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Sodium germanate is an
inorganic compound In chemistry, an inorganic compound is typically a chemical compound that lacks carbon–hydrogen bonds, that is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as '' inorganic chemi ...
with the formula Na2GeO3. It is a colorless solid. Sodium germanate is primarily used for the synthesis of other germanium compounds.


Preparation and reactions

Sodium germanate can be prepared by the fusion of germanium oxide with
sodium hydroxide Sodium hydroxide, also known as lye and caustic soda, is an inorganic compound with the formula NaOH. It is a white solid ionic compound consisting of sodium cations and hydroxide anions . Sodium hydroxide is a highly caustic base and alkal ...
at high temperatures: :2NaOH + GeO2 → Na2GeO3 + H2O An intermediate in this reaction is the protonated derivative NaHGeO3, which is a water-soluble salt.


Structure

it is structurally analogous to
sodium metasilicate Sodium metasilicate is the chemical substance with formula , which is the main component of commercial sodium silicate solutions. It is an ionic compound consisting of sodium cations and the polymeric metasilicate anions ��–sub>''n''. It is ...
, Na2SiO3, consisting of polymeric GeO32− anions made up of vertex sharing tetrahedra.C. C. Addison, Inorganic Chemistry of the Main-Group Elements, vol 1, 1973, The chemical Society,


See also

* Germanate


References

Germanates Sodium compounds {{inorganic-compound-stub