Many
gases have
toxic properties, which are often assessed using the
LC50 (median lethal concentration) measure. In the United States, many of these gases have been assigned an
NFPA 704 health rating of 4 (may be fatal) or 3 (may cause serious or permanent injury), and/or
exposure limits (
TLV,
TWA/PEL,
STEL, or
REL) determined by the
ACGIH professional association. Some, but by no means all, toxic gases are detectable by
odor
An odor (American English) or odour ( Commonwealth English; see spelling differences) is a smell or a scent caused by one or more volatilized chemical compounds generally found in low concentrations that humans and many animals can perceive ...
, which can serve as a warning. Among the best known toxic gases are
carbon monoxide
Carbon monoxide (chemical formula CO) is a poisonous, flammable gas that is colorless, odorless, tasteless, and slightly less dense than air. Carbon monoxide consists of one carbon atom and one oxygen atom connected by a triple bond. It is the si ...
,
chlorine
Chlorine is a chemical element; it has Symbol (chemistry), symbol Cl and atomic number 17. The second-lightest of the halogens, it appears between fluorine and bromine in the periodic table and its properties are mostly intermediate between ...
,
nitrogen dioxide and
phosgene.
Definitions
*Toxic: a chemical that has a median lethal concentration (LC
50) in air of more than 200
parts per million (ppm) but not more than 2,000 parts per million by volume of gas or vapor, or more than 2 milligrams per liter but not more than 20 milligrams per liter of mist, fume or dust, when administered by continuous inhalation for 1 hour (or less if death occurs within 1 hour) to albino rats weighing between 200 and 300 grams each.
*Highly Toxic: a gas that has a LC
50 in air of 200 ppm or less.
*
NFPA 704: Materials that, under emergency conditions, can cause serious or permanent injury are given a Health Hazard rating of 3. Their acute inhalation toxicity corresponds to those vapors or gases having LC
50 values greater than 1,000 ppm but less than or equal to 3,000 ppm. Materials that, under emergency conditions, can be lethal are given a Health Hazard rating of 4. Their acute inhalation toxicity corresponds to those vapors or gases having LC
50 values less than or equal to 1,000 ppm.
List
See also
*
List of Schedule 1 substances (CWC)
*
EPA list of extremely hazardous substances
*
Chemical warfare
*
Chemical weapon
*
List of chemical warfare agents
*
List of psychoactive drugs used by militaries
*
Psychochemical warfare
*
List of gases
*
Toxicity class
*
Toxicity label
Notes
References
{{reflist
External links
OSHA Limits for Air ContaminantsOSHA Permissible Exposure Limits
Chemical safety
Highly toxic gases
G
G