Feynman Ratchet
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In the philosophy of thermal and statistical physics, the Brownian ratchet or Feynman–Smoluchowski ratchet is an apparent
perpetual motion Perpetual motion is the motion of bodies that continues forever in an unperturbed system. A perpetual motion machine is a hypothetical machine that can do work indefinitely without an external energy source. This kind of machine is impossible ...
machine of the second kind (converting thermal energy into mechanical work), first analysed in 1912 as a
thought experiment A thought experiment is an imaginary scenario that is meant to elucidate or test an argument or theory. It is often an experiment that would be hard, impossible, or unethical to actually perform. It can also be an abstract hypothetical that is ...
by Polish physicist Marian Smoluchowski.M. von Smoluchowski (1912) Experimentell nachweisbare, der Ublichen Thermodynamik widersprechende Molekularphenomene, ''Phys. Zeitshur.'' 13, p.1069 cited i
Freund, Jan (2000) Stochastic Processes in Physics, Chemistry, and Biology, Springer, p.59
/ref> It was popularised by American
Nobel laureate The Nobel Prizes (, ) are awarded annually by the Royal Swedish Academy of Sciences, the Swedish Academy, the Karolinska Institutet, and the Norwegian Nobel Committee to individuals and organizations who make outstanding contributions in th ...
physicist
Richard Feynman Richard Phillips Feynman (; May 11, 1918 – February 15, 1988) was an American theoretical physicist. He is best known for his work in the path integral formulation of quantum mechanics, the theory of quantum electrodynamics, the physics of t ...
in a
physics Physics is the scientific study of matter, its Elementary particle, fundamental constituents, its motion and behavior through space and time, and the related entities of energy and force. "Physical science is that department of knowledge whi ...
lecture at the
California Institute of Technology The California Institute of Technology (branded as Caltech) is a private research university in Pasadena, California, United States. The university is responsible for many modern scientific advancements and is among a small group of institutes ...
on May 11, 1962, during his Messenger Lectures series
The Character of Physical Law ''The Character of Physical Law'' is a series of seven lectures by physicist Richard Feynman concerning the nature of the laws of physics. Feynman delivered the lectures in 1964 at Cornell University, as part of the Messenger Lectures series. The ...
in
Cornell University Cornell University is a Private university, private Ivy League research university based in Ithaca, New York, United States. The university was co-founded by American philanthropist Ezra Cornell and historian and educator Andrew Dickson W ...
in 1964 and in his text ''
The Feynman Lectures on Physics ''The Feynman Lectures on Physics'' is a physics textbook based on a great number of lectures by Richard Feynman, a Nobel laureate who has sometimes been called "The Great Explainer". The lectures were presented before undergraduate students ...
'' as an illustration of the laws of
thermodynamics Thermodynamics is a branch of physics that deals with heat, Work (thermodynamics), work, and temperature, and their relation to energy, entropy, and the physical properties of matter and radiation. The behavior of these quantities is governed b ...
. The simple machine, consisting of a tiny
paddle wheel A paddle is a handheld tool with an elongated handle and a flat, widened end (the ''blade'') used as a lever to apply force onto the bladed end. It most commonly describes a completely handheld tool used to propel a human-powered watercraft by p ...
and a ratchet, appears to be an example of a
Maxwell's demon Maxwell's demon is a thought experiment that appears to disprove the second law of thermodynamics. It was proposed by the physicist James Clerk Maxwell in 1867. In his first letter, Maxwell referred to the entity as a "finite being" or a "being ...
, able to extract mechanical work from random fluctuations (heat) in a system at
thermal equilibrium Two physical systems are in thermal equilibrium if there is no net flow of thermal energy between them when they are connected by a path permeable to heat. Thermal equilibrium obeys the zeroth law of thermodynamics. A system is said to be in t ...
, in violation of the
second law of thermodynamics The second law of thermodynamics is a physical law based on Universal (metaphysics), universal empirical observation concerning heat and Energy transformation, energy interconversions. A simple statement of the law is that heat always flows spont ...
. Detailed analysis by Feynman and others showed why it cannot actually do this.


The machine

The device consists of a gear known as a ratchet that rotates freely in one direction but is prevented from rotating in the opposite direction by a pawl. The ratchet is connected by an axle to a
paddle wheel A paddle is a handheld tool with an elongated handle and a flat, widened end (the ''blade'') used as a lever to apply force onto the bladed end. It most commonly describes a completely handheld tool used to propel a human-powered watercraft by p ...
that is immersed in a
fluid In physics, a fluid is a liquid, gas, or other material that may continuously motion, move and Deformation (physics), deform (''flow'') under an applied shear stress, or external force. They have zero shear modulus, or, in simpler terms, are M ...
of
molecule A molecule is a group of two or more atoms that are held together by Force, attractive forces known as chemical bonds; depending on context, the term may or may not include ions that satisfy this criterion. In quantum physics, organic chemi ...
s at
temperature Temperature is a physical quantity that quantitatively expresses the attribute of hotness or coldness. Temperature is measurement, measured with a thermometer. It reflects the average kinetic energy of the vibrating and colliding atoms making ...
T_1. The molecules constitute a heat bath in that they undergo random
Brownian motion Brownian motion is the random motion of particles suspended in a medium (a liquid or a gas). The traditional mathematical formulation of Brownian motion is that of the Wiener process, which is often called Brownian motion, even in mathematical ...
with a mean
kinetic energy In physics, the kinetic energy of an object is the form of energy that it possesses due to its motion. In classical mechanics, the kinetic energy of a non-rotating object of mass ''m'' traveling at a speed ''v'' is \fracmv^2.Resnick, Rober ...
that is determined by the
temperature Temperature is a physical quantity that quantitatively expresses the attribute of hotness or coldness. Temperature is measurement, measured with a thermometer. It reflects the average kinetic energy of the vibrating and colliding atoms making ...
. The device is imagined as being small enough that the impulse from a single molecular collision can turn the paddle. Although such collisions would tend to turn the rod in either direction with equal probability, the pawl allows the ratchet to rotate in one direction only. The net effect of many such random collisions would seem to be that the ratchet rotates continuously in that direction. The ratchet's motion then can be used to do
work Work may refer to: * Work (human activity), intentional activity people perform to support themselves, others, or the community ** Manual labour, physical work done by humans ** House work, housework, or homemaking ** Working animal, an ani ...
on other systems, for example lifting a weight (''m'') against gravity. The energy necessary to do this work apparently would come from the heat bath, without any heat gradient (i.e. the motion leeches energy from the temperature of the air). Were such a machine to work successfully, its operation would violate the
second law of thermodynamics The second law of thermodynamics is a physical law based on Universal (metaphysics), universal empirical observation concerning heat and Energy transformation, energy interconversions. A simple statement of the law is that heat always flows spont ...
, one form of which states: "It is impossible for any device that operates on a cycle to receive heat from a single reservoir and produce a net amount of work."


Why it fails

Although at first sight the Brownian ratchet seems to extract useful work from Brownian motion, Feynman demonstrated that if the entire device is at the same temperature, the ratchet will not rotate continuously in one direction but will move randomly back and forth, and therefore will not produce any useful work. The reason is that since the pawl is at the same temperature as the paddle, it will also undergo Brownian motion, "bouncing" up and down. It therefore will intermittently fail by allowing a ratchet tooth to slip backward under the pawl while it is up. Another issue is that when the pawl rests on the sloping face of the tooth, the spring which returns the pawl exerts a sideways force on the tooth which tends to rotate the ratchet in a backwards direction. Feynman demonstrated that if the temperature T_2 of the ratchet and pawl is the same as the temperature T_1 of the paddle, then the failure rate must equal the rate at which the ratchet ratchets forward, so that no net motion results over long enough periods or in an ensemble averaged sense. A simple but rigorous proof that no net motion occurs no matter what shape the teeth are was given by Magnasco. If, on the other hand, T_2 is less than T_1, the ratchet will indeed move forward, and produce useful work. In this case, though, the energy is extracted from the temperature gradient between the two thermal reservoirs, and some
waste heat Waste heat is heat that is produced by a machine, or other process that uses energy, as a byproduct of doing work. All such processes give off some waste heat as a fundamental result of the laws of thermodynamics. Waste heat has lower utility ...
is exhausted into the lower temperature reservoir by the pawl. In other words, the device functions as a miniature
heat engine A heat engine is a system that transfers thermal energy to do mechanical or electrical work. While originally conceived in the context of mechanical energy, the concept of the heat engine has been applied to various other kinds of energy, pa ...
, in compliance with the second law of thermodynamics. Conversely, if T_2 is greater than T_1, the device will rotate in the opposite direction. The Feynman ratchet model led to the similar concept of Brownian motors,
nanomachine Molecular machines are a class of molecules typically described as an assembly of a discrete number of molecular components intended to produce mechanical movements in response to specific stimuli, mimicking macromolecular devices such as switch ...
s which can extract useful work not from thermal noise but from
chemical potential In thermodynamics, the chemical potential of a Chemical specie, species is the energy that can be absorbed or released due to a change of the particle number of the given species, e.g. in a chemical reaction or phase transition. The chemical potent ...
s and other microscopic nonequilibrium sources, in compliance with the laws of thermodynamics.
Diode A diode is a two-Terminal (electronics), terminal electronic component that conducts electric current primarily in One-way traffic, one direction (asymmetric electrical conductance, conductance). It has low (ideally zero) Electrical resistance ...
s are an electrical analog of the ratchet and pawl, and for the same reason cannot produce useful work by rectifying Johnson noise in a circuit at uniform temperature. Millonas as well as Mahato extended the same notion to correlation ratchets driven by mean-zero (unbiased) nonequilibrium noise with a nonvanishing correlation function of odd order greater than one.


History

The ratchet and pawl was first discussed as a second law-violating device by
Gabriel Lippmann Gabriel Lippmann ( ; 16 August 1845 – 12 July 1921) was a French physicist who received the Nobel Prize in Physics in 1908 "for his method of reproducing colours photographically based on the phenomenon of interference". Early life and educa ...
in 1900. In 1912, Polish physicist Marian Smoluchowski gave the first correct qualitative explanation of why the device fails; thermal motion of the pawl allows the ratchet's teeth to slip backwards. Feynman did the first quantitative analysis of the device in 1962 using the
Maxwell–Boltzmann distribution In physics (in particular in statistical mechanics), the Maxwell–Boltzmann distribution, or Maxwell(ian) distribution, is a particular probability distribution named after James Clerk Maxwell and Ludwig Boltzmann. It was first defined and use ...
, showing that if the temperature of the paddle ''T''1 was greater than the temperature of the ratchet ''T''2, it would function as a
heat engine A heat engine is a system that transfers thermal energy to do mechanical or electrical work. While originally conceived in the context of mechanical energy, the concept of the heat engine has been applied to various other kinds of energy, pa ...
, but if ''T''1 = ''T''2 there would be no net motion of the paddle. In 1996, J. M. R. Parrondo and Pep Español used a variation of the above device in which no ratchet is present, only two paddles, to show that the axle connecting the paddles and ratchet conducts heat between reservoirs; they argued that although Feynman's conclusion was correct, his analysis was flawed because of his erroneous use of the quasistatic approximation, resulting in incorrect equations for efficiency. Marcelo Osvaldo Magnasco and Gustavo Stolovitzky (1998) extended this analysis to consider the full ratchet device, and showed that the power output of the device is far smaller than the Carnot efficiency claimed by Feynman. A paper in 2000 by Derek Abbott, Bruce R. Davis and Parrondo, reanalyzed the problem and extended it to the case of multiple ratchets, showing a link with Parrondo's paradox. Léon Brillouin in 1950 discussed an electrical circuit analogue that uses a
rectifier A rectifier is an electrical device that converts alternating current (AC), which periodically reverses direction, to direct current (DC), which flows in only one direction. The process is known as ''rectification'', since it "straightens" t ...
(such as a diode) instead of a ratchet. The idea was the diode would rectify the Johnson noise thermal current fluctuations produced by the
resistor A resistor is a passive two-terminal electronic component that implements electrical resistance as a circuit element. In electronic circuits, resistors are used to reduce current flow, adjust signal levels, to divide voltages, bias active e ...
, generating a
direct current Direct current (DC) is one-directional electric current, flow of electric charge. An electrochemical cell is a prime example of DC power. Direct current may flow through a conductor (material), conductor such as a wire, but can also flow throug ...
which could be used to perform work. In the detailed analysis it was shown that the thermal fluctuations within the diode generate an
electromotive force In electromagnetism and electronics, electromotive force (also electromotance, abbreviated emf, denoted \mathcal) is an energy transfer to an electric circuit per unit of electric charge, measured in volts. Devices called electrical ''transducer ...
that cancels the voltage from rectified current fluctuations. Therefore, just as with the ratchet, the circuit will produce no useful energy if all the components are at thermal equilibrium (at the same temperature); a DC current will be produced only when the diode is at a lower temperature than the resistor.


Granular gas

Researchers from the
University of Twente The University of Twente ( ; Abbreviation, abbr. ) is a Public university, public technical university located in Enschede, Netherlands. The university has been placed in the top 170 universities in the world by multiple central ranking tables. ...
, the University of Patras in Greece, and the Foundation for Fundamental Research on Matter have constructed a Feynman–Smoluchowski engine which, when not in thermal equilibrium, converts pseudo-
Brownian motion Brownian motion is the random motion of particles suspended in a medium (a liquid or a gas). The traditional mathematical formulation of Brownian motion is that of the Wiener process, which is often called Brownian motion, even in mathematical ...
into
work Work may refer to: * Work (human activity), intentional activity people perform to support themselves, others, or the community ** Manual labour, physical work done by humans ** House work, housework, or homemaking ** Working animal, an ani ...
by means of a granular gas,"Classical thought experiment brought to life in granular gas"
'' Foundation for Fundamental Research on Matter'', Utrecht, 18 June 2010. Retrieved on 2010-06-24.
which is a conglomeration of solid particles vibrated with such vigour that the system assumes a gas-like state. The constructed engine consisted of four vanes which were allowed to rotate freely in a vibrofluidized granular gas. Because the ratchet's gear and pawl mechanism, as described above, permitted the axle to rotate only in one direction, random collisions with the moving beads caused the vane to rotate. This seems to contradict Feynman's hypothesis. However, this system is not in perfect thermal equilibrium: energy is constantly being supplied to maintain the fluid motion of the beads. Vigorous vibrations on top of a shaking device mimic the nature of a molecular gas. Unlike an
ideal gas An ideal gas is a theoretical gas composed of many randomly moving point particles that are not subject to interparticle interactions. The ideal gas concept is useful because it obeys the ideal gas law, a simplified equation of state, and is ...
, though, in which tiny particles move constantly, stopping the shaking would simply cause the beads to drop. In the experiment, this necessary out-of-equilibrium environment was thus maintained. Work was not immediately being done, though; the ratchet effect only commenced beyond a critical shaking strength. For very strong shaking, the vanes of the paddle wheel interacted with the gas, forming a convection roll, sustaining their rotation.


See also

* Quantum stirring, ratchets, and pumping *


Notes


External links


The Feynman Lectures on Physics Vol. I Ch. 46: Ratchet and pawlCoupled Brownian Motors - Can we get work out of unbiased fluctuation?


;Articles * * * *Lukasz Machura: ''Performance of Brownian Motors''. University of Augsburg, 2006
PDF
* * * *Qiu C, Punke M, Tian Y, Han Y, Wang S, Su Y, Salvalaglio M, Pan X, Srolovitz D J, Han J (2024)
Grain boundaries are Brownian ratchets
Science 385 (6712): 980:985
doi:10.1126/science.adp1516
{{DEFAULTSORT:Brownian Ratchet Thought experiments in physics Richard Feynman Philosophy of thermal and statistical physics Nanotechnology Perpetual motion