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In
geoscience Earth science or geoscience includes all fields of natural science related to the planet Earth. This is a branch of science dealing with the physical, chemical, and biological complex constitutions and synergistic linkages of Earth's four spheres ...
, paleosol (''palaeosol'' in
Great Britain Great Britain is an island in the North Atlantic Ocean off the north-west coast of continental Europe, consisting of the countries England, Scotland, and Wales. With an area of , it is the largest of the British Isles, the List of European ...
and
Australia Australia, officially the Commonwealth of Australia, is a country comprising mainland Australia, the mainland of the Australia (continent), Australian continent, the island of Tasmania and list of islands of Australia, numerous smaller isl ...
) is an ancient
soil Soil, also commonly referred to as earth, is a mixture of organic matter, minerals, gases, water, and organisms that together support the life of plants and soil organisms. Some scientific definitions distinguish dirt from ''soil'' by re ...
that formed in the past. The definition of the term in
geology Geology (). is a branch of natural science concerned with the Earth and other astronomical objects, the rocks of which they are composed, and the processes by which they change over time. Modern geology significantly overlaps all other Earth ...
and
paleontology Paleontology, also spelled as palaeontology or palæontology, is the scientific study of the life of the past, mainly but not exclusively through the study of fossils. Paleontologists use fossils as a means to classify organisms, measure ge ...
is slightly different from its use in
soil science Soil science is the study of soil as a natural resource on the surface of the Earth including soil formation, soil classification, classification and Soil survey, mapping; Soil physics, physical, Soil chemistry, chemical, Soil biology, biologica ...
. In geology and paleontology, a paleosol is a former soil preserved by burial underneath either
sediment Sediment is a solid material that is transported to a new location where it is deposited. It occurs naturally and, through the processes of weathering and erosion, is broken down and subsequently sediment transport, transported by the action of ...
s (
alluvium Alluvium (, ) is loose clay, silt, sand, or gravel that has been deposited by running water in a stream bed, on a floodplain, in an alluvial fan or beach, or in similar settings. Alluvium is also sometimes called alluvial deposit. Alluvium is ...
or
loess A loess (, ; from ) is a clastic rock, clastic, predominantly silt-sized sediment that is formed by the accumulation of wind-blown dust. Ten percent of Earth's land area is covered by loesses or similar deposition (geology), deposits. A loess ...
) or volcanic deposits (
lava Lava is molten or partially molten rock (magma) that has been expelled from the interior of a terrestrial planet (such as Earth) or a Natural satellite, moon onto its surface. Lava may be erupted at a volcano or through a Fissure vent, fractu ...
flows or
volcanic ash Volcanic ash consists of fragments of rock, mineral crystals, and volcanic glass, produced during volcanic eruptions and measuring less than 2 mm (0.079 inches) in diameter. The term volcanic ash is also often loosely used to r ...
), which in the case of older deposits have
lithified Lithification (from the Ancient Greek word ''lithos'' meaning 'rock' and the Latin-derived suffix ''-ific'') is the process in which sediments compact under pressure, expel connate fluids, and gradually become solid rock. Essentially, lithificati ...
into rock. In
Quaternary The Quaternary ( ) is the current and most recent of the three periods of the Cenozoic Era in the geologic time scale of the International Commission on Stratigraphy (ICS), as well as the current and most recent of the twelve periods of the ...
geology,
sedimentology Sedimentology encompasses the study of modern sediments such as sand, silt, and clay, and the processes that result in their formation (erosion and weathering), transport, deposition and diagenesis. Sedimentologists apply their understanding of m ...
,
paleoclimatology Paleoclimatology ( British spelling, palaeoclimatology) is the scientific study of climates predating the invention of meteorological instruments, when no direct measurement data were available. As instrumental records only span a tiny part of ...
, and geology in general, it is the typical and accepted practice to use the term "paleosol" to designate such "''fossil soils''" found buried within sedimentary and volcanic deposits exposed in all continents. In soil science the definition differs slightly: paleosols are soils formed long ago that have no relationship in their chemical and physical characteristics to the present-day climate or vegetation. Such soils are found within extremely old continental
craton A craton ( , , or ; from "strength") is an old and stable part of the continental lithosphere, which consists of Earth's two topmost layers, the crust and the uppermost mantle. Having often survived cycles of merging and rifting of contine ...
s, or in small scattered locations in outliers of other ancient rock domains.


Properties

Because of the changes in the Earth's
climate Climate is the long-term weather pattern in a region, typically averaged over 30 years. More rigorously, it is the mean and variability of meteorological variables over a time spanning from months to millions of years. Some of the meteoro ...
over the last 50 million years, soils formed under tropical
rainforest Rainforests are forests characterized by a closed and continuous tree Canopy (biology), canopy, moisture-dependent vegetation, the presence of epiphytes and lianas and the absence of wildfire. Rainforests can be generally classified as tropi ...
(or even
savanna A savanna or savannah is a mixed woodland-grassland (i.e. grassy woodland) biome and ecosystem characterised by the trees being sufficiently widely spaced so that the canopy does not close. The open canopy allows sufficient light to reach th ...
) have become exposed to increasingly
arid Aridity is the condition of geographical regions which make up approximately 43% of total global available land area, characterized by low annual precipitation, increased temperatures, and limited water availability.Perez-Aguilar, L. Y., Plata ...
climates which cause former oxisols, ultisols or even alfisols to dry out in such a manner that a very hard crust is formed. This process has occurred so extensively in most parts of
Australia Australia, officially the Commonwealth of Australia, is a country comprising mainland Australia, the mainland of the Australia (continent), Australian continent, the island of Tasmania and list of islands of Australia, numerous smaller isl ...
as to restrict soil development—the former soil is effectively the
parent material Parent material is the underlying geological material (generally bedrock or a superficial deposits, superficial or drift (geology), drift deposit) in which soil horizons form. Soils typically inherit a great deal of structure and minerals from th ...
for a new soil, but it is so unweatherable that only a very poorly developed soil can exist in present dry climates, especially when they have become much drier during glacial periods in the
Quaternary The Quaternary ( ) is the current and most recent of the three periods of the Cenozoic Era in the geologic time scale of the International Commission on Stratigraphy (ICS), as well as the current and most recent of the twelve periods of the ...
. In other parts of Australia and in many parts of Africa, drying out of former soils has not been so severe. This has led to large areas of relict
podsol Podzols, also known as podosols, spodosols, or espodossolos, are the typical soils of coniferous or Taiga, boreal forests and also the typical soils of eucalypt forests and heathlands in southern Australia. In Western Europe, podzols develop on he ...
s in quite dry climates in the far southern inland of Australia (where
temperate rainforest Temperate rainforests are rainforests with coniferous or Broad-leaved tree, broadleaf forests that occur in the temperate zone and receive heavy rain. Temperate rainforests occur in oceanic moist regions around the world: the Pacific temperate ...
was formerly dominant) and to the formation of torrox soils (a suborder of oxisols) in
southern Africa Southern Africa is the southernmost region of Africa. No definition is agreed upon, but some groupings include the United Nations geoscheme for Africa, United Nations geoscheme, the intergovernmental Southern African Development Community, and ...
. Here, present climates allow, effectively, the maintenance of the old soils in climates under which they could not have formed from the parent material during the
Mesozoic The Mesozoic Era is the Era (geology), era of Earth's Geologic time scale, geological history, lasting from about , comprising the Triassic, Jurassic and Cretaceous Period (geology), Periods. It is characterized by the dominance of archosaurian r ...
and
Paleocene The Paleocene ( ), or Palaeocene, is a geological epoch (geology), epoch that lasted from about 66 to 56 mya (unit), million years ago (mya). It is the first epoch of the Paleogene Period (geology), Period in the modern Cenozoic Era (geology), ...
. Paleosols in this sense are always exceedingly infertile soils, containing available
phosphorus Phosphorus is a chemical element; it has Chemical symbol, symbol P and atomic number 15. All elemental forms of phosphorus are highly Reactivity (chemistry), reactive and are therefore never found in nature. They can nevertheless be prepared ar ...
levels orders of magnitude lower than in temperate regions with younger soils. Ecological studies have shown that this has forced highly specialised evolution amongst Australian flora to obtain minimal
nutrient A nutrient is a substance used by an organism to survive, grow and reproduce. The requirement for dietary nutrient intake applies to animals, plants, fungi and protists. Nutrients can be incorporated into cells for metabolic purposes or excret ...
supplies. The fact that
soil formation Soil formation, also known as pedogenesis, is the process of soil genesis as regulated by the effects of place, environment, and history. Biogeochemical processes act to both create and destroy order ( anisotropy) within soils. These alteration ...
is not occurring makes ecologically sustainable management even more difficult. However, paleosols often contain the most exceptional
biodiversity Biodiversity is the variability of life, life on Earth. It can be measured on various levels. There is for example genetic variability, species diversity, ecosystem diversity and Phylogenetics, phylogenetic diversity. Diversity is not distribut ...
due to the absence of
competition Competition is a rivalry where two or more parties strive for a common goal which cannot be shared: where one's gain is the other's loss (an example of which is a zero-sum game). Competition can arise between entities such as organisms, indi ...
.


Taxonomic classification

The record of paleosols extends into the
Precambrian The Precambrian ( ; or pre-Cambrian, sometimes abbreviated pC, or Cryptozoic) is the earliest part of Earth's history, set before the current Phanerozoic Eon. The Precambrian is so named because it preceded the Cambrian, the first period of t ...
in Earth's history, with rare paleosols older than 2.5 billion years. Geology, biology, and the atmosphere all changed significantly over that time, with dramatic shifts at the
Great Oxidation Event The Great Oxidation Event (GOE) or Great Oxygenation Event, also called the Oxygen Catastrophe, Oxygen Revolution, Oxygen Crisis or Oxygen Holocaust, was a time interval during the Earth's Paleoproterozoic era when the Earth's atmosphere an ...
(2.42 billion years ago) and during the
Paleozoic The Paleozoic ( , , ; or Palaeozoic) Era is the first of three Era (geology), geological eras of the Phanerozoic Eon. Beginning 538.8 million years ago (Ma), it succeeds the Neoproterozoic (the last era of the Proterozoic Eon) and ends 251.9 Ma a ...
, when complex animals and land plants proliferated. Consequently, our modern soil classification system cannot be readily applied to paleosols. For example, a modern alfisol—broadly defined as a forest soil—would not have existed prior to the evolution of trees. More problematically, it is specifically defined by chemical properties that would not be preserved in the rock record. While modern soil orders are often used to describe paleosols in a qualitative sense, a paleosol-specific naming scheme has been proposed, although it is only used sporadically in the literature. Until a paleosol-specific naming scheme is fully adopted, many paleo- pedologists have stuck to using the taxonomic classification of soils provided by the United States Department of Agriculture (USDA). The
USDA soil taxonomy USDA soil taxonomy (ST) developed by the United States Department of Agriculture and the National Cooperative Soil Survey provides an elaborate Soil classification, classification of soil types according to several parameters (most commonly their p ...
attempts to use the measurable properties and objective features within soils to classify them. The methodology developed a hierarchical structure among the different soil taxa, classifying the soils initially at a general level, then assigning soils to progressively more limited subdivisions. The USDA soil taxonomy does come with drawbacks, including an emphasis on observable features, new nomenclature, and hierarchical organization. The emphasis on observable features can make the soil taxonomy similar in appearance to a legal document. The hierarchical structure cannot be applied more deeply than the order level regarding paleosols. However, despite these drawbacks, the USDA soil taxonomy is still the most comprehensive and influential soil classification system to date. To distinguish and identify paleosols from one another, certain diagnostic horizons and features need to be taken into account. For instance, all paleosols have an A horizon, but histosols have an O horizon above the A horizon.


Identification

Rye & Holland (1998) laid out five criteria for identifying a paleosol. While this was prompted by the need for more stringent identification of Precambrian paleosols, it is applicable to paleosols of any age. The criteria are: * Formed in situ on
bedrock In geology, bedrock is solid rock that lies under loose material ( regolith) within the crust of Earth or another terrestrial planet. Definition Bedrock is the solid rock that underlies looser surface material. An exposed portion of bed ...
, * soft-sediment deformation at the top of the profile, and * up-profile changes in chemistry, texture, and mineralogy consistent with terrestrial weathering processes. In the field, physical signs of a paleosol include evidence of horizonation (e.g., color and textural changes), bedrock incorporated into a finer overlying
lithology The lithology of a rock unit is a description of its physical characteristics visible at outcrop, in hand or core samples, or with low magnification microscopy. Physical characteristics include colour, texture, grain size, and composition. Lit ...
(corestones), and evidence of surface processes (e.g., root traces, organic matter, burrows,
redox Redox ( , , reduction–oxidation or oxidation–reduction) is a type of chemical reaction in which the oxidation states of the reactants change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is t ...
alteration). Below is a list of soils and some of their diagnostic features that provides a framework for telling these paleosols, or even modern soils, apart:


Entisol (incipient soil)

Horizons (top-to-bottom): A & C This soil has a very slight degree of soil formation. Original crystalline, metamorphic, or sedimentary features of the parent material experienced little alteration from soil formation. Most are found on young geomorphic surfaces such as flood plains and on steep slopes where erosion removes material as the soil forms. Signs of early successional vegetation of grasses and other herbs and shrubs. Root traces are diagnostic of this type of paleosol because of the small amount of alteration from their parent material in other respects. However, for Entisols of Ordivician age or older, a peak in magnetic susceptibility is indicative of an Entisol.


Inceptisol (young soil)

Horizons: A, sometimes E, Bw, & C These soils represent a stage of formation beyond Entisols, but not to the degree of development in other soil orders. Typically can be imagined as having a light-colored surface horizon over a moderately weathered subsurface horizon. Forms in low-rolling parts of landscapes in and around steep mountain fronts. Shrubby woodlands of pole trees that form during recolonization of
disturbed ground In ecology, a disturbance is a change in environmental conditions that causes a pronounced change in an ecosystem. Disturbances often act quickly and with great effect, to alter the physical structure or arrangement of biotic and abiotic element ...
by forests are particularly characteristic of this paleosol. Open woodlands and wooded grasslands are also characteristic of this paleosol.


Andisol (volcanic ash soil)

Horizons: A, Bw, & C These are soils of volcanic ash of siliceous nature, consisting of bubbles or shards of volcanic glass with a high internal surface area. This soil weathers rapidly to imogolite and smectite. Thus they are highly fertile, rich in organic matter, and have particularly low bulk density. These properties and the aforementioned weathering products typically alter during burial, sometimes to distinctive minerals like celadonite and clinoptilolite. At least 60% recognizable pyroclastic fragments in thin sections are characteristic of this paleosol. This paleosol forms in and around volcanoes.


Histosol (peaty soil)

Horizons: O, A, sometimes Bg, & C Organic-rich soils with thick peaty horizons, that form in cool, well drained localities or low-lying, permanently waterlogged areas. The primary formation process is accumulation of peat (organic matter), meaning organic matter is produced faster than it can decompose in the soil. The leaching or formation of gley minerals (pyrite or siderite) overprinting prior soil or sedimentary features is associated with peat accumulation.


Spodosol (sandy forest soil)

Horizons: A, E, sometimes Bh, Bs, & C A subsurface horizon enriched with iron and aluminum oxides or organic matter is characteristic of Spodosols. Displays opaque cements that form distinctive radially cracked, concretionary rims to abundant quartz grains in thin sections. Spodosols form on hilly bedrock or low, rolling quartz-rich sediments. Found principally in humid climates in which clay and soluble salts are dissolved and washed out of the profile and most common in temperate regions. Characteristic vegetation are conifer forests and other kinds of evergreen woody vegetation that can tolerate low nutrient levels and high soil acidity.


Alfisol (fertile forest soil)

Horizons: A, sometimes E, Bt, sometimes Bk, & C Base-rich forested soils that have a light-colored surface horizon over a clayey subsurface horizon, rich in exchangeable cations. If paleosols contain nodules of carbonate in a horizon deep within the profile, such base saturation can be assumed. If lacking in carbonate nodules, Alfisols can be distinguished by the abundance of base rich clays or by molecular weathering ratios of alumina/bases of less than 2. These soils are not found at the poles or on high mountain tops.


Ultisol (base-poor forest soil)

Horizons: A, sometimes E, Bt, & C Base-poor forest soils that are similar to Alfisols at first glance. However, Ultisols are more deeply weathered of mineral nutrients. There should not be any calcareous material anywhere within an Ultisol profile and have molecular weathering ratios of alumina/bases of more than 2. Kaolinite and highly weathered aluminous minerals such as gibbsite are common in the profile. Low-base status is attributed to a long formation time. Form mostly on older parts of landscapes, such as rolling hills of bedrock, high alluvial terraces, and plateau tops. Natural vegetation consists of coniferous or hardwood forests.


Oxisol (tropical deeply-weathered soil)

Horizons: A, Bo, sometimes Bv, & C Deeply weathered soils with texturally uniform profiles. Dominated by kaolinitic clays or other base-poor oxides such as gibbsite or boehmite. Contains molecular weathering ratios of alumina/bases of 10 or more. These soils have deeply weathered mottled horizons. Characteristic of this type of paleosol is a stable microstructure of sand-sized spherical micropeds of iron-stained lay. Very old, often amounting to tens of millions of years. Found on stable continental locations on gentle slopes of plateaus, terraces, and plains. The natural vegetation for Oxisols is a rainforest.


Vertisol (swelling clay soil)

Horizons: A, Bw, & C These are uniform, thick, clayey soils that have deep, wide cracks. Cracking can produce a hummock-and-swale topography. Mostly composed of smectitic clays. Most Vertisols are found on intermediate to basaltic materials. Found mainly in flat terrain at the foot of gentle slopes. Climate and vegetation are dry and sparse enough that alkaline reactions can be maintained. Vegetation ranges from grassland to open woodland, with wooded grassland being common.


Mollisol (grassland soil)

Horizons: A, sometimes Bt, Bk, sometimes By, & C Well-developed, base-rich, surface horizon of intimately mixed clay and organic matter. An abundance of fine root traces and crumb ped structures are characteristic of this paleosol. The surface horizon characteristic of this paleosol is created by fine root systems of grassy vegetation and the burrowing activity of many soil invertebrate species. Mollisols are found in low, rolling, or flat country.


Aridisol (desert soil)

Horizons: A, sometimes Bt, Bk, sometimes By, & C Forms in arid to semi-arid regions, and that lack of rain allows for the creation of shallow calcareous, gypsiferous, or salty horizons. These cements form large nodules or continuous layers. Light-colored, soft, and often vesicular surface horizon. Subsurface horizons are not cemented with any of the aforementioned cements. Mostly found in low-lying areas because steep slopes in arid regions tend to be eroded back to bedrock. Vegetation is sparse and includes prickly shrubs and cacti.


Gelisol (permafrost soil)

Horizons: A, sometimes By, & C Soils with ground ice or other permafrost features within one meter of the surface. In paleosols, locations of ice can be preserved as clastic dikes, freeze banding, or other deformations created by ground ice. Tillites and other glacigenic deposits are indicative of Gelisols. These soils form under polar desert, tundra, and taiga vegetation. Includes a surprising array of histic epipedons, desert pavements, salic, and calcic horizons. Many other factors, such as ped structures, such as the presence of blocky, angular or granular peds and fabric type, like clinobimasepic plasmic fabric, are structures that can help one identify if they are dealing with a paleosol. Some of these structures are very helpful when narrowing down the paleosol that is being identified. However, any paleosol should be verified geochemically before use in proxy-based reconstructions; post-deposition alteration processes, such as potassium
metasomatism Metasomatism (from the Greek μετά ''metá'' "change" and σῶμα ''sôma'' "body") is the chemical alteration of a rock by hydrothermal and other fluids. It is traditionally defined as metamorphism which involves a change in the chemical com ...
, can change a paleosol's chemistry without dramatically altering its physical appearance.


Applications


Paleoclimate reconstructions

Palaeosols are frequently used as palaeoclimatological tools for gauging the climate in which they formed. Because rates and styles of weathering are dependent on climatic factors, paleosols can be used to reconstruct variables of past climate. Mean annual precipitation (MAP) and air temperature (MAAT) are two commonly-reconstructed variables which, along with seasonality and in conjunction with other paleoenvironmental tools, can be used to describe past terrestrial climates. A suite of paleoclimatic proxies exist and while they vary in focus, many rely on changes in chemical composition throughout a soil profile that occur during weathering, burial, and post-burial processes. Their use depends on factors such as post-burial alteration, parent material, and soil order; not every proxy is applicable to every paleosol. Most proxies are applicable to Phanerozoic paleosols (not older), as landscape processes changed dramatically after the rise of land plants. Seasonality (the presence and strength of seasons) requires a more nuanced reconstruction approach. Proposed seasonality proxies primarily rely on a soil wetting/drying process, during which pedogenic carbonate can form; like other proxies, this tool is continually being tested and refined.


Paleoatmosphere reconstructions

Soils form in near-constant contact with the
atmosphere An atmosphere () is a layer of gases that envelop an astronomical object, held in place by the gravity of the object. A planet retains an atmosphere when the gravity is great and the temperature of the atmosphere is low. A stellar atmosph ...
, so their chemical composition is affected by the composition of the atmosphere through both direct and indirect pathways. The oxidation of paleosols has been used as an indicator of atmospheric oxygen, which has risen over Earth's history. Paleosols have also been used to reconstruct atmospheric carbon dioxide levels, based on modern studies of
soil carbon Soil carbon is the solid carbon stored in global Soil, soils. This includes both soil organic matter and Inorganic compound, inorganic carbon as carbonate minerals. It is vital to the soil capacity in our ecosystem. Soil carbon is a carbon sink in ...
gas exchange, carbon isotopes in pedogenic carbonate nodules, and mass-balance approaches taking multiple atmospheric gases (typically
carbon dioxide Carbon dioxide is a chemical compound with the chemical formula . It is made up of molecules that each have one carbon atom covalent bond, covalently double bonded to two oxygen atoms. It is found in a gas state at room temperature and at norma ...
,
oxygen Oxygen is a chemical element; it has chemical symbol, symbol O and atomic number 8. It is a member of the chalcogen group (periodic table), group in the periodic table, a highly reactivity (chemistry), reactive nonmetal (chemistry), non ...
, and
methane Methane ( , ) is a chemical compound with the chemical formula (one carbon atom bonded to four hydrogen atoms). It is a group-14 hydride, the simplest alkane, and the main constituent of natural gas. The abundance of methane on Earth makes ...
) into account. These methods are being actively developed in the field of early Earth research.


Paleobotany

Paleosols are an important archive of information about ancient ecosystems and various components of fossil soils can be used to study past plant life. Paleosols often contain ancient plant materials such as
pollen Pollen is a powdery substance produced by most types of flowers of seed plants for the purpose of sexual reproduction. It consists of pollen grains (highly reduced Gametophyte#Heterospory, microgametophytes), which produce male gametes (sperm ...
grains and phytoliths, a biomineralized form of
silica Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , commonly found in nature as quartz. In many parts of the world, silica is the major constituent of sand. Silica is one of the most complex and abundant f ...
produced by many plants such as grasses. Both pollen and phytolith fossils from different plant species have characteristic shapes that can be traced back to their parent plants. Over long geological time scales, phytoliths may not necessarily be preserved in paleosols due to ability of the poorly crystalline silica to dissolve. Another indicator of plant community composition in paleosols is the carbon isotopic signature. The ratio of different carbon
isotopes Isotopes are distinct nuclear species (or ''nuclides'') of the same chemical element. They have the same atomic number (number of protons in their nuclei) and position in the periodic table (and hence belong to the same chemical element), but ...
in organic matter in paleosols reflects the proportions of plants using C3 photosynthesis, which grow in cooler and wetter climates, versus plants using C4 photosynthesis, which are better adapted to hotter and drier conditions. Other methods for detecting past plant life in paleosols are based on identifying the remains of leaf waxes, which are slow to break down in soils over time.


Paleoseismology

As records of previous Earth surfaces that can be stacked on one another, paleosol sequences are also valuable for paleoseismology.


See also

* Paleopedology * Paleopedological record *
Pedogenesis Soil formation, also known as pedogenesis, is the process of soil genesis as regulated by the effects of place, environment, and history. Biogeochemical processes act to both create and destroy order (anisotropy) within soils. These alterations ...
*
Pedology (soil study) Pedology (from Greek: πέδον, ''pedon'', "soil"; and λόγος, ''logos'', "study") is a discipline within soil science which focuses on understanding and characterizing soil formation, evolution, and the theoretical frameworks for modelin ...


References


External links

* {{Soil type Pedology Historical geology Types of soil