Pigmented Structural Glass
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Pigmented structural glass, also known generically as structural glass and as vitreous marble, and marketed under the names Carrara glass, Sani Onyx, and Vitrolite, among others, is a high-strength, colored
glass Glass is an amorphous (non-crystalline solid, non-crystalline) solid. Because it is often transparency and translucency, transparent and chemically inert, glass has found widespread practical, technological, and decorative use in window pane ...
. Developed in the United States in 1900, it was widely used around the world in the first half of the 20th century in
Art Deco Art Deco, short for the French (), is a style of visual arts, architecture, and product design that first Art Deco in Paris, appeared in Paris in the 1910s just before World War I and flourished in the United States and Europe during the 1920 ...
and
Streamline Moderne Streamline Moderne is an international style of Art Deco architecture and design that emerged in the 1930s. Inspired by Aerodynamics, aerodynamic design, it emphasized curving forms, long horizontal lines, and sometimes nautical elements. In indu ...
buildings. It also found use as a material for signs, tables, and areas requiring a hygienic surface. Over time, the trademarked name "Vitrolite" became a generic term for the glass.


Overview

Pigmented structural glass was developed in 1900 in the United States by the Marrietta Manufacturing Company of
Indianapolis Indianapolis ( ), colloquially known as Indy, is the List of capitals in the United States, capital and List of municipalities in Indiana, most populous city of the U.S. state of Indiana and the county seat of Marion County, Indiana, Marion ...
,
Indiana Indiana ( ) is a U.S. state, state in the Midwestern United States, Midwestern region of the United States. It borders Lake Michigan to the northwest, Michigan to the north and northeast, Ohio to the east, the Ohio River and Kentucky to the s ...
. The product was made by combining
borax The BORAX Experiments were a series of safety experiments on boiling water nuclear reactors conducted by Argonne National Laboratory in the 1950s and 1960s at the National Reactor Testing Station in eastern Idaho.
,
cryolite Cryolite ( Na3 Al F6, sodium hexafluoroaluminate) is a rare mineral identified with the once-large deposit at Ivittuut on the west coast of Greenland, mined commercially until 1987. It is used in the reduction ("smelting") of aluminium, in pest ...
,
kaolinite Kaolinite ( ; also called kaolin) is a clay mineral, with the chemical composition Al2 Si2 O5( OH)4. It is a layered silicate mineral, with one tetrahedral sheet of silica () linked through oxygen atoms to one octahedral sheet of alumina () ...
,
manganese Manganese is a chemical element; it has Symbol (chemistry), symbol Mn and atomic number 25. It is a hard, brittle, silvery metal, often found in minerals in combination with iron. Manganese was first isolated in the 1770s. It is a transition m ...
,
silica Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , commonly found in nature as quartz. In many parts of the world, silica is the major constituent of sand. Silica is one of the most complex and abundant f ...
,
feldspar Feldspar ( ; sometimes spelled felspar) is a group of rock-forming aluminium tectosilicate minerals, also containing other cations such as sodium, calcium, potassium, or barium. The most common members of the feldspar group are the ''plagiocl ...
, and
fluorspar Fluorite (also called fluorspar) is the mineral form of calcium fluoride, CaF2. It belongs to the halide minerals. It crystallizes in isometric cubic habit, although octahedral and more complex isometric forms are not uncommon. The Mohs scal ...
. The
fluoride Fluoride (). According to this source, is a possible pronunciation in British English. is an Inorganic chemistry, inorganic, Monatomic ion, monatomic Ion#Anions and cations, anion of fluorine, with the chemical formula (also written ), whose ...
s made the glass opaque. These materials were fused into glass at a temperature of and then annealed. The annealing process took much longer than it did for
plate glass Plate glass, flat glass or sheet glass is a type of glass, initially produced in plane form, commonly used for windows, glass doors, transparent walls, and windscreens. For modern architectural and automotive applications, the flat glass is ...
, often lasting three to five days. This left the glass very strong, with a
compressive strength In mechanics, compressive strength (or compression strength) is the capacity of a material or Structural system, structure to withstand Structural load, loads tending to reduce size (Compression (physics), compression). It is opposed to ''tensil ...
about 40 percent greater than
marble Marble is a metamorphic rock consisting of carbonate minerals (most commonly calcite (CaCO3) or Dolomite (mineral), dolomite (CaMg(CO3)2) that have recrystallized under the influence of heat and pressure. It has a crystalline texture, and is ty ...
. If the product was to be affixed to another surface (such as the exterior of a building), one side of the slab was grooved before the glass hardened. The exposed side(s) of the material was flame polished, which left the product highly reflective and brilliant. Later manufacturing techniques used fine sand to polish the surface, followed by
felt Felt is a textile that is produced by matting, condensing, and pressing fibers together. Felt can be made of natural fibers such as wool or animal fur, or from synthetic fibers such as petroleum-based acrylic fiber, acrylic or acrylonitrile or ...
blocks and
iron(III) oxide Iron(III) oxide or ferric oxide is the inorganic compound with the formula . It occurs in nature as the mineral hematite, which serves as the primary source of iron for the steel industry. It is also known as red iron oxide, especially when use ...
powder. Originally, only beige, black, and white colors were available. But by the 1930s, new manufacturing methods could make pigmented structure glass
translucent In the field of optics, transparency (also called pellucidity or diaphaneity) is the physical property of allowing light to pass through the material without appreciable light scattering by particles, scattering of light. On a macroscopic scale ...
, and more than 30 colors were available. In time, even
agate Agate ( ) is a banded variety of chalcedony. Agate stones are characterized by alternating bands of different colored chalcedony and sometimes include macroscopic quartz. They are common in nature and can be found globally in a large number of d ...
- and marble-like color patterns were available. Black structural glass was sometimes
silvered Silvering is the chemical process of coating a non-conductive substrate such as glass with a reflective substance, to produce a mirror. While the metal is often silver, the term is used for the application of any reflective metal. Process ...
, to give it a reflective finish. Pigmented structural glass could be manufactured in flat panels or curves, and in a wide range of sizes and thicknesses. Small mosaic tiles, affixed to flexible fabric, were another option for fitting the product to curved surfaces. In time, manufacturers learned that pigmented structural glass could be carved, cut, inlaid, laminated, sandblasted, and sculpted to create a wide range of finishes and textures. When translucent, it could be illuminated from within.


Manufacturing history

Pigmented structural glass was originally marketed under the name "Sani Onyx" by Marrietta Manufacturing. The company also used the name "Sani Rox", while the term "vitreous marble" was coined by the firm as a general descriptive. By 1906, the
Pittsburgh Plate Glass Company PPG Industries, Inc. is an American ''Fortune'' 500 company and global supplier of paints, coatings, and specialty materials. With headquarters in Pittsburgh, Pennsylvania, PPG operates in more than 70 countries around the globe. By revenue it ...
had developed its own pigmented structural glass, which it called "Carrara glass". The same year, the Penn-American Plate Company began making a pigmented structural glass which it called "Novus Sanitary Structural Glass". In 1916, The Vitrolite Company began manufacturing the product under the name "Vitrolite", which eventually became a generic name for pigmented structural glass. In time, about eight American firms made pigmented structural glass, although Carrara glass and Vitrolite dominated the market. Names used by these and other companies to market the product included "Argentine", "Glastone", "Marbrunite", "Nuralite", and "Opalite". Pigmented structural glass was also manufactured by
Pilkington Brothers Pilkington is a glass-manufacturing company which is based in Lathom, Lancashire, England. It includes several legal entities in the UK, and is a subsidiary of Japanese company Nippon Sheet Glass (NSG). It was formerly an independent company li ...
in the
United Kingdom The United Kingdom of Great Britain and Northern Ireland, commonly known as the United Kingdom (UK) or Britain, is a country in Northwestern Europe, off the coast of European mainland, the continental mainland. It comprises England, Scotlan ...
. Marrietta Manufacturing originally marketed pigmented structural glass as a lining for refrigerators. Industrial consumers quickly found new uses for the product as countertops, dados, bathroom partitions, storefront signs, and tabletops. By the early 1920s, it was advertised as an inexpensive alternative to marble or ceramic tile. The Art Deco and Steamline Moderne architectural movements vastly increased the market for pigmented structural glass. Its first important architectural use came in 1912, when it was used for bathroom stall partitions and dados in the
Woolworth Building The Woolworth Building is a residential building and early skyscraper at 233 Broadway (Manhattan), Broadway in the Tribeca neighborhood of Lower Manhattan in New York City. Designed by Cass Gilbert, it was the tallest building in the world f ...
in
New York City New York, often called New York City (NYC), is the most populous city in the United States, located at the southern tip of New York State on one of the world's largest natural harbors. The city comprises five boroughs, each coextensive w ...
. By 1929, of pigmented structural glass was being manufactured in the United States. Throughout the 1930s, the product also found a use as cladding for storefronts, entryways, lobbies, and even as ceiling material. It was seen as an inexpensive means of making a dated building look modern. The Great Depression significantly reduced the demand for pigmented structural glass. American production reached only in 1933. By the 1950s, changing architectural tastes had vastly reduced the demand for the product. The last two American manufacturers ceased production about 1960: Libbey-Owens-Ford shut down its pigmented structural glass plant in 1958, followed by Pittsburgh Plate Glass in the early 1960s. Production continued in the United Kingdom until 1968, and in
Bavaria Bavaria, officially the Free State of Bavaria, is a States of Germany, state in the southeast of Germany. With an area of , it is the list of German states by area, largest German state by land area, comprising approximately 1/5 of the total l ...
,
Germany Germany, officially the Federal Republic of Germany, is a country in Central Europe. It lies between the Baltic Sea and the North Sea to the north and the Alps to the south. Its sixteen States of Germany, constituent states have a total popu ...
, until the end of the 20th century.


Characteristics

Unlike
masonry Masonry is the craft of building a structure with brick, stone, or similar material, including mortar plastering which are often laid in, bound, and pasted together by mortar (masonry), mortar. The term ''masonry'' can also refer to the buildin ...
, pigmented structural glass does not craze, swell, or warp. It is highly burn and stain resistant, and is
colorfast Colour fastness is a term—used in the dyeing of textile materials—that characterizes a material's colour's resistance to Color fade, fading or Glossary of dyeing terms#R, running. Colour fastness is the property of dyes and it is directly propo ...
. Since it is a glass, it is impervious to moisture. It cannot absorb
pathogenic bacteria Pathogenic bacteria are bacteria that can cause disease. This article focuses on the bacteria that are pathogenic to humans. Most species of bacteria are harmless and many are Probiotic, beneficial but others can cause infectious diseases. The nu ...
,
virus A virus is a submicroscopic infectious agent that replicates only inside the living Cell (biology), cells of an organism. Viruses infect all life forms, from animals and plants to microorganisms, including bacteria and archaea. Viruses are ...
es,
pathogenic fungi Pathogenic fungi are fungi that cause disease in humans or other organisms. Although fungi are eukaryotic, many pathogenic fungi are microorganisms. Approximately 300 fungi are known to be pathogenic to humans; their study is called "medical mycolo ...
, or
parasites Parasitism is a close relationship between species, where one organism, the parasite, lives (at least some of the time) on or inside another organism, the host, causing it some harm, and is adapted structurally to this way of life. The en ...
, and is easy to render
aseptic Asepsis is the state of being free from disease-causing micro-organisms (such as pathogenic bacteria, viruses, pathogenic fungi, and parasites). There are two categories of asepsis: medical and surgical. The modern day notion of asepsis is deri ...
.


References

;Notes ;Citations


Bibliography

* * * * * * * * * *{{cite book, ref={{sfnRef, ''The Modern Hospital Yearbook'', 1919, author=, chapter=The Vitrolite Co., title=The Modern Hospital Yearbook, location=Chicago, publisher=The Modern Hospital Publishing Company, date=1919, chapter-url=https://books.google.com/books?id=NcoyAQAAMAAJ&q=vitrolite&pg=PA692 Glass trademarks and brands Building materials