A selenite fluoride is a chemical compound or salt that contains
fluoride
Fluoride (). According to this source, is a possible pronunciation in British English. is an inorganic, monatomic anion of fluorine, with the chemical formula (also written ), whose salts are typically white or colorless. Fluoride salts typ ...
and
selenite
Selenite may refer to:
Substances containing selenium
*A selenium-containing anion or ionic compound with the SeO32− anion:
**Selenite (ion), anion is a selenium oxoanion with the chemical formula SeO32−
***Selenous acid, the conjugate acid, w ...
anion
An ion () is an atom or molecule with a net electrical charge.
The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by convent ...
s ( and ). These are
mixed anion compounds
Mixed anion compounds, heteroanionic materials or mixed anion materials are chemical compounds containing cations and more than one kind of anion. The compounds contain a single phase, rather than just a mixture.
Use in materials science
By havin ...
. Some have third anions, including
nitrate
Nitrate is a polyatomic ion
A polyatomic ion, also known as a molecular ion, is a covalent bonded set of two or more atoms, or of a metal complex, that can be considered to behave as a single unit and that has a net charge that is not zer ...
(),
molybdate
In chemistry a molybdate is a compound containing an oxoanion with molybdenum in its highest oxidation state of 6. Molybdenum can form a very large range of such oxoanions which can be discrete structures or polymeric extended structures, althoug ...
(),
oxalate (),
selenate (),
silicate
In chemistry, a silicate is any member of a family of polyatomic anions consisting of silicon and oxygen, usually with the general formula , where . The family includes orthosilicate (), metasilicate (), and pyrosilicate (, ). The name is al ...
() and
tellurate
In chemistry tellurate is a compound containing an oxyanion of tellurium where tellurium has an oxidation number of +6. In the naming of inorganic compounds it is a suffix that indicates a polyatomic anion with a central tellurium atom. ().
Naming
A selenite fluoride compound may also be called a fluoride oxoselenate(IV) using IUPAC naming for inorganic compounds.
Production
Rare earth selenite fluorides can be produced by dissolving the rare earth
selenate into molten
lithium fluoride at over 800°C, whereupon the selenate loses oxygen to become selenite, and crystals of the selenite fluoride can form.
Another similar method involves heating the rare earth oxide, with a rare earth fluoride and selenium dioxide with a
caesium bromide flux. If glass or silica containers are used, they are eaten away by the molten flux and silicates are formed some of which may be fluoride selenite silicate compounds.
Related
Related to these are the
selenite chlorides and
selenite bromides by varying the halogenide. Similar compounds by varying the
chalcogen also include the
sulfite fluorides and
tellurite fluorides.
List
SHG=
second harmonic generator
References
{{Fluorides
Selenites
Fluorides
Mixed anion compounds