Hugo M. Rietveld (7 March 1932 – 16 July 2016
) was a Dutch
crystallographer who is famous for single handedly publishing joint work of Loopstra, van Laar and himself on the full profile refinement method in powder diffraction, which became later known as the
Rietveld refinement
Rietveld refinement is a technique described by Hugo Rietveld for use in the characterisation of crystalline materials. The neutron diffraction, neutron and x-ray crystallography, X-ray Powder diffraction, diffraction of powder samples results in ...
method. The method was developed by Loopstra and van Laar and programmed in Algol by Rietveld to refine neutron diffraction data, but is applicable to other diffraction experiments as well, like X-ray diffraction. The Rietveld refinement uses a
least squares
The method of least squares is a mathematical optimization technique that aims to determine the best fit function by minimizing the sum of the squares of the differences between the observed values and the predicted values of the model. The me ...
approach to refine a theoretical line profile (calculated from a known or postulated crystal structure) until it matches the measured profile. The introduction of this technique which used the full profile instead of individual reflections was a significant step forward in the diffraction analysis of powder samples.
Biography
Rietveld was born in
the Hague
The Hague ( ) is the capital city of the South Holland province of the Netherlands. With a population of over half a million, it is the third-largest city in the Netherlands. Situated on the west coast facing the North Sea, The Hague is the c ...
. After completing Grammar School in the Netherlands he moved to
Australia
Australia, officially the Commonwealth of Australia, is a country comprising mainland Australia, the mainland of the Australia (continent), Australian continent, the island of Tasmania and list of islands of Australia, numerous smaller isl ...
and studied physics at the
University of Western Australia
University of Western Australia (UWA) is a public research university in the Australian state of Western Australia. The university's main campus is in Crawley, Western Australia, Crawley, a suburb in the City of Perth local government area. UW ...
in
Perth
Perth () is the list of Australian capital cities, capital city of Western Australia. It is the list of cities in Australia by population, fourth-most-populous city in Australia, with a population of over 2.3 million within Greater Perth . The ...
. In 1964 he obtained his
PhD
A Doctor of Philosophy (PhD, DPhil; or ) is a terminal degree that usually denotes the highest level of academic achievement in a given discipline and is awarded following a course of graduate study and original research. The name of the deg ...
degree under
Edward Norman Maslen with a thesis entitled "The Structure of
p-Diphenylbenzene and Other Compounds", a single crystal
neutron
The neutron is a subatomic particle, symbol or , that has no electric charge, and a mass slightly greater than that of a proton. The Discovery of the neutron, neutron was discovered by James Chadwick in 1932, leading to the discovery of nucle ...
and
X-ray diffraction
X-ray diffraction is a generic term for phenomena associated with changes in the direction of X-ray beams due to interactions with the electrons around atoms. It occurs due to elastic scattering, when there is no change in the energy of the waves. ...
study.
Dorothy Hodgkin
Dorothy Mary Crowfoot Hodgkin (née Crowfoot; 12 May 1910 – 29 July 1994) was a Nobel Prize-winning English chemist who advanced the technique of X-ray crystallography to determine the structure of biomolecules, which became essential for ...
was an external examiner on his thesis. This investigation was the first single crystal
neutron diffraction
Neutron diffraction or elastic neutron scattering is the application of neutron scattering to the determination of the atomic and/or magnetic structure of a material. A sample to be examined is placed in a beam of Neutron temperature, thermal or ...
study in
Australia
Australia, officially the Commonwealth of Australia, is a country comprising mainland Australia, the mainland of the Australia (continent), Australian continent, the island of Tasmania and list of islands of Australia, numerous smaller isl ...
and was conducted at the
High Flux Australian Reactor
The High Flux Australian Reactor (HIFAR) was Australia's first Research reactor, nuclear research reactor. It was built at the Australian Atomic Energy Commission (AAEC) research establishment at , Sydney, New South Wales. The reactor was in ope ...
(
HIFAR
The High Flux Australian Reactor (HIFAR) was Australia's first nuclear research reactor. It was built at the Australian Atomic Energy Commission (AAEC) research establishment at , Sydney, New South Wales. The reactor was in operation between 195 ...
) in the
Lucas Heights suburb of
Sydney
Sydney is the capital city of the States and territories of Australia, state of New South Wales and the List of cities in Australia by population, most populous city in Australia. Located on Australia's east coast, the metropolis surrounds Syd ...
.
In 1964 he became a research officer at the
Energy Research Centre of the Netherlands
The Energy Research Centre of the Netherlands (ECN) is one of the largest energy research institute in Europe and holds a strong international position. With and for the market, ECN develops knowledge and technology that enable a transition to a ...
(
Energieonderzoek Centrum Nederland, ECN) in
Petten
Petten is a village in the Netherlands, Dutch province of North Holland. It is a part of the municipality of Schagen, and lies about 15 km northwest of Alkmaar, on the North Sea. The population is ca. 1900.
Petten's economy is based on agricu ...
, where he worked together with Bert Loopstra and Bob van Laar on the structure solution and refinement of
uranate
A uranate is a ternary oxide involving the element uranium in one of the oxidation states 4, 5 or 6. A typical chemical formula is MxUyOz, where M represents a cation. The uranium atom in uranates(VI) has two short collinear U–O bonds and eith ...
s and other
ceramic
A ceramic is any of the various hard, brittle, heat-resistant, and corrosion-resistant materials made by shaping and then firing an inorganic, nonmetallic material, such as clay, at a high temperature. Common examples are earthenware, porcela ...
compounds using neutron
powder diffraction
Powder diffraction is a scientific technique using X-ray, neutron, or electron diffraction on powder or microcrystalline samples for structural characterization of materials. An instrument dedicated to performing such powder measurements is ca ...
. In 1967 he implemented the full profile refinement method in a computer program, which he published as his own achievement under his own name in his 1969 citation classic. After publishing this important project alone, Rietveld found his position in the small Petten group increasingly difficult. In 1974 he successfully applied for the post of head of the ECN library, a function that had been vacant for some time, and consequently he left science. He remained with the library until his retirement in 1992.
[Obituary Hugo Rietveld (1932–2016), '']loc. cit.
{{Italic title
''Loc. cit.'' (Latin, short for ''loco citato'', meaning "in the place cited") is a footnote or endnote term used to repeat the title and page number for a given work (and author). ''Loc. cit.'' is used in place of ibid. when the ref ...
''
Awards
*
The Royal Swedish Academy of Sciences
The Royal Swedish Academy of Sciences () is one of the royal academies of Sweden. Founded on 2 June 1739, it is an independent, non-governmental scientific organization that takes special responsibility for promoting natural sciences and mathem ...
awarded Hugo M. Rietveld, the
Aminoff prize in
Stockholm
Stockholm (; ) is the Capital city, capital and List of urban areas in Sweden by population, most populous city of Sweden, as well as the List of urban areas in the Nordic countries, largest urban area in the Nordic countries. Approximately ...
, 31 March 1995.
* Barrett Award on behalf of the
Denver
Denver ( ) is a List of municipalities in Colorado#Consolidated city and county, consolidated city and county, the List of capitals in the United States, capital and List of municipalities in Colorado, most populous city of the U.S. state of ...
X-ray
An X-ray (also known in many languages as Röntgen radiation) is a form of high-energy electromagnetic radiation with a wavelength shorter than those of ultraviolet rays and longer than those of gamma rays. Roughly, X-rays have a wavelength ran ...
Conference Organizing Committee in
Denver
Denver ( ) is a List of municipalities in Colorado#Consolidated city and county, consolidated city and county, the List of capitals in the United States, capital and List of municipalities in Colorado, most populous city of the U.S. state of ...
,
U.S.
The United States of America (USA), also known as the United States (U.S.) or America, is a country primarily located in North America. It is a federal republic of 50 states and a federal capital district, Washington, D.C. The 48 contiguous ...
, 6 August 2003.
* The Royal Award of Officer in the
Order of Oranje-Nassau
The Order of Orange-Nassau () is a civil and military Dutch order of chivalry founded on 4 April 1892 by the queen regent, Emma of the Netherlands.
The order is a chivalric order open to "everyone who has performed acts of special merits for ...
, for his outstanding contribution to the field of
chemistry
Chemistry is the scientific study of the properties and behavior of matter. It is a physical science within the natural sciences that studies the chemical elements that make up matter and chemical compound, compounds made of atoms, molecules a ...
.
Alkmaar
Alkmaar () is a List of cities in the Netherlands by province, city and List of municipalities of the Netherlands, municipality in the Netherlands, located in the Provinces of the Netherlands, province of North Holland. Alkmaar is well known fo ...
,
Netherlands
, Terminology of the Low Countries, informally Holland, is a country in Northwestern Europe, with Caribbean Netherlands, overseas territories in the Caribbean. It is the largest of the four constituent countries of the Kingdom of the Nether ...
, 28 October 2004.
* Award for Distinguished Powder Diffractionists, awarded by The European Diffraction Conferences, handed out on 30 August 2010 in
Darmstadt
Darmstadt () is a city in the States of Germany, state of Hesse in Germany, located in the southern part of the Frankfurt Rhine Main Area, Rhine-Main-Area (Frankfurt Metropolitan Region). Darmstadt has around 160,000 inhabitants, making it the ...
.
* Hans-Kühl-Medal 2010, awarded by
Gesellschaft Deutscher Chemiker
The German Chemical Society () is a learned society and professional association founded in 1949 to represent the interests of German chemists in local, national and international contexts. GDCh "brings together people working in chemistry and th ...
(GDCh), Fachgruppe Bauchemie, handed out on 7 October 2010 in
Dortmund
Dortmund (; ; ) is the third-largest city in North Rhine-Westphalia, after Cologne and Düsseldorf, and the List of cities in Germany by population, ninth-largest city in Germany. With a population of 614,495 inhabitants, it is the largest city ...
.
Further reading
* Bob van Laar, Henk Schenk, The development of powder profile refinement at the Reactor Centre Netherlands at Petten. International Union of Crystallography (December 2017).
* Young, R. A. (Ed.). (1993). The Rietveld method (Vol. 6). Oxford. Oxford University Press.
*
References
{{DEFAULTSORT:Rietveld, Hugo
1932 births
2016 deaths
Crystallographers
Dutch expatriates in Australia
20th-century Dutch physicists
Scientists from The Hague
University of Western Australia alumni