Sanguisorbic acid is a constituent of some
ellagitannin
image:Castalagin.svg, 130px, Castalagin is a representative ellagitannin, characterized by coupled gallic acid substituents
The ellagitannins are a diverse class of hydrolyzable tannins, a type of polyphenol formed primarily from the oxidative link ...
s. It is constituted by a
hexahydroxydiphenic acid
Hexahydroxydiphenic acid is an organic compound with the formula HO)3C6HCO2Hsub>2. It is the oxidatively coupled derivative of gallic acid It is a white solid, although samples are typically brown owing to oxidation.
Occurrence
left, 142px, ...
unit linked by an O-C bond to a
gallic acid
Gallic acid (also known as 3,4,5-trihydroxybenzoic acid) is a trihydroxybenzoic acid with the formula C6 H2( OH)3CO2H. It is classified as a phenolic acid. It is found in gallnuts, sumac, witch hazel, tea leaves, oak bark, and other plant ...
. The differences with its isomers,
valoneic acid and
nonahydroxytriphenic acid
Nonahydroxytriphenic acid is a moiety found in some ellagitannins such as roburin A, B,C and D, castalagin
Castalagin is an ellagitannin, a type of hydrolyzable tannin, found in oak and chestnut wood and in the stem barks of ''Terminalia leiocarpa ...
, are that the hydroxyl that links the
hexahydroxydiphenoyl
Hexahydroxydiphenic acid is an organic compound with the formula HO)3C6HCO2Hsub>2. It is the oxidatively coupled derivative of gallic acid It is a white solid, although samples are typically brown owing to oxidation.
Occurrence
left, 142px, ...
(HHDP) group to the
galloyl
Gallic acid (also known as 3,4,5-trihydroxybenzoic acid) is a trihydroxybenzoic acid with the formula C6 H2( OH)3CO2H. It is classified as a phenolic acid. It is found in gallnuts, sumac, witch hazel, tea leaves, oak bark, and other plant ...
group belongs to the galloyl group in valoneic acid, while in nonahydroxytriphenic acid, the
hexahydroxydiphenic acid
Hexahydroxydiphenic acid is an organic compound with the formula HO)3C6HCO2Hsub>2. It is the oxidatively coupled derivative of gallic acid It is a white solid, although samples are typically brown owing to oxidation.
Occurrence
left, 142px, ...
unit is linked by a C-C bond to
gallic acid
Gallic acid (also known as 3,4,5-trihydroxybenzoic acid) is a trihydroxybenzoic acid with the formula C6 H2( OH)3CO2H. It is classified as a phenolic acid. It is found in gallnuts, sumac, witch hazel, tea leaves, oak bark, and other plant ...
.

It is found in
2,3-O-hexahydroxydiphenoyl-4,6-O-sanguisorboyl-(α/β)-glucose, an ellagitannin found in ''
Rubus sanctus''. It is also found in
lambertianin A,
B,
C and
D, all ellagitannins found in ''
Rubus lambertianus''.
See also
*
Valoneic acid
References
External links
Plant polyphenols: vegetable tannins revisited by Edwin Haslam, page 136
Ellagitannins
Biphenyls
Dihydroxybenzoic acids
Trihydroxybenzoic acids
Catechols
Pyrogallols
Diphenyl ethers
Tricarboxylic acids
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