Laws Of Science
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Scientific laws or laws of science are statements, based on repeated
experiment An experiment is a procedure carried out to support or refute a hypothesis, or determine the efficacy or likelihood of something previously untried. Experiments provide insight into cause-and-effect by demonstrating what outcome occurs whe ...
s or
observation Observation in the natural sciences is an act or instance of noticing or perceiving and the acquisition of information from a primary source. In living beings, observation employs the senses. In science, observation can also involve the percep ...
s, that describe or predict a range of natural phenomena. The term ''law'' has diverse usage in many cases (approximate, accurate, broad, or narrow) across all fields of
natural science Natural science or empirical science is one of the branches of science concerned with the description, understanding and prediction of natural phenomena, based on empirical evidence from observation and experimentation. Mechanisms such as peer ...
(
physics Physics is the scientific study of matter, its Elementary particle, fundamental constituents, its motion and behavior through space and time, and the related entities of energy and force. "Physical science is that department of knowledge whi ...
,
chemistry Chemistry is the scientific study of the properties and behavior of matter. It is a physical science within the natural sciences that studies the chemical elements that make up matter and chemical compound, compounds made of atoms, molecules a ...
,
astronomy Astronomy is a natural science that studies celestial objects and the phenomena that occur in the cosmos. It uses mathematics, physics, and chemistry in order to explain their origin and their overall evolution. Objects of interest includ ...
,
geoscience Earth science or geoscience includes all fields of natural science related to the planet Earth. This is a branch of science dealing with the physical, chemical, and biological complex constitutions and synergistic linkages of Earth's four spheres ...
,
biology Biology is the scientific study of life and living organisms. It is a broad natural science that encompasses a wide range of fields and unifying principles that explain the structure, function, growth, History of life, origin, evolution, and ...
). Laws are developed from data and can be further developed through
mathematics Mathematics is a field of study that discovers and organizes methods, Mathematical theory, theories and theorems that are developed and Mathematical proof, proved for the needs of empirical sciences and mathematics itself. There are many ar ...
; in all cases they are directly or indirectly based on
empirical evidence Empirical evidence is evidence obtained through sense experience or experimental procedure. It is of central importance to the sciences and plays a role in various other fields, like epistemology and law. There is no general agreement on how the ...
. It is generally understood that they implicitly reflect, though they do not explicitly assert, causal relationships fundamental to reality, and are discovered rather than invented. Scientific laws summarize the results of experiments or observations, usually within a certain range of application. In general, the accuracy of a law does not change when a new theory of the relevant phenomenon is worked out, but rather the scope of the law's application, since the mathematics or statement representing the law does not change. As with other kinds of scientific knowledge, scientific laws do not express absolute certainty, as mathematical laws do. A scientific law may be contradicted, restricted, or extended by future observations. A law can often be formulated as one or several statements or
equation In mathematics, an equation is a mathematical formula that expresses the equality of two expressions, by connecting them with the equals sign . The word ''equation'' and its cognates in other languages may have subtly different meanings; for ...
s, so that it can predict the outcome of an experiment. Laws differ from
hypotheses A hypothesis (: hypotheses) is a proposed explanation for a phenomenon. A scientific method, scientific hypothesis must be based on observations and make a testable and reproducible prediction about reality, in a process beginning with an educ ...
and postulates, which are proposed during the scientific process before and during validation by experiment and observation. Hypotheses and postulates are not laws, since they have not been verified to the same degree, although they may lead to the formulation of laws. Laws are narrower in scope than scientific theories, which may entail one or several laws. Science distinguishes a law or theory from facts. Calling a law a
fact A fact is a truth, true data, datum about one or more aspects of a circumstance. Standard reference works are often used to Fact-checking, check facts. Science, Scientific facts are verified by repeatable careful observation or measurement by ...
is ambiguous, an
overstatement Hyperbole (; adj. hyperbolic ) is the use of exaggeration as a rhetorical device or figure of speech. In rhetoric, it is also sometimes known as auxesis (literally 'growth'). In poetry and oratory, it emphasizes, evokes strong feelings, and cre ...
, or an
equivocation In logic, equivocation ("calling two different things by the same name") is an informal fallacy resulting from the use of a particular word or expression in multiple senses within an argument. It is a type of ambiguity that stems from a phrase ...
. The nature of scientific laws has been much discussed in
philosophy Philosophy ('love of wisdom' in Ancient Greek) is a systematic study of general and fundamental questions concerning topics like existence, reason, knowledge, Value (ethics and social sciences), value, mind, and language. It is a rational an ...
, but in essence scientific laws are simply empirical conclusions reached by the scientific method; they are intended to be neither laden with
ontological Ontology is the philosophical study of being. It is traditionally understood as the subdiscipline of metaphysics focused on the most general features of reality. As one of the most fundamental concepts, being encompasses all of reality and every ...
commitments nor statements of logical absolutes.
Social science Social science (often rendered in the plural as the social sciences) is one of the branches of science, devoted to the study of societies and the relationships among members within those societies. The term was formerly used to refer to the ...
s such as
economics Economics () is a behavioral science that studies the Production (economics), production, distribution (economics), distribution, and Consumption (economics), consumption of goods and services. Economics focuses on the behaviour and interac ...
have also attempted to formulate scientific laws, though these generally have much less predictive power.


Overview

A scientific law always applies to a
physical system A physical system is a collection of physical objects under study. The collection differs from a set: all the objects must coexist and have some physical relationship. In other words, it is a portion of the physical universe chosen for analys ...
under repeated conditions, and it implies that there is a causal relationship involving the elements of the system. Factual and well-confirmed statements like "Mercury is liquid at standard temperature and pressure" are considered too specific to qualify as scientific laws. A central problem in the
philosophy of science Philosophy of science is the branch of philosophy concerned with the foundations, methods, and implications of science. Amongst its central questions are the difference between science and non-science, the reliability of scientific theories, ...
, going back to
David Hume David Hume (; born David Home; – 25 August 1776) was a Scottish philosopher, historian, economist, and essayist who was best known for his highly influential system of empiricism, philosophical scepticism and metaphysical naturalism. Beg ...
, is that of distinguishing causal relationships (such as those implied by laws) from principles that arise due to
constant conjunction In philosophy, constant conjunction is a relationship between two events, where one event is invariably followed by the other: if the occurrence of A is always followed by B, A and B are said to be ''constantly conjoined''. A critical philosophic ...
. Laws differ from scientific theories in that they do not posit a mechanism or explanation of phenomena: they are merely distillations of the results of repeated observation. As such, the applicability of a law is limited to circumstances resembling those already observed, and the law may be found to be false when extrapolated.
Ohm's law Ohm's law states that the electric current through a Electrical conductor, conductor between two Node (circuits), points is directly Proportionality (mathematics), proportional to the voltage across the two points. Introducing the constant of ...
only applies to linear networks;
Newton's law of universal gravitation Newton's law of universal gravitation describes gravity as a force by stating that every particle attracts every other particle in the universe with a force that is Proportionality (mathematics)#Direct proportionality, proportional to the product ...
only applies in weak gravitational fields; the early laws of
aerodynamics Aerodynamics () is the study of the motion of atmosphere of Earth, air, particularly when affected by a solid object, such as an airplane wing. It involves topics covered in the field of fluid dynamics and its subfield of gas dynamics, and is an ...
, such as
Bernoulli's principle Bernoulli's principle is a key concept in fluid dynamics that relates pressure, speed and height. For example, for a fluid flowing horizontally Bernoulli's principle states that an increase in the speed occurs simultaneously with a decrease i ...
, do not apply in the case of
compressible flow Compressible flow (or gas dynamics) is the branch of fluid mechanics that deals with flows having significant changes in fluid density. While all flows are compressibility, compressible, flows are usually treated as being incompressible flow, incom ...
such as occurs in
transonic Transonic (or transsonic) flow is air flowing around an object at a speed that generates regions of both subsonic and Supersonic speed, supersonic airflow around that object. The exact range of speeds depends on the object's critical Mach numb ...
and
supersonic Supersonic speed is the speed of an object that exceeds the speed of sound (Mach 1). For objects traveling in dry air of a temperature of 20 °C (68 °F) at sea level, this speed is approximately . Speeds greater than five times ...
flight;
Hooke's law In physics, Hooke's law is an empirical law which states that the force () needed to extend or compress a spring by some distance () scales linearly with respect to that distance—that is, where is a constant factor characteristic of ...
only applies to strain below the
elastic limit In materials science and engineering, the yield point is the point on a stress–strain curve that indicates the limit of elastic behavior and the beginning of plastic behavior. Below the yield point, a material will deform elastically and w ...
;
Boyle's law Boyle's law, also referred to as the Boyle–Mariotte law or Mariotte's law (especially in France), is an empirical gas laws, gas law that describes the relationship between pressure and volume of a confined gas. Boyle's law has been stated as: ...
applies with perfect accuracy only to the ideal gas, etc. These laws remain useful, but only under the specified conditions where they apply. Many laws take
mathematical Mathematics is a field of study that discovers and organizes methods, Mathematical theory, theories and theorems that are developed and Mathematical proof, proved for the needs of empirical sciences and mathematics itself. There are many ar ...
forms, and thus can be stated as an equation; for example, the law of conservation of energy can be written as \Delta E = 0, where E is the total amount of energy in the universe. Similarly, the
first law of thermodynamics The first law of thermodynamics is a formulation of the law of conservation of energy in the context of thermodynamic processes. For a thermodynamic process affecting a thermodynamic system without transfer of matter, the law distinguishes two ...
can be written as \mathrmU=\delta Q-\delta W\,, and
Newton's second law Newton's laws of motion are three physical laws that describe the relationship between the motion of an object and the forces acting on it. These laws, which provide the basis for Newtonian mechanics, can be paraphrased as follows: # A body re ...
can be written as \textstyle F = \frac. While these scientific laws explain what our senses perceive, they are still empirical (acquired by observation or scientific experiment) and so are not like mathematical theorems which can be proved purely by mathematics. Like theories and hypotheses, laws make predictions; specifically, they predict that new observations will conform to the given law. Laws can be falsified if they are found in contradiction with new data. Some laws are only approximations of other more general laws, and are good approximations with a restricted domain of applicability. For example, Newtonian dynamics (which is based on Galilean transformations) is the low-speed limit of special relativity (since the Galilean transformation is the low-speed approximation to the Lorentz transformation). Similarly, the Newtonian gravitation law is a low-mass approximation of general relativity, and
Coulomb's law Coulomb's inverse-square law, or simply Coulomb's law, is an experimental scientific law, law of physics that calculates the amount of force (physics), force between two electric charge, electrically charged particles at rest. This electric for ...
is an approximation to quantum electrodynamics at large distances (compared to the range of weak interactions). In such cases it is common to use the simpler, approximate versions of the laws, instead of the more accurate general laws. Laws are constantly being tested experimentally to increasing degrees of precision, which is one of the main goals of science. The fact that laws have never been observed to be violated does not preclude testing them at increased accuracy or in new kinds of conditions to confirm whether they continue to hold, or whether they break, and what can be discovered in the process. It is always possible for laws to be invalidated or proven to have limitations, by repeatable experimental evidence, should any be observed. Well-established laws have indeed been invalidated in some special cases, but the new formulations created to explain the discrepancies generalize upon, rather than overthrow, the originals. That is, the invalidated laws have been found to be only close approximations, to which other terms or factors must be added to cover previously unaccounted-for conditions, e.g. very large or very small scales of time or space, enormous speeds or masses, etc. This, rather than unchanging knowledge, physical laws are better viewed as a series of improving and more precise generalizations.


Properties

Scientific laws are typically conclusions based on repeated scientific
experiment An experiment is a procedure carried out to support or refute a hypothesis, or determine the efficacy or likelihood of something previously untried. Experiments provide insight into cause-and-effect by demonstrating what outcome occurs whe ...
s and observations over many years and which have become accepted universally within the
scientific community The scientific community is a diverse network of interacting scientists. It includes many "working group, sub-communities" working on particular scientific fields, and within particular institutions; interdisciplinary and cross-institutional acti ...
. A scientific law is " inferred from particular facts, applicable to a defined group or class of
phenomena A phenomenon ( phenomena), sometimes spelled phaenomenon, is an observable Event (philosophy), event. The term came into its modern Philosophy, philosophical usage through Immanuel Kant, who contrasted it with the noumenon, which ''cannot'' be ...
, and expressible by the statement that a particular phenomenon always occurs if certain conditions be present". The production of a summary description of our environment in the form of such laws is a fundamental aim of
science Science is a systematic discipline that builds and organises knowledge in the form of testable hypotheses and predictions about the universe. Modern science is typically divided into twoor threemajor branches: the natural sciences, which stu ...
. Several general properties of scientific laws, particularly when referring to laws in
physics Physics is the scientific study of matter, its Elementary particle, fundamental constituents, its motion and behavior through space and time, and the related entities of energy and force. "Physical science is that department of knowledge whi ...
, have been identified. Scientific laws are: * True, at least within their regime of validity. By definition, there have never been repeatable contradicting observations. * Universal. They appear to apply everywhere in the universe. * Simple. They are typically expressed in terms of a single mathematical equation. * Absolute. Nothing in the universe appears to affect them. * Stable. Unchanged since first discovered (although they may have been shown to be approximations of more accurate laws), * All-encompassing. Everything in the universe apparently must comply with them (according to observations). * Generally
conservative Conservatism is a cultural, social, and political philosophy and ideology that seeks to promote and preserve traditional institutions, customs, and values. The central tenets of conservatism may vary in relation to the culture and civiliza ...
of quantity. * Often expressions of existing homogeneities ( symmetries) of
space Space is a three-dimensional continuum containing positions and directions. In classical physics, physical space is often conceived in three linear dimensions. Modern physicists usually consider it, with time, to be part of a boundless ...
and time. * Typically theoretically reversible in time (if non-
quantum In physics, a quantum (: quanta) is the minimum amount of any physical entity (physical property) involved in an interaction. The fundamental notion that a property can be "quantized" is referred to as "the hypothesis of quantization". This me ...
), although time itself is irreversible. * Broad. In physics, laws exclusively refer to the broad domain of matter, motion, energy, and force itself, rather than more specific
systems A system is a group of interacting or interrelated elements that act according to a set of rules to form a unified whole. A system, surrounded and influenced by its environment, is described by its boundaries, structure and purpose and is exp ...
in the universe, such as living systems, e.g. the
mechanics Mechanics () is the area of physics concerned with the relationships between force, matter, and motion among Physical object, physical objects. Forces applied to objects may result in Displacement (vector), displacements, which are changes of ...
of the
human body The human body is the entire structure of a Human, human being. It is composed of many different types of Cell (biology), cells that together create Tissue (biology), tissues and subsequently Organ (biology), organs and then Organ system, org ...
. The term "scientific law" is traditionally associated with the
natural sciences Natural science or empirical science is one of the branches of science concerned with the description, understanding and prediction of natural phenomena, based on empirical evidence from observation and experimentation. Mechanisms such as peer ...
, though the
social sciences Social science (often rendered in the plural as the social sciences) is one of the branches of science, devoted to the study of society, societies and the Social relation, relationships among members within those societies. The term was former ...
also contain laws. For example, Zipf's law is a law in the social sciences which is based on
mathematical statistics Mathematical statistics is the application of probability theory and other mathematical concepts to statistics, as opposed to techniques for collecting statistical data. Specific mathematical techniques that are commonly used in statistics inc ...
. In these cases, laws may describe general trends or expected behaviors rather than being absolutes. In natural science, impossibility assertions come to be widely accepted as overwhelmingly probable rather than considered proved to the point of being unchallengeable. The basis for this strong acceptance is a combination of extensive evidence of something not occurring, combined with an underlying
theory A theory is a systematic and rational form of abstract thinking about a phenomenon, or the conclusions derived from such thinking. It involves contemplative and logical reasoning, often supported by processes such as observation, experimentation, ...
, very successful in making predictions, whose assumptions lead logically to the conclusion that something is impossible. While an impossibility assertion in natural science can never be absolutely proved, it could be refuted by the observation of a single
counterexample A counterexample is any exception to a generalization. In logic a counterexample disproves the generalization, and does so rigorously in the fields of mathematics and philosophy. For example, the fact that "student John Smith is not lazy" is a c ...
. Such a counterexample would require that the assumptions underlying the theory that implied the impossibility be re-examined. Some examples of widely accepted impossibilities in
physics Physics is the scientific study of matter, its Elementary particle, fundamental constituents, its motion and behavior through space and time, and the related entities of energy and force. "Physical science is that department of knowledge whi ...
are perpetual motion machines, which violate the law of conservation of energy, exceeding the
speed of light The speed of light in vacuum, commonly denoted , is a universal physical constant exactly equal to ). It is exact because, by international agreement, a metre is defined as the length of the path travelled by light in vacuum during a time i ...
, which violates the implications of
special relativity In physics, the special theory of relativity, or special relativity for short, is a scientific theory of the relationship between Spacetime, space and time. In Albert Einstein's 1905 paper, Annus Mirabilis papers#Special relativity, "On the Ele ...
, the
uncertainty principle The uncertainty principle, also known as Heisenberg's indeterminacy principle, is a fundamental concept in quantum mechanics. It states that there is a limit to the precision with which certain pairs of physical properties, such as position a ...
of
quantum mechanics Quantum mechanics is the fundamental physical Scientific theory, theory that describes the behavior of matter and of light; its unusual characteristics typically occur at and below the scale of atoms. Reprinted, Addison-Wesley, 1989, It is ...
, which asserts the impossibility of simultaneously knowing both the position and the momentum of a particle, and
Bell's theorem Bell's theorem is a term encompassing a number of closely related results in physics, all of which determine that quantum mechanics is incompatible with local hidden-variable theories, given some basic assumptions about the nature of measuremen ...
: no physical theory of local hidden variables can ever reproduce all of the predictions of quantum mechanics.


Laws as consequences of mathematical symmetries

Some laws reflect mathematical symmetries found in nature (e.g. the Pauli exclusion principle reflects identity of electrons, conservation laws reflect
homogeneity Homogeneity and heterogeneity are concepts relating to the Uniformity (chemistry), uniformity of a Chemical substance, substance, process or image. A homogeneous feature is uniform in composition or character (i.e., color, shape, size, weight, ...
of
space Space is a three-dimensional continuum containing positions and directions. In classical physics, physical space is often conceived in three linear dimensions. Modern physicists usually consider it, with time, to be part of a boundless ...
, time, and
Lorentz transformations In physics, the Lorentz transformations are a six-parameter family of linear transformations from a coordinate frame in spacetime to another frame that moves at a constant velocity relative to the former. The respective inverse transformation ...
reflect rotational symmetry of
spacetime In physics, spacetime, also called the space-time continuum, is a mathematical model that fuses the three dimensions of space and the one dimension of time into a single four-dimensional continuum. Spacetime diagrams are useful in visualiz ...
). Many fundamental physical laws are mathematical consequences of various symmetries of space, time, or other aspects of nature. Specifically,
Noether's theorem Noether's theorem states that every continuous symmetry of the action of a physical system with conservative forces has a corresponding conservation law. This is the first of two theorems (see Noether's second theorem) published by the mat ...
connects some conservation laws to certain symmetries. For example, conservation of energy is a consequence of the shift symmetry of time (no moment of time is different from any other), while conservation of momentum is a consequence of the symmetry (homogeneity) of space (no place in space is special, or different from any other). The indistinguishability of all particles of each fundamental type (say, electrons, or photons) results in the Dirac and Bose quantum statistics which in turn result in the Pauli exclusion principle for
fermion In particle physics, a fermion is a subatomic particle that follows Fermi–Dirac statistics. Fermions have a half-integer spin (spin 1/2, spin , Spin (physics)#Higher spins, spin , etc.) and obey the Pauli exclusion principle. These particles i ...
s and in Bose–Einstein condensation for
boson In particle physics, a boson ( ) is a subatomic particle whose spin quantum number has an integer value (0, 1, 2, ...). Bosons form one of the two fundamental classes of subatomic particle, the other being fermions, which have half odd-intege ...
s.
Special relativity In physics, the special theory of relativity, or special relativity for short, is a scientific theory of the relationship between Spacetime, space and time. In Albert Einstein's 1905 paper, Annus Mirabilis papers#Special relativity, "On the Ele ...
uses
rapidity In special relativity, the classical concept of velocity is converted to rapidity to accommodate the limit determined by the speed of light. Velocities must be combined by Einstein's velocity-addition formula. For low speeds, rapidity and velo ...
to express motion according to the symmetries of hyperbolic rotation, a transformation mixing
space Space is a three-dimensional continuum containing positions and directions. In classical physics, physical space is often conceived in three linear dimensions. Modern physicists usually consider it, with time, to be part of a boundless ...
and time. Symmetry between inertial and gravitational
mass Mass is an Intrinsic and extrinsic properties, intrinsic property of a physical body, body. It was traditionally believed to be related to the physical quantity, quantity of matter in a body, until the discovery of the atom and particle physi ...
results in
general relativity General relativity, also known as the general theory of relativity, and as Einstein's theory of gravity, is the differential geometry, geometric theory of gravitation published by Albert Einstein in 1915 and is the current description of grav ...
. The
inverse square law In science, an inverse-square law is any scientific law stating that the observed "intensity" of a specified physical quantity is inversely proportional to the square of the distance from the source of that physical quantity. The fundamental cau ...
of interactions mediated by massless bosons is the mathematical consequence of the 3-dimensionality of
space Space is a three-dimensional continuum containing positions and directions. In classical physics, physical space is often conceived in three linear dimensions. Modern physicists usually consider it, with time, to be part of a boundless ...
. One strategy in the search for the most fundamental laws of nature is to search for the most general mathematical symmetry group that can be applied to the fundamental interactions.


Laws of physics


Conservation laws


Conservation and symmetry

Conservation laws are fundamental laws that follow from the homogeneity of space, time and phase, in other words ''symmetry''. *
Noether's theorem Noether's theorem states that every continuous symmetry of the action of a physical system with conservative forces has a corresponding conservation law. This is the first of two theorems (see Noether's second theorem) published by the mat ...
: Any quantity with a continuously differentiable symmetry in the action has an associated conservation law. *
Conservation of mass In physics and chemistry, the law of conservation of mass or principle of mass conservation states that for any system closed to all transfers of matter the mass of the system must remain constant over time. The law implies that mass can neith ...
was the first law to be understood since most macroscopic physical processes involving masses, for example, collisions of massive particles or fluid flow, provide the apparent belief that mass is conserved. Mass conservation was observed to be true for all chemical reactions. In general, this is only approximative because with the advent of relativity and experiments in nuclear and particle physics: mass can be transformed into energy and vice versa, so mass is not always conserved but part of the more general conservation of mass–energy. *
Conservation of energy The law of conservation of energy states that the total energy of an isolated system remains constant; it is said to be Conservation law, ''conserved'' over time. In the case of a Closed system#In thermodynamics, closed system, the principle s ...
,
momentum In Newtonian mechanics, momentum (: momenta or momentums; more specifically linear momentum or translational momentum) is the product of the mass and velocity of an object. It is a vector quantity, possessing a magnitude and a direction. ...
and
angular momentum Angular momentum (sometimes called moment of momentum or rotational momentum) is the rotational analog of Momentum, linear momentum. It is an important physical quantity because it is a Conservation law, conserved quantity – the total ang ...
for isolated systems can be found to be symmetries in time, translation, and rotation. * Conservation of charge was also realized since charge has never been observed to be created or destroyed and only found to move from place to place.


Continuity and transfer

Conservation laws can be expressed using the general
continuity equation A continuity equation or transport equation is an equation that describes the transport of some quantity. It is particularly simple and powerful when applied to a conserved quantity, but it can be generalized to apply to any extensive quantity ...
(for a conserved quantity) can be written in differential form as: : \frac=-\nabla \cdot \mathbf where ''ρ'' is some quantity per unit volume, J is the
flux Flux describes any effect that appears to pass or travel (whether it actually moves or not) through a surface or substance. Flux is a concept in applied mathematics and vector calculus which has many applications in physics. For transport phe ...
of that quantity (change in quantity per unit time per unit area). Intuitively, the
divergence In vector calculus, divergence is a vector operator that operates on a vector field, producing a scalar field giving the rate that the vector field alters the volume in an infinitesimal neighborhood of each point. (In 2D this "volume" refers to ...
(denoted ∇⋅) of a
vector field In vector calculus and physics, a vector field is an assignment of a vector to each point in a space, most commonly Euclidean space \mathbb^n. A vector field on a plane can be visualized as a collection of arrows with given magnitudes and dire ...
is a measure of flux diverging radially outwards from a point, so the negative is the amount piling up at a point; hence the rate of change of density in a region of space must be the amount of flux leaving or collecting in some region (see the main article for details). In the table below, the fluxes flows for various physical quantities in transport, and their associated continuity equations, are collected for comparison. : More general equations are the convection–diffusion equation and Boltzmann transport equation, which have their roots in the continuity equation.


Laws of classical mechanics


Principle of least action

Classical mechanics, including
Newton's laws Newton's laws of motion are three physical laws that describe the relationship between the motion of an object and the forces acting on it. These laws, which provide the basis for Newtonian mechanics, can be paraphrased as follows: # A body re ...
, Lagrange's equations, Hamilton's equations, etc., can be derived from the following principle: : \delta \mathcal = \delta\int_^ L(\mathbf, \mathbf, t) \, dt = 0 where \mathcal is the action; the integral of the Lagrangian : L(\mathbf, \mathbf, t) = T(\mathbf, t)-V(\mathbf, \mathbf, t) of the physical system between two times ''t''1 and ''t''2. The kinetic energy of the system is ''T'' (a function of the rate of change of the
configuration Configuration or configurations may refer to: Computing * Computer configuration or system configuration * Configuration file, a software file used to configure the initial settings for a computer program * Configurator, also known as choice board ...
of the system), and
potential energy In physics, potential energy is the energy of an object or system due to the body's position relative to other objects, or the configuration of its particles. The energy is equal to the work done against any restoring forces, such as gravity ...
is ''V'' (a function of the configuration and its rate of change). The configuration of a system which has ''N''
degrees of freedom In many scientific fields, the degrees of freedom of a system is the number of parameters of the system that may vary independently. For example, a point in the plane has two degrees of freedom for translation: its two coordinates; a non-infinite ...
is defined by generalized coordinates q = (''q''1, ''q''2, ... ''qN''). There are generalized momenta conjugate to these coordinates, p = (''p''1, ''p''2, ..., ''pN''), where: : p_i = \frac The action and Lagrangian both contain the dynamics of the system for all times. The term "path" simply refers to a curve traced out by the system in terms of the generalized coordinates in the configuration space, i.e. the curve q(''t''), parameterized by time (see also
parametric equation In mathematics, a parametric equation expresses several quantities, such as the coordinates of a point (mathematics), point, as Function (mathematics), functions of one or several variable (mathematics), variables called parameters. In the case ...
for this concept). The action is a '' functional'' rather than a '' function'', since it depends on the Lagrangian, and the Lagrangian depends on the path q(''t''), so the action depends on the ''entire'' "shape" of the path for all times (in the time interval from ''t''1 to ''t''2). Between two instants of time, there are infinitely many paths, but one for which the action is stationary (to the first order) is the true path. The stationary value for the ''entire continuum'' of Lagrangian values corresponding to some path, ''not just one value'' of the Lagrangian, is required (in other words it is ''not'' as simple as "differentiating a function and setting it to zero, then solving the equations to find the points of
maxima and minima In mathematical analysis, the maximum and minimum of a function are, respectively, the greatest and least value taken by the function. Known generically as extremum, they may be defined either within a given range (the ''local'' or ''relative ...
etc", rather this idea is applied to the entire "shape" of the function, see
calculus of variations The calculus of variations (or variational calculus) is a field of mathematical analysis that uses variations, which are small changes in Function (mathematics), functions and functional (mathematics), functionals, to find maxima and minima of f ...
for more details on this procedure). Notice ''L'' is ''not'' the total energy ''E'' of the system due to the difference, rather than the sum: : E=T+V The following general approaches to classical mechanics are summarized below in the order of establishment. They are equivalent formulations. Newton's is commonly used due to simplicity, but Hamilton's and Lagrange's equations are more general, and their range can extend into other branches of physics with suitable modifications. : From the above, any equation of motion in classical mechanics can be derived. Corollaries in mechanics : * Euler's laws of motion * Euler's equations (rigid body dynamics) Corollaries in
fluid mechanics Fluid mechanics is the branch of physics concerned with the mechanics of fluids (liquids, gases, and plasma (physics), plasmas) and the forces on them. Originally applied to water (hydromechanics), it found applications in a wide range of discipl ...
:
Equations describing fluid flow in various situations can be derived, using the above classical equations of motion and often conservation of mass, energy and momentum. Some elementary examples follow. *
Archimedes' principle Archimedes' principle states that the upward buoyant force that is exerted on a body immersed in a fluid, whether fully or partially, is equal to the weight of the fluid that the body displaces. Archimedes' principle is a law of physics fun ...
*
Bernoulli's principle Bernoulli's principle is a key concept in fluid dynamics that relates pressure, speed and height. For example, for a fluid flowing horizontally Bernoulli's principle states that an increase in the speed occurs simultaneously with a decrease i ...
* Poiseuille's law *
Stokes' law In fluid dynamics, Stokes' law gives the frictional force – also called drag force – exerted on spherical objects moving at very small Reynolds numbers in a viscous fluid. It was derived by George Gabriel Stokes in 1851 by solving the S ...
*
Navier–Stokes equations The Navier–Stokes equations ( ) are partial differential equations which describe the motion of viscous fluid substances. They were named after French engineer and physicist Claude-Louis Navier and the Irish physicist and mathematician Georg ...
* Faxén's law


Laws of gravitation and relativity

Some of the more famous laws of nature are found in
Isaac Newton Sir Isaac Newton () was an English polymath active as a mathematician, physicist, astronomer, alchemist, theologian, and author. Newton was a key figure in the Scientific Revolution and the Age of Enlightenment, Enlightenment that followed ...
's theories of (now)
classical mechanics Classical mechanics is a Theoretical physics, physical theory describing the motion of objects such as projectiles, parts of Machine (mechanical), machinery, spacecraft, planets, stars, and galaxies. The development of classical mechanics inv ...
, presented in his ''
Philosophiae Naturalis Principia Mathematica Philosophy ('love of wisdom' in Ancient Greek) is a systematic study of general and fundamental questions concerning topics like existence, reason, knowledge, value, mind, and language. It is a rational and critical inquiry that reflects on ...
'', and in
Albert Einstein Albert Einstein (14 March 187918 April 1955) was a German-born theoretical physicist who is best known for developing the theory of relativity. Einstein also made important contributions to quantum mechanics. His mass–energy equivalence f ...
's
theory of relativity The theory of relativity usually encompasses two interrelated physics theories by Albert Einstein: special relativity and general relativity, proposed and published in 1905 and 1915, respectively. Special relativity applies to all physical ph ...
.


Modern laws

Special relativity In physics, the special theory of relativity, or special relativity for short, is a scientific theory of the relationship between Spacetime, space and time. In Albert Einstein's 1905 paper, Annus Mirabilis papers#Special relativity, "On the Ele ...
:
The two postulates of special relativity are not "laws" in themselves, but assumptions of their nature in terms of ''relative motion''. They can be stated as "the laws of physics are the same in all inertial frames" and "the
speed of light The speed of light in vacuum, commonly denoted , is a universal physical constant exactly equal to ). It is exact because, by international agreement, a metre is defined as the length of the path travelled by light in vacuum during a time i ...
is constant and has the same value in all inertial frames". The said postulates lead to the
Lorentz transformations In physics, the Lorentz transformations are a six-parameter family of linear transformations from a coordinate frame in spacetime to another frame that moves at a constant velocity relative to the former. The respective inverse transformation ...
– the transformation law between two
frame of reference In physics and astronomy, a frame of reference (or reference frame) is an abstract coordinate system, whose origin (mathematics), origin, orientation (geometry), orientation, and scale (geometry), scale have been specified in physical space. It ...
s moving relative to each other. For any 4-vector : A' =\Lambda A this replaces the
Galilean transformation In physics, a Galilean transformation is used to transform between the coordinates of two reference frames which differ only by constant relative motion within the constructs of Newtonian physics. These transformations together with spatial rotati ...
law from classical mechanics. The Lorentz transformations reduce to the Galilean transformations for low velocities much less than the speed of light ''c''. The magnitudes of 4-vectors are invariants – ''not'' "conserved", but the same for all inertial frames (i.e. every observer in an inertial frame will agree on the same value), in particular if ''A'' is the
four-momentum In special relativity, four-momentum (also called momentum–energy or momenergy) is the generalization of the classical three-dimensional momentum to four-dimensional spacetime. Momentum is a vector in three dimensions; similarly four-momentum i ...
, the magnitude can derive the famous invariant equation for mass–energy and momentum conservation (see
invariant mass The invariant mass, rest mass, intrinsic mass, proper mass, or in the case of bound systems simply mass, is the portion of the total mass of an object or system of objects that is independent of the overall motion of the system. More precisely, ...
): : E^2 = (pc)^2 + (mc^2)^2 in which the (more famous)
mass–energy equivalence In physics, mass–energy equivalence is the relationship between mass and energy in a system's rest frame. The two differ only by a multiplicative constant and the units of measurement. The principle is described by the physicist Albert Einstei ...
is a special case.
General relativity General relativity, also known as the general theory of relativity, and as Einstein's theory of gravity, is the differential geometry, geometric theory of gravitation published by Albert Einstein in 1915 and is the current description of grav ...
:
General relativity is governed by the
Einstein field equations In the General relativity, general theory of relativity, the Einstein field equations (EFE; also known as Einstein's equations) relate the geometry of spacetime to the distribution of Matter#In general relativity and cosmology, matter within it. ...
, which describe the curvature of space-time due to mass–energy equivalent to the gravitational field. Solving the equation for the geometry of space warped due to the mass distribution gives the
metric tensor In the mathematical field of differential geometry, a metric tensor (or simply metric) is an additional structure on a manifold (such as a surface) that allows defining distances and angles, just as the inner product on a Euclidean space allows ...
. Using the geodesic equation, the motion of masses falling along the geodesics can be calculated. Gravitoelectromagnetism :
In a relatively flat spacetime due to weak gravitational fields, gravitational analogues of Maxwell's equations can be found; the GEM equations, to describe an analogous '' gravitomagnetic field''. They are well established by the theory, and experimental tests form ongoing research. :


Classical laws

Kepler's laws, though originally discovered from planetary observations (also due to
Tycho Brahe Tycho Brahe ( ; ; born Tyge Ottesen Brahe, ; 14 December 154624 October 1601), generally called Tycho for short, was a Danish astronomer of the Renaissance, known for his comprehensive and unprecedentedly accurate astronomical observations. He ...
), are true for any ''
central force In classical mechanics, a central force on an object is a force that is directed towards or away from a point called center of force. \mathbf(\mathbf) = F( \mathbf ) where F is a force vector, ''F'' is a scalar valued force function (whose abso ...
s''. :


Thermodynamics

: *
Newton's law of cooling In the study of heat transfer, Newton's law of cooling is a physical law which states that the rate of heat loss of a body is directly proportional to the difference in the temperatures between the body and its environment. The law is frequentl ...
*
Fourier's law Thermal conduction is the diffusion of thermal energy (heat) within one material or between materials in contact. The higher temperature object has molecules with more kinetic energy; collisions between molecules distributes this kinetic energy ...
*
Ideal gas law The ideal gas law, also called the general gas equation, is the equation of state of a hypothetical ideal gas. It is a good approximation of the behavior of many gases under many conditions, although it has several limitations. It was first stat ...
, combines a number of separately developed gas laws; **
Boyle's law Boyle's law, also referred to as the Boyle–Mariotte law or Mariotte's law (especially in France), is an empirical gas laws, gas law that describes the relationship between pressure and volume of a confined gas. Boyle's law has been stated as: ...
**
Charles's law Charles's law (also known as the law of volumes) is an experimental gas law that describes how gases tend to expand when heated. A modern statement of Charles's law is: When the pressure on a sample of a dry gas is held constant, the Kelvin ...
**
Gay-Lussac's law Gay-Lussac's law usually refers to Joseph-Louis Gay-Lussac's law of combining volumes of gases, discovered in 1808 and published in 1809. However, it sometimes refers to the proportionality of the volume of a gas to its Thermodynamic temperature ...
**
Avogadro's law Avogadro's law (sometimes referred to as Avogadro's hypothesis or Avogadro's principle) or Avogadro-Ampère's hypothesis is an experimental gas law relating the volume of a gas to the amount of substance of gas present. The law is a specific cas ...
, into one : now improved by other
equations of state In physics and chemistry, an equation of state is a thermodynamic equation relating state variables, which describe the state of matter under a given set of physical conditions, such as pressure, volume, temperature, or internal energy. Most mod ...
* Dalton's law (of partial pressures) *
Boltzmann equation The Boltzmann equation or Boltzmann transport equation (BTE) describes the statistical behaviour of a thermodynamic system not in a state of equilibrium; it was devised by Ludwig Boltzmann in 1872.Encyclopaedia of Physics (2nd Edition), R. G ...
* Carnot's theorem *
Kopp's law Kopp's law can refer to either of two relationships discovered by the German chemist Hermann Franz Moritz Kopp (1817–1892). #Kopp found "that the molecular heat capacity of a solid compound is the sum of the atomic heat capacities of the elemen ...


Electromagnetism

Maxwell's equations Maxwell's equations, or Maxwell–Heaviside equations, are a set of coupled partial differential equations that, together with the Lorentz force law, form the foundation of classical electromagnetism, classical optics, Electrical network, electr ...
give the time-evolution of the
electric Electricity is the set of physical phenomena associated with the presence and motion of matter possessing an electric charge. Electricity is related to magnetism, both being part of the phenomenon of electromagnetism, as described by Maxwel ...
and
magnetic Magnetism is the class of physical attributes that occur through a magnetic field, which allows objects to attract or repel each other. Because both electric currents and magnetic moments of elementary particles give rise to a magnetic field, m ...
fields due to
electric charge Electric charge (symbol ''q'', sometimes ''Q'') is a physical property of matter that causes it to experience a force when placed in an electromagnetic field. Electric charge can be ''positive'' or ''negative''. Like charges repel each other and ...
and current distributions. Given the fields, the
Lorentz force In electromagnetism, the Lorentz force is the force exerted on a charged particle by electric and magnetic fields. It determines how charged particles move in electromagnetic environments and underlies many physical phenomena, from the operation ...
law is the equation of motion for charges in the fields. : These equations can be modified to include magnetic monopoles, and are consistent with our observations of monopoles either existing or not existing; if they do not exist, the generalized equations reduce to the ones above, if they do, the equations become fully symmetric in electric and magnetic charges and currents. Indeed, there is a duality transformation where electric and magnetic charges can be "rotated into one another", and still satisfy Maxwell's equations. Pre-Maxwell laws :
These laws were found before the formulation of Maxwell's equations. They are not fundamental, since they can be derived from Maxwell's equations. Coulomb's law can be found from Gauss's law (electrostatic form) and the Biot–Savart law can be deduced from Ampere's law (magnetostatic form). Lenz's law and Faraday's law can be incorporated into the Maxwell–Faraday equation. Nonetheless, they are still very effective for simple calculations. *
Lenz's law Lenz's law states that the direction of the electric current Electromagnetic induction, induced in a Electrical conductor, conductor by a changing magnetic field is such that the magnetic field created by the induced current opposes changes in t ...
*
Coulomb's law Coulomb's inverse-square law, or simply Coulomb's law, is an experimental scientific law, law of physics that calculates the amount of force (physics), force between two electric charge, electrically charged particles at rest. This electric for ...
*
Biot–Savart law In physics, specifically electromagnetism, the Biot–Savart law ( or ) is an equation describing the magnetic field generated by a constant electric current. It relates the magnetic field to the magnitude, direction, length, and proximity of the ...
Other laws : *
Ohm's law Ohm's law states that the electric current through a Electrical conductor, conductor between two Node (circuits), points is directly Proportionality (mathematics), proportional to the voltage across the two points. Introducing the constant of ...
* Kirchhoff's laws * Joule's law


Photonics

Classically,
optics Optics is the branch of physics that studies the behaviour and properties of light, including its interactions with matter and the construction of optical instruments, instruments that use or Photodetector, detect it. Optics usually describes t ...
is based on a variational principle: light travels from one point in space to another in the shortest time. *
Fermat's principle Fermat's principle, also known as the principle of least time, is the link between geometrical optics, ray optics and physical optics, wave optics. Fermat's principle states that the path taken by a Ray (optics), ray between two given ...
In
geometric optics Geometry (; ) is a branch of mathematics concerned with properties of space such as the distance, shape, size, and relative position of figures. Geometry is, along with arithmetic, one of the oldest branches of mathematics. A mathematician ...
laws are based on approximations in Euclidean geometry (such as the
paraxial approximation In geometric optics, the paraxial approximation is a small-angle approximation used in Gaussian optics and ray tracing of light through an optical system (such as a lens). A paraxial ray is a ray that makes a small angle (''θ'') to the optica ...
). * Law of reflection * Law of refraction,
Snell's law Snell's law (also known as the Snell–Descartes law, the ibn-Sahl law, and the law of refraction) is a formula used to describe the relationship between the angles of incidence and refraction, when referring to light or other waves passing th ...
In
physical optics In physics, physical optics, or wave optics, is the branch of optics that studies Interference (wave propagation), interference, diffraction, Polarization (waves), polarization, and other phenomena for which the ray approximation of geometric opti ...
, laws are based on physical properties of materials. * Brewster's angle * Malus's law *
Beer–Lambert law The Beer–Bouguer–Lambert (BBL) extinction law is an empirical relationship describing the attenuation in intensity of a radiation beam passing through a macroscopically homogenous medium with which it interacts. Formally, it states that the ...
In actuality, optical properties of matter are significantly more complex and require quantum mechanics.


Laws of quantum mechanics

Quantum mechanics has its roots in postulates. This leads to results which are not usually called "laws", but hold the same status, in that all of quantum mechanics follows from them. These postulates can be summarized as follows: * The state of a physical system, be it a particle or a system of many particles, is described by a
wavefunction In quantum physics, a wave function (or wavefunction) is a mathematical description of the quantum state of an isolated quantum system. The most common symbols for a wave function are the Greek letters and (lower-case and capital psi (letter) ...
. * Every physical quantity is described by an operator acting on the system; the measured quantity has a probabilistic nature. * The
wavefunction In quantum physics, a wave function (or wavefunction) is a mathematical description of the quantum state of an isolated quantum system. The most common symbols for a wave function are the Greek letters and (lower-case and capital psi (letter) ...
obeys the
Schrödinger equation The Schrödinger equation is a partial differential equation that governs the wave function of a non-relativistic quantum-mechanical system. Its discovery was a significant landmark in the development of quantum mechanics. It is named after E ...
. Solving this wave equation predicts the time-evolution of the system's behavior, analogous to solving Newton's laws in classical mechanics. * Two
identical particles In quantum mechanics, indistinguishable particles (also called identical or indiscernible particles) are particles that cannot be distinguished from one another, even in principle. Species of identical particles include, but are not limited to, ...
, such as two electrons, cannot be distinguished from one another by any means. Physical systems are classified by their symmetry properties. These postulates in turn imply many other phenomena, e.g.,
uncertainty principle The uncertainty principle, also known as Heisenberg's indeterminacy principle, is a fundamental concept in quantum mechanics. It states that there is a limit to the precision with which certain pairs of physical properties, such as position a ...
s and the Pauli exclusion principle. :


Radiation laws

Applying electromagnetism, thermodynamics, and quantum mechanics, to atoms and molecules, some laws of
electromagnetic radiation In physics, electromagnetic radiation (EMR) is a self-propagating wave of the electromagnetic field that carries momentum and radiant energy through space. It encompasses a broad spectrum, classified by frequency or its inverse, wavelength ...
and light are as follows. *
Stefan–Boltzmann law The Stefan–Boltzmann law, also known as ''Stefan's law'', describes the intensity of the thermal radiation emitted by matter in terms of that matter's temperature. It is named for Josef Stefan, who empirically derived the relationship, and Lu ...
*
Planck's law In physics, Planck's law (also Planck radiation law) describes the spectral density of electromagnetic radiation emitted by a black body in thermal equilibrium at a given temperature , when there is no net flow of matter or energy between the ...
of black-body radiation *
Wien's displacement law In physics, Wien's displacement law states that the black-body radiation curve for different temperatures will peak at different wavelengths that are inversely proportional to the temperature. The shift of that peak is a direct consequence of ...
* Radioactive decay law


Laws of chemistry

Chemical laws are those laws of nature relevant to
chemistry Chemistry is the scientific study of the properties and behavior of matter. It is a physical science within the natural sciences that studies the chemical elements that make up matter and chemical compound, compounds made of atoms, molecules a ...
. Historically, observations led to many empirical laws, though now it is known that chemistry has its foundations in
quantum mechanics Quantum mechanics is the fundamental physical Scientific theory, theory that describes the behavior of matter and of light; its unusual characteristics typically occur at and below the scale of atoms. Reprinted, Addison-Wesley, 1989, It is ...
. Quantitative analysis :
The most fundamental concept in chemistry is the law of conservation of mass, which states that there is no detectable change in the quantity of matter during an ordinary
chemical reaction A chemical reaction is a process that leads to the chemistry, chemical transformation of one set of chemical substances to another. When chemical reactions occur, the atoms are rearranged and the reaction is accompanied by an Gibbs free energy, ...
. Modern physics shows that it is actually
energy Energy () is the physical quantity, quantitative physical property, property that is transferred to a physical body, body or to a physical system, recognizable in the performance of Work (thermodynamics), work and in the form of heat and l ...
that is conserved, and that energy and mass are related; a concept which becomes important in
nuclear chemistry Nuclear chemistry is the sub-field of chemistry dealing with radioactivity, nuclear processes, and transformations in the nuclei of atoms, such as nuclear transmutation and nuclear properties. It is the chemistry of radioactive elements such as t ...
.
Conservation of energy The law of conservation of energy states that the total energy of an isolated system remains constant; it is said to be Conservation law, ''conserved'' over time. In the case of a Closed system#In thermodynamics, closed system, the principle s ...
leads to the important concepts of equilibrium,
thermodynamics Thermodynamics is a branch of physics that deals with heat, Work (thermodynamics), work, and temperature, and their relation to energy, entropy, and the physical properties of matter and radiation. The behavior of these quantities is governed b ...
, and kinetics. Additional laws of chemistry elaborate on the law of conservation of mass.
Joseph Proust Joseph Louis Proust (26 September 1754 – 5 July 1826) was a French people, French chemist. He was best known for his discovery of the law of definite proportions in 1797, stating that chemical compounds always combine in constant proportions. ...
's
law of definite composition In chemistry, the law of definite proportions, sometimes called Proust's law or the law of constant composition, states that a given chemical compound contains its constituent elements in a fixed ratio (by mass) and does not depend on its source ...
says that pure chemicals are composed of elements in a definite formulation; we now know that the structural arrangement of these elements is also important. Dalton's
law of multiple proportions In chemistry, the law of multiple proportions states that in compounds which contain two particular chemical elements, the amount of Element A per measure of Element B will differ across these compounds by ratios of small whole numbers. For inst ...
says that these chemicals will present themselves in proportions that are small whole numbers; although in many systems (notably biomacromolecules and
minerals In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid substance with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. (2011): M ...
) the ratios tend to require large numbers, and are frequently represented as a fraction. The law of definite composition and the law of multiple proportions are the first two of the three laws of
stoichiometry Stoichiometry () is the relationships between the masses of reactants and Product (chemistry), products before, during, and following chemical reactions. Stoichiometry is based on the law of conservation of mass; the total mass of reactants must ...
, the proportions by which the chemical elements combine to form chemical compounds. The third law of stoichiometry is the
law of reciprocal proportions The law of reciprocal proportions, also called law of equivalent proportions or law of permanent ratios, is one of the basic laws of stoichiometry. It relates the proportions in which elements combine across a number of different elements. It was f ...
, which provides the basis for establishing equivalent weights for each chemical element. Elemental equivalent weights can then be used to derive atomic weights for each element. More modern laws of chemistry define the relationship between energy and its transformations. Reaction kinetics and equilibria : * In equilibrium, molecules exist in mixture defined by the transformations possible on the timescale of the equilibrium, and are in a ratio defined by the intrinsic energy of the molecules—the lower the intrinsic energy, the more abundant the molecule. Le Chatelier's principle states that the system opposes changes in conditions from equilibrium states, i.e. there is an opposition to change the state of an equilibrium reaction. * Transforming one structure to another requires the input of energy to cross an energy barrier; this can come from the intrinsic energy of the molecules themselves, or from an external source which will generally accelerate transformations. The higher the energy barrier, the slower the transformation occurs. * There is a hypothetical intermediate, or ''transition structure'', that corresponds to the structure at the top of the energy barrier. The
Hammond–Leffler postulate Hammond's postulate (or alternatively the Hammond–Leffler postulate), is a hypothesis in physical organic chemistry which describes the geometric structure of the transition state in an organic chemical reaction. First proposed by George S. Ham ...
states that this structure looks most similar to the product or starting material which has intrinsic energy closest to that of the energy barrier. Stabilizing this hypothetical intermediate through chemical interaction is one way to achieve
catalysis Catalysis () is the increase in rate of a chemical reaction due to an added substance known as a catalyst (). Catalysts are not consumed by the reaction and remain unchanged after it. If the reaction is rapid and the catalyst recycles quick ...
. * All chemical processes are reversible (law of
microscopic reversibility The principle of microscopic reversibility in physics and chemistry is twofold: * First, it states that the microscopic detailed dynamics of particles and fields is time-reversible because the microscopic equations of motion are symmetric with respe ...
) although some processes have such an energy bias, they are essentially irreversible. * The reaction rate has the mathematical parameter known as the rate constant. The
Arrhenius equation In physical chemistry, the Arrhenius equation is a formula for the temperature dependence of reaction rates. The equation was proposed by Svante Arrhenius in 1889, based on the work of Dutch chemist Jacobus Henricus van 't Hoff who had noted in 188 ...
gives the temperature and
activation energy In the Arrhenius model of reaction rates, activation energy is the minimum amount of energy that must be available to reactants for a chemical reaction to occur. The activation energy (''E''a) of a reaction is measured in kilojoules per mole (k ...
dependence of the rate constant, an empirical law. Thermochemistry : *
Dulong–Petit law The Dulong–Petit law, a thermodynamic law proposed by French physicists Pierre Louis Dulong and Alexis Thérèse Petit, states that the classical expression for the molar specific heat capacity of certain chemical elements is constant for tempe ...
*
Gibbs–Helmholtz equation The Gibbs–Helmholtz equation is a thermodynamic equation used to calculate changes in the Gibbs free energy of a system as a function of temperature. It was originally presented in an 1882 paper entitled " Die Thermodynamik chemischer Vorgänge" ...
* Hess's law Gas laws : *
Raoult's law Raoult's law ( law) is a relation of physical chemistry, with implications in thermodynamics. Proposed by French chemist François-Marie Raoult in 1887, it states that the partial pressure of each component of an ideal mixture of ''liquids'' is ...
*
Henry's law In physical chemistry, Henry's law is a gas law that states that the amount of dissolved gas in a liquid is directly proportional at equilibrium to its partial pressure above the liquid. The proportionality factor is called Henry's law constant ...
Chemical transport : *
Fick's laws of diffusion Fick's laws of diffusion describe diffusion and were first posited by Adolf Fick in 1855 on the basis of largely experimental results. They can be used to solve for the diffusion coefficient, . Fick's first law can be used to derive his second ...
*
Graham's law Graham's law of effusion (also called Graham's law of diffusion) was formulated by Scottish physical chemist Thomas Graham in 1848. Keith J. Laidler and John M. Meiser, ''Physical Chemistry'' (Benjamin/Cummings 1982), pp. 18–19 Graham fou ...
* Lamm equation


Laws of biology


Ecology

* Competitive exclusion principle or Gause's law


Genetics

* Mendelian laws (Dominance and Uniformity, segregation of genes, and Independent Assortment) *
Hardy–Weinberg principle In population genetics, the Hardy–Weinberg principle, also known as the Hardy–Weinberg equilibrium, model, theorem, or law, states that Allele frequency, allele and genotype frequencies in a population will remain constant from generation ...


Natural selection

Whether or not
Natural Selection Natural selection is the differential survival and reproduction of individuals due to differences in phenotype. It is a key mechanism of evolution, the change in the Heredity, heritable traits characteristic of a population over generation ...
is a "law of nature" is controversial among biologists.Byerly HC: Natural selection as a law: Principles and processes. Am Nat. 1983; 121(5): 739–745. Henry Byerly, an American philosopher known for his work on evolutionary theory, discussed the problem of interpreting a principle of natural selection as a law. He suggested a formulation of natural selection as a framework principle that can contribute to a better understanding of evolutionary theory. His approach was to express relative fitness, the propensity of a
genotype The genotype of an organism is its complete set of genetic material. Genotype can also be used to refer to the alleles or variants an individual carries in a particular gene or genetic location. The number of alleles an individual can have in a ...
to increase in proportionate representation in a competitive environment, as a function of adaptedness (adaptive design) of the organism.


Laws of Earth sciences


Geography

* Arbia's law of geography * Tobler's first law of geography * Tobler's second law of geography


Geology

* Archie's law * Buys Ballot's law * Birch's law * Byerlee's law *
Principle of original horizontality The principle of original horizontality states that layers of sediment are originally deposited horizontally under the action of gravity. It is a relative dating technique. The principle is important to the analysis of folded and tilted strata. ...
*
Law of superposition The law of superposition is an axiom that forms one of the bases of the sciences of geology, archaeology, and other fields pertaining to geological stratigraphy. In its plainest form, it states that in undeformed stratigraphic sequences, the ...
* Principle of lateral continuity * Principle of cross-cutting relationships * Principle of faunal succession * Principle of inclusions and components * Walther's law


Other fields

Some
mathematical Mathematics is a field of study that discovers and organizes methods, Mathematical theory, theories and theorems that are developed and Mathematical proof, proved for the needs of empirical sciences and mathematics itself. There are many ar ...
theorem In mathematics and formal logic, a theorem is a statement (logic), statement that has been Mathematical proof, proven, or can be proven. The ''proof'' of a theorem is a logical argument that uses the inference rules of a deductive system to esta ...
s and
axiom An axiom, postulate, or assumption is a statement that is taken to be true, to serve as a premise or starting point for further reasoning and arguments. The word comes from the Ancient Greek word (), meaning 'that which is thought worthy or ...
s are referred to as laws because they provide logical foundation to empirical laws. Examples of other observed phenomena sometimes described as laws include the Titius–Bode law of planetary positions, Zipf's law of linguistics, and
Moore's law Moore's law is the observation that the Transistor count, number of transistors in an integrated circuit (IC) doubles about every two years. Moore's law is an observation and Forecasting, projection of a historical trend. Rather than a law of ...
of technological growth. Many of these laws fall within the scope of uncomfortable science. Other laws are pragmatic and observational, such as the
law of unintended consequences In the social sciences, unintended consequences (sometimes unanticipated consequences or unforeseen consequences, more colloquially called knock-on effects) are outcomes of a purposeful action that are not intended or foreseen. The term was po ...
. By analogy, principles in other fields of study are sometimes loosely referred to as "laws". These include
Occam's razor In philosophy, Occam's razor (also spelled Ockham's razor or Ocham's razor; ) is the problem-solving principle that recommends searching for explanations constructed with the smallest possible set of elements. It is also known as the principle o ...
as a principle of philosophy and the Pareto principle of economics.


History

The observation and detection of underlying regularities in nature date from
prehistoric Prehistory, also called pre-literary history, is the period of human history between the first known use of stone tools by hominins  million years ago and the beginning of recorded history with the invention of writing systems. The use o ...
times – the recognition of cause-and-effect relationships implicitly recognises the existence of laws of nature. The recognition of such regularities as independent scientific laws ''
per se Per se may refer to: * '' per se'', a Latin phrase meaning "by itself" or "in itself". * Illegal ''per se'', the legal usage in criminal and antitrust law * Negligence ''per se'', legal use in tort law *Per Se (restaurant) Per Se is a New Amer ...
'', though, was limited by their entanglement in
animism Animism (from meaning 'breath, spirit, life') is the belief that objects, places, and creatures all possess a distinct spiritual essence. Animism perceives all things—animals, plants, rocks, rivers, weather systems, human handiwork, and in ...
, and by the attribution of many effects that do not have readily obvious causes—such as physical phenomena—to the actions of
gods A deity or god is a supernatural being considered to be sacred and worthy of worship due to having authority over some aspect of the universe and/or life. The ''Oxford Dictionary of English'' defines ''deity'' as a God (male deity), god or god ...
, spirits,
supernatural being Supernatural phenomena or entities are those beyond the Scientific law, laws of nature. The term is derived from Medieval Latin , from Latin 'above, beyond, outside of' + 'nature'. Although the corollary term "nature" has had multiple meanin ...
s, etc. Observation and speculation about nature were intimately bound up with metaphysics and morality. In Europe, systematic theorizing about nature (''
physis Physis (; ; pl. physeis, φύσεις) is a Greek philosophical, theological, and scientific term, usually translated into English—according to its Latin translation "natura"—as "nature". The term originated in ancient Greek philosophy, a ...
'') began with the early Greek philosophers and scientists and continued into the
Hellenistic In classical antiquity, the Hellenistic period covers the time in Greek history after Classical Greece, between the death of Alexander the Great in 323 BC and the death of Cleopatra VII in 30 BC, which was followed by the ascendancy of the R ...
and Roman imperial periods, during which times the intellectual influence of
Roman law Roman law is the law, legal system of ancient Rome, including the legal developments spanning over a thousand years of jurisprudence, from the Twelve Tables (), to the (AD 529) ordered by Eastern Roman emperor Justinian I. Roman law also den ...
increasingly became paramount.
The formula "law of nature" first appears as "a live metaphor" favored by Latin poets
Lucretius Titus Lucretius Carus ( ; ;  – October 15, 55 BC) was a Roman poet and philosopher. His only known work is the philosophical poem '' De rerum natura'', a didactic work about the tenets and philosophy of Epicureanism, which usually is t ...
,
Virgil Publius Vergilius Maro (; 15 October 70 BC21 September 19 BC), usually called Virgil or Vergil ( ) in English, was an ancient Rome, ancient Roman poet of the Augustan literature (ancient Rome), Augustan period. He composed three of the most fa ...
,
Ovid Publius Ovidius Naso (; 20 March 43 BC – AD 17/18), known in English as Ovid ( ), was a Augustan literature (ancient Rome), Roman poet who lived during the reign of Augustus. He was a younger contemporary of Virgil and Horace, with whom he i ...
, Manilius, in time gaining a firm theoretical presence in the prose treatises of Seneca and Pliny. Why this Roman origin? According to istorian and classicist DarynLehoux's persuasive narrative, the idea was made possible by the pivotal role of codified law and
forensic Forensic science combines principles of law and science to investigate criminal activity. Through crime scene investigations and laboratory analysis, forensic scientists are able to link suspects to evidence. An example is determining the time and ...
argument in Roman life and culture.

For the Romans ... the place par excellence where ethics, law, nature, religion and politics overlap is the
law court Law is a set of rules that are created and are law enforcement, enforceable by social or governmental institutions to regulate behavior, with its precise definition a matter of longstanding debate. It has been variously described as a Socia ...
. When we read Seneca's ''Natural Questions'', and watch again and again just how he applies standards of evidence, witness evaluation, argument and proof, we can recognize that we are reading one of the great Roman rhetoricians of the age, thoroughly immersed in forensic method. And not Seneca alone. Legal models of scientific judgment turn up all over the place, and for example prove equally integral to
Ptolemy Claudius Ptolemy (; , ; ; – 160s/170s AD) was a Greco-Roman mathematician, astronomer, astrologer, geographer, and music theorist who wrote about a dozen scientific treatises, three of which were important to later Byzantine science, Byzant ...
's approach to verification, where the mind is assigned the role of magistrate, the senses that of disclosure of evidence, and dialectical reason that of the law itself.
The precise formulation of what are now recognized as modern and valid statements of the laws of nature dates from the 17th century in Europe, with the beginning of accurate experimentation and the development of advanced forms of mathematics. During this period,
natural philosophers Natural philosophy or philosophy of nature (from Latin ''philosophia naturalis'') is the philosophical study of physics, that is, nature and the physical universe, while ignoring any supernatural influence. It was dominant before the developme ...
such as
Isaac Newton Sir Isaac Newton () was an English polymath active as a mathematician, physicist, astronomer, alchemist, theologian, and author. Newton was a key figure in the Scientific Revolution and the Age of Enlightenment, Enlightenment that followed ...
(1642–1727) were influenced by a
religious Religion is a range of social- cultural systems, including designated behaviors and practices, morals, beliefs, worldviews, texts, sanctified places, prophecies, ethics, or organizations, that generally relate humanity to supernatural ...
view – stemming from medieval concepts of
divine law Divine law is any body of law that is perceived as deriving from a Transcendence (religion), transcendent source, such as the will of God or godsin contrast to man-made law or to secular law. According to Angelos Chaniotis and Rudolph F. Peters, di ...
– which held that God had instituted absolute, universal and immutable physical laws. In chapter 7 of ''The World'',
René Descartes René Descartes ( , ; ; 31 March 1596 – 11 February 1650) was a French philosopher, scientist, and mathematician, widely considered a seminal figure in the emergence of modern philosophy and Modern science, science. Mathematics was paramou ...
(1596–1650) described "nature" as matter itself, unchanging as created by God, thus changes in parts "are to be attributed to nature. The rules according to which these changes take place I call the 'laws of nature'." The modern
scientific method The scientific method is an Empirical evidence, empirical method for acquiring knowledge that has been referred to while doing science since at least the 17th century. Historically, it was developed through the centuries from the ancient and ...
which took shape at this time (with
Francis Bacon Francis Bacon, 1st Viscount St Alban (; 22 January 1561 – 9 April 1626) was an English philosopher and statesman who served as Attorney General and Lord Chancellor of England under King James I. Bacon argued for the importance of nat ...
(1561–1626) and
Galileo Galileo di Vincenzo Bonaiuti de' Galilei (15 February 1564 – 8 January 1642), commonly referred to as Galileo Galilei ( , , ) or mononymously as Galileo, was an Italian astronomer, physicist and engineer, sometimes described as a poly ...
(1564–1642)) contributed to a trend of separating science from
theology Theology is the study of religious belief from a Religion, religious perspective, with a focus on the nature of divinity. It is taught as an Discipline (academia), academic discipline, typically in universities and seminaries. It occupies itse ...
, with minimal speculation about
metaphysics Metaphysics is the branch of philosophy that examines the basic structure of reality. It is traditionally seen as the study of mind-independent features of the world, but some theorists view it as an inquiry into the conceptual framework of ...
and ethics. (
Natural law Natural law (, ) is a Philosophy, philosophical and legal theory that posits the existence of a set of inherent laws derived from nature and universal moral principles, which are discoverable through reason. In ethics, natural law theory asserts ...
in the political sense, conceived as universal (i.e., divorced from sectarian religion and accidents of place), was also elaborated in this period by scholars such as
Grotius Hugo Grotius ( ; 10 April 1583 – 28 August 1645), also known as Hugo de Groot () or Huig de Groot (), was a Dutch humanist, diplomat, lawyer, theologian, jurist, statesman, poet and playwright. A teenage prodigy, he was born in Delft an ...
(1583–1645),
Spinoza Baruch (de) Spinoza (24 November 163221 February 1677), also known under his Latinized pen name Benedictus de Spinoza, was a philosopher of Portuguese-Jewish origin, who was born in the Dutch Republic. A forerunner of the Age of Enlightenmen ...
(1632–1677), and
Hobbes Thomas Hobbes ( ; 5 April 1588 – 4 December 1679) was an English philosopher, best known for his 1651 book ''Leviathan'', in which he expounds an influential formulation of social contract theory. He is considered to be one of the founders ...
(1588–1679).) The distinction between
natural law Natural law (, ) is a Philosophy, philosophical and legal theory that posits the existence of a set of inherent laws derived from nature and universal moral principles, which are discoverable through reason. In ethics, natural law theory asserts ...
in the political-legal sense and law of nature or physical law in the scientific sense is a modern one, both concepts being equally derived from ''
physis Physis (; ; pl. physeis, φύσεις) is a Greek philosophical, theological, and scientific term, usually translated into English—according to its Latin translation "natura"—as "nature". The term originated in ancient Greek philosophy, a ...
'', the Greek word (translated into Latin as ''natura'') for ''nature''. Some modern philosophers, e.g. Norman Swartz, use "physical law" to mean the laws of nature as they truly are and not as they are inferred by scientists. See Norman Swartz, ''The Concept of Physical Law'' (New York: Cambridge University Press), 1985. Second edition available onlin


See also


References


Further reading

* * *
Francis Bacon Francis Bacon, 1st Viscount St Alban (; 22 January 1561 – 9 April 1626) was an English philosopher and statesman who served as Attorney General and Lord Chancellor of England under King James I. Bacon argued for the importance of nat ...
(1620). ''
Novum Organum The ''Novum Organum'', fully ''Novum Organum, sive Indicia Vera de Interpretatione Naturae'' ("New organon, or true directions concerning the interpretation of nature") or ''Instaurationis Magnae, Pars II'' ("Part II of The Great Instauratio ...
''. * * * * *


External links


Physics Formulary
a useful book in different formats containing many or the physical laws and formulae.
Eformulae.com
website containing most of the formulae in different disciplines. *
Stanford Encyclopedia of Philosophy The ''Stanford Encyclopedia of Philosophy'' (''SEP'') is a freely available online philosophy resource published and maintained by Stanford University, encompassing both an online encyclopedia of philosophy and peer-reviewed original publication ...

"Laws of Nature"
by John W. Carroll. * Baaquie, Belal E

Core Curriculum,
National University of Singapore The National University of Singapore (NUS) is a national university, national Public university, public research university in Singapore. It was officially established in 1980 by the merging of the University of Singapore and Nanyang University ...
. * Francis, Erik Max
"The laws list".Physics
Alcyone Systems * Pazameta, Zoran
"The laws of nature".
Committee for the scientific investigation of Claims of the Paranormal. * The Internet Encyclopedia of Philosophy
"Laws of Nature"
– By Norman Swartz * {{Authority control Causality * Metaphysics of science Philosophy of science Principles Laws in science Scientific method