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Cuprates
Cuprates are a class of compounds that contain copper (Cu) atom(s) in an anion. They can be broadly categorized into two main types: 1. Inorganic cuprates: These compounds have a general formula of . Some of them are non-stoichiometric. Many of these compounds are known for their superconducting properties. An example of an inorganic cuprate is the tetrachloridocuprate(II) or tetrachlorocuprate(II) (), an anionic coordination complex that features a copper atom in an oxidation state of +2, surrounded by four chloride ions. 2. Organic cuprates: These are organocopper compounds, some of which having a general formula of , where copper is in an oxidation state of +1, where at least one of the R groups can be any organic group. These compounds, characterized by copper bonded to organic groups, are frequently used in organic synthesis due to their reactivity. An example of an organic cuprate is dimethylcuprate(I) anion . One of the most studied cuprates is , a high-temperature ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
High-temperature Superconductivity
High-temperature superconductivity (high-c or HTS) is superconductivity in materials with a critical temperature (the temperature below which the material behaves as a superconductor) above , the boiling point of liquid nitrogen. They are "high-temperature" only relative to previously known superconductors, which function only closer to absolute zero. The first high-temperature superconductor was discovered in 1986 by IBM researchers Georg Bednorz and K. Alex Müller. Although the critical temperature is around , this material was modified by Ching-Wu Chu to make the first high-temperature superconductor with critical temperature . Bednorz and Müller were awarded the Nobel Prize in Physics in 1987 "for their important break-through in the discovery of superconductivity in ceramic materials". Most high-c materials are type-II superconductors. The major advantage of high-temperature superconductors is that they can be cooled using liquid nitrogen, in contrast to previously known s ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Organocopper
Organocopper chemistry is the study of the physical properties, reactions, and synthesis of organocopper compounds, which are organometallic compounds containing a carbon to copper chemical bond. They are reagents in organic chemistry. The first organocopper compound, the explosive copper(I) acetylide (), was synthesized by Rudolf Christian Böttger in 1859 by passing acetylene gas through a solution of copper(I) chloride: : Structure and bonding Organocopper compounds are diverse in structure and reactivity, but almost all are based on copper with an oxidation state of +1, sometimes denoted Cu(I) or . With 10 electrons in its valence shell, the bonding behavior of Cu(I) is similar to Ni(0), but owing to its higher oxidation state, it engages in less Pi backbonding, pi-backbonding. Organic derivatives of copper's higher oxidation states of +2 and +3 are sometimes encountered as reaction intermediates, but rarely isolated or even observed. Organocopper compounds form comp ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Non-stoichiometric
Non-stoichiometric compounds are chemical compounds, almost always solid inorganic compounds, having chemical element, elemental composition whose proportions cannot be represented by a ratio of small natural numbers (i.e. an empirical formula); most often, in such materials, some small percentage of atoms are missing or too many atoms are packed into an otherwise perfect Crystal structure, lattice work. Contrary to earlier definitions, modern understanding of non-stoichiometric compounds view them as homogeneous, and not mixtures of stoichiometric chemical compounds. Since the solids are overall electrically neutral, the defect is compensated by a change in the charge of other atoms in the solid, either by changing their oxidation state, or by replacing them with atoms of different elements with a different charge. Many metal oxides and sulfides have non-stoichiometric examples; for example, stoichiometric iron(II) oxide, which is rare, has the formula , whereas the more common ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Superconductivity
Superconductivity is a set of physical properties observed in superconductors: materials where Electrical resistance and conductance, electrical resistance vanishes and Magnetic field, magnetic fields are expelled from the material. Unlike an ordinary metallic Electrical conductor, conductor, whose resistance decreases gradually as its temperature is lowered, even down to near absolute zero, a superconductor has a characteristic Phase transition, critical temperature below which the resistance drops abruptly to zero. An electric current through a loop of superconducting wire can persist indefinitely with no power source. The superconductivity phenomenon was discovered in 1911 by Dutch physicist Heike Kamerlingh Onnes. Like ferromagnetism and Atomic spectral line, atomic spectral lines, superconductivity is a phenomenon which can only be explained by quantum mechanics. It is characterized by the Meissner effect, the complete cancellation of the magnetic field in the interior of the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Copper
Copper is a chemical element; it has symbol Cu (from Latin ) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkish-orange color. Copper is used as a conductor of heat and electricity, as a building material, and as a constituent of various metal alloys, such as sterling silver used in jewelry, cupronickel used to make marine hardware and coins, and constantan used in strain gauges and thermocouples for temperature measurement. Copper is one of the few metals that can occur in nature in a directly usable, unalloyed metallic form. This means that copper is a native metal. This led to very early human use in several regions, from . Thousands of years later, it was the first metal to be smelted from sulfide ores, ; the first metal to be cast into a shape in a mold, ; and the first metal to be purposely alloyed with another metal, tin, to create bronze, ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Rubidium
Rubidium is a chemical element; it has Symbol (chemistry), symbol Rb and atomic number 37. It is a very soft, whitish-grey solid in the alkali metal group, similar to potassium and caesium. Rubidium is the first alkali metal in the group to have a density higher than Properties of water, water. On Earth, natural rubidium comprises two isotopes: 72% is a stable isotope Rb, and 28% is slightly radioactive Rb, with a half-life of 48.8 billion years – more than three times as long as the estimated age of the universe. German chemists Robert Bunsen and Gustav Kirchhoff discovered rubidium in 1861 by the newly developed technique, Atomic emission spectroscopy#Flame emission spectroscopy, flame spectroscopy. The name comes from the Latin word , meaning deep red, the color of its emission spectrum. Rubidium's compounds have various chemical and electronic applications. Rubidium metal is easily vaporized and has a convenient spectral absorption range, making it a frequent target for ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Caesium
Caesium (IUPAC spelling; also spelled cesium in American English) is a chemical element; it has Symbol (chemistry), symbol Cs and atomic number 55. It is a soft, silvery-golden alkali metal with a melting point of , which makes it one of only five elemental metals that are liquid at or near room temperature. Caesium has physical and chemical properties similar to those of rubidium and potassium. It is pyrophoricity, pyrophoric and reacts with water even at . It is the least electronegativity, electronegative stable element, with a value of 0.79 on the Pauling scale. It has only one stable isotope, caesium-133. Caesium is mined mostly from pollucite. Caesium-137, a fission product, is extracted from waste produced by nuclear reactor technology, nuclear reactors. It has the largest atomic radius of all elements whose radii have been measured or calculated, at about 260 picometres. The German chemist Robert Bunsen and physicist Gustav Kirchhoff discovered caesium in 1860 by the new ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Potassium Superoxide
Potassium superoxide is an inorganic compound with the formula . It is a yellow paramagnetic solid that decomposes in moist air. It is a rare example of a stable salt of the superoxide anion. It is used as a scrubber, dehumidifier, and generator in rebreathers, spacecraft, submarines, and spacesuits. Production and reactions Potassium superoxide is produced by burning molten potassium in an atmosphere of excess oxygen. : The salt consists of and ions, linked by ionic bonding. The O–O distance is 1.28 Å. Reactivity Potassium superoxide is a source of superoxide, which is an oxidant and a nucleophile, depending on its reaction partner. Upon contact with water, it undergoes disproportionation to potassium hydroxide, oxygen, and hydrogen peroxide: : : It reacts with carbon dioxide, releasing oxygen: : : Theoretically, 1 kg of absorbs 0.310 kg of while releasing 0.338 kg of . One mole of absorbs 0.5 moles of and releases 0.75 moles of oxygen. Potass ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Rubidium Oxide
Rubidium oxide is the chemical compound with the formula . Rubidium oxide is highly reactive towards water, and therefore it would not be expected to occur naturally. The rubidium content in minerals is often calculated and quoted in terms of . In reality, the rubidium is typically present as a component of (actually, an impurity in) silicate or aluminosilicate. A major source of rubidium is lepidolite, , wherein Rb sometimes replaces K. is a yellow colored solid. The related species , and are colorless, pale-yellow, and orange, respectively. The alkali metal oxides crystallise in the antifluorite structure. In the antifluorite motif, the positions of the anions and cations are reversed relative to their positions in CaF2, with rubidium ions 4-coordinate (tetrahedral) and oxide ions 8-coordinate (cubic). Properties Like other alkali metal oxides, Rb2O is a strong base. Thus, Rb2O reacts exothermically with water to form rubidium hydroxide. :Rb2O + H2O → 2 ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Crystallographic Defect
A crystallographic defect is an interruption of the regular patterns of arrangement of atoms or molecules in Crystal, crystalline solids. The positions and orientations of particles, which are repeating at fixed distances determined by the Crystal structure#unit cell, unit cell parameters in crystals, exhibit a periodic crystal structure, but this is usually imperfect.Ehrhart, P. (1991Properties and interactions of atomic defects in metals and alloys, volume 25 of Landolt-Börnstein, New Series III, chapter 2, p. 88, Springer, Berlin Several types of defects are often characterized: point defects, line defects, planar defects, bulk defects. Topological homotopy establishes a mathematical method of characterization. Point defects Point defects are defects that occur only at or around a single lattice point. They are not extended in space in any dimension. Strict limits for how small a point defect is are generally not defined explicitly. However, these defects typically involve at ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Caesium Oxide
Caesium oxide (IUPAC name), or cesium oxide, describes inorganic compounds composed of caesium and oxygen. Several binary (containing only Cs and O) oxides of caesium are known.. Caesium oxide may refer to: * Caesium suboxides () * Caesium monoxide (, the most common oxide) * Caesium peroxide () * Caesium sesquioxide () * Caesium superoxide () * Caesium ozonide Caesium ozonide is an oxygen-rich chemical compound of caesium, with the chemical formula . It consists of caesium cations and ozonide anions . It can be formed by reacting ozone with caesium superoxide: : The compound reacts strongly with any ... () References {{Authority control Caesium compounds ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Alkali Metals
The alkali metals consist of the chemical elements lithium (Li), sodium (Na), potassium (K),The symbols Na and K for sodium and potassium are derived from their Latin names, ''natrium'' and ''kalium''; these are still the origins of the names for the elements in some languages, such as German and Russian. rubidium (Rb), caesium (Cs), and francium (Fr). Together with hydrogen they constitute Group (periodic table)#Group names, group 1, which lies in the s-block of the periodic table. All alkali metals have their outermost electron in an s-orbital: this shared electron configuration results in their having very similar characteristic properties. Indeed, the alkali metals provide the best example of periodic trends, group trends in properties in the periodic table, with elements exhibiting well-characterised Homologous series, homologous behaviour. This family of elements is also known as the lithium family after its leading element. The alkali metals are all shiny, hardness, sof ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
