Silicate Perovskite
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Silicate Perovskite
Silicate perovskite is either (the magnesium end-member is called bridgmanite) or (calcium silicate known as davemaoite) when arranged in a perovskite structure. Silicate perovskites are not stable at Earth's surface, and mainly exist in the lower part of Earth's mantle, between about depth. They are thought to form the main mineral phases of the lower mantle, together with ferropericlase. Discovery The existence of silicate perovskite in the mantle was first suggested in 1962, and both and had been synthesized experimentally before 1975. By the late 1970s, it had been proposed that the seismic discontinuity at about 660 km in the mantle represented a change from spinel structure minerals with an olivine composition to silicate perovskite with ferropericlase. Natural silicate perovskite was discovered in the heavily shocked Tenham meteorite. In 2014, the Commission on New Minerals, Nomenclature and Classification (CNMNC) of the International Mineralogical Associ ...
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Mindat
Mindat may refer to: Places * Mindat District, a district in Chin State, Myanmar (Burma), consisting of two townships and many villages ** Mindat Township, Myanmar *** Mindat, Chin State, a town in Chin State, Myanmar, administrative seat of Mindat Township Other uses * Mindat, alternative name for the Kʼchò language in Myanmar * Mindat Min, a Burmese prince * Mindat.org, an online mineralogy database {{dab, geo ...
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Iron(II) Oxide
Iron(II) oxide or ferrous oxide is the inorganic compound with the formula FeO. Its mineral form is known as wüstite. One of several iron oxides, it is a black-colored powder that is sometimes confused with rust, the latter of which consists of hydrated iron(III) oxide (ferric oxide). Iron(II) oxide also refers to a family of related non-stoichiometric compounds, which are typically iron deficient with compositions ranging from Fe0.84O to Fe0.95O. Preparation FeO can be prepared by the thermal decomposition of iron(II) oxalate. : The procedure is conducted under an inert atmosphere to avoid the formation of iron(III) oxide (). A similar procedure can also be used for the synthesis of manganous oxide and stannous oxide. Stoichiometric FeO can be prepared by heating Fe0.95O with metallic iron at 770 °C and 36 kbar.Wells A.F. (1984) ''Structural Inorganic Chemistry'' 5th edition Oxford University Press Reactions FeO is thermodynamically unstable below 575  ...
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Harzburgite
Harzburgite, an ultramafic, igneous rock, is a variety of peridotite consisting mostly of the two minerals olivine and low-calcium (Ca) pyroxene ( enstatite); it is named for occurrences in the Harz Mountains of Germany. It commonly contains a few percent chromium-rich spinel as an accessory mineral. Garnet-bearing harzburgite is much less common, found most commonly as xenoliths in kimberlite. Harzburgite typically forms by the extraction of partial melts from the more pyroxene-rich peridotite called lherzolite. The molten magma extracted from harzburgite may then erupt on the surface as basalt. If partial melting of the harzburgite continues, all of the pyroxene may be extracted from it to form magma, leaving behind the pyroxene-poor peridotite called dunite. Harzburgite may also form by the accumulation of olivine and low-Ca pyroxene in large magma chambers of basalt deep in continental crust (layered intrusions). Occurrence Harzburgite is the most commonly found variet ...
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Pyrolite
Pyrolite is a term used to characterize a model composition of the Earth's Upper mantle (Earth), mantle. This model is based on that a pyrolite source can produce mid-ocean ridge basalts (MORB) by partial melting. It was first proposed by Ted Ringwood (1962) as being 1 part basalt and 4 parts harzburgite, but later was revised to being 1 part tholeiitic basalt and 3 parts dunite. The term is derived from the mineral names Pyroxene, PYR-oxene and Olivine, OL-ivine. However, whether pyrolite is entirely representative of the Earth's mantle remains debated. Chemical composition and phase transition The major elements composition of pyrolite is about 44.71 molar percent (mol%) SiO2, 3.98 % Al2O3, 8.18 % FeO, 3.17 % CaO, 38.73 % MgO, 0.13 % Na2O. 1) A pyrolitic Upper mantle (Earth), Upper Mantle is mainly composed of olivine (~60 volume percent (vol%)), clinopyroxene, orthopyroxene, and garnet. Pyroxene would gradually dissolved into garnet and form Majorite, majoritic garnet. 2) A ...
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Lithology
The lithology of a rock unit is a description of its physical characteristics visible at outcrop, in hand or core samples, or with low magnification microscopy. Physical characteristics include colour, texture, grain size, and composition. Lithology may refer to either a detailed description of these characteristics, or a summary of the gross physical character of a rock. Examples of lithologies in the second sense include sandstone, slate, basalt, or limestone. Lithology is the basis of subdividing rock sequences into individual lithostratigraphic units for the purposes of mapping and correlation between areas. In certain applications, such as site investigations, lithology is described using a standard terminology such as in the European geotechnical standard Eurocode 7. Rock type The naming of a lithology is based on the rock type. The three major rock types are igneous, sedimentary, and metamorphic. Igneous rocks are formed directly from magma, which is a mixture o ...
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Post-perovskite
Post-perovskite (pPv) is a high-pressure phase of magnesium silicate (MgSiO3). It is composed of the prime oxide constituents of the Earth's rocky mantle (MgO and SiO2), and its pressure and temperature for stability imply that it is likely to occur in portions of the lowermost few hundred km of Earth's mantle. The post-perovskite phase has implications for the ''D''′′ layer, which influences the convective mixing in the mantle responsible for plate tectonics. Post-perovskite has the same crystal structure as the synthetic solid compound CaIrO3, and is often referred to as the "CaIrO3-type phase of MgSiO3" in the literature. The crystal system of post-perovskite is orthorhombic, its space group is ''Cmcm'', and its structure is a stacked SiO6-octahedral sheet along the ''b'' axis. The name "post-perovskite" derives from silicate perovskite, the stable phase of MgSiO3 throughout most of Earth's mantle, which has the perovskite structure. The prefix "post-" refers to the fa ...
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Transition Zone (Earth)
The transition zone is the part of Earth's mantle that is located between the lower and the upper mantle, most strictly between the seismic-discontinuity depths of about , but more broadly defined as the zone encompassing those discontinuities, i.e., between about depth. Earth's solid, rocky mantle, including the mantle transition zone (often abbreviated as MTZ), consists primarily of peridotite, an ultramafic igneous rock. The mantle was divided into the upper mantle, transition zone, and lower mantle as a result of sudden seismic-velocity discontinuities at depths of . This is thought to occur as a result of rearrangement of grains in olivine (which constitutes a large portion of peridotite) at a depth of , to form a denser crystal structure as a result of the increase in pressure with increasing depth. Below a depth of , evidence suggests due to pressure changes ringwoodite minerals change into two new denser phases, bridgmanite and periclase. This can be seen usi ...
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Ringwoodite
Ringwoodite is a high-pressure phase of Mg2SiO4 (magnesium silicate) formed at high temperatures and pressures of the Earth's mantle between depth. It may also contain iron and hydrogen. It is polymorphous with the olivine phase forsterite (a magnesium iron silicate). Ringwoodite is notable for being able to contain hydroxide ions within its structure. In this case two hydroxide ions usually take the place of a magnesium ion and two oxide ions. Combined with evidence of its occurrence deep in the Earth's mantle, this suggests that there is from one to three times the world ocean's equivalent of water in the mantle transition zone from 410 to 660 km deep. This mineral was first identified in the Tenham meteorite in 1969, and is inferred to be present in large quantities in the Earth's mantle. Olivine, wadsleyite, and ringwoodite are polymorphs found in the upper mantle of the earth. At depths greater than about , other minerals, including some with the perovskite st ...
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Earth
Earth is the third planet from the Sun and the only astronomical object known to Planetary habitability, harbor life. This is enabled by Earth being an ocean world, the only one in the Solar System sustaining liquid surface water. Almost all of Earth's water is contained in its global ocean, covering Water distribution on Earth, 70.8% of Earth's crust. The remaining 29.2% of Earth's crust is land, most of which is located in the form of continental landmasses within Earth's land hemisphere. Most of Earth's land is at least somewhat humid and covered by vegetation, while large Ice sheet, sheets of ice at Polar regions of Earth, Earth's polar polar desert, deserts retain more water than Earth's groundwater, lakes, rivers, and Water vapor#In Earth's atmosphere, atmospheric water combined. Earth's crust consists of slowly moving tectonic plates, which interact to produce mountain ranges, volcanoes, and earthquakes. Earth's outer core, Earth has a liquid outer core that generates a ...
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Enstatite
Enstatite is a mineral; the magnesium endmember of the pyroxene silicate mineral series enstatite (MgSiO3) – ferrosilite (FeSiO3). The magnesium rich members of the solid solution series are common rock-forming minerals found in igneous and metamorphic rocks. The intermediate composition, , has historically been known as hypersthene, although this name has been formally abandoned and replaced by orthopyroxene. When determined petrographically or chemically the composition is given as relative proportions of enstatite (En) and ferrosilite (Fs) (e.g., En80Fs20). Polymorphs and varieties Most natural crystals are orthorhombic (space group P''bca'') although three polymorphs are known. The high temperature, low pressure polymorphs are protoenstatite and protoferrosilite (also orthorhombic, space group P''bcn'') while the low temperature forms, clinoenstatite and clinoferrosilite, are monoclinic (space group P2''1/c''). Weathered enstatite with a small amount of iron takes o ...
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Orthorhombic Crystal System
In crystallography, the orthorhombic crystal system is one of the 7 crystal systems. Orthorhombic lattices result from stretching a cubic lattice along two of its orthogonal pairs by two different factors, resulting in a rectangular prism with a rectangular base (''a'' by ''b'') and height (''c''), such that ''a'', ''b'', and ''c'' are distinct. All three bases intersect at 90° angles, so the three lattice vectors remain mutually orthogonal In mathematics, orthogonality (mathematics), orthogonality is the generalization of the geometric notion of ''perpendicularity''. Although many authors use the two terms ''perpendicular'' and ''orthogonal'' interchangeably, the term ''perpendic .... Bravais lattices There are four orthorhombic Bravais lattices: primitive orthorhombic, base-centered orthorhombic, body-centered orthorhombic, and face-centered orthorhombic. For the base-centered orthorhombic lattice, the primitive cell has the shape of a right rhombic prism;See , ro ...
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Aluminium
Aluminium (or aluminum in North American English) is a chemical element; it has chemical symbol, symbol Al and atomic number 13. It has a density lower than that of other common metals, about one-third that of steel. Aluminium has a great affinity towards oxygen, passivation (chemistry), forming a protective layer of aluminium oxide, oxide on the surface when exposed to air. It visually resembles silver, both in its color and in its great ability to reflect light. It is soft, magnetism, nonmagnetic, and ductility, ductile. It has one stable isotope, 27Al, which is highly abundant, making aluminium the abundance of the chemical elements, 12th-most abundant element in the universe. The radioactive decay, radioactivity of aluminium-26, 26Al leads to it being used in radiometric dating. Chemically, aluminium is a post-transition metal in the boron group; as is common for the group, aluminium forms compounds primarily in the +3 oxidation state. The aluminium cation Al3+ ...
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