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The lower mantle, historically also known as the mesosphere, represents approximately 56% of Earth's total volume, and is the region from 660 to 2890 km below
Earth's surface Earth is the third planet from the Sun and the only astronomical object known to Planetary habitability, harbor life. This is enabled by Earth being an ocean world, the only one in the Solar System sustaining liquid surface water. Almost all ...
; between the transition zone and the
outer core Earth's outer core is a fluid layer about thick, composed of mostly iron and nickel that lies above Earth's solid Earth's inner core, inner core and below its Earth's mantle, mantle. The outer core begins approximately beneath Earth's surface ...
. The preliminary reference Earth model (PREM) separates the lower mantle into three sections, the uppermost (660–770 km), mid-lower mantle (770–2700 km), and the D layer (2700–2890 km). Pressure and temperature in the lower mantle range from 24–127 GPa and 1900–2600 K. It has been proposed that the composition of the lower mantle is pyrolitic, containing three major phases of
bridgmanite Silicate perovskite is either (the magnesium end-member is called bridgmanite) or (calcium silicate known as davemaoite) when arranged in a perovskite structure. Silicate perovskites are not stable at Earth's surface, and mainly exist in the l ...
, ferropericlase, and calcium-silicate perovskite. The high pressure in the lower mantle has been shown to induce a spin transition of iron-bearing bridgmanite and ferropericlase, which may affect both
mantle plume A mantle plume is a proposed mechanism of convection within the Earth's mantle, hypothesized to explain anomalous volcanism. Because the plume head partially melts on reaching shallow depths, a plume is often invoked as the cause of volcanic ho ...
dynamics and lower mantle chemistry. The mantle moves at about 1 cm per year. The upper boundary is defined by the sharp increase in
seismic wave A seismic wave is a mechanical wave of acoustic energy that travels through the Earth or another planetary body. It can result from an earthquake (or generally, a quake), volcanic eruption, magma movement, a large landslide and a large ma ...
velocities and
density Density (volumetric mass density or specific mass) is the ratio of a substance's mass to its volume. The symbol most often used for density is ''ρ'' (the lower case Greek letter rho), although the Latin letter ''D'' (or ''d'') can also be u ...
at a depth of . At a depth of 660 km,
ringwoodite Ringwoodite is a high-pressure phase of Mg2SiO4 (magnesium silicate) formed at high temperatures and pressures of the Earth's mantle between depth. It may also contain iron and hydrogen. It is polymorphous with the olivine phase forsterite (a ...
() decomposes into Mg-Si perovskite and
magnesiowüstite Ferropericlase or magnesiowüstite is a magnesium/iron oxide with the chemical formula that is interpreted to be one of the main constituents of the Earth's lower mantle (Earth), lower mantle together with the silicate perovskite (), a magnesium/i ...
. This reaction marks the boundary between the
upper mantle The upper mantle of Earth is a very thick layer of rock inside the planet, which begins just beneath the crust (geology), crust (at about under the oceans and about under the continents) and ends at the top of the lower mantle (Earth), lower man ...
and lower mantle. This measurement is estimated from seismic data and high-pressure laboratory experiments. The base of the mesosphere includes the D″ zone which lies just above the mantle–core boundary at approximately .


Physical properties

The lower mantle was initially labelled as the D-layer in Bullen's spherically symmetric model of the Earth. The PREM seismic model of the Earth's interior separated the D-layer into three distinctive layers defined by the discontinuity in
seismic wave A seismic wave is a mechanical wave of acoustic energy that travels through the Earth or another planetary body. It can result from an earthquake (or generally, a quake), volcanic eruption, magma movement, a large landslide and a large ma ...
velocities: * 660–770 km: A discontinuity in compression wave velocity (6–11%) followed by a steep gradient is indicative of the transformation of the mineral
ringwoodite Ringwoodite is a high-pressure phase of Mg2SiO4 (magnesium silicate) formed at high temperatures and pressures of the Earth's mantle between depth. It may also contain iron and hydrogen. It is polymorphous with the olivine phase forsterite (a ...
to bridgmanite and ferropericlase and the transition between the transition zone layer to the lower mantle. * 770–2700 km: A gradual increase in velocity indicative of the adiabatic compression of the mineral phases in the lower mantle. * 2700–2900 km: The
D-layer The ionosphere () is the ionized part of the upper atmosphere of Earth, from about to above sea level, a region that includes the thermosphere and parts of the mesosphere and exosphere. The ionosphere is ionized by solar radiation. It plays ...
is considered the transition from the lower mantle to the
outer core Earth's outer core is a fluid layer about thick, composed of mostly iron and nickel that lies above Earth's solid Earth's inner core, inner core and below its Earth's mantle, mantle. The outer core begins approximately beneath Earth's surface ...
. The temperature of the lower mantle ranges from at the topmost layer to at a depth of . Models of the temperature of the lower mantle approximate
convection Convection is single or Multiphase flow, multiphase fluid flow that occurs Spontaneous process, spontaneously through the combined effects of material property heterogeneity and body forces on a fluid, most commonly density and gravity (see buoy ...
as the primary heat transport contribution, while conduction and radiative heat transfer are considered negligible. As a result, the lower mantle's temperature gradient as a function of depth is approximately adiabatic. Calculation of the geothermal gradient observed a decrease from at the uppermost lower mantle to at .


Composition

The lower mantle is mainly composed of three components, bridgmanite, ferropericlase, and calcium-silicate perovskite (CaSiO3-perovskite). The proportion of each component has been a subject of discussion historically where the bulk composition is suggested to be, * Pyrolitic: derived from petrological composition trends from
upper mantle The upper mantle of Earth is a very thick layer of rock inside the planet, which begins just beneath the crust (geology), crust (at about under the oceans and about under the continents) and ends at the top of the lower mantle (Earth), lower man ...
peridotite Peridotite ( ) is a dense, coarse-grained igneous rock consisting mostly of the silicate minerals olivine and pyroxene. Peridotite is ultramafic, as the rock contains less than 45% silica. It is high in magnesium (Mg2+), reflecting the high pr ...
suggesting homogeneity between the upper and lower mantle with a Mg/Si ratio of 1.27. This model implies that the lower mantle is composed of 75% bridgmanite, 17% ferropericlase, and 8% CaSiO3-perovskite by volume. * Chondritic: suggests that the Earth's lower mantle was accreted from the composition of
chondritic meteorite A chondrite is a stony (non-metallic) meteorite that has not been modified by either melting or differentiation of the parent body. They are formed when various types of dust and small grains in the early Solar System accreted to form primit ...
suggesting a Mg/Si ratio of approximately 1. This infers that bridgmanite and CaSiO3-perovskites are major components. Laboratory multi-anvil compression experiments of
pyrolite Pyrolite is a term used to characterize a model composition of the Earth's Upper mantle (Earth), mantle. This model is based on that a pyrolite source can produce mid-ocean ridge basalts (MORB) by partial melting. It was first proposed by Ted Ringwo ...
simulated conditions of the adiabatic geotherm and measured the density using ''in situ''
X-ray diffraction X-ray diffraction is a generic term for phenomena associated with changes in the direction of X-ray beams due to interactions with the electrons around atoms. It occurs due to elastic scattering, when there is no change in the energy of the waves. ...
. It was shown that the density profile along the geotherm is in agreement with the PREM model. The first principle calculation of the density and velocity profile across the lower mantle geotherm of varying bridgmanite and ferropericlase proportion observed a match to the PREM model at an 8:2 proportion. This proportion is consistent with the pyrolitic bulk composition at the lower mantle. Furthermore, shear wave velocity calculations of pyrolitic lower mantle compositions considering minor elements resulted in a match with the PREM shear velocity profile within 1%. On the other hand, Brillouin spectroscopic studies at relevant pressures and temperatures revealed that a lower mantle composed of greater than 93% bridgmanite phase has corresponding shear-wave velocities to measured seismic velocities. The suggested composition is consistent with a chondritic lower mantle. Thus, the bulk composition of the lower mantle is currently a subject of discussion.


Spin transition zone

The electronic environment of two iron-bearing minerals in the lower mantle (bridgmanite, ferropericlase) transitions from a high-spin (HS) to a low-spin (LS) state. Fe2+ in ferropericlase undergoes the transition between 50–90 GPa. Bridgmanite contains both Fe3+ and Fe2+ in the structure, the Fe2+ occupy the A-site and transition to a LS state at 120 GPa. While Fe3+ occupies both A- and B-sites, the B-site Fe3+ undergoes HS to LS transition at 30–70 GPa while the A-site Fe3+ exchanges with the B-site Al3+ cation and becomes LS. This spin transition of the iron cation results in the increase in
partition coefficient In the physical sciences, a partition coefficient (''P'') or distribution coefficient (''D'') is the ratio of concentrations of a chemical compound, compound in a mixture of two immiscible solvents at partition equilibrium, equilibrium. This rati ...
between ferropericlase and bridgmanite to 10–14 depleting bridgmanite and enriching ferropericlase of Fe2+. The HS to LS transition are reported to affect the physical properties of the iron bearing minerals. For example, the density and incompressibility was reported to increase from HS to LS state in ferropericlase. The effects of the spin transition on the transport properties and
rheology Rheology (; ) is the study of the flow of matter, primarily in a fluid (liquid or gas) state but also as "soft solids" or solids under conditions in which they respond with plastic flow rather than deforming elastically in response to an applie ...
of the lower mantle is currently being investigated and discussed using numerical simulations.


History

Mesosphere (not to be confused with
mesosphere The mesosphere (; ) is the third layer of the atmosphere, directly above the stratosphere and directly below the thermosphere. In the mesosphere, temperature decreases as altitude increases. This characteristic is used to define limits: it be ...
, a layer of the
atmosphere An atmosphere () is a layer of gases that envelop an astronomical object, held in place by the gravity of the object. A planet retains an atmosphere when the gravity is great and the temperature of the atmosphere is low. A stellar atmosph ...
) is derived from "mesospheric shell", coined by
Reginald Aldworth Daly Reginald Aldworth Daly (May 19, 1871 – September 19, 1957) was a Canadian geologist. He is best known for being one of the first proponents of the giant-impact hypothesis of the formation of the Moon. Biography Reginald Daly was educated at th ...
, a
Harvard University Harvard University is a Private university, private Ivy League research university in Cambridge, Massachusetts, United States. Founded in 1636 and named for its first benefactor, the History of the Puritans in North America, Puritan clergyma ...
geology Geology (). is a branch of natural science concerned with the Earth and other astronomical objects, the rocks of which they are composed, and the processes by which they change over time. Modern geology significantly overlaps all other Earth ...
professor. In the pre-
plate tectonics Plate tectonics (, ) is the scientific theory that the Earth's lithosphere comprises a number of large tectonic plates, which have been slowly moving since 3–4 billion years ago. The model builds on the concept of , an idea developed durin ...
era, Daly (1940) inferred that the outer Earth consisted of three
spherical A sphere (from Ancient Greek, Greek , ) is a surface (mathematics), surface analogous to the circle, a curve. In solid geometry, a sphere is the Locus (mathematics), set of points that are all at the same distance from a given point in three ...
layers:
lithosphere A lithosphere () is the rigid, outermost rocky shell of a terrestrial planet or natural satellite. On Earth, it is composed of the crust and the lithospheric mantle, the topmost portion of the upper mantle that behaves elastically on time ...
(including the crust), asthenosphere, and mesospheric shell. Daly's hypothetical depths to the lithosphere-asthenosphere boundary ranged from , and the top of the mesospheric shell (base of the asthenosphere) were from . Thus, Daly's asthenosphere was inferred to be thick. According to Daly, the base of the solid Earth mesosphere could extend to the base of the mantle (and, thus, to the top of the
core Core or cores may refer to: Science and technology * Core (anatomy), everything except the appendages * Core (laboratory), a highly specialized shared research resource * Core (manufacturing), used in casting and molding * Core (optical fiber ...
). A derivative term, mesoplates, was introduced as a
heuristic A heuristic or heuristic technique (''problem solving'', '' mental shortcut'', ''rule of thumb'') is any approach to problem solving that employs a pragmatic method that is not fully optimized, perfected, or rationalized, but is nevertheless ...
, based on a combination of "mesosphere" and "plate", for postulated reference frames in which mantle
hotspots Hotspot, Hot Spot or Hot spot may refer to: Places * Hot Spot, Kentucky, a community in the United States Arts, entertainment, and media Fictional entities * Hot Spot (comics), a name for the DC Comics character Isaiah Crockett * Hot Spot (Tr ...
exist.


See also

*
Large low-shear-velocity provinces Large low-shear-velocity provinces (LLSVPs), also called large low-velocity provinces (LLVPs) or superplumes, are characteristic structures of parts of the lowermost mantle, the region surrounding the outer core deep inside the Earth. These provi ...


References

{{Earthsinterior Earth's mantle Structure of the Earth