Coal combustion products (CCPs), also called coal combustion wastes (CCWs) or coal combustion residuals (CCRs), are byproducts of burning coal. They are categorized in four groups, each based on physical and chemical forms derived from

coal Coal is a combustible black or brownish-black sedimentary rock, formed as rock strata called coal seams. Coal is mostly carbon with variable amounts of other Chemical element, elements, chiefly hydrogen, sulfur, oxygen, and nitrogen. Coal i ...

combustion Combustion, or burning, is a high-temperature exothermic redox chemical reaction between a fuel (the reductant) and an oxidant, usually atmospheric oxygen, that produces oxidized, often gaseous products, in a mixture termed as smoke. Combustion ...

methods and emission controls: CoalCombustionWastes-01

* Fly ash is captured after coal combustion by filters ( bag houses), electrostatic precipitators and other air pollution control devices. It comprises 60 percent of all coal combustion waste (labeled here as coal combustion products). It is most commonly used as a high-performance substitute for

Portland cement Portland cement is the most common type of cement in general use around the world as a basic ingredient of concrete, mortar (masonry), mortar, stucco, and non-specialty grout. It was developed from other types of hydraulic lime in England in th ...

or as clinker for Portland cement production. Cements blended with fly ash are becoming more common. Building material applications range from grouts and masonry products to cellular concrete and roofing tiles. Many asphaltic concrete pavements contain fly ash. Geotechnical applications include soil stabilization, road base, structural fill, embankments and

mine reclamation Mine reclamation is the process of modifying land that has been mined to restore it to an ecologically functional or economically usable state. Although the process of mine reclamation occurs once mining is complete, the planning of mine recl ...

. Fly ash also serves as filler in wood and plastic products, paints and metal castings. * Flue-gas desulfurization (FGD) materials are produced by chemical "

scrubber Scrubber systems (e.g. chemical scrubbers, gas scrubbers) are a diverse group of air pollution control devices that can be used to remove some particulates and/or gases from industrial exhaust streams. An early application of a carbon dioxide scr ...

" emission control systems that remove sulfur and oxides from power plant flue gas streams. FGD comprises 24 percent of all coal combustion waste. Residues vary, but the most common are FGD

gypsum Gypsum is a soft sulfate mineral composed of calcium sulfate Hydrate, dihydrate, with the chemical formula . It is widely mined and is used as a fertilizer and as the main constituent in many forms of plaster, drywall and blackboard or sidewalk ...

(or "synthetic" gypsum) and spray dryer absorbents. FGD gypsum is used in almost thirty percent of the gypsum panel products manufactured in the U.S. It is also used in agricultural applications to treat undesirable soil conditions and to improve crop performance. Other FGD materials are used in mining and land reclamation activities. *

Bottom ash Bottom ash is part of the non- combustible residue of combustion in a power plant, boiler, furnace, or incinerator. In an industrial context, it has traditionally referred to coal combustion and comprises traces of combustibles embedded in for ...

and boiler slag can be used as a raw feed for manufacturing portland cement clinker, as well as for skid control on icy roads. The two materials comprise 12 and 4 percent of coal combustion waste respectively. These materials are also suitable for geotechnical applications such as structural fills and land reclamation. The physical characteristics of bottom ash and boiler slag lend themselves as replacements for aggregate in flowable fill and in concrete masonry products. Boiler slag is also used for roofing granules and as blasting grit.

Fly ash

Fly ash, flue ash, coal ash, or pulverised fuel ash (in the UK)— plurale tantum: coal combustion residuals (CCRs)—is a coal combustion product that is composed of the

particulates Particulate matter (PM) or particulates are microscopic particles of solid or liquid matter suspension (chemistry), suspended in the atmosphere of Earth, air. An ''aerosol'' is a mixture of particulates and air, as opposed to the particulate ...

that are driven out of coal-fired

boiler A boiler is a closed vessel in which fluid (generally water) is heated. The fluid does not necessarily boil. The heated or vaporized fluid exits the boiler for use in various processes or heating applications, including water heating, centra ...

s together with the flue gases. Ash that falls to the bottom of the boiler's combustion chamber (commonly called a firebox) is called

bottom ash Bottom ash is part of the non- combustible residue of combustion in a power plant, boiler, furnace, or incinerator. In an industrial context, it has traditionally referred to coal combustion and comprises traces of combustibles embedded in for ...

. In modern coal-fired power plants, fly ash is generally captured by electrostatic precipitators or other particle filtration equipment before the flue gases reach the chimneys. Together with bottom ash removed from the bottom of the boiler, it is known as coal ash. Depending upon the source and composition of the coal being burned, the components of fly ash vary considerably, but all fly ash includes substantial amounts of

silicon dioxide Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , commonly found in nature as quartz. In many parts of the world, silica is the major constituent of sand. Silica is one of the most complex and abundan ...

(SiO₂) (both

amorphous In condensed matter physics and materials science, an amorphous solid (or non-crystalline solid) is a solid that lacks the long-range order that is a characteristic of a crystal. The terms "glass" and "glassy solid" are sometimes used synonymousl ...

and

crystalline A crystal or crystalline solid is a solid material whose constituents (such as atoms, molecules, or ions) are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macrosc ...

aluminium oxide Aluminium oxide (or aluminium(III) oxide) is a chemical compound of aluminium and oxygen with the chemical formula . It is the most commonly occurring of several Aluminium oxide (compounds), aluminium oxides, and specifically identified as alum ...

(Al₂O₃) and calcium oxide (CaO), the main mineral compounds in coal-bearing rock strata. The use of fly ash as a lightweight aggregate (LWA) offers a valuable opportunity to recycle one of the largest waste streams in the US, providing many economic and environmental benefits in the process. The minor constituents of fly ash depend upon the specific coal bed composition but may include one or more of the following elements or compounds found in trace concentrations (up to hundreds of ppm):

gallium Gallium is a chemical element; it has Chemical symbol, symbol Ga and atomic number 31. Discovered by the French chemist Paul-Émile Lecoq de Boisbaudran in 1875, elemental gallium is a soft, silvery metal at standard temperature and pressure. ...

arsenic Arsenic is a chemical element; it has Symbol (chemistry), symbol As and atomic number 33. It is a metalloid and one of the pnictogens, and therefore shares many properties with its group 15 neighbors phosphorus and antimony. Arsenic is not ...

beryllium Beryllium is a chemical element; it has Symbol (chemistry), symbol Be and atomic number 4. It is a steel-gray, hard, strong, lightweight and brittle alkaline earth metal. It is a divalent element that occurs naturally only in combination with ...

boron Boron is a chemical element; it has symbol B and atomic number 5. In its crystalline form it is a brittle, dark, lustrous metalloid; in its amorphous form it is a brown powder. As the lightest element of the boron group it has three ...

cadmium Cadmium is a chemical element; it has chemical symbol, symbol Cd and atomic number 48. This soft, silvery-white metal is chemically similar to the two other stable metals in group 12 element, group 12, zinc and mercury (element), mercury. Like z ...

chromium Chromium is a chemical element; it has Symbol (chemistry), symbol Cr and atomic number 24. It is the first element in Group 6 element, group 6. It is a steely-grey, Luster (mineralogy), lustrous, hard, and brittle transition metal. Chromium ...

hexavalent chromium Hexavalent chromium (chromium(VI), Cr(VI), chromium 6) is any chemical compound that contains the element chromium in the +6 oxidation state (thus hexavalent). It has been identified as carcinogenic, which is of concern since approximately of ...

cobalt Cobalt is a chemical element; it has Symbol (chemistry), symbol Co and atomic number 27. As with nickel, cobalt is found in the Earth's crust only in a chemically combined form, save for small deposits found in alloys of natural meteoric iron. ...

lead Lead () is a chemical element; it has Chemical symbol, symbol Pb (from Latin ) and atomic number 82. It is a Heavy metal (elements), heavy metal that is density, denser than most common materials. Lead is Mohs scale, soft and Ductility, malleabl ...

manganese Manganese is a chemical element; it has Symbol (chemistry), symbol Mn and atomic number 25. It is a hard, brittle, silvery metal, often found in minerals in combination with iron. Manganese was first isolated in the 1770s. It is a transition m ...

, mercury,

molybdenum Molybdenum is a chemical element; it has Symbol (chemistry), symbol Mo (from Neo-Latin ''molybdaenum'') and atomic number 42. The name derived from Ancient Greek ', meaning lead, since its ores were confused with lead ores. Molybdenum minerals hav ...

selenium Selenium is a chemical element; it has symbol (chemistry), symbol Se and atomic number 34. It has various physical appearances, including a brick-red powder, a vitreous black solid, and a grey metallic-looking form. It seldom occurs in this elem ...

strontium Strontium is a chemical element; it has symbol Sr and atomic number 38. An alkaline earth metal, it is a soft silver-white yellowish metallic element that is highly chemically reactive. The metal forms a dark oxide layer when it is exposed to ...

thallium Thallium is a chemical element; it has Symbol (chemistry), symbol Tl and atomic number 81. It is a silvery-white post-transition metal that is not found free in nature. When isolated, thallium resembles tin, but discolors when exposed to air. Che ...

, and

vanadium Vanadium is a chemical element; it has Symbol (chemistry), symbol V and atomic number 23. It is a hard, silvery-grey, malleable transition metal. The elemental metal is rarely found in nature, but once isolated artificially, the formation of an ...

, along with very small concentrations of dioxins, PAH compounds, and other trace carbon compounds."Managing Coal Combustion Residues in Mines", Committee on Mine Placement of Coal Combustion Wastes, National Research Council of the National Academies, 2006 In the past, fly ash was generally released into the

atmosphere An atmosphere () is a layer of gases that envelop an astronomical object, held in place by the gravity of the object. A planet retains an atmosphere when the gravity is great and the temperature of the atmosphere is low. A stellar atmosph ...

, but air pollution control standards now require that it be captured prior to release by fitting pollution control equipment. In the United States, fly ash is generally stored at coal power plants or placed in landfills. About 43% is recycled, often used as a pozzolan to produce hydraulic cement or hydraulic plaster and a replacement or partial replacement for

in concrete production. Pozzolans ensure the setting of concrete and plaster and provide concrete with more protection from wet conditions and chemical attack. In the case that fly (or bottom) ash is not produced from coal, for example when solid waste is incinerated in a waste-to-energy facility to produce electricity, the ash may contain higher levels of contaminants than coal ash. In that case the ash produced is often classified as

hazardous waste Hazardous waste is waste that must be handled properly to avoid damaging human health or the environment. Waste can be hazardous because it is Toxicity, toxic, Chemical reaction, reacts violently with other chemicals, or is Corrosion, corrosive, ...

Chemical composition and classification

Fly ash material solidifies while suspended in the exhaust gases and is collected by electrostatic precipitators or filter bags. Since the particles solidify rapidly while suspended in the exhaust gases, fly ash particles are generally spherical in shape and range in size from 0.5 μm to 300 μm. The major consequence of the rapid cooling is that few minerals have time to crystallize, and that mainly amorphous, quenched glass remains. Nevertheless, some

refractory In materials science, a refractory (or refractory material) is a material that is resistant to decomposition by heat or chemical attack and that retains its strength and rigidity at high temperatures. They are inorganic, non-metallic compound ...

phases in the pulverized coal do not melt (entirely), and remain crystalline. In consequence, fly ash is a heterogeneous material. SiO₂, Al₂O₃, Fe₂O₃ and occasionally CaO are the main chemical components present in fly ashes. The mineralogy of fly ashes is very diverse. The main phases encountered are a glass phase, together with

quartz Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The Atom, atoms are linked in a continuous framework of SiO4 silicon–oxygen Tetrahedral molecular geometry, tetrahedra, with each oxygen being shared between two tet ...

, mullite and the iron oxides

hematite Hematite (), also spelled as haematite, is a common iron oxide compound with the formula, Fe2O3 and is widely found in rocks and soils. Hematite crystals belong to the rhombohedral lattice system which is designated the alpha polymorph of . ...

magnetite Magnetite is a mineral and one of the main iron ores, with the chemical formula . It is one of the iron oxide, oxides of iron, and is ferrimagnetism, ferrimagnetic; it is attracted to a magnet and can be magnetization, magnetized to become a ...

and/or

maghemite Maghemite (Fe2O3, γ-Fe2O3) is a member of the family of iron oxides. It has the same formula as hematite, but the same spinel ferrite structure as magnetite () and is also ferrimagnetic. It is sometimes spelled as "maghaemite". ''Maghemite'' ...

. Other phases often identified are

cristobalite Cristobalite ( ) is a mineral polymorph of silica that is formed at very high temperatures. It has the same chemical formula as quartz, Si O2, but a distinct crystal structure. Both quartz and cristobalite are polymorphs with all the members o ...

, anhydrite, free lime, periclase,

calcite Calcite is a Carbonate minerals, carbonate mineral and the most stable Polymorphism (materials science), polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on ...

, sylvite, halite, portlandite,

rutile Rutile is an oxide mineral composed of titanium dioxide (TiO2), the most common natural form of TiO2. Rarer polymorphs of TiO2 are known, including anatase, akaogiite, and brookite. Rutile has one of the highest refractive indices at vis ...

and

anatase Anatase is a metastable mineral form of titanium dioxide (TiO2) with a Tetragonal crystal system, tetragonal crystal structure. Although colorless or white when pure, anatase in nature is usually a black solid due to impurities. Three other Pol ...

. The Ca-bearing minerals

anorthite Anorthite (< ''an'' 'not' + ''ortho'' 'straight') is the

calcium

gehlenite, akermanite and various calcium silicates and calcium aluminates identical to those found in

can be identified in Ca-rich fly ashes. The mercury content can reach , but is generally included in the range 0.01–1 ppm for bituminous coal. The concentrations of other trace elements vary as well according to the kind of coal combusted to form it.

Classification

Two classes of fly ash are defined by

American Society for Testing and Materials American(s) may refer to: * American, something of, from, or related to the United States of America, commonly known as the "United States" or "America" ** Americans, citizens and nationals of the United States of America ** American ancestry, p ...

(ASTM) C618: Class F fly ash and Class C fly ash. The chief difference between these classes is the amount of calcium, silica, alumina, and iron content in the ash. The chemical properties of the fly ash are largely influenced by the chemical content of the coal burned (i.e., anthracite,

bituminous Bitumen ( , ) is an immensely viscous constituent of petroleum. Depending on its exact composition, it can be a sticky, black liquid or an apparently solid mass that behaves as a liquid over very large time scales. In American English, the m ...

, and lignite). Not all fly ashes meet ASTM C618 requirements, although depending on the application, this may not be necessary. Fly ash used as a cement replacement must meet strict construction standards, but no standard environmental regulations have been established in the United States. Seventy-five percent of the fly ash must have a

fineness The fineness of a precious metal object (coin, bar, jewelry, etc.) represents the weight of ''fine metal'' therein, in proportion to the total weight which includes alloying base metals and any impurities. Alloy metals are added to increase hard ...

of 45 μm or less, and have a

carbon Carbon () is a chemical element; it has chemical symbol, symbol C and atomic number 6. It is nonmetallic and tetravalence, tetravalent—meaning that its atoms are able to form up to four covalent bonds due to its valence shell exhibiting 4 ...

content, measured by the loss on ignition (LOI), of less than 4%. In the US, LOI must be under 6%. The particle size distribution of raw fly ash tends to fluctuate constantly, due to changing performance of the coal mills and the boiler performance. This makes it necessary that, if fly ash is used in an optimal way to replace cement in concrete production, it must be processed using beneficiation methods like mechanical air classification. But if fly ash is used as a filler to replace sand in concrete production, unbeneficiated fly ash with higher LOI can be also used. Especially important is the ongoing quality verification. This is mainly expressed by quality control seals like the Bureau of Indian Standards mark or the DCL mark of the Dubai Municipality. * Class "F": The burning of harder, older anthracite and bituminous coal typically produces Class F fly ash. This fly ash is pozzolanic in nature, and contains less than 7% lime (CaO). Possessing pozzolanic properties, the glassy silica and alumina of Class F fly ash requires a cementing agent, such as Portland cement, quicklime, or hydrated lime—mixed with water to react and produce cementitious compounds. Alternatively, adding a chemical activator such as sodium silicate (water glass) to a Class F ash can form a geopolymer. * Class "C": Fly ash produced from the burning of younger lignite or sub-bituminous coal, in addition to having pozzolanic properties, also has some self-cementing properties. In the presence of water, Class C fly ash hardens and gets stronger over time. Class C fly ash generally contains more than 20% lime (CaO). Unlike Class F, self-cementing Class C fly ash does not require an activator. Alkali and sulfate () contents are generally higher in Class C fly ashes. At least one US manufacturer has announced a fly ash brick containing up to 50% Class C fly ash. Testing shows bricks meet or exceed the performance standards listed in

ASTM ASTM International, formerly known as American Society for Testing and Materials, is a standards organization that develops and publishes voluntary consensus technical international standards for a wide range of materials, products, systems and s ...

C 216 for conventional clay brick. It is also within the allowable shrinkage limits for concrete brick in ASTM C 55, Standard Specification for Concrete Building Brick. It is estimated that the production method used in fly ash bricks will reduce the embodied energy of masonry construction by up to 90%. Bricks and pavers were expected to be available in commercial quantities before the end of 2009.

Disposal and market sources

In the past, fly ash produced from coal combustion was simply entrained in flue gases and dispersed into the atmosphere. This created environmental and health concerns that prompted laws in heavily industrialized countries like the United States that have reduced fly ash emissions to less than 1% of ash produced. Worldwide, more than 65% of fly ash produced from coal power stations is disposed of in

landfill A landfill is a site for the disposal of waste materials. It is the oldest and most common form of waste disposal, although the systematic burial of waste with daily, intermediate and final covers only began in the 1940s. In the past, waste was ...

s and ash ponds. Ash that is stored or deposited outdoors can eventually leach toxic compounds into underground water aquifers. For this reason, much of the current debate around fly ash disposal revolves around creating specially lined landfills that prevent the chemical compounds from being leached into the ground water and local ecosystems. Since coal was the dominant energy source in the United States for many decades, power companies often located their coal plants near metropolitan areas. Compounding the environmental issues, the coal plants need significant amounts of water to operate their boilers, leading coal plants (and later their fly ash storage basins) to be located near metropolitan areas and near rivers and lakes which are often used as drinking supplies by nearby cities. Many of those fly ash basins were unlined and also at great risk of spilling and flooding from nearby rivers and lakes. For example, Duke Energy in

North Carolina North Carolina ( ) is a U.S. state, state in the Southeastern United States, Southeastern region of the United States. It is bordered by Virginia to the north, the Atlantic Ocean to the east, South Carolina to the south, Georgia (U.S. stat ...

has been involved in several major lawsuits related to its coal ash storage and spills into the leakage of ash into the water basin. The recycling of fly ash has become an increasing concern in recent years due to increasing landfill costs and current interest in

sustainable development Sustainable development is an approach to growth and Human development (economics), human development that aims to meet the needs of the present without compromising the ability of future generations to meet their own needs.United Nations General ...

. , coal-fired power plants in the US reported producing of fly ash, of which were reused in various applications. Environmental benefits to recycling fly ash includes reducing the demand for virgin materials that would need

quarry A quarry is a type of open-pit mining, open-pit mine in which dimension stone, rock (geology), rock, construction aggregate, riprap, sand, gravel, or slate is excavated from the ground. The operation of quarries is regulated in some juri ...

ing and cheap substitution for materials such as

Reuse

About 52 percent of CCPs in the U.S. were recycled for "beneficial uses" in 2019, according to the American Coal Ash Association. In Australia about 47% of coal ash was recycled in 2020. The chief benefit of recycling is to stabilize the environmentally harmful components of the CCPs such as arsenic, beryllium, boron, cadmium, chromium, chromium VI, cobalt, lead, manganese, mercury, molybdenum, selenium, strontium, thallium, and vanadium, along with dioxins and

polycyclic aromatic hydrocarbon A Polycyclic aromatic hydrocarbon (PAH) is any member of a class of organic compounds that is composed of multiple fused aromatic rings. Most are produced by the incomplete combustion of organic matter— by engine exhaust fumes, tobacco, incine ...

s. There is no US governmental registration or labelling of fly ash utilization in the different sectors of the economy – industry, infrastructures and agriculture. Fly ash utilization survey data, acknowledged as incomplete, are published annually by the American Coal Ash Association. Coal ash uses include (approximately in order of decreasing importance): *

Concrete Concrete is a composite material composed of aggregate bound together with a fluid cement that cures to a solid over time. It is the second-most-used substance (after water), the most–widely used building material, and the most-manufactur ...

production, as a substitute material for Portland cement, sand. * Corrosion control in

reinforced concrete Reinforced concrete, also called ferroconcrete or ferro-concrete, is a composite material in which concrete's relatively low tensile strength and ductility are compensated for by the inclusion of reinforcement having higher tensile strength or ...

(RC) structures * Fly-ash pellets which can replace normal aggregate in concrete mixture. * Embankments and other structural fills (usually for road construction) * Grout and Flowable fill production * Waste stabilization and solidification * Cement clinker production (as a substitute material for clay) *

Mine reclamation Mine reclamation is the process of modifying land that has been mined to restore it to an ecologically functional or economically usable state. Although the process of mine reclamation occurs once mining is complete, the planning of mine recl ...

* Stabilization of soft soils * Road subbase construction * As aggregate substitute material (e.g. for brick production) * Mineral filler in asphaltic concrete * Agricultural uses: soil amendment, fertilizer, cattle feeders, soil stabilization in stock feed yards, and agricultural stakes * Loose application on rivers to melt ice * Loose application on roads and parking lots for ice control Other applications include

cosmetics Cosmetics are substances that are intended for application to the body for cleansing, beautifying, promoting attractiveness, or altering appearance. They are mixtures of chemical compounds derived from either Natural product, natural source ...

toothpaste Toothpaste is a paste or gel dentifrice that is used with a toothbrush to clean and maintain the aesthetics of Human tooth, teeth. Toothpaste is used to promote oral hygiene: it is an abrasive that aids in removing dental plaque and food from th ...

, kitchen counter tops, floor and ceiling tiles, bowling balls, flotation devices,

stucco Stucco or render is a construction material made of aggregates, a binder, and water. Stucco is applied wet and hardens to a very dense solid. It is used as a decorative coating for walls and ceilings, exterior walls, and as a sculptural and ...

, utensils, tool handles, picture frames, auto bodies and boat hulls, cellular concrete,

geopolymers A geopolymer is an Inorganic compound, inorganic, often ceramic-like material, that forms a stable, Covalent bond, covalently bonded, Non-crystalline solid, non-crystalline to Crystallization of polymers, semi-crystalline network through the reac ...

roof tiles Roof tiles are overlapping tiles designed mainly to keep out precipitation such as rain or snow, and are traditionally made from locally available materials such as clay or slate. Later tiles have been made from materials such as concrete, glass ...

, roofing granules, decking, fireplace mantles,

cinder block A concrete block, also known as a cinder block in North American English, breeze block in British English, or concrete masonry unit (CMU), or by #Naming, various other terms, is a standard-size rectangular block used in building constructio ...

, PVC pipe, structural insulated panels, house siding and trim, running tracks, blasting grit, recycled plastic lumber, utility poles and crossarms, railway sleepers, highway

noise barrier A noise barrier (also called a soundwall, noise wall, sound berm, sound barrier, or acoustical barrier) is an exterior structure designed to protect inhabitants of sensitive land use areas from noise pollution. Noise barriers are the most effecti ...

s, marine pilings, doors, window frames, scaffolding, sign posts, crypts, columns, railroad ties, vinyl flooring, paving stones, shower stalls, garage doors, park benches, landscape timbers, planters, pallet blocks, molding, mail boxes,

artificial reef An artificial reef (AR) is a human-created freshwater or marine benthic structure. Typically built in areas with a generally featureless bottom to promote Marine biology#Reefs, marine life, it may be intended to control #Erosion prevention, erosio ...

, binding agent, paints and undercoatings, metal castings, and filler in wood and plastic products.

Portland cement

Owing to its pozzolanic properties, fly ash is used as a replacement for

concrete Concrete is a composite material composed of aggregate bound together with a fluid cement that cures to a solid over time. It is the second-most-used substance (after water), the most–widely used building material, and the most-manufactur ...

. The use of fly ash as a pozzolanic ingredient was recognized as early as 1914, although the earliest noteworthy study of its use was in 1937. Roman structures such as aqueducts or the Pantheon in Rome used volcanic ash or

pozzolana Pozzolana or pozzuolana ( , ), also known as pozzolanic ash (), is a natural siliceous or siliceous- aluminous material which reacts with calcium hydroxide in the presence of water at room temperature (cf. pozzolanic reaction). In this reaction ...

(which possesses similar properties to fly ash) as pozzolan in their concrete. As pozzolan greatly improves the strength and durability of concrete, the use of ash is a key factor in their preservation. Use of fly ash as a partial replacement for Portland cement is particularly suitable but not limited to Class C fly ashes. Class "F" fly ashes can have volatile effects on the entrained air content of concrete, causing reduced resistance to freeze/thaw damage. Fly ash often replaces up to 30% by mass of Portland cement, but can be used in higher dosages in certain applications. In some cases, fly ash can add to the concrete's final strength and increase its chemical resistance and durability. Fly ash can significantly improve the workability of concrete. Recently, techniques have been developed to replace partial cement with high-volume fly ash (50% cement replacement). For roller-compacted concrete (RCC) sed in dam construction replacement values of 70% have been achieved with processed fly ash at the Ghatghar dam project in Maharashtra, India. Due to the spherical shape of fly ash particles, it can increase workability of cement while reducing water demand. Proponents of fly ash claim that replacing Portland cement with fly ash reduces the

greenhouse gas Greenhouse gases (GHGs) are the gases in the atmosphere that raise the surface temperature of planets such as the Earth. Unlike other gases, greenhouse gases absorb the radiations that a planet emits, resulting in the greenhouse effect. T ...

"footprint" of concrete, as the production of one ton of Portland cement generates approximately one ton of CO₂, compared to no CO₂ generated with fly ash. New fly ash production, i.e., the burning of coal, produces approximately 20 to 30 tons of CO₂ per ton of fly ash. Since the worldwide production of Portland cement is expected to reach nearly 2 billion tons by 2010, replacement of any large portion of this cement by fly ash could significantly reduce carbon emissions associated with construction, as long as the comparison takes the production of fly ash as a given.

Embankment

Fly ash properties are unusual among engineering materials. Unlike soils typically used for embankment construction, fly ash has a large uniformity coefficient and it consists of clay-sized particles. Engineering properties that affect the use of fly ash in embankments include grain size distribution, compaction characteristics, shear strength, compressibility, permeability, and frost susceptibility. Nearly all the types of fly ash used in embankments are Class F.

Soil stabilization

Soil stabilization is the permanent physical and chemical alteration of soils to enhance their physical properties. Stabilization can increase the shear strength of a soil and/or control the shrink-swell properties of a soil, thus improving the load-bearing capacity of a sub-grade to support pavements and foundations. Stabilization can be used to treat a wide range of sub-grade materials from expansive clays to granular materials. Stabilization can be achieved with a variety of chemical additives including lime, fly ash, and Portland cement. Proper design and testing is an important component of any stabilization project. This allows for the establishment of design criteria, and determination of the proper chemical additive and admixture rate that achieves the desired engineering properties. Stabilization process benefits can include: Higher resistance (R) values, Reduction in plasticity, Lower permeability, Reduction of pavement thickness, Elimination of excavation – material hauling/handling – and base importation, Aids compaction, Provides "all-weather" access onto and within projects sites. Another form of soil treatment closely related to soil stabilization is soil modification, sometimes referred to as "mud drying" or soil conditioning. Although some stabilization inherently occurs in soil modification, the distinction is that soil modification is merely a means to reduce the moisture content of a soil to expedite construction, whereas stabilization can substantially increase the shear strength of a material such that it can be incorporated into the project's structural design. The determining factors associated with soil modification vs soil stabilization may be the existing moisture content, the end use of the soil structure and ultimately the cost benefit provided. Equipment for the stabilization and modification processes include: chemical additive spreaders, soil mixers (reclaimers), portable pneumatic storage containers, water trucks, deep lift compactors, motor graders.

Flowable fill

Fly ash is also used as a component in the production of flowable fill (also called controlled low strength material, or CLSM), which is used as self-leveling, self-compact backfill material in lieu of compacted earth or granular fill. The strength of flowable fill mixes can range from 50 to 1,200 lbf/in² (0.3 to 8.3 MPa), depending on the design requirements of the project in question. Flowable fill includes mixtures of Portland cement and filler material, and can contain mineral admixtures. Fly ash can replace either the Portland cement or fine aggregate (in most cases, river sand) as a filler material. High fly ash content mixes contain nearly all fly ash, with a small percentage of Portland cement and enough water to make the mix flowable. Low fly ash content mixes contain a high percentage of filler material, and a low percentage of fly ash, Portland cement, and water. Class F fly ash is best suited for high fly ash content mixes, whereas Class C fly ash is almost always used in low fly ash content mixes.

Asphalt concrete

Asphalt concrete Asphalt concrete (commonly called asphalt, blacktop, or pavement in North America, and Tarmacadam, tarmac or bitumen macadam in the United Kingdom and the Republic of Ireland) is a composite material commonly used to surface road surface, roads ...

is a composite material consisting of an asphalt binder and mineral aggregate commonly used to surface roads. Both Class F and Class C fly ash can typically be used as a mineral filler to fill the voids and provide contact points between larger aggregate particles in asphalt concrete mixes. This application is used in conjunction, or as a replacement for, other binders (such as Portland cement or hydrated lime). For use in asphalt pavement, the fly ash must meet mineral filler specifications outlined i
ASTM D242
The hydrophobic nature of fly ash gives pavements better resistance to stripping. Fly ash has also been shown to increase the stiffness of the asphalt matrix, improving rutting resistance and increasing mix durability.

Filler for thermoplastics

Coal and shale oil fly ashes have been used as a filler for

thermoplastics A thermoplastic, or thermosoftening plastic, is any plastic polymer material that becomes pliable or moldable at a certain elevated temperature and solidifies upon cooling. Most thermoplastics have a high molecular weight. The polymer chains as ...

that could be used for injection molding applications.

Geopolymers

More recently, fly ash has been used as a component in

, where the reactivity of the fly ash glasses can be used to create a binder similar to a hydrated

in appearance, but with potentially superior properties, including reduced CO₂ emissions, depending on the formulation.

Roller compacted concrete

UserKTrimble-AP Taum Sauk Reservoir UnderConstruction Nov 22 2009 crop1

Another application of using fly ash is in roller compacted concrete dams. Many dams in the US have been constructed with high fly ash contents. Fly ash lowers the heat of hydration allowing thicker placements to occur. Data for these can be found at the US Bureau of Reclamation. This has also been demonstrated in the Ghatghar Dam Project in

India India, officially the Republic of India, is a country in South Asia. It is the List of countries and dependencies by area, seventh-largest country by area; the List of countries by population (United Nations), most populous country since ...

Bricks

There are several techniques for manufacturing construction bricks from fly ash, producing a wide variety of products. One type of fly ash brick is manufactured by mixing fly ash with an equal amount of clay, then firing in a kiln at about This approach has the principal benefit of reducing the amount of clay required. Another type of fly ash brick is made by mixing soil, plaster of Paris, fly ash and water, and allowing the mixture to dry. Because no heat is required, this technique reduces air pollution. More modern manufacturing processes use a greater proportion of fly ash, and a high pressure manufacturing technique, which produces high strength bricks with environmental benefits. In the United Kingdom, fly ash has been used for over fifty years to make concrete building blocks. They are widely used for the inner skin of cavity walls. They are naturally more thermally insulating than blocks made with other aggregates. Ash bricks have been used in house construction in Windhoek, Namibia, since the 1970s. There is, however, a problem with the bricks in that they tend to fail or produce unsightly pop-outs. This happens when the bricks come into contact with moisture and a chemical reaction occurs causing the bricks to expand. In India, fly ash bricks are used for construction. Leading manufacturers use an industrial standard known as "Pulverized fuel ash for lime-Pozzolana mixture" using over 75% post-industrial recycled waste, and a compression process. This produces a strong product with good insulation properties and environmental benefits.

Metal matrix composites

Fly ash particles have proved their potential as good reinforcement with aluminum alloys and show the improvement of physical and mechanical properties. In particular, the compression strength, tensile strength, and hardness increase when the percentage of fly ash content is increased, whereas the density decreases. The presence of fly ash cenospheres in a pure Al matrix decreases its coefficient of thermal expansion (CTE).

Mineral extraction

It may be possible to use vacuum distillation in order to extract

germanium Germanium is a chemical element; it has Symbol (chemistry), symbol Ge and atomic number 32. It is lustrous, hard-brittle, grayish-white and similar in appearance to silicon. It is a metalloid or a nonmetal in the carbon group that is chemically ...

and

tungsten Tungsten (also called wolfram) is a chemical element; it has symbol W and atomic number 74. It is a metal found naturally on Earth almost exclusively in compounds with other elements. It was identified as a distinct element in 1781 and first ...

from fly ash and recycle them.

Waste treatment and stabilization

Fly ash, in view of its alkalinity and water absorption capacity, may be used in combination with other alkaline materials to transform

sewage sludge Sewage sludge is the residual, semi-solid material that is produced as a by-product during sewage treatment of industrial or municipal wastewater. The term "septage" also refers to sludge from simple wastewater treatment but is connected to si ...

into organic fertilizer or

biofuel Biofuel is a fuel that is produced over a short time span from Biomass (energy), biomass, rather than by the very slow natural processes involved in the formation of fossil fuels such as oil. Biofuel can be produced from plants or from agricu ...

Catalyst

Fly ash, when treated with

sodium hydroxide Sodium hydroxide, also known as lye and caustic soda, is an inorganic compound with the formula . It is a white solid ionic compound consisting of sodium cations and hydroxide anions . Sodium hydroxide is a highly corrosive base (chemistry), ...

, appears to function well as a

catalyst Catalysis () is the increase in rate of a chemical reaction due to an added substance known as a catalyst (). Catalysts are not consumed by the reaction and remain unchanged after it. If the reaction is rapid and the catalyst recycles quick ...

for converting

polyethylene Polyethylene or polythene (abbreviated PE; IUPAC name polyethene or poly(methylene)) is the most commonly produced plastic. It is a polymer, primarily used for packaging (plastic bags, plastic films, geomembranes and containers including bott ...

into substance similar to

crude oil Petroleum, also known as crude oil or simply oil, is a naturally occurring, yellowish-black liquid chemical mixture found in geological formations, consisting mainly of hydrocarbons. The term ''petroleum'' refers both to naturally occurring u ...

in a high-temperature process called

pyrolysis Pyrolysis is a process involving the Bond cleavage, separation of covalent bonds in organic matter by thermal decomposition within an Chemically inert, inert environment without oxygen. Etymology The word ''pyrolysis'' is coined from the Gree ...

and utilized in waste water treatment. In addition, fly ash, mainly class C, may be used in the stabilization/solidification process of hazardous wastes and contaminated soils. For example, the Rhenipal process uses fly ash as an admixture to stabilize

and other toxic sludges. This process has been used since 1996 to stabilize large amounts of chromium(VI) contaminated leather sludges in Alcanena, Portugal.

Environmental impacts

The majority of CCPs are landfilled, placed in mine shafts or stored in ash ponds at coal-fired power plants. As a result, they can enter into the environment via suspension in air or through release into water.

CCP contaminants and their impacts

Fly ash contains trace concentrations of

heavy metals upright=1.2, Crystals of lead.html" ;"title="osmium, a heavy metal nearly twice as dense as lead">osmium, a heavy metal nearly twice as dense as lead Heavy metals is a controversial and ambiguous term for metallic elements with relatively h ...

and other substances that are known to be detrimental to human and ecosystem health in sufficient quantities. Potentially toxic trace elements in coal include

, barium,

copper Copper is a chemical element; it has symbol Cu (from Latin ) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkish-orang ...

, mercury,

nickel Nickel is a chemical element; it has symbol Ni and atomic number 28. It is a silvery-white lustrous metal with a slight golden tinge. Nickel is a hard and ductile transition metal. Pure nickel is chemically reactive, but large pieces are slo ...

radium Radium is a chemical element; it has chemical symbol, symbol Ra and atomic number 88. It is the sixth element in alkaline earth metal, group 2 of the periodic table, also known as the alkaline earth metals. Pure radium is silvery-white, ...

thorium Thorium is a chemical element; it has symbol Th and atomic number 90. Thorium is a weakly radioactive light silver metal which tarnishes olive grey when it is exposed to air, forming thorium dioxide; it is moderately soft, malleable, and ha ...

uranium Uranium is a chemical element; it has chemical symbol, symbol U and atomic number 92. It is a silvery-grey metal in the actinide series of the periodic table. A uranium atom has 92 protons and 92 electrons, of which 6 are valence electrons. Ura ...

, and

zinc Zinc is a chemical element; it has symbol Zn and atomic number 30. It is a slightly brittle metal at room temperature and has a shiny-greyish appearance when oxidation is removed. It is the first element in group 12 (IIB) of the periodic tabl ...

. The effect of fly ash on the environment can vary based on the thermal power plant where it is produced, as well as the proportion of fly ash to

in the waste product. This is due to the different chemical make-up of the coal based on the geology of the area the coal is found and the burning process of the coal in the power plant.

Air

Because CFA particles are small (<2.5 μm) they can become suspended in the air easily. It can be carried over large distances affecting local and global populations. These particles can then be inhaled by humans and due to their small size can travel far through the pulmonary system where they can cause cardiovascular disorders or potentially

lung cancer Lung cancer, also known as lung carcinoma, is a malignant tumor that begins in the lung. Lung cancer is caused by genetic damage to the DNA of cells in the airways, often caused by cigarette smoking or inhaling damaging chemicals. Damaged ...

. If they enter the

lymphatic system The lymphatic system, or lymphoid system, is an organ system in vertebrates that is part of the immune system and complementary to the circulatory system. It consists of a large network of lymphatic vessels, lymph nodes, lymphoid organs, lympha ...

, they can enter into the bloodstream. Additionally, airborne particles can lead to water contamination. Crystalline silica and lime along with toxic chemicals represent exposure risks to human health and the environment. Fly ash contains crystalline silica which is known to cause lung disease, in particular silicosis, if inhaled. Crystalline silica is listed by the IARC and US National Toxicology Program as a known human

carcinogen A carcinogen () is any agent that promotes the development of cancer. Carcinogens can include synthetic chemicals, naturally occurring substances, physical agents such as ionizing and non-ionizing radiation, and biologic agents such as viruse ...

Water

As described previously, fly ash can contain enhanced concentrations of heavy metals which results in a significant potential for pollution. The most common techniques for disposing of CFA is in landfills or settling ponds. Fly ash can contaminate surface water through

erosion Erosion is the action of surface processes (such as Surface runoff, water flow or wind) that removes soil, Rock (geology), rock, or dissolved material from one location on the Earth's crust#Crust, Earth's crust and then sediment transport, tran ...

surface runoff Surface runoff (also known as overland flow or terrestrial runoff) is the unconfined flow of water over the ground surface, in contrast to ''channel runoff'' (or ''stream flow''). It occurs when excess rainwater, stormwater, meltwater, or other ...

, airborne particles landing on the water surface, contaminated ground water moving into surface waters, flooding drainage, or discharge from a coal ash pond. In surface waters where aquatic organisms live, these trace metals are taken up through direct ingestion or diffusion through the skin or gills. From there, trace metals can enter the bloodstream and eventually organs such as the liver or kidney where they bioaccumulate. Depending on the amount of

ingested, aquatic organisms can experience neurological complications, organ damage, or death. Bioaccumulation is enhanced further up the

food chain A food chain is a linear network of links in a food web, often starting with an autotroph (such as grass or algae), also called a producer, and typically ending at an apex predator (such as grizzly bears or killer whales), detritivore (such as ...

and can eventually impact humans through our food supply, leading to disease or cancer. Groundwater is often the source for drinking water, so heavy metal contamination in groundwater can have detrimental effects on human health.

Soil

Coal creates an

alkaline In chemistry, an alkali (; from the Arabic word , ) is a basic salt of an alkali metal or an alkaline earth metal. An alkali can also be defined as a base that dissolves in water. A solution of a soluble base has a pH greater than 7.0. The ...

dust when combusted, with a pH ranging from 8 to 12. Fly ash dust can be deposited on

topsoil Topsoil is the upper layer of soil. It has the highest concentration of organic matter and microorganisms and is where most of the Earth's biological soil activity occurs. Description Topsoil is composed of mineral particles and organic mat ...

increasing the pH and affecting the plants and animals in the surrounding ecosystem. Soils contaminated by fly ash showed an increase in

bulk density In materials science, bulk density, also called apparent density, is a material property defined as the mass of the many particles of the material divided by the bulk volume. Bulk volume is defined as the total volume the particles occupy, includ ...

and water capacity, but a decrease in

hydraulic conductivity In science and engineering, hydraulic conductivity (, in SI units of meters per second), is a property of porous materials, soils and Rock (geology), rocks, that describes the ease with which a fluid (usually water) can move through the porosity, ...

and cohesiveness. The effect of fly ash on soils and microorganisms in the soils are influenced by the pH of the ash and trace metal concentrations in the ash. Microbial communities in contaminated soil have shown reductions in respiration and nitrification. These contaminated soils can be detrimental or beneficial to plant development. Fly ash typically has beneficial outcomes when it corrects nutrient deficiencies in the soil. Most detrimental effects were observed when boron phytotoxicity occurs.

Plants

Fly ash can be used as a soil additive as described above. Although CFA addition can increase plant biomass when the CFA/soil ratio is low, it can result in a decline in plant biomass at higher ratios. Studies have shown that elevated CFA levels reduced seedling height as well as root and leaf length. High CFA exposure has been found to reduce the efficiency of photosynthesis.

Spills and Releases

Aerial view of ash slide site Dec 23 2008 TVA

Where fly ash is stored in bulk, it is usually stored wet rather than dry to minimize fugitive dust. The resulting impoundments ( ash ponds) are typically large and stable for long periods, but any breach of their dams or bunding is rapid and on a massive scale.

= United States of America

Human health impacts

The National Academy of Sciences noted in 2007 that "the presence of high contaminant levels in many CCR (coal combustion residue) leachates may create human health and ecological concerns".

Lead (Pb)

Lead is a hazardous heavy metal found in CFA which is highly mobile in the environment. If released from a CCP, it can contaminate water systems and soils, harming marine life and reducing biodiversity. Lead exposure in living organisms can damage blood circulation, the central nervous system, kidneys, and the heart. Even at low exposure levels, Pb exposure can inhibit heme synthesis, thereby impacting neurological function. Exposure to Pb is particularly dangerous for children.

Mercury (Hg)

Mercury is also a potential constituent of CCPs. It is released during the coal combustion process as elemental Hg, particle bound Hg, or oxidized Hg²⁺. Elemental Hg is highly reactive. If lreleased into a water system, elemental Hg from CCPs can react with bacteria and be converted to methy mercury (MeHg). MeHg moves through the food chain and can bioaccumulate in mammals. This is harmful because Hg is a neurotoxin. MeHg exposure is particularly of concern during pregnancy.

Arsenic (As)

Arsenic Arsenic is a chemical element; it has Symbol (chemistry), symbol As and atomic number 33. It is a metalloid and one of the pnictogens, and therefore shares many properties with its group 15 neighbors phosphorus and antimony. Arsenic is not ...

exists in many oxidation states and therefore can engage in many chemical reactions. The impact of As on health is highly dependent on its

oxidation state In chemistry, the oxidation state, or oxidation number, is the hypothetical Electrical charge, charge of an atom if all of its Chemical bond, bonds to other atoms are fully Ionic bond, ionic. It describes the degree of oxidation (loss of electrons ...

. Direct ingestion of As by humans can result in acute toxicity which can be mild such as vomitting or nausea or extreme such as

psychosis In psychopathology, psychosis is a condition in which a person is unable to distinguish, in their experience of life, between what is and is not real. Examples of psychotic symptoms are delusions, hallucinations, and disorganized or inco ...

. Chronic exposure can cause heart failure or blood diseases such as

leukopenia Leukopenia () is a decrease in the number of white blood cells (leukocytes). It places individuals at increased risk of infection as white blood cells are the body's primary defense against infections. Signs and symptoms Symptoms may include: * s ...

. Material Safety Data Sheets recommend a number of safety precautions be taken when handling or working with fly ash. These include wearing protective goggles, respirators and disposable clothing and avoiding agitating the fly ash in order to minimize the amount which becomes airborne.

Regulations

United States of America

In 1980 the U.S. Congress defined coal ash as a "special waste" that would not be regulated under the stringent hazardous waste permitting requirements of the Resource Conservation and Recovery Act (RCRA). In its amendments to RCRA, Congress directed the Environmental Protection Agency (EPA) to study the special waste issue and make a determination as to whether stricter permit regulation was necessary. In 2000, EPA stated that coal fly ash did not need to be regulated as a hazardous waste. As a result, most power plants were not required to install geomembranes or leachate collection systems in ash ponds. Following many contamination incidents described in "Spills and Releases," the U.S. Environmental Protection Agency (EPA) published a Coal Combustion Residuals (CCR) regulation in 2015. The agency continued to classify coal ash as non-hazardous (thereby avoiding strict permitting requirements under Subtitle C of the

Resource Conservation and Recovery Act The Resource Conservation and Recovery Act (RCRA), enacted in 1976, is the primary federal law in the United States governing the disposal of solid waste and hazardous waste.United States. Resource Conservation and Recovery Act. , , ''et seq., ...

(RCRA), but with new restrictions: # Existing ash ponds that are contaminating groundwater must stop receiving CCR, and close or retrofit with a liner. # Existing ash ponds and landfills must comply with structural and location restrictions, where applicable, or close. # A pond no longer receiving CCR is still subject to all regulations unless it is dewatered and covered by 2018. # New ponds and landfills must include a geomembrane liner over a layer of compacted soil. The regulation was designed to prevent pond failures and protect groundwater. Enhanced inspection, record keeping and monitoring is required. Procedures for closure are also included and include capping, liners, and dewatering. The CCR regulation has since been subject to litigation.

European Union

The EU has established the European Waste Catalogue (EWC) to classify waste based on type and production method which, as of 2014, was required to be incorporated into member-state legislations. Under the EWC, CFA is also designated as non-hazardous. In China, the largest producer of CFA, fly ash management is overseen by The National Development and Reform Commission and the Ministry of Environmental Protection. When CFA is not reutilized, it is stored in designated facilities; however, there has been concern over these facilitie's proximity to residential areas.

India

The

Ministry of Environment, Forest and Climate Change The Ministry of Environment, Forest and Climate Change (MoEFCC) is an Government of India, Indian government Ministry (government department), ministry. The ministry Portfolio (government), portfolio is currently held by Bhupender Yadav, Union ...

first published a gazette notification in 1999 specifying use of fly ash and mandating a target date for all thermal power plants to comply by ensuring 100% utilisation. Subsequent amendments in 2003 and 2009 shifted the deadline for compliance to 2014. As reported by Central Electricity Authority, New Delhi, as of 2015, only 60% of fly ash produced was being utilised. This has resulted in the latest notification in 2015 which has set December 31, 2017, as the revised deadline to achieve 100% utilisation. Out of the approximately 55.7% fly ash utilised, bulk of it (42.3%) goes into cement production whereas only about 0.74% is used as an additive in concrete. Researchers in India are actively addressing this challenge by working on fly ash as an admixture for concrete and activated pozzolanic cement such as geopolymer to help achieve the target of 100% utilisation. The biggest scope clearly lies in the area of increasing the quantity of fly ash being incorporated in concrete. India produced 280 Million Tonnes of Cement in 2016 . With housing sector consuming 67% of the cement, there is a huge scope for incorporating fly ash in both the increasing share of PPC and low to moderate strength concrete. There is a misconception that the Indian codes IS 456:2000 for Concrete and Reinforced Concrete and IS 3812.1:2013 for Fly Ash restrict the use of Fly Ash to less than 35%. Similar misconceptions exists in countries like US but evidence to the contrary is the use of HVFA in many large projects where design mixes have been used under strict quality control. It is suggested that in order to make the most of the research results presented in the paper, Ultra High Volume Fly ash Concrete (UHVFA) concrete is urgently developed for widespread use in India using local fly ash.

In the geologic record

Due to the ignition of coal deposits by the Siberian Traps during the

Permian–Triassic extinction event The Permian–Triassic extinction event (also known as the P–T extinction event, the Late Permian extinction event, the Latest Permian extinction event, the End-Permian extinction event, and colloquially as the Great Dying,) was an extinction ...

around 252 million years ago, large amounts of char very similar to modern fly ash were released into the oceans, which is preserved in the geologic record in marine deposits located in the Canadian High Arctic. It has been hypothesised that the fly ash could have resulted in toxic environmental conditions.

References

External links

Evaluation of Dust Exposures at Lehigh Portland Cement Company, Union Bridge, MD, a NIOSH Report, HETA 2000-0309-2857

Determination of Airborne Crystalline Silica Treatise by NIOSH

American Coal Ash Association

Fly Ash Info, the Ash Library Website
University of Kentucky

(document) * ttps://web.archive.org/web/20100916220847/http://www.peer.org/campaigns/publichealth/coalash/index.php Public Employees for Environmental Responsibility: Coal Combustion Waste
UK Quality Ash Association
: A site promoting the many uses of fly ash in the UK
Coal Ash Is More Radioactive than Nuclear Waste
''Scientific American'' (13 December 2007)
UK Quality Ash Association
A web site providing further information on the applications for PFA.
Asian Coal Ash Association
A web site providing further information on technologies and trade related to coal combustion products. {{Concrete navbox Coal technology Waste