Nitryl Cyanide
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Nitryl cyanide is an energetic chemical compound with the formula NCNO2. Nitryl cyanide is a possible precursor to the theoretical
explosive An explosive (or explosive material) is a reactive substance that contains a great amount of potential energy that can produce an explosion if released suddenly, usually accompanied by the production of light, heat, sound, and pressure. An ex ...
2,4,6-trinitro-1,3,5-triazine.


Synthesis

Nitryl cyanide was first synthesized in 2014. The reaction of
nitronium tetrafluoroborate Nitronium tetrafluoroborate is an inorganic compound with formula NO2BF4. It is a salt of nitronium cation and tetrafluoroborate anion. It is a colorless crystalline solid, which reacts with water to form the corrosive acids HF and HNO3. As su ...
with ''tert''-butyldimethylsilyl cyanide at −30 °C produces nitryl cyanide, with ''tert''-butyldimethylsilyl fluoride and
boron trifluoride Boron trifluoride is the inorganic compound with the formula . This pungent, colourless, and toxic gas forms white fumes in moist air. It is a useful Lewis acid and a versatile building block for other boron compounds. Structure and bonding The g ...
as byproducts. : The
conversion Conversion or convert may refer to: Arts, entertainment, and media * ''The Convert'', a 2023 film produced by Jump Film & Television and Brouhaha Entertainment * "Conversion" (''Doctor Who'' audio), an episode of the audio drama ''Cyberman'' * ...
of this method is only 50%, and using an excess of ''tert''-butyldimethylsilyl causes the yield to drop even further.


References

Nitro compounds Cyanides Explosives {{Explosive-stub