Rozenite is a hydrous

iron Iron is a chemical element; it has symbol Fe () and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, forming much of Earth's o ...

sulfate mineral The sulfate minerals are a class of minerals that include the sulfate ion () within their structure. The sulfate minerals occur commonly in primary evaporite depositional environments, as gangue minerals in hydrothermal Vein (geology), veins and as ...

, Fe²⁺SO₄·4(H₂O). It occurs as a secondary mineral, formed under low humidity at less than as an alteration of copper-free

melanterite Melanterite is a mineral form of hydrous iron(II) sulfate: FeSO4·7H2O. It is the iron analogue of the copper sulfate chalcanthite. It alters to siderotil by Dehydration, loss of water. It is a secondary sulfate mineral which forms from the oxida ...

, which is a post mine alteration product of

pyrite The mineral pyrite ( ), or iron pyrite, also known as fool's gold, is an iron sulfide with the chemical formula Fe S2 (iron (II) disulfide). Pyrite is the most abundant sulfide mineral. Pyrite's metallic luster and pale brass-yellow hue ...

marcasite The mineral marcasite, sometimes called "white iron pyrite", is iron sulfide (FeS2) with orthorhombic crystal structure. It is physically and crystallographically distinct from pyrite, which is iron sulfide with cubic crystal structure. Both ...

. It also occurs in

lacustrine A lake is often a naturally occurring, relatively large and fixed body of water on or near the Earth's surface. It is localized in a basin or interconnected basins surrounded by dry land. Lakes lie completely on land and are separate from t ...

sediments and

coal Coal is a combustible black or brownish-black sedimentary rock, formed as rock strata called coal seams. Coal is mostly carbon with variable amounts of other Chemical element, elements, chiefly hydrogen, sulfur, oxygen, and nitrogen. Coal i ...

seams. Associated minerals include melanterite,

epsomite Epsomite, Epsom salt, or magnesium sulfate heptahydrate, is a hydrous magnesium sulfate mineral with formula . Physical properties Epsomite crystallizes in the orthorhombic system. The normal form is as massive encrustations, while acicula ...

jarosite Jarosite is a basic hydrous sulfate of potassium and ferric iron (Fe-III) with a chemical formula of KFe3(SO4)2(OH)6. This sulfate mineral is formed in ore deposits by the oxidation of iron sulfides. Jarosite is often produced as a byproduct dur ...

gypsum Gypsum is a soft sulfate mineral composed of calcium sulfate Hydrate, dihydrate, with the chemical formula . It is widely mined and is used as a fertilizer and as the main constituent in many forms of plaster, drywall and blackboard or sidewalk ...

sulfur Sulfur ( American spelling and the preferred IUPAC name) or sulphur ( Commonwealth spelling) is a chemical element; it has symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms ...

, pyrite, marcasite and

limonite Limonite () is an iron ore consisting of a mixture of hydrated iron(III) oxide-hydroxides in varying composition. The generic formula is frequently written as , although this is not entirely accurate as the ratio of oxide to hydroxide can vary qu ...

. It was first described in 1960 for an occurrence on Ornak Mountain, Western Tatra Mountains,

Małopolskie Lesser Poland Voivodeship ( ) is a voivodeship in southern Poland. It has an area of , and a population of 3,404,863 (2019). Its capital and largest city is Kraków. The province's name recalls the traditional name of a historic Polish region, L ...

Poland Poland, officially the Republic of Poland, is a country in Central Europe. It extends from the Baltic Sea in the north to the Sudetes and Carpathian Mountains in the south, bordered by Lithuania and Russia to the northeast, Belarus and Ukrai ...

. It was named for Polish mineralogist Zygmunt Rozen (1874–1936). The thermal expansion of rozenite was studied from to using

neutron diffraction Neutron diffraction or elastic neutron scattering is the application of neutron scattering to the determination of the atomic and/or magnetic structure of a material. A sample to be examined is placed in a beam of Neutron temperature, thermal or ...

. Rozenite exhibits negative linear

thermal expansion Thermal expansion is the tendency of matter to increase in length, area, or volume, changing its size and density, in response to an increase in temperature (usually excluding phase transitions). Substances usually contract with decreasing temp ...

, meaning that it expands in one direction upon cooling.

References

Sulfate minerals Iron(II) minerals Monoclinic minerals Minerals in space group 14 {{sulfate-mineral-stub