
An ion beam is a beam of
ions
An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by convent ...
, a type of
charged particle beam. Ion beams have many uses in
electronics manufacturing (principally
ion implantation
Ion implantation is a low-temperature process by which ions of one element are accelerated into a solid target, thereby changing the target's physical, chemical, or electrical properties. Ion implantation is used in semiconductor device fabrica ...
) and other industries. There are many
ion beam sources, some derived from the
mercury vapor thrusters developed by
NASA
The National Aeronautics and Space Administration (NASA ) is an independent agencies of the United States government, independent agency of the federal government of the United States, US federal government responsible for the United States ...
in the 1960s. The most widely used ion beams are of singly-charged ions.
Units
Ion current density is typically measured in mA/cm
2, and ion energy in
electronvolt
In physics, an electronvolt (symbol eV), also written electron-volt and electron volt, is the measure of an amount of kinetic energy gained by a single electron accelerating through an Voltage, electric potential difference of one volt in vacuum ...
s (eV). The use of eV is convenient for converting between voltage and energy, especially when dealing with singly charged ion beams.
Broad-beam ion sources
Most commercial applications use two popular types of ion source, gridded and gridless, which differ in current and power characteristics and the ability to control ion trajectories.
In both cases
electron
The electron (, or in nuclear reactions) is a subatomic particle with a negative one elementary charge, elementary electric charge. It is a fundamental particle that comprises the ordinary matter that makes up the universe, along with up qua ...
s are needed to generate an ion beam. The most common types of
electron emitter are
hot filament and hollow
cathode
A cathode is the electrode from which a conventional current leaves a polarized electrical device such as a lead-acid battery. This definition can be recalled by using the mnemonic ''CCD'' for ''Cathode Current Departs''. Conventional curren ...
.
Gridded ion source
In a gridded ion source,
DC or
RF discharge are used to generate ions, which are then accelerated and decimated using grids and apertures. Here, the DC discharge current or the RF discharge power are used to control the beam current.
The ion current density
that can be accelerated using a gridded ion source is limited by the
space charge effect, which is described by
Child's law:
where
is the voltage between the grids,
is the distance between the grids, and
is the ion mass.
The grids are spaced as closely as possible to increase the current density, typically
. The ions used have a significant impact on the maximum ion beam current, since
. All else being equal, the maximum ion beam current with
krypton
Krypton (from 'the hidden one') is a chemical element; it has symbol (chemistry), symbol Kr and atomic number 36. It is a colorless, odorless noble gas that occurs in trace element, trace amounts in the Earth's atmosphere, atmosphere and is of ...
is only 69% of the maximum ion current of an
argon
Argon is a chemical element; it has symbol Ar and atomic number 18. It is in group 18 of the periodic table and is a noble gas. Argon is the third most abundant gas in Earth's atmosphere, at 0.934% (9340 ppmv). It is more than twice as abu ...
beam; with
xenon
Xenon is a chemical element; it has symbol Xe and atomic number 54. It is a dense, colorless, odorless noble gas found in Earth's atmosphere in trace amounts. Although generally unreactive, it can undergo a few chemical reactions such as the ...
the ratio drops to 55%.
Gridless ion sources
In a gridless ion source, ions are generated by a flow of electrons, without grids. The most common gridless ion source is the
end-Hall ion source, with which the discharge current and the gas flow are used to control the beam current.
Applications
Material modification and analysis
Ion beams can be used for material modification (e.g. by
sputtering
In physics, sputtering is a phenomenon in which microscopic particles of a solid material are ejected from its surface, after the material is itself bombarded by energetic particles of a plasma or gas. It occurs naturally in outer space, and c ...
or ion beam etching) and for
ion beam analysis.
Ion beam application, etching, or sputtering, is a technique conceptually similar to
sandblasting
Sandblasting, sometimes known as abrasive blasting, is the operation of forcibly propelling a stream of abrasive material against a surface under high pressure to smooth a rough surface, roughen a smooth surface, shape a surface or remove su ...
, but using individual atoms in an ion beam to
ablate a target.
Reactive ion etching is an important extension that uses chemical reactivity to enhance the physical sputtering effect.
In a typical use in
semiconductor manufacturing
Semiconductor device fabrication is the process used to manufacture semiconductor devices, typically integrated circuits (ICs) such as microprocessors, microcontrollers, and memories (such as Random-access memory, RAM and flash memory). It is a ...
, a
mask
A mask is an object normally worn on the face, typically for protection, disguise, performance, or entertainment, and often employed for rituals and rites. Masks have been used since antiquity for both ceremonial and practical purposes, ...
can selectively expose a layer of
photoresist
A photoresist (also known simply as a resist) is a light-sensitive material used in several processes, such as photolithography and photoengraving, to form a patterned coating on a surface. This process is crucial in the electronics industry.
T ...
on a
substrate made of a
semiconductor
A semiconductor is a material with electrical conductivity between that of a conductor and an insulator. Its conductivity can be modified by adding impurities (" doping") to its crystal structure. When two regions with different doping level ...
material, such as a
silicon dioxide
Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , commonly found in nature as quartz. In many parts of the world, silica is the major constituent of sand. Silica is one of the most complex and abundan ...
or
gallium arsenide
Gallium arsenide (GaAs) is a III-V direct band gap semiconductor with a Zincblende (crystal structure), zinc blende crystal structure.
Gallium arsenide is used in the manufacture of devices such as microwave frequency integrated circuits, monoli ...
wafer. The wafer is developed, and for a positive photoresist, the exposed portions are removed in a chemical process. The result is a pattern left on the surface areas of the wafer that had been masked from exposure. The wafer is then placed in a
vacuum chamber
A vacuum chamber is a rigid enclosure from which air and other gases are removed by a vacuum pump. This results in a low-pressure environment within the chamber, commonly referred to as a vacuum. A vacuum environment allows researchers to c ...
, and exposed to the ion beam. The impact of the ions erodes the target, abrading away the areas not covered by the photoresist.
Focused ion beam (FIB) instruments have numerous applications for characterization of thin-film devices. Using a focused, high-brightness ion beam in a scanned raster pattern, material is removed (sputtered) in precise rectilinear patterns revealing a two-dimensional, or stratigraphic profile of a solid material. The most common application is to verify the integrity of the gate oxide layer in a CMOS transistor. A single excavation site exposes a cross section for analysis using a scanning electron microscope. Dual excavations on either side of a thin lamella bridge are utilized for preparing transmission electron microscope samples.
[
Giannuzzi, Lucille A., Stevie, Fred A. ''Introduction to Focused Ion Beams: Instrumentation, Theory, Techniques, and Practice'', Springer 2005 – 357 pages
]
Another common use of FIB instruments is for
design verification and/or
failure analysis of semiconductor devices. Design verification combines selective material removal with gas-assisted material deposition of conductive, dielectric, or insulating materials. Engineering prototype devices may be modified using the ion beam in combination with gas-assisted material deposition in order to rewire an integrated circuit's conductive pathways. The techniques are effectively used to verify the correlation between the CAD design and the actual functional prototype circuit, thereby avoiding the creation of a new mask for the purpose of testing design changes.
Ions beams are also used for analysis purposes in Materials science. For example sputtering techniques can be used for surface analysis or depth profiling by performing
secondary ion mass spectrometry. It is also possible to gain information from the spectroscopy of transmitted or backscattered primary ions, e.g. depth profiles can be obtained from
Rutherford backscattering (RBS) spectra.
In difference to secondary ion spectroscopy scattering based techniques like RBS are often less destructive to the sample.
Biology
In
radiobiology
Radiobiology (also known as radiation biology, and uncommonly as actinobiology) is a field of clinical and basic medical sciences that involves the study of the effects of radiation on living tissue (including ionizing radiation, ionizing and non- ...
a broad or
focused ion beam is used to study mechanisms of inter- and intra- cellular communication,
signal transduction
Signal transduction is the process by which a chemical or physical signal is transmitted through a cell as a biochemical cascade, series of molecular events. Proteins responsible for detecting stimuli are generally termed receptor (biology), rece ...
and DNA damage and
repair
The technical meaning of maintenance involves functional checks, servicing, repairing or replacing of necessary devices, equipment, machinery, building infrastructure and supporting utilities in industrial, business, and residential installat ...
.
Medicine
Ion beams are also used in
particle therapy, most often in the treatment of cancer.
Space applications
Ion beams produced by ion and plasma thrusters on board a spacecraft can be used to transmit a force to a nearby object (e.g. another spacecraft, an asteroid, etc.) that is irradiated by the beam. This innovative propulsion technique named
Ion Beam Shepherd has been shown to be effective in the area of active space debris removal as well as asteroid deflection.
High-energy ion beams
High-energy ion beams produced by
particle accelerator
A particle accelerator is a machine that uses electromagnetic fields to propel electric charge, charged particles to very high speeds and energies to contain them in well-defined particle beam, beams. Small accelerators are used for fundamental ...
s are used in
atomic physics
Atomic physics is the field of physics that studies atoms as an isolated system of electrons and an atomic nucleus. Atomic physics typically refers to the study of atomic structure and the interaction between atoms. It is primarily concerned wit ...
,
nuclear physics
Nuclear physics is the field of physics that studies atomic nuclei and their constituents and interactions, in addition to the study of other forms of nuclear matter.
Nuclear physics should not be confused with atomic physics, which studies th ...
and
particle physics
Particle physics or high-energy physics is the study of Elementary particle, fundamental particles and fundamental interaction, forces that constitute matter and radiation. The field also studies combinations of elementary particles up to the s ...
.
As weapon
Ion beams can theoretically be used to make a weapon, but this has not been demonstrated. Electron beam weapons were tested by the U.S. Navy in the early 20th century, but the
hose instability effect prevents them from being accurate at a distance of over approximately 30 inches.
See also
*
Ion source
An ion source is a device that creates atomic and molecular ions. Ion sources are used to form ions for mass spectrometers, optical emission spectrometers, particle accelerators, ion implanters and ion engines.
Electron ionization
Elect ...
*
Ion thruster
An ion thruster, ion drive, or ion engine is a form of electric propulsion used for spacecraft propulsion. An ion thruster creates a cloud of positive ions from a neutral gas by ionizing it to extract some electrons from its atoms. The i ...
*
Ion wind
References
External links
Stopping parameters of ion beams in solids calculated by MELF-GOS model
ISOLDE – Facility dedicated to the production of a large variety of radioactive ion beams located at CERN
{{DEFAULTSORT:Ion Beam
Plasma technology and applications
Semiconductor device fabrication
Semiconductor analysis
Thin film deposition
Ions
Accelerator physics