Shale Groups
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Shale is a fine-grained,
clastic Clastic rocks are composed of fragments, or clasts, of pre-existing minerals and rock. A clast is a fragment of geological detritus,Essentials of Geology, 3rd Ed, Stephen Marshak, p. G-3 chunks, and smaller grains of rock broken off other rocks by ...
sedimentary rock Sedimentary rocks are types of rock (geology), rock formed by the cementation (geology), cementation of sediments—i.e. particles made of minerals (geological detritus) or organic matter (biological detritus)—that have been accumulated or de ...
formed from
mud Mud (, or Middle Dutch) is loam, silt or clay mixed with water. Mud is usually formed after rainfall or near water sources. Ancient mud deposits hardened over geological time to form sedimentary rock such as shale or mudstone (generally cal ...
that is a mix of flakes of
clay minerals Clay minerals are hydrous aluminium phyllosilicates (e.g. kaolin, Al2 Si2 O5( OH)4), sometimes with variable amounts of iron, magnesium, alkali metals, alkaline earths, and other cations found on or near some planetary surfaces. Clay mineral ...
(hydrous aluminium phyllosilicates, e.g.,
kaolin Kaolinite ( ; also called kaolin) is a clay mineral, with the chemical composition Al2 Si2 O5( OH)4. It is a layered silicate mineral, with one tetrahedral sheet of silica () linked through oxygen atoms to one octahedral sheet of alumina (). ...
, Al2 Si2 O5( OH)4) and tiny fragments (
silt Silt is granular material of a size between sand and clay and composed mostly of broken grains of quartz. Silt may occur as a soil (often mixed with sand or clay) or as sediment mixed in suspension (chemistry), suspension with water. Silt usually ...
-sized particles) of other minerals, especially
quartz Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The Atom, atoms are linked in a continuous framework of SiO4 silicon–oxygen Tetrahedral molecular geometry, tetrahedra, with each oxygen being shared between two tet ...
and
calcite Calcite is a Carbonate minerals, carbonate mineral and the most stable Polymorphism (materials science), polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on ...
.Blatt, Harvey and Robert J. Tracy (1996) ''Petrology: Igneous, Sedimentary and Metamorphic'', 2nd ed., Freeman, pp. 281–292 Shale is characterized by its tendency to split into thin layers ( laminae) less than one centimeter in thickness. This property is called '' fissility''. Shale is the most common sedimentary rock. The term ''shale'' is sometimes applied more broadly, as essentially a synonym for
mudrock Mudrocks are a class of fine-grained siliciclastic sedimentary rocks. The varying types of mudrocks include siltstone, claystone, mudstone and shale. Most of the particles of which the stone is composed are less than and are too small to ...
, rather than in the narrower sense of clay-rich fissile mudrock.


Texture

Shale typically exhibits varying degrees of fissility. Because of the parallel orientation of clay mineral flakes in shale, it breaks into thin layers, often splintery and usually parallel to the otherwise indistinguishable
bedding planes In geology, a bed is a layer of sediment, sedimentary rock, or volcanic rock "bounded above and below by more or less well-defined bedding surfaces".Neuendorf, K.K.E., J.P. Mehl, Jr., and J.A. Jackson, eds., 2005. ''Glossary of Geology'' (5th ed ...
.Blatt, Harvey and Robert J. Tracy (1996) ''Petrology: Igneous, Sedimentary and Metamorphic'', 2nd ed., Freeman, pp. 281–292 Non-fissile
rocks In geology, rock (or stone) is any naturally occurring solid mass or aggregate of minerals or mineraloid matter. It is categorized by the minerals included, its chemical composition, and the way in which it is formed. Rocks form the Earth's ...
of similar composition and particle size (less than 0.0625 mm) are described as
mudstone Mudstone, a type of mudrock, is a fine-grained sedimentary rock whose original constituents were clays or muds. Mudstone is distinguished from ''shale'' by its lack of fissility.Blatt, H., and R.J. Tracy, 1996, ''Petrology.'' New York, New York, ...
s (1/3 to 2/3 silt particles) or
claystones Mudrocks are a class of fine-grained Sedimentary rock#Clastic sedimentary rocks, siliciclastic sedimentary rocks. The varying types of mudrocks include siltstone, claystone, mudstone and shale. Most of the particles of which the stone is compo ...
(less than 1/3 silt). Rocks with similar particle sizes but with less clay (greater than 2/3 silt) and therefore grittier are
siltstone Siltstone, also known as aleurolite, is a clastic sedimentary rock that is composed mostly of silt. It is a form of mudrock with a low clay mineral content, which can be distinguished from shale by its lack of fissility. Although its permeabil ...
s.


Composition and color

Shales are typically gray in color and are composed of clay minerals and quartz grains. The addition of variable amounts of minor constituents alters the color of the rock. Red, brown and green colors are indicative of
ferric oxide Iron(III) oxide or ferric oxide is the inorganic compound with the formula . It occurs in nature as the mineral hematite, which serves as the primary source of iron for the steel industry. It is also known as red iron oxide, especially when us ...
(
hematite Hematite (), also spelled as haematite, is a common iron oxide compound with the formula, Fe2O3 and is widely found in rocks and soils. Hematite crystals belong to the rhombohedral lattice system which is designated the alpha polymorph of . ...
– reds),
iron hydroxide An iron oxide is a chemical compound composed of iron and oxygen. Several iron oxides are recognized. Often they are non-stoichiometric. Ferric oxyhydroxides are a related class of compounds, perhaps the best known of which is rust. Iron oxide ...
(
goethite Goethite (, ) is a mineral of the diaspore group, consisting of iron(III) oxide-hydroxide, specifically the α- polymorph. It is found in soil and other low-temperature environments such as sediment. Goethite has been well known since ancient t ...
– browns and
limonite Limonite () is an iron ore consisting of a mixture of hydrated iron(III) oxide-hydroxides in varying composition. The generic formula is frequently written as , although this is not entirely accurate as the ratio of oxide to hydroxide can vary qu ...
– yellow), or
micaceous Micas ( ) are a group of silicate minerals whose outstanding physical characteristic is that individual mica crystals can easily be split into fragile elastic plates. This characteristic is described as ''perfect basal cleavage''. Mica is co ...
minerals (
chlorite The chlorite ion, or chlorine dioxide anion, is the halite (oxyanion), halite with the chemical formula of . A chlorite (compound) is a compound that contains this group, with chlorine in the oxidation state of +3. Chlorites are also known as s ...
,
biotite Biotite is a common group of phyllosilicate minerals within the mica group, with the approximate chemical formula . It is primarily a solid-solution series between the iron- endmember annite, and the magnesium-endmember phlogopite; more al ...
and
illite Illite, also called hydromica or hydromuscovite, is a group of closely related non-expanding clay minerals. Illite is a secondary mineral precipitate, and an example of a phyllosilicate, or layered alumino-silicate. Its structure is a 2:1 sandw ...
– greens). The color shifts from reddish to greenish as
iron Iron is a chemical element; it has symbol Fe () and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, forming much of Earth's o ...
in the
oxidized Redox ( , , reduction–oxidation or oxidation–reduction) is a type of chemical reaction in which the oxidation states of the reactants change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is ...
(
ferric In chemistry, iron(III) or ''ferric'' refers to the chemical element, element iron in its +3 oxidation number, oxidation state. ''Ferric chloride'' is an alternative name for iron(III) chloride (). The adjective ''ferrous'' is used instead for i ...
) state is converted to iron in the reduced (
ferrous In chemistry, iron(II) refers to the chemical element, element iron in its +2 oxidation number, oxidation state. The adjective ''ferrous'' or the prefix ''ferro-'' is often used to specify such compounds, as in ''ferrous chloride'' for iron(II ...
) state. Black shale results from the presence of greater than one percent
carbonaceous Carbonaceous refers to something relating to, containing, or composed of carbon. It is a descriptor used for the attribute of any substance rich in carbon. Particularly, ''carbonaceous hydrocarbons'' are very unsaturated, high- molecular-weight h ...
material and indicates a reducing environment. Pale blue to blue-green shales typically are rich in
carbonate minerals Carbonate minerals are those minerals containing the carbonate ion, . Carbonate divisions Anhydrous carbonates *Calcite group: trigonal **Calcite CaCO3 **Gaspéite (Ni,Mg,Fe2+)CO3 **Magnesite MgCO3 **Otavite CdCO3 **Rhodochrosite MnCO3 **Sider ...
. Clays are the major constituent of shales and other mudrocks. The clay minerals represented are largely
kaolinite Kaolinite ( ; also called kaolin) is a clay mineral, with the chemical composition Al2 Si2 O5( OH)4. It is a layered silicate mineral, with one tetrahedral sheet of silica () linked through oxygen atoms to one octahedral sheet of alumina () ...
,
montmorillonite Montmorillonite is a very soft phyllosilicate group of minerals that form when they precipitate from water solution as microscopic crystals, known as clay. It is named after Montmorillon in France. Montmorillonite, a member of the smectite grou ...
and illite. Clay minerals of Late
Tertiary Tertiary (from Latin, meaning 'third' or 'of the third degree/order..') may refer to: * Tertiary period, an obsolete geologic period spanning from 66 to 2.6 million years ago * Tertiary (chemistry), a term describing bonding patterns in organic ch ...
mudstones are expandable smectites, whereas in older rocks (especially in mid-to early
Paleozoic The Paleozoic ( , , ; or Palaeozoic) Era is the first of three Era (geology), geological eras of the Phanerozoic Eon. Beginning 538.8 million years ago (Ma), it succeeds the Neoproterozoic (the last era of the Proterozoic Eon) and ends 251.9 Ma a ...
shales) illites predominate. The transformation of smectite to illite produces
silica Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , commonly found in nature as quartz. In many parts of the world, silica is the major constituent of sand. Silica is one of the most complex and abundant f ...
,
sodium Sodium is a chemical element; it has Symbol (chemistry), symbol Na (from Neo-Latin ) and atomic number 11. It is a soft, silvery-white, highly reactive metal. Sodium is an alkali metal, being in group 1 element, group 1 of the peri ...
,
calcium Calcium is a chemical element; it has symbol Ca and atomic number 20. As an alkaline earth metal, calcium is a reactive metal that forms a dark oxide-nitride layer when exposed to air. Its physical and chemical properties are most similar to it ...
,
magnesium Magnesium is a chemical element; it has Symbol (chemistry), symbol Mg and atomic number 12. It is a shiny gray metal having a low density, low melting point and high chemical reactivity. Like the other alkaline earth metals (group 2 ...
, iron and water. These released elements form
authigenic Authigenesis is the process whereby a mineral or sedimentary rock deposit is generated where it is found or observed. Such deposits are described as authigenic. Authigenic sedimentary Mineral, minerals form during or after sedimentation by Precipita ...
quartz Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The Atom, atoms are linked in a continuous framework of SiO4 silicon–oxygen Tetrahedral molecular geometry, tetrahedra, with each oxygen being shared between two tet ...
,
chert Chert () is a hard, fine-grained sedimentary rock composed of microcrystalline or cryptocrystalline quartz, the mineral form of silicon dioxide (SiO2). Chert is characteristically of biological origin, but may also occur inorganically as a prec ...
,
calcite Calcite is a Carbonate minerals, carbonate mineral and the most stable Polymorphism (materials science), polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on ...
, dolomite,
ankerite Ankerite, also known as '' brown spar''礦物學名詞: (俄英中对照試用本) Mineralogical Terminology (Russian-English-Chinese version). — Beijing: 中國科学院. 編譯出版委員会 Compilation and Publication Committee of Chinese A ...
, hematite and
albite Albite is a plagioclase feldspar mineral. It is the sodium endmember of the plagioclase solid solution series. It represents a plagioclase with less than 10% anorthite content. The pure albite endmember has the formula . It is a tectosilicat ...
, all trace to minor (except quartz) minerals found in shales and other mudrocks. A typical shale is composed of about 58% clay minerals, 28% quartz, 6%
feldspar Feldspar ( ; sometimes spelled felspar) is a group of rock-forming aluminium tectosilicate minerals, also containing other cations such as sodium, calcium, potassium, or barium. The most common members of the feldspar group are the ''plagiocl ...
, 5% carbonate minerals, and 2%
iron oxides An iron oxide is a chemical compound composed of iron and oxygen. Several iron oxides are recognized. Often they are nonstoichiometric, non-stoichiometric. Ferric oxyhydroxides are a related class of compounds, perhaps the best known of which is ...
. Most of the quartz is
detrital Detritus (; adj. ''detrital'' ) is particles of rock derived from pre-existing rock through weathering and erosion.Essentials of Geology, 3rd Ed, Stephen Marshak, p G-7 A fragment of detritus is called a clast.Essentials of Geology, 3rd Ed, Stephen ...
(part of the original sediments that formed the shale) rather than authigenic (crystallized within the shale after deposition). Shales and other mudrocks contain roughly 95 percent of the organic matter in all sedimentary rocks. However, this amounts to less than one percent by mass in an average shale. Black shales, which form in
anoxic Anoxia means a total depletion in the level of oxygen, an extreme form of hypoxia or "low oxygen". The terms anoxia and hypoxia are used in various contexts: * Anoxic waters, sea water, fresh water or groundwater that are depleted of dissolved ox ...
conditions, contain reduced free
carbon Carbon () is a chemical element; it has chemical symbol, symbol C and atomic number 6. It is nonmetallic and tetravalence, tetravalent—meaning that its atoms are able to form up to four covalent bonds due to its valence shell exhibiting 4 ...
along with
ferrous iron In chemistry, iron(II) refers to the element iron in its +2 oxidation state. The adjective ''ferrous'' or the prefix ''ferro-'' is often used to specify such compounds, as in ''ferrous chloride'' for iron(II) chloride (). The adjective ''ferr ...
(Fe2+) and
sulfur Sulfur ( American spelling and the preferred IUPAC name) or sulphur ( Commonwealth spelling) is a chemical element; it has symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms ...
(S2−).
Amorphous In condensed matter physics and materials science, an amorphous solid (or non-crystalline solid) is a solid that lacks the long-range order that is a characteristic of a crystal. The terms "glass" and "glassy solid" are sometimes used synonymousl ...
iron sulfide Iron sulfide or iron sulphide can refer to range of chemical compounds composed of iron and sulfur. Minerals By increasing order of stability: * Iron(II) sulfide, FeS * Greigite, Fe3S4 (cubic) * Pyrrhotite, Fe1−xS (where x = 0 to 0.2) (monocli ...
, along with carbon, produce the black coloration. Because amorphous iron sulfide gradually converts to
pyrite The mineral pyrite ( ), or iron pyrite, also known as fool's gold, is an iron sulfide with the chemical formula Fe S2 (iron (II) disulfide). Pyrite is the most abundant sulfide mineral. Pyrite's metallic luster and pale brass-yellow hue ...
, which is not an important pigment, young shales may be quite dark from their iron sulfide content, in spite of a modest carbon content (less than 1%), while a black color in an ancient shale indicates a high carbon content. Most shales are marine in origin, and the
groundwater Groundwater is the water present beneath Earth's surface in rock and Pore space in soil, soil pore spaces and in the fractures of stratum, rock formations. About 30 percent of all readily available fresh water in the world is groundwater. A unit ...
in shale formations is often highly saline. There is evidence that shale acts as a semipermeable medium, allowing water to pass through while retaining dissolved salts.


Formation

The fine particles that compose shale can remain suspended in water long after the larger particles of sand have been deposited. As a result, shales are typically deposited in very slow moving water and are often found in lakes and
lagoon A lagoon is a shallow body of water separated from a larger body of water by a narrow landform, such as reefs, barrier islands, barrier peninsulas, or isthmuses. Lagoons are commonly divided into ''coastal lagoons'' (or ''barrier lagoons'') an ...
al deposits, in
river delta A river delta is a landform, archetypically triangular, created by the deposition of the sediments that are carried by the waters of a river, where the river merges with a body of slow-moving water or with a body of stagnant water. The creat ...
s, on
floodplain A floodplain or flood plain or bottomlands is an area of land adjacent to a river. Floodplains stretch from the banks of a river channel to the base of the enclosing valley, and experience flooding during periods of high Discharge (hydrolog ...
s and offshore below the
wave base The wave base, in physical oceanography, is the maximum depth at which a water wave's passage causes significant water motion. At water depths deeper than the wave base, bottom sediments and the seafloor are no longer stirred by the wave motion ...
. Thick deposits of shale are found near ancient continental margins and
foreland basins Foreland may refer to: * a landform projecting into the sea, such as a headland or a promontory * an area of land in front of something **Foreland basin, in geology, the zone that receives sediment from an adjacent mountain chain **Glacier foreland ...
. Some of the most widespread shale formations were deposited by epicontinental seas. Black shales are common in
Cretaceous The Cretaceous ( ) is a geological period that lasted from about 143.1 to 66 mya (unit), million years ago (Mya). It is the third and final period of the Mesozoic Era (geology), Era, as well as the longest. At around 77.1 million years, it is the ...
strata on the margins of the
Atlantic Ocean The Atlantic Ocean is the second largest of the world's five borders of the oceans, oceanic divisions, with an area of about . It covers approximately 17% of Earth#Surface, Earth's surface and about 24% of its water surface area. During the ...
, where they were deposited in fault-bounded silled basins associated with the opening of the Atlantic during the breakup of
Pangaea Pangaea or Pangea ( ) was a supercontinent that existed during the late Paleozoic and early Mesozoic eras. It assembled from the earlier continental units of Gondwana, Euramerica and Siberia during the Carboniferous period approximately 335 mi ...
. These basins were anoxic, in part because of restricted circulation in the narrow Atlantic, and in part because the very warm Cretaceous seas lacked the circulation of cold bottom water that oxygenates the deep oceans today. Most clay must be deposited as aggregates and floccules, since the settling rate of individual clay particles is extremely slow.
Flocculation In colloidal chemistry, flocculation is a process by which colloidal particles come out of Suspension (chemistry), suspension to sediment in the form of floc or flake, either spontaneously or due to the addition of a clarifying agent. The actio ...
is very rapid once the clay encounters highly saline sea water. Whereas individual clay particles are less than 4 microns in size, the clumps of clay particles produced by flocculation vary in size from a few tens of microns to over 700 microns in diameter. The floccules start out water-rich, but much of the water is expelled from the floccules as the clay minerals bind more tightly together over time (a process called syneresis). Clay pelletization by organisms that
filter feed Filter feeders are aquatic animals that acquire nutrients by feeding on organic matters, food particles or smaller organisms (bacteria, microalgae and zooplanktons) suspended in water, typically by having the water pass over or through a specia ...
is important where flocculation is inhibited. Filter feeders produce an estimated 12 metric tons of clay pellets per square kilometer per year along the U.S. Gulf Coast. As sediments continue to accumulate, the older, more deeply buried sediments begin to undergo
diagenesis Diagenesis () is the process of physical and chemical changes in sediments first caused by water-rock interactions, microbial activity, and compaction after their deposition. Increased pressure and temperature only start to play a role as sedi ...
. This mostly consists of compaction and
lithification Lithification (from the Ancient Greek word ''lithos'' meaning 'rock' and the Latin-derived suffix ''-ific'') is the process in which sediments compact under pressure, expel connate fluids, and gradually become solid rock. Essentially, lithificati ...
of the clay and silt particles. Early stages of diagenesis, described as ''eogenesis'', take place at shallow depths (a few tens of meters) and are characterized by
bioturbation Bioturbation is defined as the reworking of soils and sediments by animals or plants. It includes burrowing, ingestion, and defecation of sediment grains. Bioturbating activities have a profound effect on the environment and are thought to be a ...
and mineralogical changes in the sediments, with only slight compaction.
Pyrite The mineral pyrite ( ), or iron pyrite, also known as fool's gold, is an iron sulfide with the chemical formula Fe S2 (iron (II) disulfide). Pyrite is the most abundant sulfide mineral. Pyrite's metallic luster and pale brass-yellow hue ...
may be formed in anoxic mud at this stage of diagenesis. Deeper burial is accompanied by ''mesogenesis'', during which most of the compaction and lithification takes place. As the sediments come under increasing pressure from overlying sediments, sediment grains move into more compact arrangements, ductile grains (such as
clay mineral Clay minerals are hydrous aluminium phyllosilicates (e.g. kaolin, Al2 Si2 O5( OH)4), sometimes with variable amounts of iron, magnesium, alkali metals, alkaline earths, and other cations found on or near some planetary surfaces. Clay minera ...
grains) are deformed, and
pore space Porosity or void fraction is a measure of the void (i.e. "empty") spaces in a material, and is a fraction of the volume of voids over the total volume, between 0 and 1, or as a percentage between 0% and 100%. Strictly speaking, some tests measure ...
is reduced. In addition to this physical compaction, chemical compaction may take place via
pressure solution In structural geology and diagenesis, pressure solution or pressure dissolution is a deformation mechanism that involves the dissolution of minerals at grain-to-grain contacts into an aqueous pore fluid in areas of relatively high stress an ...
. Points of contact between grains are under the greatest strain, and the strained mineral is more
soluble In chemistry, solubility is the ability of a substance, the solute, to form a solution with another substance, the solvent. Insolubility is the opposite property, the inability of the solute to form such a solution. The extent of the solubi ...
than the rest of the grain. As a result, the contact points are dissolved away, allowing the grains to come into closer contact. It is during compaction that shale develops its fissility, likely through mechanical compaction of the original open framework of clay particles. The particles become strongly oriented into parallel layers that give the shale its distinctive fabric. Fissility likely develops early in the compaction process, at relatively shallow depth, since fissility does not seem to vary with depth in thick formations. Kaolinite flakes have less tendency to align in parallel layers than other clays, so kaolinite-rich clay is more likely to form nonfissile mudstone than shale. On the other hand, black shales often have very pronounced fissility (''paper shales'') due to binding of
hydrocarbon In organic chemistry, a hydrocarbon is an organic compound consisting entirely of hydrogen and carbon. Hydrocarbons are examples of group 14 hydrides. Hydrocarbons are generally colourless and Hydrophobe, hydrophobic; their odor is usually fain ...
molecules to the faces of the clay particles, which weakens the binding between particles. Lithification follows closely on compaction, as increased temperatures at depth hasten deposition of
cement A cement is a binder, a chemical substance used for construction that sets, hardens, and adheres to other materials to bind them together. Cement is seldom used on its own, but rather to bind sand and gravel ( aggregate) together. Cement mi ...
that binds the grains together. Pressure solution contributes to cementing, as the mineral dissolved from strained contact points is redeposited in the unstrained pore spaces. The clay minerals may be altered as well. For example,
smectite A smectite (; ; ) is a mineral mixture of various swelling sheet silicates (phyllosilicates), which have a three-layer 2:1 (TOT) structure and belong to the clay minerals. Smectites mainly consist of montmorillonite, but can often contain secon ...
is altered to
illite Illite, also called hydromica or hydromuscovite, is a group of closely related non-expanding clay minerals. Illite is a secondary mineral precipitate, and an example of a phyllosilicate, or layered alumino-silicate. Its structure is a 2:1 sandw ...
at temperatures of about , releasing water in the process. Other alteration reactions include the alteration of smectite to
chlorite The chlorite ion, or chlorine dioxide anion, is the halite (oxyanion), halite with the chemical formula of . A chlorite (compound) is a compound that contains this group, with chlorine in the oxidation state of +3. Chlorites are also known as s ...
and of
kaolinite Kaolinite ( ; also called kaolin) is a clay mineral, with the chemical composition Al2 Si2 O5( OH)4. It is a layered silicate mineral, with one tetrahedral sheet of silica () linked through oxygen atoms to one octahedral sheet of alumina () ...
to illite at temperatures between . Because of these reactions, illite composes 80% of
Precambrian The Precambrian ( ; or pre-Cambrian, sometimes abbreviated pC, or Cryptozoic) is the earliest part of Earth's history, set before the current Phanerozoic Eon. The Precambrian is so named because it preceded the Cambrian, the first period of t ...
shales, versus about 25% of young shales. Unroofing of buried shale is accompanied by ''telogenesis'', the third and final stage of diagenesis. As erosion reduces the depth of burial, renewed exposure to
meteoric water Meteoric water, derived from precipitation such as snow and rain, includes water from lakes, rivers, and ice melts, all of which indirectly originate from precipitation. The journey of meteoric water from the atmosphere to the Earth's surface is a ...
produces additional changes to the shale, such as dissolution of some of the cement to produce
secondary porosity Porosity or void fraction is a measure of the void (i.e. "empty") spaces in a material, and is a fraction of the volume of voids over the total volume, between 0 and 1, or as a percentage between 0% and 100%. Strictly speaking, some tests measure ...
. Pyrite may be oxidized to produce
gypsum Gypsum is a soft sulfate mineral composed of calcium sulfate Hydrate, dihydrate, with the chemical formula . It is widely mined and is used as a fertilizer and as the main constituent in many forms of plaster, drywall and blackboard or sidewalk ...
. ''Black shales'' are dark, as a result of being especially rich in unoxidized
carbon Carbon () is a chemical element; it has chemical symbol, symbol C and atomic number 6. It is nonmetallic and tetravalence, tetravalent—meaning that its atoms are able to form up to four covalent bonds due to its valence shell exhibiting 4 ...
. Common in some Paleozoic and
Mesozoic The Mesozoic Era is the Era (geology), era of Earth's Geologic time scale, geological history, lasting from about , comprising the Triassic, Jurassic and Cretaceous Period (geology), Periods. It is characterized by the dominance of archosaurian r ...
strata In geology and related fields, a stratum (: strata) is a layer of Rock (geology), rock or sediment characterized by certain Lithology, lithologic properties or attributes that distinguish it from adjacent layers from which it is separated by v ...
, black shales were deposited in
anoxic Anoxia means a total depletion in the level of oxygen, an extreme form of hypoxia or "low oxygen". The terms anoxia and hypoxia are used in various contexts: * Anoxic waters, sea water, fresh water or groundwater that are depleted of dissolved ox ...
, reducing environments, such as in stagnant water columns. Some black shales contain abundant heavy metals such as
molybdenum Molybdenum is a chemical element; it has Symbol (chemistry), symbol Mo (from Neo-Latin ''molybdaenum'') and atomic number 42. The name derived from Ancient Greek ', meaning lead, since its ores were confused with lead ores. Molybdenum minerals hav ...
,
uranium Uranium is a chemical element; it has chemical symbol, symbol U and atomic number 92. It is a silvery-grey metal in the actinide series of the periodic table. A uranium atom has 92 protons and 92 electrons, of which 6 are valence electrons. Ura ...
,
vanadium Vanadium is a chemical element; it has Symbol (chemistry), symbol V and atomic number 23. It is a hard, silvery-grey, malleable transition metal. The elemental metal is rarely found in nature, but once isolated artificially, the formation of an ...
, and
zinc Zinc is a chemical element; it has symbol Zn and atomic number 30. It is a slightly brittle metal at room temperature and has a shiny-greyish appearance when oxidation is removed. It is the first element in group 12 (IIB) of the periodic tabl ...
. The enriched values are of controversial origin, having been alternatively attributed to input from
hydrothermal Hydrothermal circulation in its most general sense is the circulation of hot water (Ancient Greek ὕδωρ, ''water'',Liddell, H.G. & Scott, R. (1940). ''A Greek-English Lexicon. revised and augmented throughout by Sir Henry Stuart Jones. with th ...
fluids during or after sedimentation or to slow accumulation from
sea water Seawater, or sea water, is water from a sea or ocean. On average, seawater in the world's oceans has a salinity of about 3.5% (35 g/L, 35 ppt, 600 mM). This means that every kilogram (roughly one liter by volume) of seawater has approximate ...
over long periods of sedimentation. File:Shale in Potokgraben.jpg, Shale in Potokgraben, the
Karawanks The Karawanks or Karavankas or Karavanks (; , ) are a mountain range of the Southern Limestone Alps on the border between Slovenia to the south and Austria to the north. With a total length of in an east–west direction, the Karawanks chain is o ...
,
Austria Austria, formally the Republic of Austria, is a landlocked country in Central Europe, lying in the Eastern Alps. It is a federation of nine Federal states of Austria, states, of which the capital Vienna is the List of largest cities in Aust ...
File:MesselShaleSplitting.JPG, Splitting shale ( Messel oil shale) with a large knife to reveal fossils File:Shale 8040.jpg,
Weathering Weathering is the deterioration of rocks, soils and minerals (as well as wood and artificial materials) through contact with water, atmospheric gases, sunlight, and biological organisms. It occurs '' in situ'' (on-site, with little or no move ...
shale at a road cut in southeastern
Kentucky Kentucky (, ), officially the Commonwealth of Kentucky, is a landlocked U.S. state, state in the Southeastern United States, Southeastern region of the United States. It borders Illinois, Indiana, and Ohio to the north, West Virginia to the ...
Fossil A fossil (from Classical Latin , ) is any preserved remains, impression, or trace of any once-living thing from a past geological age. Examples include bones, shells, exoskeletons, stone imprints of animals or microbes, objects preserve ...
s, animal tracks or burrows and even raindrop impressions are sometimes preserved on shale bedding surfaces. Shales may also contain
concretion A concretion is a hard and compact mass formed by the precipitation of mineral cement within the spaces between particles, and is found in sedimentary rock or soil. Concretions are often ovoid or spherical in shape, although irregular shapes a ...
s consisting of pyrite,
apatite Apatite is a group of phosphate minerals, usually hydroxyapatite, fluorapatite and chlorapatite, with high concentrations of Hydroxide, OH−, Fluoride, F− and Chloride, Cl− ion, respectively, in the crystal. The formula of the admixture of ...
, or various carbonate minerals. Shales that are subject to heat and pressure of
metamorphism Metamorphism is the transformation of existing Rock (geology), rock (the protolith) to rock with a different mineral composition or Texture (geology), texture. Metamorphism takes place at temperatures in excess of , and often also at elevated ...
alter into a hard, fissile,
metamorphic rock Metamorphic rocks arise from the transformation of existing rock to new types of rock in a process called metamorphism. The original rock ( protolith) is subjected to temperatures greater than and, often, elevated pressure of or more, caus ...
known as
slate Slate is a fine-grained, foliated, homogeneous, metamorphic rock derived from an original shale-type sedimentary rock composed of clay or volcanic ash through low-grade, regional metamorphism. It is the finest-grained foliated metamorphic ro ...
. With continued increase in
metamorphic grade Metamorphism is the transformation of existing rock (the protolith) to rock with a different mineral composition or texture. Metamorphism takes place at temperatures in excess of , and often also at elevated pressure or in the presence of chem ...
the sequence is
phyllite Phyllite ( ) is a type of foliation (geology), foliated metamorphic rock formed from slate that is further metamorphosed so that very fine grained white mica achieves a preferred orientation.Stephen Marshak ''Essentials of Geology'', 3rd ed. I ...
, then
schist Schist ( ) is a medium-grained metamorphic rock generally derived from fine-grained sedimentary rock, like shale. It shows pronounced ''schistosity'' (named for the rock). This means that the rock is composed of mineral grains easily seen with a l ...
and finally
gneiss Gneiss (pronounced ) is a common and widely distributed type of metamorphic rock. It is formed by high-temperature and high-pressure metamorphic processes acting on formations composed of igneous or sedimentary rocks. This rock is formed under p ...
.


As hydrocarbon source rock

Shale is the most common
source rock In petroleum geology, source rock is a sedimentary rock which has generated hydrocarbons or which has the potential to generate hydrocarbons. Source rocks are one of the necessary elements of a working petroleum system. They are organic-rich sedim ...
for hydrocarbons (
natural gas Natural gas (also fossil gas, methane gas, and gas) is a naturally occurring compound of gaseous hydrocarbons, primarily methane (95%), small amounts of higher alkanes, and traces of carbon dioxide and nitrogen, hydrogen sulfide and helium ...
and
petroleum Petroleum, also known as crude oil or simply oil, is a naturally occurring, yellowish-black liquid chemical mixture found in geological formations, consisting mainly of hydrocarbons. The term ''petroleum'' refers both to naturally occurring un ...
). The lack of coarse sediments in most shale beds reflects the absence of strong currents in the waters of the depositional basin. These might have oxygenated the waters and destroyed organic matter before it could accumulate. The absence of carbonate rock in shale beds reflects the absence of organisms that might have secreted carbonate skeletons, also likely due to an anoxic environment. As a result, about 95% of organic matter in sedimentary rocks is found in shales and other mudrocks. Individual shale beds typically have an organic matter content of about 1%, but the richest source rocks may contain as much as 40% organic matter. The organic matter in shale is converted over time from the original proteins,
polysaccharides Polysaccharides (), or polycarbohydrates, are the most abundant carbohydrates found in food. They are long-chain polymeric carbohydrates composed of monosaccharide units bound together by glycosidic linkages. This carbohydrate can react with wat ...
,
lipids Lipids are a broad group of organic compounds which include fats, waxes, sterols, fat-soluble vitamins (such as vitamins Vitamin A, A, Vitamin D, D, Vitamin E, E and Vitamin K, K), monoglycerides, diglycerides, phospholipids, and others. The fu ...
, and other organic molecules to
kerogen Kerogen is solid, insoluble organic matter in sedimentary rocks. It consists of a variety of organic materials, including dead plants, algae, and other microorganisms, that have been compressed and heated by geological processes. All the kero ...
, which at the higher temperatures found at greater depths of burial is further converted to
graphite Graphite () is a Crystallinity, crystalline allotrope (form) of the element carbon. It consists of many stacked Layered materials, layers of graphene, typically in excess of hundreds of layers. Graphite occurs naturally and is the most stable ...
and petroleum.


Historical mining terminology

Before the mid-19th century, the terms
slate Slate is a fine-grained, foliated, homogeneous, metamorphic rock derived from an original shale-type sedimentary rock composed of clay or volcanic ash through low-grade, regional metamorphism. It is the finest-grained foliated metamorphic ro ...
, shale and
schist Schist ( ) is a medium-grained metamorphic rock generally derived from fine-grained sedimentary rock, like shale. It shows pronounced ''schistosity'' (named for the rock). This means that the rock is composed of mineral grains easily seen with a l ...
were not sharply distinguished. In the context of underground
coal mining Coal mining is the process of resource extraction, extracting coal from the ground or from a mine. Coal is valued for its Energy value of coal, energy content and since the 1880s has been widely used to Electricity generation, generate electr ...
, shale was frequently referred to as slate well into the 20th century. Black shale associated with coal seams is called black metal.


See also

* * * * * * * * * *


References


External links

{{Rock type Industrial minerals