Hexamolybdenum is a

molybdenum Molybdenum is a chemical element; it has Symbol (chemistry), symbol Mo (from Neo-Latin ''molybdaenum'') and atomic number 42. The name derived from Ancient Greek ', meaning lead, since its ores were confused with lead ores. Molybdenum minerals hav ...

dominant

alloy An alloy is a mixture of chemical elements of which in most cases at least one is a metal, metallic element, although it is also sometimes used for mixtures of elements; herein only metallic alloys are described. Metallic alloys often have prop ...

discovered during a nanomineralogy investigation of the

Allende meteorite The Allende meteorite is the largest carbonaceous chondrite ever found on Earth. The fireball was witnessed at 01:05 on February 8, 1969, falling over the Mexican state of Chihuahua. After it broke up in the atmosphere, an extensive search for p ...

. Hexamolybdenum was discovered in a small ultra

refractory In materials science, a refractory (or refractory material) is a material that is resistant to decomposition by heat or chemical attack and that retains its strength and rigidity at high temperatures. They are inorganic, non-metallic compound ...

inclusion Inclusion or Include may refer to: Sociology * Social inclusion, action taken to support people of different backgrounds sharing life together. ** Inclusion (disability rights), promotion of people with disabilities sharing various aspects of lif ...

within the Allende meteorite. This inclusion has been named ACM-1. Hexamolybdenum is

hexagonal In geometry, a hexagon (from Greek , , meaning "six", and , , meaning "corner, angle") is a six-sided polygon. The total of the internal angles of any simple (non-self-intersecting) hexagon is 720°. Regular hexagon A regular hexagon is d ...

, with a calculated

density Density (volumetric mass density or specific mass) is the ratio of a substance's mass to its volume. The symbol most often used for density is ''ρ'' (the lower case Greek letter rho), although the Latin letter ''D'' (or ''d'') can also be u ...

of 11.90 g/cm³. The new mineral was found along with

allendeite Allendeite, Sc4Zr3O12, is an oxide mineral. Allendeite was discovered in a small ultrarefractory inclusion within the Allende meteorite. This inclusion has been named ACM-1. It is one of several scandium rich minerals that have been found in met ...

. These minerals, are believed to demonstrate conditions during the early stages of the

Solar System The Solar SystemCapitalization of the name varies. The International Astronomical Union, the authoritative body regarding astronomical nomenclature, specifies capitalizing the names of all individual astronomical objects but uses mixed "Sola ...

, as is the case with many CV3 carbonaceous chondrites such as the Allende meteorite. Hexamolybdenum lies on a continuum of high-temperature alloys that are found in meteorites and allows a link between

osmium Osmium () is a chemical element; it has Symbol (chemistry), symbol Os and atomic number 76. It is a hard, brittle, bluish-white transition metal in the platinum group that is found as a Abundance of elements in Earth's crust, trace element in a ...

ruthenium Ruthenium is a chemical element; it has symbol Ru and atomic number 44. It is a rare transition metal belonging to the platinum group of the periodic table. Like the other metals of the platinum group, ruthenium is unreactive to most chem ...

, and

iron Iron is a chemical element; it has symbol Fe () and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, forming much of Earth's o ...

rich meteoritic alloys. The name hexamolybdenum refers to the crystal symmetry (primitive hexagonal) and the molybdenum rich composition. The Allende meteorite fell in 1969 near Pueblito de Allende, Chihuahua,

Mexico Mexico, officially the United Mexican States, is a country in North America. It is the northernmost country in Latin America, and borders the United States to the north, and Guatemala and Belize to the southeast; while having maritime boundar ...

Occurrence

Hexamolybdenum was found as nano-crystals in an ultrarefractory inclusion in the Allende meteorite. The Allende meteorite has shown to be full of new minerals, after nearly forty years it has produced one in ten of the now known minerals in meteorites. This CV3

carbonaceous chondrite Carbonaceous chondrites or C chondrites are a class of chondritic meteorites comprising at least 8 known groups and many ungrouped meteorites. They include some of the most primitive known meteorites. The C chondrites represent only a small propo ...

was the largest ever recovered on earth and is referred to as the best-studied meteorite in history. The inclusion has only been viewed via

electron microscopy An electron microscope is a microscope that uses a beam of electrons as a source of illumination. It uses electron optics that are analogous to the glass lenses of an optical light microscope to control the electron beam, for instance focusing i ...

. The hexamolybdenum specimen was lost during an attempted ion probe analysis of a bordering grain. Other specimens can be found, however, in the Smithsonian Institution's National Museum of Natural History Allende section USNM 3509HC12 and in section USNM 7590 of NWA 1934, another VC3 chondrite. It has also been reported from the NWA 1934 CV3 carbonaceous chondrite meteorite from the Erfoud region of

Morocco Morocco, officially the Kingdom of Morocco, is a country in the Maghreb region of North Africa. It has coastlines on the Mediterranean Sea to the north and the Atlantic Ocean to the west, and has land borders with Algeria to Algeria–Morocc ...

and in the Danubian placer of

Straubing Straubing (; Central Bavarian: ''Strauwing'') is an independent city in Lower Bavaria, southern Germany. It is seat of the Districts of Germany, district of Straubing-Bogen. Annually in August the Gäubodenvolksfest, the second largest fair in Ba ...

Bavaria Bavaria, officially the Free State of Bavaria, is a States of Germany, state in the southeast of Germany. With an area of , it is the list of German states by area, largest German state by land area, comprising approximately 1/5 of the total l ...

Chemical composition

Hexamolybdenum is an (molybdenum,

iridium Iridium is a chemical element; it has the symbol Ir and atomic number 77. This very hard, brittle, silvery-white transition metal of the platinum group, is considered the second-densest naturally occurring metal (after osmium) with a density ...

) alloy.

Appearance

Color Color (or colour in English in the Commonwealth of Nations, Commonwealth English; American and British English spelling differences#-our, -or, see spelling differences) is the visual perception based on the electromagnetic spectrum. Though co ...

, streak, luster,

hardness In materials science, hardness (antonym: softness) is a measure of the resistance to plastic deformation, such as an indentation (over an area) or a scratch (linear), induced mechanically either by Pressing (metalworking), pressing or abrasion ...

, tenacity,

cleavage Cleavage may refer to: Science * Cleavage (crystal), the way in which a crystal or mineral tends to split * Cleavage (embryo), the division of cells in an early embryo * Cleavage (geology), foliation of rock perpendicular to stress, a result of ...

fracture Fracture is the appearance of a crack or complete separation of an object or material into two or more pieces under the action of stress (mechanics), stress. The fracture of a solid usually occurs due to the development of certain displacemen ...

, and

refractive index In optics, the refractive index (or refraction index) of an optical medium is the ratio of the apparent speed of light in the air or vacuum to the speed in the medium. The refractive index determines how much the path of light is bent, or refrac ...

could not be observed because the grain size was too small and the section bearing the mineral was optically thick.

References

{{Reflist, 30em Hexagonal minerals Minerals in space group 194 Native element minerals Molybdenum minerals Ferrous alloys Ruthenium minerals Iron minerals Iridium minerals Osmium compounds

Occurrence

Chemical composition

Appearance

See also

References