Rosseland Mean Opacity
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Opacity is the measure of impenetrability to
electromagnetic In physics, electromagnetism is an interaction that occurs between particles with electric charge via electromagnetic fields. The electromagnetic force is one of the four fundamental forces of nature. It is the dominant force in the interacti ...
or other kinds of
radiation In physics, radiation is the emission or transmission of energy in the form of waves or particles through space or a material medium. This includes: * ''electromagnetic radiation'' consisting of photons, such as radio waves, microwaves, infr ...
, especially visible
light Light, visible light, or visible radiation is electromagnetic radiation that can be visual perception, perceived by the human eye. Visible light spans the visible spectrum and is usually defined as having wavelengths in the range of 400– ...
. In
radiative transfer Radiative transfer (also called radiation transport) is the physical phenomenon of energy transfer in the form of electromagnetic radiation. The propagation of radiation through a medium is affected by absorption, emission, and scattering process ...
, it describes the absorption and scattering of radiation in a
medium Medium may refer to: Aircraft *Medium bomber, a class of warplane * Tecma Medium, a French hang glider design Arts, entertainment, and media Films * ''The Medium'' (1921 film), a German silent film * ''The Medium'' (1951 film), a film vers ...
, such as a plasma,
dielectric In electromagnetism, a dielectric (or dielectric medium) is an Insulator (electricity), electrical insulator that can be Polarisability, polarised by an applied electric field. When a dielectric material is placed in an electric field, electric ...
, shielding material, glass, etc. An opaque object is neither transparent (allowing all light to pass through) nor
translucent In the field of optics, transparency (also called pellucidity or diaphaneity) is the physical property of allowing light to pass through the material without appreciable light scattering by particles, scattering of light. On a macroscopic scale ...
(allowing some light to pass through). When light strikes an interface between two substances, in general, some may be reflected, some absorbed, some scattered, and the rest transmitted (also see
refraction In physics, refraction is the redirection of a wave as it passes from one transmission medium, medium to another. The redirection can be caused by the wave's change in speed or by a change in the medium. Refraction of light is the most commo ...
). Reflection can be
diffuse Diffusion is the net movement of anything (for example, atoms, ions, molecules, energy) generally from a region of higher concentration to a region of lower concentration. Diffusion is driven by a gradient in Gibbs free energy or chemical p ...
, for example light reflecting off a white wall, or
specular Specular reflection, or regular reflection, is the mirror-like reflection of waves, such as light, from a surface. The law of reflection states that a reflected ray of light emerges from the reflecting surface at the same angle to the surf ...
, for example light reflecting off a mirror. An opaque substance transmits no light, and therefore reflects, scatters, or absorbs all of it. Other categories of visual appearance, related to the perception of regular or diffuse reflection and transmission of light, have been organized under the concept of cesia in an order system with three variables, including opacity, transparency and translucency among the involved aspects. Both
mirror A mirror, also known as a looking glass, is an object that Reflection (physics), reflects an image. Light that bounces off a mirror forms an image of whatever is in front of it, which is then focused through the lens of the eye or a camera ...
s and
carbon black Carbon black (with subtypes acetylene black, channel black, furnace black, lamp black and thermal black) is a material produced by the incomplete combustion of coal tar, vegetable matter, or petroleum products, including fuel oil, fluid cataly ...
are opaque. Opacity depends on the
frequency Frequency is the number of occurrences of a repeating event per unit of time. Frequency is an important parameter used in science and engineering to specify the rate of oscillatory and vibratory phenomena, such as mechanical vibrations, audio ...
of the light being considered. For instance, some kinds of
glass Glass is an amorphous (non-crystalline solid, non-crystalline) solid. Because it is often transparency and translucency, transparent and chemically inert, glass has found widespread practical, technological, and decorative use in window pane ...
, while transparent in the visual range, are largely opaque to
ultraviolet Ultraviolet radiation, also known as simply UV, is electromagnetic radiation of wavelengths of 10–400 nanometers, shorter than that of visible light, but longer than X-rays. UV radiation is present in sunlight and constitutes about 10% of ...
light. More extreme frequency-dependence is visible in the
absorption line Absorption spectroscopy is spectroscopy that involves techniques that measure the absorption (electromagnetic radiation), absorption of electromagnetic radiation, as a function of frequency or wavelength, due to its interaction with a sample. Th ...
s of cold
gas Gas is a state of matter that has neither a fixed volume nor a fixed shape and is a compressible fluid. A ''pure gas'' is made up of individual atoms (e.g. a noble gas like neon) or molecules of either a single type of atom ( elements such as ...
es. Opacity can be quantified in many ways . Different processes can lead to opacity, including absorption, reflection, and
scattering In physics, scattering is a wide range of physical processes where moving particles or radiation of some form, such as light or sound, are forced to deviate from a straight trajectory by localized non-uniformities (including particles and radiat ...
.


Etymology

Late
Middle English Middle English (abbreviated to ME) is a form of the English language that was spoken after the Norman Conquest of 1066, until the late 15th century. The English language underwent distinct variations and developments following the Old English pe ...
opake, from Latin opacus 'darkened'. The current spelling (rare before the 19th century) has been influenced by the French form.


Radiopacity

''Radiopacity'' is preferentially used to describe opacity of
X-rays An X-ray (also known in many languages as Röntgen radiation) is a form of high-energy electromagnetic radiation with a wavelength shorter than those of ultraviolet rays and longer than those of gamma rays. Roughly, X-rays have a wavelength ran ...
. In modern medicine, radiodense substances are those that will not allow X-rays or similar radiation to pass. Radiographic imaging has been revolutionized by radiodense
contrast media A contrast agent (or contrast medium) is a substance used to increase the contrast of structures or fluids within the body in medical imaging. Contrast agents absorb or alter external electromagnetism or ultrasound, which is different from radio ...
, which can be passed through the bloodstream, the
gastrointestinal tract The gastrointestinal tract (GI tract, digestive tract, alimentary canal) is the tract or passageway of the Digestion, digestive system that leads from the mouth to the anus. The tract is the largest of the body's systems, after the cardiovascula ...
, or into the cerebral spinal fluid and utilized to highlight
CT scan A computed tomography scan (CT scan), formerly called computed axial tomography scan (CAT scan), is a medical imaging technique used to obtain detailed internal images of the body. The personnel that perform CT scans are called radiographers or ...
or X-ray images. Radiopacity is one of the key considerations in the design of various devices such as guidewires or
stent In medicine, a stent is a tube usually constructed of a metallic alloy or a polymer. It is inserted into the Lumen (anatomy), lumen (hollow space) of an anatomic vessel or duct to keep the passageway open. Stenting refers to the placement of ...
s that are used during
radiological In physics, radiation is the emission or transmission of energy in the form of waves or particles through space or a material medium. This includes: * ''electromagnetic radiation'' consisting of photons, such as radio waves, microwaves, infr ...
intervention. The radiopacity of a given endovascular device is important since it allows the device to be tracked during the interventional procedure.


Quantitative definition

The words "opacity" and "opaque" are often used as colloquial terms for objects or media with the properties described above. However, there is also a specific, quantitative definition of "opacity", used in astronomy, plasma physics, and other fields, given here. In this use, "opacity" is another term for the
mass attenuation coefficient The mass attenuation coefficient, or mass narrow beam attenuation coefficient of a material is the attenuation coefficient normalized by the density of the material; that is, the attenuation per unit mass (rather than per unit of distance). Thus, ...
(or, depending on context,
mass absorption coefficient The mass attenuation coefficient, or mass narrow beam attenuation coefficient of a material is the attenuation coefficient normalized by the density of the material; that is, the attenuation per unit mass (rather than per unit of distance). Thus, ...
, the difference is described
here Here may refer to: Music * ''Here'' (Adrian Belew album), 1994 * ''Here'' (Alicia Keys album), 2016 * ''Here'' (Cal Tjader album), 1979 * ''Here'' (Edward Sharpe album), 2012 * ''Here'' (Idina Menzel album), 2004 * ''Here'' (Merzbow album), ...
) \kappa_\nu at a particular frequency \nu of electromagnetic radiation. More specifically, if a beam of light with frequency \nu travels through a medium with opacity \kappa_\nu and mass density \rho, both constant, then the intensity will be reduced with distance ''x'' according to the formula I(x) = I_0 e^ where * ''x'' is the distance the light has traveled through the medium * I(x) is the intensity of light remaining at distance ''x'' * I_0 is the initial intensity of light, at x = 0 For a given medium at a given frequency, the opacity has a numerical value that may range between 0 and infinity, with units of length2/mass. Opacity in air pollution work refers to the percentage of light blocked instead of the attenuation coefficient (aka extinction coefficient) and varies from 0% light blocked to 100% light blocked: \text = 100\% \left(1-\frac \right)


Planck and Rosseland opacities

It is customary to define the average opacity, calculated using a certain weighting scheme. Planck opacity (also known as Planck-Mean-Absorption-Coefficient) uses the normalized Planck black-body radiation energy density distribution, B_(T), as the weighting function, and averages \kappa_\nu directly: \kappa_

\left( \right) \int_0^\infty \kappa_\nu B_\nu(T) d\nu ,
where \sigma is the Stefan–Boltzmann constant. Rosseland opacity (after Svein Rosseland), on the other hand, uses a temperature derivative of the Planck distribution, u(\nu, T)=\partial B_\nu(T)/\partial T, as the weighting function, and averages \kappa_\nu^, \frac = \frac. The photon
mean free path In physics, mean free path is the average distance over which a moving particle (such as an atom, a molecule, or a photon) travels before substantially changing its direction or energy (or, in a specific context, other properties), typically as a ...
is \lambda_\nu = (\kappa_\nu \rho)^. The Rosseland opacity is derived in the diffusion approximation to the radiative transport equation. It is valid whenever the radiation field is isotropic over distances comparable to or less than a radiation mean free path, such as in local thermal equilibrium. In practice, the mean opacity for Thomson electron scattering is: \kappa_ = 0.20(1+X) \,\mathrm where X is the hydrogen mass fraction. For nonrelativistic thermal bremsstrahlung, or free-free transitions, assuming solar
metallicity In astronomy, metallicity is the Abundance of the chemical elements, abundance of Chemical element, elements present in an object that are heavier than hydrogen and helium. Most of the normal currently detectable (i.e. non-Dark matter, dark) matt ...
, it is: \kappa_(\rho, T) = 0.64 \times 10^ (\rho ~ ^(T[])^ ^2 ^. The Rosseland mean attenuation coefficient is:George B. Rybicki and Alan Lightman, Alan P. Lightman,
Radiative Processes in Astrophysics
1979 .
\frac = \frac.


See also

*
Absorption (electromagnetic radiation) In physics, absorption of electromagnetic radiation is how matter (typically electrons bound in atoms) takes up a photon's energy—and so transforms electromagnetic energy into internal energy of the absorber (for example, thermal energy). ...
*
Mathematical descriptions of opacity When an electromagnetic wave travels through a medium in which it gets attenuated (this is called an " opaque" or " attenuating" medium), it undergoes exponential decay as described by the Beer–Lambert law. However, there are many possible ways to ...
*
Molar absorptivity In chemistry, the molar absorption coefficient or molar attenuation coefficient () is a measurement of how strongly a chemical species absorbs, and thereby attenuates, light at a given wavelength. It is an intrinsic property of the species. The ...
*
Reflection (physics) Reflection is the change in direction of a wavefront at an interface between two different media so that the wavefront returns into the medium from which it originated. Common examples include the reflection of light, sound and water waves. The ...
*
Gloss (optics) Gloss is an optical property which indicates how well a surface reflects light in a specular (mirror-like) direction. It is one of the important parameters that are used to describe the visual appearance of an object. Other categories of visual ...
* Cesia (visual appearance) *
Scattering theory In physics, scattering is a wide range of physical processes where moving particles or radiation of some form, such as light or sound, are forced to deviate from a straight trajectory by localized non-uniformities (including particles and radiat ...
*
Transparency and translucency In the field of optics, transparency (also called pellucidity or diaphaneity) is the physical property of allowing light to pass through the material without appreciable scattering of light. On a macroscopic scale (one in which the dimensions a ...
* Kappa mechanism


References

{{reflist Electromagnetic radiation Scattering, absorption and radiative transfer (optics) Spectroscopy Glass physics Physical properties Optics