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Rimstone, also called gours, is a type of
speleothem A speleothem (; ) is a geological formation made by mineral deposits that accumulate over time in natural caves. Speleothems most commonly form in calcareous caves due to carbonate dissolution reactions. They can take a variety of forms, depen ...
(cave formation) in the form of a stone dam. Rimstone is made up of
calcite Calcite is a Carbonate minerals, carbonate mineral and the most stable Polymorphism (materials science), polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on ...
and other minerals that build up in cave pools. The formation created, which looks like stairs, often extends into
flowstone Flowstones are sheetlike deposits of calcite or other carbonate minerals, formed where water flows down the walls or along the floors of a cave. They are typically found in "solution caves", in limestone, where they are the most common speleothe ...
above or below the original rimstone. Often, rimstone is covered with small, micro-gours on horizontal surfaces. Rimstone basins may form terraces that extend over hundreds of feet, with single basins known up to 200 feet long from Tham Xe Biang Fai in Laos.


Formation

Rimstone dams form where there is some
gradient In vector calculus, the gradient of a scalar-valued differentiable function f of several variables is the vector field (or vector-valued function) \nabla f whose value at a point p gives the direction and the rate of fastest increase. The g ...
, and hence flow, over the edge of a pool. Crystallization begins to occur at the
air An atmosphere () is a layer of gases that envelop an astronomical object, held in place by the gravity of the object. A planet retains an atmosphere when the gravity is great and the temperature of the atmosphere is low. A stellar atmosph ...
/
water Water is an inorganic compound with the chemical formula . It is a transparent, tasteless, odorless, and Color of water, nearly colorless chemical substance. It is the main constituent of Earth's hydrosphere and the fluids of all known liv ...
/ rock interface. The turbulence caused by flow over the edge of the building dam may contribute to the outgassing or loss of
carbon dioxide Carbon dioxide is a chemical compound with the chemical formula . It is made up of molecules that each have one carbon atom covalent bond, covalently double bonded to two oxygen atoms. It is found in a gas state at room temperature and at norma ...
from
water Water is an inorganic compound with the chemical formula . It is a transparent, tasteless, odorless, and Color of water, nearly colorless chemical substance. It is the main constituent of Earth's hydrosphere and the fluids of all known liv ...
, and result in precipitation of mineral on this edge. When dams form under running water, they tend to be higher when the passage is steeper. Shallow-gradient dams tend to be lower and more sinuous in nature. Rimstone is one of the most common cave formations, after flowstone,
stalactite A stalactite (, ; , ) is a mineral formation that hangs from the ceiling of caves, hot springs, or man-made structures such as bridges and mines. Any material that is soluble and that can be deposited as a colloid, or is in suspension (chemistry ...
s, and
stalagmite A stalagmite (, ; ; ) is a type of rock formation that rises from the floor of a cave due to the accumulation of material deposited on the floor from ceiling drippings. Stalagmites are typically composed of calcium carbonate, but may consist ...
s.


Concrete derived micro-gours

Rimstone or gours can be formed by the secondary deposits derived from concrete, lime or mortar. These secondary deposits consisting primarily of calcium carbonate, are called
calthemite Calthemite is a secondary deposit, derived from concrete, Lime (material), lime, Mortar (masonry), mortar or other calcareous material outside the cave environment.Smith, G.K. (2016). "Calcite straw stalactites growing from concrete structures" ...
s and mimics the shapes and forms of cave speleothems to create
stalactite A stalactite (, ; , ) is a mineral formation that hangs from the ceiling of caves, hot springs, or man-made structures such as bridges and mines. Any material that is soluble and that can be deposited as a colloid, or is in suspension (chemistry ...
s, stalagmites, flowstone and gours.Smith, G. K. (2016). "Calcite straw stalactites growing from concrete structures". ''Cave and Karst Science'' 43(1), pp. 4–10. Gours form beneath
concrete Concrete is a composite material composed of aggregate bound together with a fluid cement that cures to a solid over time. It is the second-most-used substance (after water), the most–widely used building material, and the most-manufactur ...
structures on a floor with a gradual sloping surface or on the side of rounded stalagmites derived from concrete. Most of the calcium carbonate carried by the leachate is deposited as stalactites (when the drop rate is slower than one drop per minute), leaving little in solution to be carried to the ground to create stalagmites, flowstone and gours. The leachate which does reach the ground usually evaporates quickly due to air movement beneath the concrete structure, hence micro-gours are more common. The secondary deposits derived from concrete are the result of concrete degradation, where
calcium Calcium is a chemical element; it has symbol Ca and atomic number 20. As an alkaline earth metal, calcium is a reactive metal that forms a dark oxide-nitride layer when exposed to air. Its physical and chemical properties are most similar to it ...
ions An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by convent ...
are leached out of the concrete in solution and redeposited on the underside of a concrete structure.
Calcium carbonate Calcium carbonate is a chemical compound with the chemical formula . It is a common substance found in Rock (geology), rocks as the minerals calcite and aragonite, most notably in chalk and limestone, eggshells, gastropod shells, shellfish skel ...
deposition as micro-gours occur when the solution drops to the ground under the concrete structure. Carbon dioxide is absorbed into the
alkaline In chemistry, an alkali (; from the Arabic word , ) is a basic salt of an alkali metal or an alkaline earth metal. An alkali can also be defined as a base that dissolves in water. A solution of a soluble base has a pH greater than 7.0. The ...
leachate solution, which facilitates the chemical reactions to precipitate any calcium carbonate remaining in solution as a stalagmite and micro-gours. This chemical reaction creating
calthemite Calthemite is a secondary deposit, derived from concrete, Lime (material), lime, Mortar (masonry), mortar or other calcareous material outside the cave environment.Smith, G.K. (2016). "Calcite straw stalactites growing from concrete structures" ...
s, is different from that which creates speleothems in limestone caves. Secondary deposits, which create stalagmites, stalactites, flowstone, rimstone etc., outside the natural
cave Caves or caverns are natural voids under the Earth's Planetary surface, surface. Caves often form by the weathering of rock and often extend deep underground. Exogene caves are smaller openings that extend a relatively short distance undergrou ...
environment, are referred to as “
calthemite Calthemite is a secondary deposit, derived from concrete, Lime (material), lime, Mortar (masonry), mortar or other calcareous material outside the cave environment.Smith, G.K. (2016). "Calcite straw stalactites growing from concrete structures" ...
s”. These concrete derived secondary deposits cannot be referred to as “
speleothem A speleothem (; ) is a geological formation made by mineral deposits that accumulate over time in natural caves. Speleothems most commonly form in calcareous caves due to carbonate dissolution reactions. They can take a variety of forms, depen ...
s” due to the definition of the word.Hill, C. A. and Forti, P., (1997). ''Cave Minerals of the World'', Second edition. untsville, Alabama: National Speleological Society Inc.Moore, G. W. (1952). "Speleothems – a new cave term". ''National Speleological Society News'', Vol.10(6), p. 2.


References

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Sources


The Virtual Cave's page on Rimstone
Speleothems