Trifluorides are compounds in which one atom or ion has three fluorine atoms or ions associated. Many metals form trifluorides, such as iron, the
rare-earth element
The rare-earth elements (REE), also called the rare-earth metals or rare earths, and sometimes the lanthanides or lanthanoids (although scandium and yttrium, which do not belong to this series, are usually included as rare earths), are a set o ...
s, and the metals in the groups
3,
13 and
15 of the periodic table. Most metal trifluorides are poorly soluble in water except
ferric fluoride and
indium(III) fluoride, but several are soluble in other solvents.
List of trifluorides
*
Actinium trifluoride, AcF
3
*
Aluminium trifluoride
Aluminium fluoride is an inorganic compound with the formula . It forms hydrates . Anhydrous and its hydrates are all colorless solids. Anhydrous is used in the production of aluminium. Several occur as minerals.
Occurrence and production
Aside ...
, AlF
3
*
Americium trifluoride, AmF
3
*
Antimony trifluoride, SbF
3, sometimes called Swart's reagent
*
Arsenic trifluoride, AsF
3
*
Berkelium trifluoride, BkF
3
*
Bismuth trifluoride, BiF
3
*
Boron trifluoride
Boron trifluoride is the inorganic compound with the formula . This pungent, colourless, and toxic gas forms white fumes in moist air. It is a useful Lewis acid and a versatile building block for other boron compounds.
Structure and bonding
The g ...
, BF
3, a pungent colourless toxic gas
*
Bromotrifluoromethane
Bromotrifluoromethane, commonly referred to by the code numbers Halon 1301, R13B1, Halon 13B1 or BTM, is an organic halide with the chemical formula carbon, Cbromine, Brfluorine, F3. It is used for gaseous fire suppression as a far less toxic alte ...
, CBrF
3, (carbon monobromide trifluoride)
*
Bromine trifluoride, BrF
3
*
Californium trifluoride, CaF
3
*
Carbon trifluoride, C
2F
6, Hexafluoroethane
*
Cerium trifluoride
Cerium(III) fluoride (or cerium trifluoride), CeF3, is an ionic compound of the rare earth metal cerium and fluorine.
It appears as a mineral in the form of Fluocerite, fluocerite-(Ce) - a very rare mineral species related mainly to pegmatites an ...
, CeF
3
*
Chlorine trifluoride, ClF
3
*
Chromium trifluoride, CrF
3
*
Cobalt trifluoride, CoF
3
*
Curium trifluoride, CmF
3
*
Diethylaminosulfur trifluoride (DAST) is the organosulfur compound with the formula Et
2NSF
3
*
Dysprosium trifluoride, DyF
3
*
Einsteinium trifluoride, EsF
3
*
Europium trifluoride, EuF
3
*
Erbium trifluoride, ErF
3
*
Fluoroform
Fluoroform, or trifluoromethane, is the chemical compound with the formula . It is a hydrofluorocarbon as well as being a part of the haloforms, a class of compounds with the formula (X = halogen) with C3v symmetry. Fluoroform is used in divers ...
(trifluoromethane), CHF
3
*
Gadolinium trifluoride, GdF
3
*
Gallium trifluoride, GaF
3
*
Gold trifluoride, AuF
3
*
Holmium trifluoride, HoF
3
*
Indium trifluoride, InF
3
*
Iodine trifluoride, IF
3, a yellow solid which decomposes above −28 °C
*
Iridium trifluoride, IrF
3
*
Iron trifluoride, FeF
3
*
Lanthanum trifluoride
Lanthanum trifluoride is a refractory ionic compound of lanthanum and fluorine. The chemical formula is .
The LaF3 structure
Bonding is ionic with lanthanum highly coordinated. The cation sits at the center of a trigonal prism. Nine fluorine ...
, LaF
3
*
Lutetium trifluoride, LuF
3
*
Manganese trifluoride, MnF
3
*
Neodymium trifluoride, NdF
3
*
Neptunium trifluoride, NpF
3
*
Nitrogen trifluoride
Nitrogen trifluoride is the inorganic compound with the formula (). It is a colorless, non-flammable, toxic gas with a slightly musty odor. In contrast with ammonia, it is nonbasic. It finds increasing use within the manufacturing of flat-panel ...
, NF
3, a colorless, toxic, odourless, nonflammable gas
*
Palladium(II,IV) fluoride, Pd
6">F6 empirical formula PdF
3
*
Phosphorus trifluoride
Phosphorus trifluoride (formula P F3), is a colorless and odorless gas. It is highly toxic and reacts slowly with water. Its main use is as a ligand in metal complexes. As a ligand, it parallels carbon monoxide in metal carbonyls, and indee ...
, PF
3, a colorless and odorless gas
*
Plutonium trifluoride, PuF
3
*
Praseodymium trifluoride, PrF
3
*
Promethium trifluoride, PmF
3
*
Rhodium trifluoride, RhF
3
*
Samarium trifluoride, SmF
3
*
Scandium trifluoride
Scandium(III) fluoride, ScF3, is an ionic compound. This salt is slightly soluble in water but dissolves in the presence of excess fluoride to form the ScF63− anion.
Production
ScF3 can be produced by reacting scandium and fluorine.S.A.Cotton, ...
, ScF
3
*
Silver trifluoride, AgF
3, an unstable, bright-red, diamagnetic compound
*
Sulfur trifluoride, SF
3, has radical, unstable
*
Terbium trifluoride, TbF
3
*
Thallium trifluoride, TlF
3
*
Thiazyl trifluoride
Thiazyl trifluoride is a chemical compound of nitrogen, sulfur, and fluorine, having the formula . It exists as a stable, colourless gas, and is an important precursor to other sulfur-nitrogen-fluorine compounds. It has tetrahedral molecular geome ...
, NSF
3, a stable, colourless gas, and important precursor to other sulfur-nitrogen-fluorine compounds
*
Thiophosphoryl trifluoride, PSF
3, colourless gas spontaneously burning with a very cool flame
*
Thulium trifluoride, TmF
3
*
Titanium trifluoride, TiF
3
*
Uranium trifluoride, UF
3
*
Vanadium trifluoride, VF
3
*
Vanadium(V) oxytrifluoride
Vanadium(V) oxytrifluoride is a chemical compound with the chemical formula, formula Vanadium, VOxygen, OFluorine, F3. It is one of several vanadium(V) oxyhalides. VOF3 is a yellowish orange powder that is sensitive to moisture. Characteristic o ...
, VOF
3
*
Ytterbium trifluoride, YbF
3
*
Yttrium trifluoride, YF
3
References
{{Chemistry index
Fluorides