Phenolic Acids
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Phenolic acids or phenolcarboxylic acids ? are phenolic compounds and types of
aromatic acid Aromatic acids are a type of aromatic compound. Included in that class are substances containing an aromatic ring and an organic acid functional group. There are several categories of aromatic acids including: *Phenolic acids: substances containin ...
compounds. Included in that class are substances containing a phenolic ring and an organic
carboxylic acid In organic chemistry, a carboxylic acid is an organic acid that contains a carboxyl group () attached to an Substituent, R-group. The general formula of a carboxylic acid is often written as or , sometimes as with R referring to an organyl ...
function (C6-C1 skeleton). Two important naturally occurring types of phenolic acids are
hydroxybenzoic acid Hydroxybenzoic acid may refer to several related chemical compounds: * 2-Hydroxybenzoic acid (salicylic acid, ''o''-hydroxybenzoic acid) * 3-Hydroxybenzoic acid (''m''-hydroxybenzoic acid) * 4-Hydroxybenzoic acid (''p''-hydroxybenzoic acid) See ...
s and
hydroxycinnamic acid Hydroxycinnamic acids (hydroxycinnamates) are a class of aromatic acids or phenylpropanoids having a C6–C3 skeleton. These compounds are hydroxy derivatives of cinnamic acid. In the category of List of phytochemicals in food, phytochemicals tha ...
s, which are derived from non-phenolic molecules of benzoic and
cinnamic acid Cinnamic acid is an organic compound with the formula phenyl, C6H5-CH=CH-Carboxylic acid, COOH. It is a white crystalline compound that is slightly soluble in water, and freely soluble in many organic solvents. Classified as an unsaturated carboxy ...
, respectively.


Occurrences

Phenolic acids can be found in many plant species. Their content in
dried fruit Dried fruit is fruit from which the majority of the original water content has been removed prior to cooking or being eaten on its own. Drying may occur either naturally, by sun, through the use of industrial dehydrators, or by freeze drying. ...
s can be high. Natural phenols in
horse gram ''Macrotyloma uniflorum'' (horsegram, also known as horse gram, kulthi bean, gahat, hurali, or Madras gram) is a legume native to tropical southern Asia, known for its distinct taste and texture, widely used legume in many cuisines. It is also kno ...
s (''Macrotyloma uniflorum'') are mostly phenolic acids, namely 3,4-dihydroxy benzoic, ''p''-hydroxy benzoic, vanillic, caffeic, ''p''-coumaric, ferulic, syringic, and
sinapinic acid Sinapinic acid, or sinapic acid (Sinapine - Origin: L. Sinapi, sinapis, mustard, Gr., cf. F. Sinapine.), is a small naturally occurring hydroxycinnamic acid. It is a member of the phenylpropanoid family. It is a commonly used matrix in MALDI mas ...
s. Phenolic acids can be found in several mushroom-forming species of
basidiomycetes Basidiomycota () is one of two large division (mycology), divisions that, together with the Ascomycota, constitute the subkingdom Dikarya (often referred to as the "higher fungi") within the kingdom Fungi. Members are known as basidiomycetes. Mor ...
. It is also a part of the humic substances, which are the major organic constituents of soil humus. Many phenolic acids can be found in
human urine Urine is a liquid by-product of metabolism in humans and many other animals. In placental mammals, urine flows from the kidneys through the ureters to the urinary bladder and exits the urethra through the penile meatus (males) or urethral meatu ...
.


Chemistry

Immobilized ''
Candida antarctica ''Moesziomyces antarcticus '' is a species of fungus in the order Ustilaginales. The species occurs as a yeast and was originally isolated from Antarctic lake sediment. It is a rare cause of human fungaemia infections. The yeast is a source of i ...
'' lipase can be used to catalyze the direct acetylation of
flavonoids Flavonoids (or bioflavonoids; from the Latin word ''flavus'', meaning yellow, their color in nature) are a class of polyphenolic secondary metabolites found in plants, and thus commonly consumed in the diets of humans. Chemically, flavonoids ...
with phenolic acids.


See also

*
Benzoic acid Benzoic acid () is a white (or colorless) solid organic compound with the formula , whose structure consists of a benzene ring () with a carboxyl () substituent. The benzoyl group is often abbreviated "Bz" (not to be confused with "Bn," which ...
*
Aromatic alcohol In organic chemistry, the aromatic alcohols or aryl-alcohols are a class of chemical compounds containing a hydroxyl group (− O H) bonded indirectly to an aromatic hydrocarbon group, in contrast to the phenols, where the hydroxyl group is bonded ...
*
List of phytochemicals in food The following is a list of phytochemicals present in foods. Terpenoids (isoprenoids) Carotenoids ( tetraterpenoids) ''Carotenes'' orange pigments * α-Carotene – to vitamin A: carrots, pumpkins, maize, tangerine, orange * β-Carote ...


References

{{Phenolic acid Phenolic acids