Ultrapotassic igneous rocks are a class of rare, volumetrically minor, generally

ultramafic Ultramafic rocks (also referred to as ultrabasic rocks, although the terms are not wholly equivalent) are igneous and meta-igneous rocks with a very low silica content (less than 45%), generally >18% MgO, high FeO, low potassium, and are usua ...

or mafic silica-depleted

igneous rocks Igneous rock ( ), or magmatic rock, is one of the three main Rock (geology)#Classification, rock types, the others being sedimentary rock, sedimentary and metamorphic rock, metamorphic. Igneous rocks are formed through the cooling and solidifi ...

. While there are debates on the exact classifications of ultrapotassic rocks, they are defined by using the chemical screens K₂O/Na₂O > 3 in much of the scientific literature. However caution is indicated in interpreting the use of the term "ultrapotassic", and the nomenclature of these rocks continues to be debated, with some classifications using K₂O/Na₂O > 2 to indicate a rock is ultrapotassic.

Conditions of formation

The

magma Magma () is the molten or semi-molten natural material from which all igneous rocks are formed. Magma (sometimes colloquially but incorrectly referred to as ''lava'') is found beneath the surface of the Earth, and evidence of magmatism has also ...

s that produce ultrapotassic rocks are produced by a variety of mechanisms and from a variety of sources, but generally occur in a heterogenous, anomalous, phlogopite-bearing

upper mantle The upper mantle of Earth is a very thick layer of rock inside the planet, which begins just beneath the crust (geology), crust (at about under the oceans and about under the continents) and ends at the top of the lower mantle (Earth), lower man ...

. The following conditions are favorable for the formation of ultrapotassic magmas. * partial melting at a great depth * low degrees of partial melting * lithophile element ( K, Ba, Cs, Rb) enrichment in sources * enriched

peridotite Peridotite ( ) is a dense, coarse-grained igneous rock consisting mostly of the silicate minerals olivine and pyroxene. Peridotite is ultramafic, as the rock contains less than 45% silica. It is high in magnesium (Mg2+), reflecting the high pr ...

(variety harzburgite), especially in potassium *

pyroxene The pyroxenes (commonly abbreviated Px) are a group of important rock-forming inosilicate minerals found in many igneous and metamorphic rocks. Pyroxenes have the general formula , where X represents ions of calcium (Ca), sodium (Na), iron ( ...

and phlogopite-rich volumes within the mantle, not from peridotite alone *

carbon dioxide Carbon dioxide is a chemical compound with the chemical formula . It is made up of molecules that each have one carbon atom covalent bond, covalently double bonded to two oxygen atoms. It is found in a gas state at room temperature and at norma ...

or water (each condition leading to a distinctive magma); * reaction of melts with surrounding rock as they rise from their sources Mantle sources of ultrapotassic magmas may contain subducted sediments, or the sources may have been enriched in potassium by melts or fluids partly derived from subducted sediments. Phlogopite and/or potassic

amphibole Amphibole ( ) is a group of inosilicate minerals, forming prism or needlelike crystals, composed of double chain tetrahedra, linked at the vertices and generally containing ions of iron and/or magnesium in their structures. Its IMA symbol is ...

are typical in the sources from which many such magmas have been derived. Ultrapotassic

granite Granite ( ) is a coarse-grained (phanerite, phaneritic) intrusive rock, intrusive igneous rock composed mostly of quartz, alkali feldspar, and plagioclase. It forms from magma with a high content of silica and alkali metal oxides that slowly coo ...

s are uncommon and may be produced by melting of the continental crust above upwelling mafic magma, such as at

rift In geology, a rift is a linear zone where the lithosphere is being pulled apart and is an example of extensional tectonics. Typical rift features are a central linear downfaulted depression, called a graben, or more commonly a half-graben ...

zones.

Types of ultrapotassic rocks

* Lamprophyres and melilitic rocks *

Kimberlite Kimberlite is an igneous rock and a rare variant of peridotite. It is most commonly known as the main host matrix for diamonds. It is named after the town of Kimberley, Northern Cape, Kimberley in South Africa, where the discovery of an 83.5-Car ...

Lamproite Lamproite is an ultrapotassic mantle-derived volcanic or subvolcanic rock. It has low CaO, Al2O3, Na2O, high K2O/Al2O3, a relatively high MgO content and extreme enrichment in incompatible elements. Lamproites are geographically widespre ...

* Orangeite (see Group II

kimberlite Kimberlite is an igneous rock and a rare variant of peridotite. It is most commonly known as the main host matrix for diamonds. It is named after the town of Kimberley, Northern Cape, Kimberley in South Africa, where the discovery of an 83.5-Car ...

) *

Feldspathoid The feldspathoids are a group of tectosilicate minerals which resemble feldspar Feldspar ( ; sometimes spelled felspar) is a group of rock-forming aluminium tectosilicate minerals, also containing other cations such as sodium, calcium, pota ...

-bearing rocks such as leucitites * K-feldspar enriched leucogranites * Vaugnerite and Durbachite

Economic importance

The economic importance of ultrapotassic rocks is wide and varied. Because

lamproite Lamproite is an ultrapotassic mantle-derived volcanic or subvolcanic rock. It has low CaO, Al2O3, Na2O, high K2O/Al2O3, a relatively high MgO content and extreme enrichment in incompatible elements. Lamproites are geographically widespre ...

s and lamprophyres are all produced at depths of 120 km or greater, they are known to be a major source of

diamond Diamond is a Allotropes of carbon, solid form of the element carbon with its atoms arranged in a crystal structure called diamond cubic. Diamond is tasteless, odourless, strong, brittle solid, colourless in pure form, a poor conductor of e ...

deposits and thus can bring diamonds to the surface as xenocrysts. Additionally, ultrapotassic granites are a known host for granite-hosted

gold Gold is a chemical element; it has chemical symbol Au (from Latin ) and atomic number 79. In its pure form, it is a brightness, bright, slightly orange-yellow, dense, soft, malleable, and ductile metal. Chemically, gold is a transition metal ...

mineralization and well as significant porphyry-style mineralization. Ultrapotassic A-type intracontinental granites may also be associated with fluorite and columbite – tantalite mineralization.

References

Ultrapotassic rocks Igneous petrology Geochemistry {{igneous-petrology-stub