Molten salt is

salt In common usage, salt is a mineral composed primarily of sodium chloride (NaCl). When used in food, especially in granulated form, it is more formally called table salt. In the form of a natural crystalline mineral, salt is also known as r ...

which is solid at

standard temperature and pressure Standard temperature and pressure (STP) or standard conditions for temperature and pressure are various standard sets of conditions for experimental measurements used to allow comparisons to be made between different sets of data. The most used ...

but liquified due to elevated temperature. A salt that is liquid even at standard temperature and pressure is usually called a room-temperature

ionic liquid An ionic liquid (IL) is a salt (chemistry), salt in the liquid state at ambient conditions. In some contexts, the term has been restricted to salts whose melting point is below a specific temperature, such as . While ordinary liquids such as wate ...

, and molten salts are technically a class of ionic liquids.

Examples

As a reference, molten

sodium chloride Sodium chloride , commonly known as Salt#Edible salt, edible salt, is an ionic compound with the chemical formula NaCl, representing a 1:1 ratio of sodium and chloride ions. It is transparent or translucent, brittle, hygroscopic, and occurs a ...

table salt In common usage, salt is a mineral composed primarily of sodium chloride (NaCl). When used in food, especially in granulated form, it is more formally called table salt. In the form of a natural crystalline mineral, salt is also known as ro ...

has a melting point (m.p.) of . A variety of eutectic mixtures have been developed with lower melting points:

Chlorides

Lithium chloride Lithium chloride is a chemical compound with the formula Li Cl. The salt is a typical ionic compound (with certain covalent characteristics), although the small size of the Li+ ion gives rise to properties not seen for other alkali metal chlorid ...

and

potassium chloride Potassium chloride (KCl, or potassium salt) is a metal halide salt composed of potassium and chlorine. It is odorless and has a white or colorless vitreous crystal appearance. The solid dissolves readily in water, and its solutions have a sa ...

, m.p. .

Nitrates

Alkali metal nitrate Alkali metal nitrates are chemical compounds consisting of an alkali metal (lithium, sodium, potassium, rubidium and caesium) and the nitrate ion. Only two are of major commercial value, the sodium and potassium salts. They are white, water-sol ...

s are relatively low melting and thermally stable. The least stable, (m.p. ) decomposes only at . At the other extreme, cesium nitrate melts at and decomposes at 584 °C. *60:40 mixture of

sodium nitrate Sodium nitrate is the chemical compound with the chemical formula, formula . This alkali metal nitrate salt (chemistry), salt is also known as Chile saltpeter (large deposits of which were historically mined in Chile) to distinguish it from ordi ...

and

potassium nitrate Potassium nitrate is a chemical compound with a sharp, salty, bitter taste and the chemical formula . It is a potassium salt of nitric acid. This salt consists of potassium cations and nitrate anions , and is therefore an alkali metal nit ...

is a liquid between . It has a

heat of fusion In thermodynamics, the enthalpy of fusion of a substance, also known as (latent) heat of fusion, is the change in its enthalpy resulting from providing energy, typically heat, to a specific quantity of the substance to change its state from a s ...

of 161 J/g, and a

heat capacity Heat capacity or thermal capacity is a physical property of matter, defined as the amount of heat to be supplied to an object to produce a unit change in its temperature. The SI unit of heat capacity is joule per kelvin (J/K). Heat capacity is a ...

of 1.53 J/(g·K). *1:1 mixture :, m.p. . *40:7:53 ::, m. p. , stable to .

Uses

Molten salts have a variety of uses.

Production of magnesium and aluminium

One industrial application is the production of magnesium, which begins with production of magnesium chloride by chlorination of

magnesium oxide Magnesium oxide (MgO), or magnesia, is a white hygroscopic solid mineral that occurs naturally as periclase and is a source of magnesium (see also oxide). It has an empirical formula of MgO and consists of a lattice of Mg2+ ions and O2− ions ...

: :

Electrolysis In chemistry and manufacturing, electrolysis is a technique that uses Direct current, direct electric current (DC) to drive an otherwise non-spontaneous chemical reaction. Electrolysis is commercially important as a stage in the separation of c ...

of the resulting molten magnesium chloride is conducted at : :

Aluminium Aluminium (or aluminum in North American English) is a chemical element; it has chemical symbol, symbol Al and atomic number 13. It has a density lower than that of other common metals, about one-third that of steel. Aluminium has ...

metal is produced from aluminium oxides by electrolysis of a molten mixture of sodium hexafluoroaluminate and alumina at . This conversion is called the Hall-Haroult process.

Heat transfer

Molten salts (fluoride, chloride, and

nitrate Nitrate is a polyatomic ion with the chemical formula . salt (chemistry), Salts containing this ion are called nitrates. Nitrates are common components of fertilizers and explosives. Almost all inorganic nitrates are solubility, soluble in wa ...

) can be used as heat transfer fluids as well as for

thermal storage Thermal energy storage (TES) is the storage of thermal energy for later reuse. Employing widely different technologies, it allows surplus thermal energy to be stored for hours, days, or months. Scale both of storage and use vary from small t ...

. This thermal storage is used in

concentrated solar power Concentrated solar power (CSP, also known as concentrating solar power, concentrated solar thermal) systems generate solar power by using mirrors or lenses to concentrate a large area of sunlight into a receiver. Electricity is generated whe ...

plants. Molten-salt reactors are a type of nuclear reactor that uses molten salt(s) as a coolant or as a solvent in which the fissile material is dissolved. Experimental salts using lithium can be formed that have a melting point of 116 °C while still having a heat capacity of 1.54 J/(g·K).Reddy, Ramana G.
Novel Molten Salts Thermal Energy Storage for Concentrating Solar Power Generation
page 9 ''University of Alabama College of Engineering''. Retrieved 9 December 2014.

Other uses

Molten

chloride The term chloride refers to a compound or molecule that contains either a chlorine anion (), which is a negatively charged chlorine atom, or a non-charged chlorine atom covalently bonded to the rest of the molecule by a single bond (). The pr ...

salt mixtures are commonly used as

quenching In materials science, quenching is the rapid cooling of a workpiece in water, gas, oil, polymer, air, or other fluids to obtain certain material properties. A type of heat treating, quenching prevents undesired low-temperature processes, suc ...

baths for various alloy

heat treatment Heat treating (or heat treatment) is a group of industrial, thermal and metalworking processes used to alter the physical, and sometimes chemical, properties of a material. The most common application is metallurgical. Heat treatments are a ...

s, such as annealing and martempering of

steel Steel is an alloy of iron and carbon that demonstrates improved mechanical properties compared to the pure form of iron. Due to steel's high Young's modulus, elastic modulus, Yield (engineering), yield strength, Fracture, fracture strength a ...

Cyanide In chemistry, cyanide () is an inorganic chemical compound that contains a functional group. This group, known as the cyano group, consists of a carbon atom triple-bonded to a nitrogen atom. Ionic cyanides contain the cyanide anion . This a ...

and chloride salt mixtures are used for surface modification of alloys such as carburizing and nitrocarburizing of steel.

Cryolite Cryolite ( Na3 Al F6, sodium hexafluoroaluminate) is a rare mineral identified with the once-large deposit at Ivittuut on the west coast of Greenland, mined commercially until 1987. It is used in the reduction ("smelting") of aluminium, in pest ...

fluoride Fluoride (). According to this source, is a possible pronunciation in British English. is an Inorganic chemistry, inorganic, Monatomic ion, monatomic Ion#Anions and cations, anion of fluorine, with the chemical formula (also written ), whose ...

salt) is used as a

solvent A solvent (from the Latin language, Latin ''wikt:solvo#Latin, solvō'', "loosen, untie, solve") is a substance that dissolves a solute, resulting in a Solution (chemistry), solution. A solvent is usually a liquid but can also be a solid, a gas ...

for

aluminium oxide Aluminium oxide (or aluminium(III) oxide) is a chemical compound of aluminium and oxygen with the chemical formula . It is the most commonly occurring of several Aluminium oxide (compounds), aluminium oxides, and specifically identified as alum ...

in the production of aluminium in the Hall-Héroult process. Fluoride, chloride, and hydroxide salts can be used as solvents in pyroprocessing of

nuclear fuel Nuclear fuel refers to any substance, typically fissile material, which is used by nuclear power stations or other atomic nucleus, nuclear devices to generate energy. Oxide fuel For fission reactors, the fuel (typically based on uranium) is ...

Ambient-temperature molten salts

Ambient-temperature molten salts (also known as

s) are present in the liquid phase at

standard conditions for temperature and pressure Standard temperature and pressure (STP) or standard conditions for temperature and pressure are various standard sets of conditions for experimental measurements used to allow comparisons to be made between different sets of data. The most used ...

. Examples of such salts include ''N''-ethylpyridinium

bromide A bromide ion is the negatively charged form (Br−) of the element bromine, a member of the halogens group on the periodic table. Most bromides are colorless. Bromides have many practical roles, being found in anticonvulsants, flame-retard ...

and

aluminium chloride Aluminium chloride, also known as aluminium trichloride, is an inorganic compound with the formula . It forms a hexahydrate with the formula , containing six water molecules of hydration. Both the anhydrous form and the hexahydrate are col ...

mix, discovered in 1951, and ethylammonium nitrate discovered by Paul Walden. Other ionic liquids take advantage of asymmetrical quaternary ammonium cations like alkylated imidazolium ions, and large, branched anions like the

bistriflimide Bistriflimide, also known variously as bis(trifluoromethane)sulfonimide, bis(trifluoromethanesulfonyl)imide, bis(trifluoromethanesulfonyl)imidate (and variations thereof), informally and somewhat inaccurately as triflimide or triflimidate'','' or ...

ion.

References

Bibliography

*C.F. Baes
''The chemistry and thermodynamics of molten salt reactor fuels''
Proc. AIME Nuclear Fuel Reprocessing Symposium, Ames, Iowa, USA, 1969 (August 25),

External links

Proc. Roy. Soc.
{{Authority control Energy storage Inorganic solvents Ionic liquids Metallurgical processes