Quantum Discord
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In
quantum information theory Quantum information is the information of the state of a quantum system. It is the basic entity of study in quantum information theory, and can be manipulated using quantum information processing techniques. Quantum information refers to both t ...
, quantum discord is a measure of nonclassical correlations between two subsystems of a
quantum system Quantum mechanics is the fundamental physical Scientific theory, theory that describes the behavior of matter and of light; its unusual characteristics typically occur at and below the scale of atoms. Reprinted, Addison-Wesley, 1989, It is ...
. It includes correlations that are due to
quantum physical Quantum mechanics is the fundamental physical theory that describes the behavior of matter and of light; its unusual characteristics typically occur at and below the scale of atoms. Reprinted, Addison-Wesley, 1989, It is the foundation of a ...
effects but do not necessarily involve
quantum entanglement Quantum entanglement is the phenomenon where the quantum state of each Subatomic particle, particle in a group cannot be described independently of the state of the others, even when the particles are separated by a large distance. The topic o ...
. The notion of quantum discord was introduced by Harold Ollivier and
Wojciech H. Zurek Wojciech Hubert Zurek (; born 1951) is a Polish and American theoretical physicist and a leading authority on quantum theory, especially decoherence and non-equilibrium dynamics of symmetry breaking and resulting defect generation (known as the K ...
Wojciech H. Zurek, ''Einselection and decoherence from an information theory perspective'',
Annalen der Physik ''Annalen der Physik'' (English: ''Annals of Physics'') is one of the oldest scientific journals on physics; it has been published since 1799. The journal publishes original, peer-reviewed papers on experimental, theoretical, applied, and mathem ...
vol. 9, 855–864 (2000
abstract
/ref>Harold Ollivier and Wojciech H. Zurek, ''Quantum Discord: A Measure of the Quantumness of Correlations'',
Physical Review Letters ''Physical Review Letters'' (''PRL''), established in 1958, is a peer-reviewed, scientific journal that is published 52 times per year by the American Physical Society. The journal is considered one of the most prestigious in the field of physics ...
vol. 88, 017901 (2001
abstract
/ref> and, independently by Leah Henderson and
Vlatko Vedral Vlatko Vedral (born 1971) is a Serbian-born British physicist. He is best known for his contributions to quantum information theory, quantum mechanics, and quantum entanglement. He earned his Bachelor of Science and Doctor of Philosophy degrees ...
. Olliver and Zurek referred to it also as a measure of ''quantumness'' of correlations. From the work of these two research groups it follows that quantum correlations can be present in certain mixed
separable states In quantum mechanics, separable states are multipartite quantum states that can be written as a convex combination of product states. Product states are multipartite quantum states that can be written as a tensor product of states in each space. ...
;Paolo Giorda, Matteo G. A. Paris: ''Gaussian quantum discord'', quant-ph arXiv:1003.3207v2 (submitted on 16 Mar 2010, version of 22 March 2010
p. 1
/ref> In other words, separability alone does not imply the absence of quantum correlations. The notion of quantum discord thus goes beyond the distinction which had been made earlier between entangled versus separable (non-entangled) quantum states.


Definition and mathematical relations

In mathematical terms, quantum discord is defined in terms of the quantum mutual information. More specifically, quantum discord is the difference between two expressions which each, in the
classical limit The classical limit or correspondence limit is the ability of a physical theory to approximate or "recover" classical mechanics when considered over special values of its parameters. The classical limit is used with physical theories that predict n ...
, represent the
mutual information In probability theory and information theory, the mutual information (MI) of two random variables is a measure of the mutual Statistical dependence, dependence between the two variables. More specifically, it quantifies the "Information conten ...
. These two expressions are: :I (A; B) = H (A) + H (B) - H (A,B) :J (A; B) = H (A) - H (A, B) where, in the classical case, ''H''(''A'') is the
information entropy In information theory, the entropy of a random variable quantifies the average level of uncertainty or information associated with the variable's potential states or possible outcomes. This measures the expected amount of information needed ...
, ''H''(''A'', ''B'') the joint entropy and ''H''(''A'', ''B'') the
conditional entropy In information theory, the conditional entropy quantifies the amount of information needed to describe the outcome of a random variable Y given that the value of another random variable X is known. Here, information is measured in shannons, n ...
, and the two expressions yield identical results. In the nonclassical case, the quantum physics analogy for the three terms are used – ''S''(''ρA'') the
von Neumann entropy In physics, the von Neumann entropy, named after John von Neumann, is a measure of the statistical uncertainty within a description of a quantum system. It extends the concept of Gibbs entropy from classical statistical mechanics to quantum statis ...
, ''S''(''ρ'') the joint quantum entropy and ''S''(''ρA'', ''ρB'') a quantum generalization of conditional entropy (not to be confused with conditional quantum entropy), respectively, for
probability density function In probability theory, a probability density function (PDF), density function, or density of an absolutely continuous random variable, is a Function (mathematics), function whose value at any given sample (or point) in the sample space (the s ...
''ρ''; :I (\rho) = S (\rho_A) + S (\rho_B) - S (\rho) :J_A (\rho) = S (\rho_B) - S (\rho_B, \rho_A) The difference between the two expressions defines the basis-dependent quantum discord :\mathcal D_A (\rho) = I (\rho) - J_(\rho), which is asymmetrical in the sense that \mathcal D_A (\rho) can differ from \mathcal D_B (\rho).Borivoje Dakić, Vlatko Vedral, Caslav Brukner: ''Necessary and sufficient condition for nonzero quantum discord'', Phys. Rev. Lett., vol. 105, nr. 19, 190502 (2010), (submitted 1 April 2010, version of 3 November 2010) The notation ''J'' represents the part of the correlations that can be attributed to classical correlations and varies in dependence on the chosen
eigenbasis In linear algebra, an eigenvector ( ) or characteristic vector is a vector that has its direction unchanged (or reversed) by a given linear transformation. More precisely, an eigenvector \mathbf v of a linear transformation T is scaled by a c ...
; therefore, in order for the quantum discord to reflect the purely nonclassical correlations independently of basis, it is necessary that ''J'' first be maximized over the set of all possible projective
measurements Measurement is the quantification of attributes of an object or event, which can be used to compare with other objects or events. In other words, measurement is a process of determining how large or small a physical quantity is as compared to ...
onto the eigenbasis: :\mathcal D_A (\rho) = I (\rho) - \max_ J_ (\rho) = S (\rho_A) - S(\rho) + \min_ S (\rho_ ) Nonzero quantum discord indicates the presence of correlations that are due to noncommutativity of quantum operators. For
pure state In quantum physics, a quantum state is a mathematical entity that embodies the knowledge of a quantum system. Quantum mechanics specifies the construction, evolution, and measurement of a quantum state. The result is a prediction for the system re ...
s, the quantum discord becomes a measure of
quantum entanglement Quantum entanglement is the phenomenon where the quantum state of each Subatomic particle, particle in a group cannot be described independently of the state of the others, even when the particles are separated by a large distance. The topic o ...
,Animesh Datta, Anil Shaji, Carlton M. Caves: ''Quantum discord and the power of one qubit'', uant-ph 4 Sep 2007, p. 4 more specifically, in that case it equals the entropy of entanglement. Vanishing quantum discord is a criterion for the pointer states, which constitute preferred effectively classical states of a system. Quantum discord must be non-negative and states with vanishing quantum discord can in fact be identified with pointer states. Other conditions have been identified which can be seen in analogy to the
Peres–Horodecki criterion The Peres–Horodecki criterion is a necessary condition, for the joint density matrix \rho of two quantum mechanical systems A and B, to be separable. It is also called the PPT criterion, for ''positive partial transpose''. In the 2×2 and 2× ...
and in relation to the strong subadditivity of the von Neumann entropy.Vaibhav Madhok, Animesh Datta: ''Role of quantum discord in quantum communication'' , (submitted 5 July 2011) Efforts have been made to extend the definition of quantum discord to continuous variable systems, in particular to bipartite systems described by Gaussian states.Gerardo Adesso, Animesh Datta: ''Quantum versus classical correlations in Gaussian states'', Phys. Rev. Lett. 105, 030501 (2010), available from arXiv:1003.4979v2 uant-ph 15 July 2010 WorkS. Pirandola, G. Spedalieri, S. L. Braunstein, N. J. Cerf, S. Lloyd: ''Optimality of Gaussian Discord'', Phys. Rev. Lett. 113, 140405 (2014), available from , 26 Nov 2014 has demonstrated that the upper-bound of Gaussian discord indeed coincides with the actual quantum discord of a Gaussian state, when the latter belongs to a suitable large family of Gaussian states. Computing quantum discord is NP-complete and hence difficult to compute in the general case. For certain classes of two-qubit states, quantum discord can be calculated analytically.


Properties

Zurek provided a physical interpretation for discord by showing that it "determines the difference between the efficiency of quantum and classical
Maxwell's demon Maxwell's demon is a thought experiment that appears to disprove the second law of thermodynamics. It was proposed by the physicist James Clerk Maxwell in 1867. In his first letter, Maxwell referred to the entity as a "finite being" or a "being ...
s...in extracting work from collections of correlated quantum systems".W. H. Zurek: ''Quantum discord and Maxwell's demons",
Physical Review A ''Physical Review A'' (also known as PRA) is a monthly peer-reviewed scientific journal published by the American Physical Society covering atomic, molecular, and optical physics and quantum information. the editor was Jan M. Rost ( Max Planck ...
, vol. 67, 012320 (2003)
abstract
Discord can also be viewed in operational terms as an "entanglement consumption in an extended quantum state merging protocol". Providing evidence for non-entanglement quantum correlations normally involves elaborate
quantum tomography Quantum tomography or quantum state tomography is the process by which a quantum state is reconstructed using measurements on an ensemble of identical quantum states. The source of these states may be any device or system which prepares quantum st ...
methods; however, in 2011, such correlations could be demonstrated experimentally in a room temperature nuclear magnetic resonance system, using
chloroform Chloroform, or trichloromethane (often abbreviated as TCM), is an organochloride with the formula and a common solvent. It is a volatile, colorless, sweet-smelling, dense liquid produced on a large scale as a precursor to refrigerants and po ...
molecules that represent a two-
qubit In quantum computing, a qubit () or quantum bit is a basic unit of quantum information—the quantum version of the classic binary bit physically realized with a two-state device. A qubit is a two-state (or two-level) quantum-mechanical syste ...
quantum system. Non-linear classicality witnesses have been implemented with Bell-state measurements in photonic systems. Quantum discord has been seen as a possible basis for the performance in terms of
quantum computation A quantum computer is a computer that exploits quantum mechanical phenomena. On small scales, physical matter exhibits properties of both particles and waves, and quantum computing takes advantage of this behavior using specialized hardware. C ...
ascribed to certain mixed-state quantum systems,Animesh Datta, Anil Shaji, Carlton M. Caves: ''Quantum discord and the power of one qubit'', arXiv:0709.0548v1 uant-ph 4 Sep 2007
p. 1
/ref> with a ''mixed quantum state'' representing a
statistical ensemble In physics, specifically statistical mechanics, an ensemble (also statistical ensemble) is an idealization consisting of a large number of virtual copies (sometimes infinitely many) of a system, considered all at once, each of which represents a ...
of pure states (see
quantum statistical mechanics Quantum statistical mechanics is statistical mechanics applied to quantum mechanical systems. It relies on constructing density matrices that describe quantum systems in thermal equilibrium. Its applications include the study of collections o ...
). The view that quantum discord can be a resource for quantum processors was further cemented in 2012, where experiments established that discord between bipartite systems can be consumed to encode information that can only be accessed by coherent quantum interactions.M. Gu, H. Chrzanowski, S. Assad, T. Symul, K. Modi, T. C.Ralph, V.Vedral, P.K. Lam. "Observing the operational significance of discord consumption", Nature Physics 8, 671–675, 2012

Quantum discord is an indicator of minimum coherence (physics), coherence in one subsystem of a composite quantum system and as such it plays a resource role in interferometric schemes of phase estimation.D. Girolami, T. Tufarelli, and G. Adesso, Characterizing Nonclassical Correlations via Local Quantum Uncertainty, Phys. Rev. Lett. 110, 240402 (2013

/ref>D. Girolami et al., Quantum Discord Determines the Interferometric Power of Quantum States, Phys. Rev. Lett. 112, 210401 (2014

/ref> A recent workS. Pirandola: ''Quantum discord as a resource for quantum cryptography'', Sci. Rep. 4, 6956 (2014), available fro

/ref> has identified quantum discord as a resource for quantum cryptography, being able to guarantee the security of quantum key distribution in the complete absence of entanglement. Quantum discord is in some ways different from quantum entanglement. Quantum discord is more resilient to Quantum decoherence#Dissipation, dissipative environments than is quantum entanglement. This has been shown for Markovian environments as well as for non-Markovian environments based on a comparison of the dynamics of discord with that of
concurrence In Western jurisprudence, concurrence (also contemporaneity or simultaneity) is the apparent need to prove the simultaneous occurrence of both ("guilty action") and ("guilty mind"), to constitute a crime; except in crimes of strict liabilit ...
, where discord has proven to be more robust. At least for certain models of a qubit pair which is in thermal equilibrium and form an
open quantum system In physics, an open quantum system is a quantum-mechanical system that interacts with an external quantum system, which is known as the ''environment'' or a ''bath''. In general, these interactions significantly change the dynamics of the system a ...
in contact with a
heat bath In thermodynamics, heat is energy in transfer between a thermodynamic system and its surroundings by such mechanisms as thermal conduction, radiation, electromagnetic radiation, and friction, which are microscopic in nature, involving sub-at ...
, the quantum discord increases with temperature in certain temperature ranges, thus displaying a behaviour that is quite in contrast with that of entanglement, and that furthermore, surprisingly, the classical correlation actually decreases as the quantum discord increases. Nonzero quantum discord can persist even in the limit of one of the subsystems undergoing an infinite acceleration, whereas under this condition the quantum entanglement drops to zero due to the
Unruh effect The Unruh effect (also known as the Fulling–Davies–Unruh effect) is a theoretical prediction in quantum field theory that an observer who is uniformly accelerating through empty space will perceive a thermal bath. This means that even in the ...
. Quantum discord has been studied in quantum many-body systems. Its behavior reflects
quantum phase transition In physics, a quantum phase transition (QPT) is a phase transition between different quantum phases ( phases of matter at zero temperature). Contrary to classical phase transitions, quantum phase transitions can only be accessed by varying a phys ...
s and other properties of quantum spin chains and beyond.


Alternative measures

An operational measure, in terms of distillation of local pure states, is the 'quantum deficit'. The one-way and zero-way versions were shown to be equal to the relative entropy of quantumness. Other measures of nonclassical correlations include the measurement induced disturbance (MID) measure and the localized noneffective unitary (LNU) distance and various entropy-based measures. There exists a geometric indicator of discord based on Hilbert-Schmidt distance, which obeys a factorization law, can be put in relation to von Neumann measurements,S. Lu, S. Fu: ''Geometric measure of quantum discord'', Phys. Rev. A, vol. 82, no. 3, 034302 (2010) but is not in general a faithful measure. Faithful, computable and operational measures of discord-type correlations are the local quantum uncertainty and the interferometric power.


Multipartite Generalizations

The original definition of quantum discord is only defined for bipartite systems. The multipartite generalization for N parties was performed by Radhakrishnan, Lauriere, and Byrnes C. Radhakrishnan, M. Lauriere, T. Byrnes. "Multipartite Generalization of Quantum Discord", Phys. Rev. Lett. 124, 110401, 2020

/ref> and has the definition :\mathcal D_ (\rho) = \min_ -S_ (\rho) + S_ (\rho) + \dots + S_ (\rho) , where we introduced the notation for the conditional entropy without measurement as : S_ (\rho) = S(\rho) - S (\rho_) and conditional entropy with measurement as : S_ (\rho) = \sum_ p_^A S (\Pi_^ \rho \Pi_^/p_^A ) . The measurements are minimized over all conditional measurements : \Pi^_ = \Pi^_ \otimes \Pi^_ \dots \otimes \Pi^_ and take place in the order A_1 \rightarrow A_2 \rightarrow \dots A_. For conditional measurements, the basis can be adaptively changed depending on the outcome of the previous measurement. This type of measurement ensures that multipartite discord is (i) zero iff the state is a classically correlated state; (ii) a non-negative quantity; (iii) reduces to the standard definition of discord for bipartite-like correlated subsystems.


References

{{Reflist Quantum information science