Kieserite, or magnesium sulfate monohydrate, is a hydrous

magnesium sulfate Magnesium sulfate or magnesium sulphate is a chemical compound, a salt with the formula , consisting of magnesium cations (20.19% by mass) and sulfate anions . It is a white crystalline solid, soluble in water but not in ethanol. Magnesi ...

mineral with formula (MgSO₄·H₂O). It has a vitreous luster and it is colorless, grayish-white or yellowish. Its hardness is 3.5 and crystallizes in the

monoclinic In crystallography, the monoclinic crystal system is one of the seven crystal systems. A crystal system is described by three Vector (geometric), vectors. In the monoclinic system, the crystal is described by vectors of unequal lengths, as in t ...

crystal system In crystallography, a crystal system is a set of point groups (a group of geometric symmetries with at least one fixed point). A lattice system is a set of Bravais lattices (an infinite array of discrete points). Space groups (symmetry groups ...

. Gunningite is the zinc member of the kieserite group of minerals.

Etymology

It is named after

Dietrich Georg von Kieser Dietrich () is an ancient German name meaning "ruler of the people", but also "keeper of the keys" or "lockpick" (either the tool or the profession). Given name * Dietrich, Count of Oldenburg (c. 1398–1440) * Thierry of Alsace (; 1099–1168), ...

(Jena, Germany 1862).

Occurrence

Kieserite commonly occurs in marine

evaporite An evaporite () is a water- soluble sedimentary mineral deposit that results from concentration and crystallization by evaporation from an aqueous solution. There are two types of evaporite deposits: marine, which can also be described as oce ...

s and rarely in

volcanic A volcano is commonly defined as a vent or fissure in the crust of a planetary-mass object, such as Earth, that allows hot lava, volcanic ash, and gases to escape from a magma chamber below the surface. On Earth, volcanoes are most often fo ...

environments as a sublimate. It occurs in association with

halite Halite ( ), commonly known as rock salt, is a type of salt, the mineral (natural) form of sodium chloride ( Na Cl). Halite forms isometric crystals. The mineral is typically colorless or white, but may also be light blue, dark blue, purple, pi ...

carnallite Carnallite (also carnalite) is an evaporite mineral, a hydrated potassium magnesium chloride with formula KCl.MgCl2·6(H2O). It is variably colored yellow to white, reddish, and sometimes colorless or blue. It is usually massive to fibrous with r ...

polyhalite Polyhalite is an evaporite mineral, a hydrated sulfate of potassium, calcium and magnesium with formula: . Polyhalite crystallizes in the triclinic system, although crystals are very rare. The normal habit is massive to fibrous. It is typica ...

, anhydrite,

boracite Boracite is a magnesium borate mineral with formula: Mg3 B7 O13 Cl. It occurs as blue green, colorless, gray, yellow to white crystals in the orthorhombic - pyramidal crystal system. Boracite also shows pseudo-isometric cubical and octahedral fo ...

, sulfoborite, leonite, epsomite and celestine.

Mars

In early 2005,

Mars Express ''Mars Express'' is a space exploration mission by the European Space Agency, European Space Agency (ESA) exploring the planet Mars and its moons since 2003, and the first planetary mission attempted by ESA. ''Mars Express'' consisted of two ...

, a

European Space Agency The European Space Agency (ESA) is a 23-member International organization, international organization devoted to space exploration. With its headquarters in Paris and a staff of around 2,547 people globally as of 2023, ESA was founded in 1975 ...

orbiter, discovered evidence of kieserite in patches of

Valles Marineris Valles Marineris (; Latin for ''Mariner program, Mariner Valleys'', named after the Mariner 9 Mars orbiter of 1971–72 which discovered it) is a system of canyons that runs along the Mars, Martian surface east of the Tharsis region. At more than ...

(the largest canyon on

Mars Mars is the fourth planet from the Sun. It is also known as the "Red Planet", because of its orange-red appearance. Mars is a desert-like rocky planet with a tenuous carbon dioxide () atmosphere. At the average surface level the atmosph ...

), along with

gypsum Gypsum is a soft sulfate mineral composed of calcium sulfate Hydrate, dihydrate, with the chemical formula . It is widely mined and is used as a fertilizer and as the main constituent in many forms of plaster, drywall and blackboard or sidewalk ...

and polyhydrated

sulfate The sulfate or sulphate ion is a polyatomic anion with the empirical formula . Salts, acid derivatives, and peroxides of sulfate are widely used in industry. Sulfates occur widely in everyday life. Sulfates are salts of sulfuric acid and many ...

s. This is direct evidence of Mars's watery past and augments similar discoveries made by the

Mars Exploration Rover NASA's Mars Exploration Rover (MER) mission was a robotic space mission involving two Mars rovers, ''Spirit (rover), Spirit'' and ''Opportunity (rover), Opportunity'', exploring the planet Mars. It began in 2003 with the launch of the two rove ...

Opportunity in 2004.

Moons of Jupiter

Kieserite might also be a rock-forming mineral in the icy mantle of the outer three

Galilean moons The Galilean moons (), or Galilean satellites, are the four largest moons of Jupiter. They are, in descending-size order, Ganymede (moon), Ganymede, Callisto (moon), Callisto, Io (moon), Io, and Europa (moon), Europa. They are the most apparent m ...

( Europa, Ganymede,

Callisto CALLISTO (''Cooperative Action Leading to Launcher Innovation in Stage Toss-back Operations'') is a reusable VTVL Prototype, demonstrator propelled by a small 40 kN Japanese LOX-LH2 rocket engine. It is being developed jointly by the CNES, French ...

). At pressures higher than 2.7

GPa Grading in education is the application of standardized measurements to evaluate different levels of student achievement in a course. Grades can be expressed as letters (usually A to F), as a range (for example, 1 to 6), percentages, or as num ...

, kieserite transforms to a triclinic crystal structure.

Uses

It is used in the production of Epsom salt and as a fertilizer, the overall global annual usage in agriculture in the mid 1970s was 2.3 million tons. Kieserite crystal structure

Kieserite is also used for cleaning hard water deposits from tiles, stones, and other pool and fountain lining materials. Due to its hardness, which is greater than hard water deposits but less than tiles and other water feature linings, it is blasted at the hard water deposits to remove them. When used as a fertilizer, response to kieserite is likely where: * Soil Mg levels are low * pH is high * Intensive liming occurs to raise the pH * Nitrogen is applied as ammonium, as this can lead to an antagonism between ammonium and magnesium * Compacted soils exist * There is a period of wet/cold weather * Dry weather occurs, leading to low magnesium mobility in the soil profile.

References