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Pozzolana
Pozzolana or pozzuolana ( , ), also known as pozzolanic ash (), is a natural siliceous or siliceous- aluminous material which reacts with calcium hydroxide in the presence of water at room temperature (cf. pozzolanic reaction). In this reaction insoluble calcium silicate hydrate and calcium aluminate hydrate compounds are formed possessing cementitious properties. The designation pozzolana is derived from one of the primary deposits of volcanic ash used by the Romans in Italy, at Pozzuoli. The modern definition of pozzolana encompasses any volcanic material ( pumice or volcanic ash), predominantly composed of fine volcanic glass, that is used as a pozzolan. Note the difference with the term pozzolan, which exerts no bearing on the specific origin of the material, as opposed to pozzolana, which can only be used for pozzolans of volcanic origin, primarily composed of volcanic glass. Historical use Pozzolanas such as Santorin earth were used in the Eastern Mediterranean ...
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Roman Concrete
Roman concrete, also called , was used in construction in ancient Rome. Like its modern equivalent, Roman concrete was based on a hydraulic-setting cement added to an aggregate. Many buildings and structures still standing today, such as bridges, reservoirs and aqueducts, were built with this material, which attests to both its versatility and its durability. Its strength was sometimes enhanced by the incorporation of pozzolanic ash where available (particularly in the Bay of Naples). The addition of ash prevented cracks from spreading. Recent research has shown that the incorporation of mixtures of different types of lime, forming conglomerate "clasts" allowed the concrete to self-repair cracks. Roman concrete was in widespread use from about 150 BC; some scholars believe it was developed a century before that. It was often used in combination with facings and other supports, and interiors were further decorated by stucco, fresco paintings, or coloured marble. Further inn ...
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Cement
A cement is a binder, a chemical substance used for construction that sets, hardens, and adheres to other materials to bind them together. Cement is seldom used on its own, but rather to bind sand and gravel ( aggregate) together. Cement mixed with fine aggregate produces mortar for masonry, or with sand and gravel, produces concrete. Concrete is the most widely used material in existence and is behind only water as the planet's most-consumed resource. Cements used in construction are usually inorganic, often lime- or calcium silicate-based, and are either hydraulic or less commonly non-hydraulic, depending on the ability of the cement to set in the presence of water (see hydraulic and non-hydraulic lime plaster). Hydraulic cements (e.g., Portland cement) set and become adhesive through a chemical reaction between the dry ingredients and water. The chemical reaction results in mineral hydrates that are not very water-soluble. This allows setting in wet conditions or u ...
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Cosa
Cosa was an ancient Roman city near the present Ansedonia in southwestern Tuscany, Italy. It is sited on a hill 113 m above sea level and 140 km northwest of Rome on the Tyrrhenian Sea coast. It has assumed a position of prominence in Roman archaeology owing to its excavation. History The Etruscan town (called ''Cusi'' or ''Cosia'') may have been where modern Orbetello stands; a fortification wall in polygonal masonry at Orbetello's lagoon may be in phase with the walls of Cosa. Cosa was founded by the Romans as a Latin colony in 273 BC, on the ''Ager Cosanus'', land confiscated from the defeated Etruscans, to solidify the control of the Romans and offer the Republic a protected port. The town was linked to Rome by the Via Aurelia from about 241 BC. The Second Punic War (218 to 201 BC) in which Hannibal had left a trail of devastation across Italy affected the town like many Latin colonies and the rich bought up both public land and the small farms of the poor. Ne ...
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Pozzolan
Pozzolans are a broad class of siliceous and aluminous materials which, in themselves, possess little or no cementitious value but which will, in finely divided form and in the presence of water, react chemically with calcium hydroxide (Ca(OH)2) at ordinary temperature to form compounds possessing cementitious properties. The quantification of the capacity of a pozzolan to react with calcium hydroxide and water is given by measuring its pozzolanic activity. ''Pozzolana'' are naturally occurring pozzolans of volcanic origin. History Mixtures of calcined lime and finely ground, active aluminosilicate materials were pioneered and developed as inorganic binders in the Ancient world. Architectural remains of the Minoan civilization on Crete have shown evidence of the combined use of slaked lime and additions of finely ground potsherds for waterproof renderings in baths, cisterns and aqueducts. Evidence of the deliberate use of volcanic materials such as volcanic ashes or tuffs b ...
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Pozzuoli
Pozzuoli (; ; ) is a city and (municipality) of the Metropolitan City of Naples, in the Italian region of Campania. It is the main city of the Phlegrean Peninsula. History Antiquity Pozzuoli began as the Greek colony of ''Dicaearchia'' () founded in about 531 BC in Magna Graecia with the consent of nearby Cumae when refugees from Samos escaped from the tyranny of Polycrates. The Samnites occupied Dicaearchia in 421 BC after conquering Cumae and may have changed its name to Fistelia. It enjoyed considerable political and commercial autonomy favoured by the excellent position of its port with the Campanian hinterland. The Roman occupation of Campania after the end of the 1st Samnite War from 341 BC marked the start of the Romanisation of the Greek-Samnite city. During the Second Punic War (218–201 BC), Rome recognised the strategic importance of the port of Puteoli and reinforced the defences and introduced a garrison to protect the town from Hannibal, who failed to ...
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Pozzolanic Reaction
The pozzolanic activity is a measure for the degree of reaction over time or the reaction rate between a pozzolan and Ca2+ or calcium hydroxide (Ca(OH)2) in the presence of water. The rate of the pozzolanic reaction is dependent on the intrinsic characteristics of the pozzolan such as the specific surface area, the chemical composition and the active phase content. Physical surface adsorption is not considered as being part of the pozzolanic activity, because no irreversible molecular bonds are formed in the process. Reaction The pozzolanic reaction is the chemical reaction that occurs in portland cement upon the addition of pozzolans. It is the main reaction involved in the Roman concrete invented in Ancient Rome and used to build, for example, the Pantheon. The pozzolanic reaction converts a silica-rich precursor with no cementing properties, to a calcium silicate, with good cementing properties. In chemical terms, the pozzolanic reaction occurs between calcium hydroxide, a ...
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Ancient Rome
In modern historiography, ancient Rome is the Roman people, Roman civilisation from the founding of Rome, founding of the Italian city of Rome in the 8th century BC to the Fall of the Western Roman Empire, collapse of the Western Roman Empire in the 5th century AD. It encompasses the Roman Kingdom (753–509 BC), the Roman Republic (50927 BC), and the Roman Empire (27 BC476 AD) until the fall of the western empire. Ancient Rome began as an Italic peoples, Italic settlement, traditionally dated to 753 BC, beside the River Tiber in the Italian peninsula. The settlement grew into the city and polity of Rome, and came to control its neighbours through a combination of treaties and military strength. It eventually controlled the Italian Peninsula, assimilating the Greece, Greek culture of southern Italy (Magna Graecia) and the Etruscans, Etruscan culture, and then became the dominant power in the Mediterranean region and parts of Europe. At its hei ...
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Italy
Italy, officially the Italian Republic, is a country in Southern Europe, Southern and Western Europe, Western Europe. It consists of Italian Peninsula, a peninsula that extends into the Mediterranean Sea, with the Alps on its northern land border, as well as List of islands of Italy, nearly 800 islands, notably Sicily and Sardinia. Italy shares land borders with France to the west; Switzerland and Austria to the north; Slovenia to the east; and the two enclaves of Vatican City and San Marino. It is the List of European countries by area, tenth-largest country in Europe by area, covering , and the third-most populous member state of the European Union, with nearly 59 million inhabitants. Italy's capital and List of cities in Italy, largest city is Rome; other major cities include Milan, Naples, Turin, Palermo, Bologna, Florence, Genoa, and Venice. The history of Italy goes back to numerous List of ancient peoples of Italy, Italic peoples—notably including the ancient Romans, ...
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Pozzolanic Activity
The pozzolanic activity is a measure for the degree of reaction over time or the reaction rate between a pozzolan and Ca2+ or calcium hydroxide (Ca(OH)2) in the presence of water. The rate of the pozzolanic reaction is dependent on the intrinsic characteristics of the pozzolan such as the specific surface area, the chemical composition and the active phase content. Physical surface adsorption is not considered as being part of the pozzolanic activity, because no irreversible molecular bonds are formed in the process. Reaction The pozzolanic reaction is the chemical reaction that occurs in portland cement upon the addition of pozzolans. It is the main reaction involved in the Roman concrete invented in Ancient Rome and used to build, for example, the Pantheon. The pozzolanic reaction converts a silica-rich precursor with no cementing properties, to a calcium silicate, with good cementing properties. In chemical terms, the pozzolanic reaction occurs between calcium hydroxide, a ...
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Trass
Trass is the local name of a volcanic tuff occurring in the Eifel, where it is worked for hydraulic mortar. It is a grey or cream-coloured fragmental rock, largely composed of pumiceous dust, and may be regarded as a trachytic tuff. It much resembles the Italian pozzolana and is applied to like purposes. Mixed with lime and sand, or with Portland cement, it is extensively employed for hydraulic work, especially in the Netherlands; while the compact varieties have been used as a building material and as a fire-stone in ovens. Trass was formerly worked extensively in the Brohl valley and is now obtained from the valley of the Nette, near Andernach. See also * Pozzolan *Pozzolana * Pozzolanic reaction *Pumice Pumice (), called pumicite in its powdered or dust form, is a volcanic rock that consists of extremely vesicular rough-textured volcanic glass, which may or may not contain crystals. It is typically light-colored. Scoria is another vesicula ... References ...
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Lime (mineral)
Lime is an inorganic material composed primarily of calcium oxides and hydroxides. It is also the name for calcium oxide which is used as an industrial mineral and is made by heating calcium carbonate in a kiln. Calcium oxide can occur as a product of coal-seam fires and in altered limestone xenoliths in volcanic ejecta. The International Mineralogical Association recognizes lime as a mineral with the chemical formula of CaO. The word ''lime'' originates with its earliest use as building mortar and has the sense of ''sticking or adhering''. These materials are still used in large quantities in the manufacture of steel and as building and engineering materials (including limestone products, cement, concrete, and mortar), as chemical feedstocks, for sugar refining, and other uses. Lime industries and the use of many of the resulting products date from prehistoric times in both the Old World and the New World. Lime is used extensively for wastewater treatment with ferrous ...
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Mineral
In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid substance with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. (2011): Minerals'; p. 1. In the series ''Geology: Landforms, Minerals, and Rocks''. Rosen Publishing Group. The Geology, geological definition of mineral normally excludes compounds that occur only in living organisms. However, some minerals are often biogenic (such as calcite) or organic compounds in the sense of chemistry (such as mellite). Moreover, living organisms often synthesize inorganic minerals (such as hydroxylapatite) that also occur in rocks. The concept of mineral is distinct from rock (geology), rock, which is any bulk solid geologic material that is relatively homogeneous at a large enough scale. A rock may consist of one type of mineral or may be an aggregate (geology), aggregate of two or more different types of minerals, spaci ...
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