Hopper Crystal
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A hopper crystal is a form of
crystal A crystal or crystalline solid is a solid material whose constituents (such as atoms, molecules, or ions) are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macros ...
, the shape of which resembles that of a pyramidal
hopper Hopper or hoppers may refer to: Places * Hopper, Illinois * Hopper, West Virginia * Hopper, a mountain and valley in the Hunza–Nagar District of Pakistan * Hopper (crater), a crater on Mercury People * Hopper (surname) Insects * Hopper, the ...
container. The edges of hopper crystals are fully developed, but the interior spaces are not filled in. This results in what appears to be a hollowed out step
lattice Lattice may refer to: Arts and design * Latticework, an ornamental criss-crossed framework, an arrangement of crossing laths or other thin strips of material * Lattice (music), an organized grid model of pitch ratios * Lattice (pastry), an or ...
formation, as if someone had removed interior sections of the individual crystals. In fact, the "removed" sections never filled in, because the crystal was growing so rapidly that there was not enough time (or material) to fill in the gaps. The interior edges of a hopper crystal still show the crystal form characteristic to the specific
mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid substance with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. (2011): Mi ...
, and so appear to be a series of smaller and smaller stepped down miniature versions of the original crystal. Hoppering occurs when
electrical attraction Electricity is the set of physical phenomena associated with the presence and motion of matter possessing an electric charge. Electricity is related to magnetism, both being part of the phenomenon of electromagnetism, as described by Maxwel ...
is higher along the edges of the crystal; this causes faster growth at the edges than near the face centers. This attraction draws the mineral
molecule A molecule is a group of two or more atoms that are held together by Force, attractive forces known as chemical bonds; depending on context, the term may or may not include ions that satisfy this criterion. In quantum physics, organic chemi ...
s more strongly than the interior sections of the crystal, thus the edges develop more quickly. However, the basic physics of this type of growth is the same as that of
dendrite A dendrite (from Ancient Greek language, Greek δένδρον ''déndron'', "tree") or dendron is a branched cytoplasmic process that extends from a nerve cell that propagates the neurotransmission, electrochemical stimulation received from oth ...
s but, because the anisotropy in the solid–liquid inter-facial energy is so large, the dendrite so produced exhibits a faceted morphology. Hoppering is common in many minerals, including lab-grown
bismuth Bismuth is a chemical element; it has symbol Bi and atomic number 83. It is a post-transition metal and one of the pnictogens, with chemical properties resembling its lighter group 15 siblings arsenic and antimony. Elemental bismuth occurs nat ...
,
galena Galena, also called lead glance, is the natural mineral form of lead(II) sulfide (PbS). It is the most important ore of lead and an important source of silver. Galena is one of the most abundant and widely distributed sulfide minerals. It crysta ...
,
quartz Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The Atom, atoms are linked in a continuous framework of SiO4 silicon–oxygen Tetrahedral molecular geometry, tetrahedra, with each oxygen being shared between two tet ...
(called skeletal or fenster crystals),
gold Gold is a chemical element; it has chemical symbol Au (from Latin ) and atomic number 79. In its pure form, it is a brightness, bright, slightly orange-yellow, dense, soft, malleable, and ductile metal. Chemically, gold is a transition metal ...
,
calcite Calcite is a Carbonate minerals, carbonate mineral and the most stable Polymorphism (materials science), polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on ...
,
halite Halite ( ), commonly known as rock salt, is a type of salt, the mineral (natural) form of sodium chloride ( Na Cl). Halite forms isometric crystals. The mineral is typically colorless or white, but may also be light blue, dark blue, purple, pi ...
(salt), and
water Water is an inorganic compound with the chemical formula . It is a transparent, tasteless, odorless, and Color of water, nearly colorless chemical substance. It is the main constituent of Earth's hydrosphere and the fluids of all known liv ...
(ice). In 2017,
Frito-Lay Frito-Lay, Inc. (; ) is an American food company that manufactures, markets, and sells snack foods. It began in the early 1930s as two companies, Fritos, the Frito Company and Lay's, H.W. Lay & Company, that merged in 1961. Frito-Lay itself merg ...
filed for (and later received) a patent for a salt cube hopper crystal. Because the shape increases surface area to volume, it allows people to taste more salt compared to the amount actually consumed.


References

{{Reflist
Hopper crystals
in ''
A New Kind of Science ''A New Kind of Science'' is a book by Stephen Wolfram, published by his company Wolfram Research under the imprint Wolfram Media in 2002. It contains an empirical and systematic study of computational systems such as cellular automata. Wolfram ...
'' by
Stephen Wolfram Stephen Wolfram ( ; born 29 August 1959) is a British-American computer scientist, physicist, and businessman. He is known for his work in computer algebra and theoretical physics. In 2012, he was named a fellow of the American Mathematical So ...
, p. 993.


External links


Images of hopper crystals, Glendale Community College Earth Science Image Archive
Crystals