some 12,575 apply globally. The headquarters is in West Conshohocken, Pennsylvania, about northwest of Philadelphia. It was founded in 1902 as the American Section of the International Association for Testing Materials. In addition to its traditional standards work, ASTM operates several global initiatives advancing additive manufacturing, advanced manufacturing, and emerging technologies, including the Additive Manufacturing Center of Excellence (AM CoE), the acquisition oWohlers Associatesfor market intelligence and advisory services, and the NIST-funded Standardization Center of Excellence (SCOE). History In 1898, a group of scientists and engineers, led by chemist, industry leader, and proponent of standardization Ch ...
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Diffusion
Diffusion is the net movement of anything (for example, atoms, ions, molecules, energy) generally from a region of higher concentration to a region of lower concentration. Diffusion is driven by a gradient in Gibbs free energy or chemical potential. It is possible to diffuse "uphill" from a region of lower concentration to a region of higher concentration, as in spinodal decomposition. Diffusion is a stochastic process due to the inherent randomness of the diffusing entity and can be used to model many real-life stochastic scenarios. Therefore, diffusion and the corresponding mathematical models are used in several fields beyond physics, such as statistics, probability theory, information theory, neural networks, finance, and marketing. The concept of diffusion is widely used in many fields, including physics (Molecular diffusion, particle diffusion), chemistry, biology, sociology, economics, statistics, data science, and finance (diffusion of people, ideas, data and price v ...
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Screw Cap
A screw cap or closure is a common type of closure for bottles, jars, and tubes. History Screw caps had been used in Europe since the 1500s and a British patent was filed in 1810 by Peter Durand acting on behalf of Nicolas Appert. John Landis Mason patented in 1858 a screw-on lid for a jar that became known as the Mason jar. Usage A screw closure is a mechanical device which is screwed on and off of a "finish" on a container. Either continuous threads or lugs are used. It must be engineered to be cost-effective, to provide an effective seal (and barrier), to be compatible with the contents, to be easily opened by the consumer, often to be reclosable, and to comply with product, package, and environmental laws and regulations. Manufacturers may ensure the integrity of a screw cap using a cap torque tester. Some closures need to be tamper resistant and have child-resistant packaging features. A tamper-evident band is a common tamper warning for screw caps of bottles ...
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