Gamow Factor
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The Gamow factor, Sommerfeld factor or Gamow–Sommerfeld factor, named after physicists
George Gamow George Gamow (sometimes Gammoff; born Georgiy Antonovich Gamov; ; 4 March 1904 – 19 August 1968) was a Soviet and American polymath, theoretical physicist and cosmologist. He was an early advocate and developer of Georges Lemaître's Big Ba ...
or after
Arnold Sommerfeld Arnold Johannes Wilhelm Sommerfeld (; 5 December 1868 – 26 April 1951) was a German Theoretical physics, theoretical physicist who pioneered developments in Atomic physics, atomic and Quantum mechanics, quantum physics, and also educated and ...
, is a probability factor for two nuclear particles' chance of overcoming the
Coulomb barrier The Coulomb barrier, named after Coulomb's law, which is in turn named after physicist Charles-Augustin de Coulomb, is the energy barrier due to electrostatic interaction that two nuclei need to overcome so they can get close enough to undergo a ...
in order to undergo nuclear reactions, for example in
nuclear fusion Nuclear fusion is a nuclear reaction, reaction in which two or more atomic nuclei combine to form a larger nuclei, nuclei/neutrons, neutron by-products. The difference in mass between the reactants and products is manifested as either the rele ...
. By
classical physics Classical physics refers to physics theories that are non-quantum or both non-quantum and non-relativistic, depending on the context. In historical discussions, ''classical physics'' refers to pre-1900 physics, while '' modern physics'' refers to ...
, there is almost no possibility for protons to fuse by crossing each other's Coulomb barrier at temperatures commonly observed to cause fusion, such as those found in the
Sun The Sun is the star at the centre of the Solar System. It is a massive, nearly perfect sphere of hot plasma, heated to incandescence by nuclear fusion reactions in its core, radiating the energy from its surface mainly as visible light a ...
. In 1927 it was discovered that there is a significant chance for nuclear fusion due to
quantum tunnelling In physics, quantum tunnelling, barrier penetration, or simply tunnelling is a quantum mechanical phenomenon in which an object such as an electron or atom passes through a potential energy barrier that, according to classical mechanics, shoul ...
. While the probability of overcoming the Coulomb barrier increases rapidly with increasing particle energy, for a given temperature, the probability of a particle having such an energy falls off very fast, as described by the
Maxwell–Boltzmann distribution In physics (in particular in statistical mechanics), the Maxwell–Boltzmann distribution, or Maxwell(ian) distribution, is a particular probability distribution named after James Clerk Maxwell and Ludwig Boltzmann. It was first defined and use ...
. Gamow found that, taken together, these effects mean that for any given temperature, the particles that fuse are mostly in a temperature-dependent narrow range of energies known as the Gamow window. The maximum of the distribution is called the Gamow peak.


Description

The probability of two nuclear particles overcoming their electrostatic barriers is given by the following factor: : P_\text(E) = e^, where E_\text is the Gamow energy : E_\text \equiv 2 \mu c^2 (\pi \alpha Z_\text Z_\text)^2, where \mu= \frac is the
reduced mass In physics, reduced mass is a measure of the effective inertial mass of a system with two or more particles when the particles are interacting with each other. Reduced mass allows the two-body problem to be solved as if it were a one-body probl ...
of the two particles. The constant \alpha is the
fine-structure constant In physics, the fine-structure constant, also known as the Sommerfeld constant, commonly denoted by (the Alpha, Greek letter ''alpha''), is a Dimensionless physical constant, fundamental physical constant that quantifies the strength of the el ...
, c is the
speed of light The speed of light in vacuum, commonly denoted , is a universal physical constant exactly equal to ). It is exact because, by international agreement, a metre is defined as the length of the path travelled by light in vacuum during a time i ...
, and Z_\text and Z_\text are the respective
atomic number The atomic number or nuclear charge number (symbol ''Z'') of a chemical element is the charge number of its atomic nucleus. For ordinary nuclei composed of protons and neutrons, this is equal to the proton number (''n''p) or the number of pro ...
s of each particle. It is sometimes rewritten using the Sommerfeld parameter , such that : P_\text(E) = e^, where is a
dimensionless quantity Dimensionless quantities, or quantities of dimension one, are quantities implicitly defined in a manner that prevents their aggregation into unit of measurement, units of measurement. ISBN 978-92-822-2272-0. Typically expressed as ratios that a ...
used in
nuclear astrophysics Nuclear astrophysics studies the origin of the chemical elements and isotopes, and the role of nuclear energy generation, in cosmic sources such as stars, supernovae, novae, and violent binary-star interactions. It is an interdisciplinary part ...
in the calculation of reaction rates between two nuclei and it also appears in the definition of the astrophysical ''S''-factor. It is defined as : \eta = \frac = \alpha Z_1 Z_2 \sqrt, where is the
elementary charge The elementary charge, usually denoted by , is a fundamental physical constant, defined as the electric charge carried by a single proton (+1 ''e'') or, equivalently, the magnitude of the negative electric charge carried by a single electron, ...
, is the magnitude of the relative incident
velocity Velocity is a measurement of speed in a certain direction of motion. It is a fundamental concept in kinematics, the branch of classical mechanics that describes the motion of physical objects. Velocity is a vector (geometry), vector Physical q ...
in the centre-of-mass frame.


Derivation


1D problem

The derivation consists in the one-dimensional case of quantum tunnelling using the
WKB approximation In mathematical physics, the WKB approximation or WKB method is a technique for finding approximate solutions to Linear differential equation, linear differential equations with spatially varying coefficients. It is typically used for a Semiclass ...
. Considering a wave function of a particle of mass ''m'', we take area 1 to be where a wave is emitted, area 2 the potential barrier which has height ''V'' and width ''l'' (at 0), and area 3 its other side, where the wave is arriving, partly transmitted and partly reflected. For wave numbers ''k'' -1and energy ''E'' we get: : \Psi_1=Ae^e^ : \Psi_2=B_1e^+B_2e^ : \Psi_3=(C_1e^+C_2e^)\cdot e^ where k = \sqrt and k' = \sqrt, both in /m This is solved for given ''A'' and phase ''α'' by taking the boundary conditions at the barrier edges, at x=0 and x=l: there \Psi_(t) and its derivatives must be equal on both sides. For k'l \gg 1, this is easily solved by ignoring the time exponential and considering the real part alone (the imaginary part has the same behaviour). We get, up to factors * depending on the ''β'' phases which are typically of order 1, and * of the order of /=\sqrt (assumed not very large, since ''V'' is greater than ''E'' (not marginally)): \Psi_1=Ae^ , \Psi_3=C_1e^+C_2e^, \Psi_2\approx Ae^ +Ae^: B_1,B_2\approx A and C_1, C_2 \approx \fracA\frac e^. Next, the
alpha decay Alpha decay or α-decay is a type of radioactive decay in which an atomic nucleus emits an alpha particle (helium nucleus). The parent nucleus transforms or "decays" into a daughter product, with a mass number that is reduced by four and an a ...
can be modelled as a symmetric one-dimensional problem, with a standing wave between two symmetric potential barriers at q_0 and -(q_0+l), and emitting waves at both outer sides of the barriers. Solving this can in principle be done by taking the solution of the first problem, translating it by q_0 and gluing it to an identical solution reflected around x=0. Due to the symmetry of the problem, the emitting waves on both sides must have equal amplitudes (''A''), but their phases (''α'') may be different. This gives a single extra parameter; however, gluing the two solutions at x=0 requires two boundary conditions (for both the wave function and its derivative), so in general there is no solution. In particular, re-writing \Psi_3 (after translation by q_0) as a sum of a cosine and a sine of kx, each having a different factor that depends on ''k'' and ''β;'' the factor of the sine must vanish, so that the solution can be glued symmetrically to its reflection. Since the factor is in general complex (hence its vanishing imposes two constraints, representing the two boundary conditions), this can in general be solved by adding an imaginary part of ''k'', which gives the extra parameter needed. Thus ''E'' will have an imaginary part as well. The physical meaning of this is that the
standing wave In physics, a standing wave, also known as a stationary wave, is a wave that oscillates in time but whose peak amplitude profile does not move in space. The peak amplitude of the wave oscillations at any point in space is constant with respect t ...
in the middle decays; the waves newly emitted have therefore smaller amplitudes, so that their amplitude decays in time but grows with distance. The ''decay constant'', denoted ''λ'' /s is assumed small compared to E/\hbar. ''λ'' can be estimated without solving explicitly, by noting its effect on the probability current conservation law. Since the probability flows from the middle to the sides, we have: : \frac \int_^ \Psi^*\Psi\ dx = 2 \frac\left(\Psi_1^* \frac- \Psi_1 \frac \right) , note the factor of 2 is due to having two emitted waves. Taking \Psi\sim e^, this gives: : \lambda\frac (q_0+l)\left(A\frac\right)^2 e^\approx2\fracA^2k. Since the quadratic dependence on k'l is negligible relative to its exponential dependence, we may write: : \lambda\approx4\frac \frac\cdot e^. Remembering the imaginary part added to ''k'' is much smaller than the real part, we may now neglect it and get: : \lambda\approx4\frac\cdot \frac\cdot e^. Note that \frac=\sqrt is the particle velocity, so the first factor is the classical rate by which the particle trapped between the barriers (2q_0 apart) hits them.


3D problem

Finally, moving to the three-dimensional problem, the spherically symmetric
Schrödinger equation The Schrödinger equation is a partial differential equation that governs the wave function of a non-relativistic quantum-mechanical system. Its discovery was a significant landmark in the development of quantum mechanics. It is named after E ...
reads (expanding the wave function \psi(r,\theta,\phi) = \chi(r)u(\theta,\phi) in
spherical harmonics In mathematics and physical science, spherical harmonics are special functions defined on the surface of a sphere. They are often employed in solving partial differential equations in many scientific fields. The table of spherical harmonics co ...
and looking at the ''l''-th term): : \frac\left(\frac+\frac\frac\right)=\left(V(r)+\frac\frac-E\right)\chi. Since \ell>0 amounts to enlarging the potential, and therefore substantially reducing the
decay rate Radioactive decay (also known as nuclear decay, radioactivity, radioactive disintegration, or nuclear disintegration) is the process by which an unstable atomic nucleus loses energy by radiation. A material containing unstable nuclei is conside ...
(given its exponential dependence on \sqrt): we focus on \ell=0, and get a very similar problem to the previous one with \chi(r) = \Psi(r)/r , except that now the potential as a function of ''r'' is not a
step function In mathematics, a function on the real numbers is called a step function if it can be written as a finite linear combination of indicator functions of intervals. Informally speaking, a step function is a piecewise constant function having on ...
. In short \frac\left(\ddot\chi+\frac\dot\chi\right)=\left(V(r)-E\right)\chi. The main effect of this on the amplitudes is that we must replace the argument in the exponent, taking an integral of 2\sqrt/\hbar over the distance where V(r)>E rather than multiplying by width ''l''. We take the
Coulomb potential Electric potential (also called the ''electric field potential'', potential drop, the electrostatic potential) is defined as electric potential energy per unit of electric charge. More precisely, electric potential is the amount of work (physic ...
: : V(r) = \frac where \varepsilon_0 is the vacuum electric permittivity, ''e'' the
electron charge C, or c, is the third letter of the Latin alphabet, used in the modern English alphabet, the alphabets of other western European languages and others worldwide. Its name in English is ''cee'' (pronounced ), plural ''cees''. History "C ...
, ''z'' = 2 is the charge number of the alpha particle and ''Z'' the charge number of the nucleus (''Z''–''z'' after emitting the particle). The integration limits are then: r_2 = \frac , where we assume the nuclear potential energy is still relatively small, and r_1, which is where the nuclear negative potential energy is large enough so that the overall potential is smaller than ''E''. Thus, the argument of the exponent in ''λ'' is: : 2\frac \int_^\sqrt \,dr=2\frac\int_^\sqrt\,dr. This can be solved by substituting t=\sqrt and then t=\cos(\theta) and solving for θ, giving: : 2r_2\frac cos^(\sqrt)-\sqrt\sqrt2\frac\left cos^(\sqrt)-\sqrt\sqrt\right/math> where x = r_1/r_2. Since ''x'' is small, the ''x''-dependent factor is of the order 1. Assuming x\ll 1, the ''x''-dependent factor can be replaced by \arccos0=\pi/2, giving:
\lambda\approx e^ with E_=\frac.
Which is the same as the formula given in the beginning of the article with Z_\text=z, Z_\text=Z-z and the fine-structure constant \alpha=\frac: \sqrt=\sqrt/(4\epsilon_0\hbar) _aeZ_be For a
radium Radium is a chemical element; it has chemical symbol, symbol Ra and atomic number 88. It is the sixth element in alkaline earth metal, group 2 of the periodic table, also known as the alkaline earth metals. Pure radium is silvery-white, ...
alpha decay, ''Z'' = 88, ''z'' = 2 and ''m'' ≈ 4 ''m''p, ''E''G is approximately 50  GeV. Gamow calculated the slope of \log(\lambda) with respect to ''E'' at an energy of 5 
MeV In physics, an electronvolt (symbol eV), also written electron-volt and electron volt, is the measure of an amount of kinetic energy gained by a single electron accelerating through an electric potential difference of one volt in vacuum. When us ...
to be ~ 1014 J−1, compared to the experimental value of .


Gamow peak

For an ideal gas, the
Maxwell–Boltzmann distribution In physics (in particular in statistical mechanics), the Maxwell–Boltzmann distribution, or Maxwell(ian) distribution, is a particular probability distribution named after James Clerk Maxwell and Ludwig Boltzmann. It was first defined and use ...
is proportional to :P_\text(E)\propto e^=e^ where \langle v^2 \rangle is the average squared speed of all particles, k_ is the
Boltzmann constant The Boltzmann constant ( or ) is the proportionality factor that relates the average relative thermal energy of particles in a ideal gas, gas with the thermodynamic temperature of the gas. It occurs in the definitions of the kelvin (K) and the ...
and ''T'' is absolute temperature. The fusion probability is the product of the Maxwell–Boltzmann distribution factor and the Gamow factor :P_\text(E)=P_\text(E)\cdot P_\text(E) =\exp\left(-\frac-\sqrt\right) The maximum of the fusion probability is given by \partial P_\text/\partial E=0, which yields :E_=\left _\left(\frac\right)^2\right. This quantity is known as the Gamow peak. Expanding P_\text around E_ gives: :P_\text(E)\approx P_\text(E_\text)\cdot\left +\left(\frac\right)^2+\cdots\right where (in joule) :\Delta(T)=4\sqrt=\frac ^_(k_T)^ is the Gamow window.


History

In 1927,
Ernest Rutherford Ernest Rutherford, 1st Baron Rutherford of Nelson (30 August 1871 – 19 October 1937) was a New Zealand physicist who was a pioneering researcher in both Atomic physics, atomic and nuclear physics. He has been described as "the father of nu ...
published an article in ''Philosophical Magazine'' on a problem related to
Hans Geiger Johannes Wilhelm Geiger ( , ; ; 30 September 1882 – 24 September 1945) was a German nuclear physicist. He is known as the inventor of the Geiger counter, a device used to detect ionizing radiation, and for carrying out the Rutherford scatt ...
's 1921 experiment of scattering
alpha particles Alpha particles, also called alpha rays or alpha radiation, consist of two protons and two neutrons bound together into a particle identical to a helium-4 nucleus. They are generally produced in the process of alpha decay but may also be produce ...
from
uranium Uranium is a chemical element; it has chemical symbol, symbol U and atomic number 92. It is a silvery-grey metal in the actinide series of the periodic table. A uranium atom has 92 protons and 92 electrons, of which 6 are valence electrons. Ura ...
. Previous experiments with thorium C' (now called
polonium Polonium is a chemical element; it has symbol Po and atomic number 84. A rare and highly radioactive metal (although sometimes classified as a metalloid) with no stable isotopes, polonium is a chalcogen and chemically similar to selenium and tel ...
-262) confirmed that uranium has a Coulomb barrier of 8.57 MeV, however uranium emitted alpha particles of 4.2 MeV. The emitted energy was too low to overcome the barrier. On 29 July 1928, George Gamow, and independently the next day Ronald Wilfred Gurney and
Edward Condon Edward Uhler Condon (March 2, 1902 – March 26, 1974) was an American nuclear physicist, a pioneer in quantum mechanics, and a participant during World War II in the development of radar and, very briefly, of nuclear weapons as part of the Ma ...
submitted their solution based on quantum tunnelling to the journal ''Zeitschrift für Physik''. Their work was based on previous work on tunnelling by
J. Robert Oppenheimer J. Robert Oppenheimer (born Julius Robert Oppenheimer ; April 22, 1904 – February 18, 1967) was an American theoretical physics, theoretical physicist who served as the director of the Manhattan Project's Los Alamos Laboratory during World ...
, Gregor Wentzel,
Lothar Wolfgang Nordheim LotharHis name is sometimes misspelled as ''Lother''. Wolfgang Nordheim (November 7, 1899, Munich – October 5, 1985, La Jolla, California) was a German-born American theoretical physicist. He was a pioneer in the applications of quantum mech ...
, and
Ralph H. Fowler Sir Ralph Howard Fowler (17 January 1889 – 28 July 1944) was an English physicist, physical chemist, and astronomer. Education Ralph H. Fowler was born at Roydon, Essex, Roydon, Essex, on 17 January 1889 to Howard Fowler, from Burnham-on-Sea, ...
. Gurney and Condon cited also
Friedrich Hund Friedrich Hermann Hund (4 February 1896 – 31 March 1997) was a German physicist from Karlsruhe known for his work on atoms and molecules. He is known for the Hund's rules to predict the electron configuration of chemical elements. His work on H ...
. In 1931,
Arnold Sommerfeld Arnold Johannes Wilhelm Sommerfeld (; 5 December 1868 – 26 April 1951) was a German Theoretical physics, theoretical physicist who pioneered developments in Atomic physics, atomic and Quantum mechanics, quantum physics, and also educated and ...
introduced a similar factor (a
Gaunt factor The Gaunt factor (or Kramers–Gaunt factor) is a correction factor that accounts for the effect of quantum mechanics on an object's continuous x-ray absorption or emission spectrum. In cases where classical physics provides a close approximation to ...
) for the discussion of
bremsstrahlung In particle physics, bremsstrahlung (; ; ) is electromagnetic radiation produced by the deceleration of a charged particle when deflected by another charged particle, typically an electron by an atomic nucleus. The moving particle loses kinetic ...
. Gamow popularized his personal version of the discovery in his 1970's book, ''My World Line: An Informal Autobiography.''


See also

* Stellar_nucleosynthesis#Reaction_rate


Notes


References

{{reflist


External links


Modeling Alpha Half-life (Georgia State University)
''hyperphysics.phy-astr.gsu.edu'' Nuclear physics George Gamow