The spherical model is a model of
ferromagnetism
Ferromagnetism is a property of certain materials (such as iron) which results in a large observed magnetic permeability, and in many cases a large magnetic coercivity allowing the material to form a permanent magnet. Ferromagnetic materials a ...
similar to the
Ising model
The Ising model () (or Lenz-Ising model or Ising-Lenz model), named after the physicists Ernst Ising and Wilhelm Lenz, is a mathematical model of ferromagnetism in statistical mechanics. The model consists of discrete variables that represent ...
, which was solved in 1952 by
T. H. Berlin and
M. Kac. It has the remarkable property that for linear dimension ''d'' greater than four, the
critical exponents that govern the behaviour of the system near the critical point are independent of ''d'' and the geometry of the system. It is one of the few models of ferromagnetism that can be solved exactly in the presence of an external field.
Formulation
The model describes a set of particles on a lattice
containing ''N'' sites. Each site ''j'' of
contains a spin
which interacts only with its nearest neighbours and an external field ''H''. It differs from the Ising model in that the
are no longer restricted to
, but can take all real values, subject to the constraint that
:
which in a homogeneous system ensures that the average of the square of any spin is one, as in the usual Ising model.
The
partition function generalizes from that of the
Ising model
The Ising model () (or Lenz-Ising model or Ising-Lenz model), named after the physicists Ernst Ising and Wilhelm Lenz, is a mathematical model of ferromagnetism in statistical mechanics. The model consists of discrete variables that represent ...
to
:
where
is the
Dirac delta function,
are the edges of the lattice, and
and
, where ''T'' is the temperature of the system, ''k'' is the
Boltzmann constant
The Boltzmann constant ( or ) is the proportionality factor that relates the average relative kinetic energy of particles in a gas with the thermodynamic temperature of the gas. It occurs in the definitions of the kelvin and the gas consta ...
and ''J'' the coupling constant of the nearest-neighbour interactions.
Berlin and Kac saw this as an approximation to the usual Ising model, arguing that the
-summation in the Ising model can be viewed as a sum over all corners of an ''N''-dimensional
hypercube
In geometry, a hypercube is an ''n''-dimensional analogue of a square () and a cube (). It is a closed, compact, convex figure whose 1-skeleton consists of groups of opposite parallel line segments aligned in each of the space's dimensions ...
in
-space. The becomes an
integration
Integration may refer to:
Biology
* Multisensory integration
* Path integration
* Pre-integration complex, viral genetic material used to insert a viral genome into a host genome
*DNA integration, by means of site-specific recombinase technolo ...
over the
surface of a hypersphere passing through all such corners.
It was rigorously proved by Kac and C. J. Thompson
[ M. Kac and C. J. Thompson, ''Spherical model and the infinite spin dimensionality limit'', Physica Norvegica, 5(3-4):163-168, 1971.] that the spherical model is a limiting case of the
N-vector model.
Equation of state
Solving the partition function and using a calculation of the
free energy yields an equation describing the
magnetization
In classical electromagnetism, magnetization is the vector field that expresses the density of permanent or induced magnetic dipole moments in a magnetic material. Movement within this field is described by direction and is either Axial or Di ...
''M'' of the system
:
for the function ''g'' defined as
:
The
internal energy
The internal energy of a thermodynamic system is the total energy contained within it. It is the energy necessary to create or prepare the system in its given internal state, and includes the contributions of potential energy and internal kinet ...
per site is given by
:
an exact relation relating internal energy and magnetization.
Critical behaviour
For
the
critical temperature occurs at
absolute zero
Absolute zero is the lowest limit of the thermodynamic temperature scale, a state at which the enthalpy and entropy of a cooled ideal gas reach their minimum value, taken as zero kelvin. The fundamental particles of nature have minimum vibrati ...
, resulting in no phase transition for the spherical model. For ''d'' greater than 2, the spherical model exhibits the typical ferromagnetic behaviour, with a finite
Curie temperature
In physics and materials science, the Curie temperature (''T''C), or Curie point, is the temperature above which certain materials lose their permanent magnetic properties, which can (in most cases) be replaced by induced magnetism. The Cu ...
where ferromagnetism ceases. The critical behaviour of the spherical model was derived in the completely general circumstances that the dimension ''d'' may be a real non-integer dimension.
The critical exponents
and
in the zero-field case which dictate the behaviour of the system close to were derived to be
:
:
:
:
which are independent of the dimension of ''d'' when it is greater than four, the dimension being able to take any real value.
References
*
R. J. Baxter, ''Exactly solved models in statistical mechanics'', London, Academic Press, 1982
2007 Dover reprint, with a new chapter "Subsequent Developments"
Further reading
* {{cite journal , last1=Berlin , first1=T. H. , last2=Kac , first2=M. , title=The spherical model of a ferromagnet , url=http://link.aps.org/abstract/PR/v86/p821 , doi=10.1103/PhysRev.86.821 , mr=0049829 , year=1952 , journal=Physical Review , series=Series 2 , volume=86 , issue=6 , pages=821–835 , bibcode = 1952PhRv...86..821B
Lattice models
Exactly solvable models