Environmental Isotopes
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The environmental isotopes are a subset of
isotope Isotopes are distinct nuclear species (or ''nuclides'') of the same chemical element. They have the same atomic number (number of protons in their Atomic nucleus, nuclei) and position in the periodic table (and hence belong to the same chemica ...
s, both
stable A stable is a building in which working animals are kept, especially horses or oxen. The building is usually divided into stalls, and may include storage for equipment and feed. Styles There are many different types of stables in use tod ...
and
radioactive Radioactive decay (also known as nuclear decay, radioactivity, radioactive disintegration, or nuclear disintegration) is the process by which an unstable atomic nucleus loses energy by radiation. A material containing unstable nuclei is conside ...
, which are the object of
isotope geochemistry Isotope geochemistry is an aspect of geology based upon the study of natural variations in the relative abundances of isotopes of various Chemical element, elements. Variations in isotopic abundance are measured by isotope-ratio mass spectrometry, ...
. They are primarily used as tracers to see how things move around within the ocean-atmosphere system, within terrestrial
biome A biome () is a distinct geographical region with specific climate, vegetation, and animal life. It consists of a biological community that has formed in response to its physical environment and regional climate. In 1935, Tansley added the ...
s, within the Earth's surface, and between these broad domains.


Isotope geochemistry

Chemical elements are defined by their number of protons, but the mass of the atom is determined by the number of protons and neutrons in the nucleus. Isotopes are atoms that are of a specific element, but have different numbers of neutrons and thus different
mass number The mass number (symbol ''A'', from the German word: ''Atomgewicht'', "atomic weight"), also called atomic mass number or nucleon number, is the total number of protons and neutrons (together known as nucleons) in an atomic nucleus. It is appro ...
s. The ratio between isotopes of an element varies slightly in the world, so in order to study isotopic ratio changes across the world, changes in isotope ratios are defined as deviations from a standard, multiplied by 1000. This unit is a "
per mil The phrase per mille () indicates parts per thousand. The associated symbol is , similar to a per cent sign but with an extra zero in the divisor. Major dictionaries do not agree on the spelling, giving other options of per mil, per mill, p ...
". As a convention, the ratio is of the heavier isotope to the lower isotope. \delta \ce = \left( \frac -1 \right) \times 1000 ‰ These variations in isotopes can occur through many types of fractionation. They are generally classified as mass independent fractionation and mass dependent fractionation. An example of a mass independent process is the fractionation of oxygen atoms in
ozone Ozone () (or trioxygen) is an Inorganic compound, inorganic molecule with the chemical formula . It is a pale blue gas with a distinctively pungent smell. It is an allotrope of oxygen that is much less stable than the diatomic allotrope , break ...
. This is due to the
kinetic isotope effect In physical organic chemistry, a kinetic isotope effect (KIE) is the change in the reaction rate of a chemical reaction when one of the atoms in the reactants is replaced by one of its isotopes. Formally, it is the ratio of rate constants for t ...
(KIE) and is caused by different isotope molecules reacting at different speeds. An example of a mass dependent process is the fractionation of water as it transitions from the liquid to gas phase. Water molecules with heavier isotopes ( 18O and 2H) tend to stay in the liquid phase as water molecules with lighter isotopes ( 16O and 1H) preferentially move to the gas phase. Of the different isotopes that exist, one common classification is distinguishing
radioactive isotopes A radionuclide (radioactive nuclide, radioisotope or radioactive isotope) is a nuclide that has excess numbers of either neutrons or protons, giving it excess nuclear energy, and making it unstable. This excess energy can be used in one of three ...
from
stable isotopes The term stable isotope has a meaning similar to stable nuclide, but is preferably used when speaking of nuclides of a specific element. Hence, the plural form stable isotopes usually refers to isotopes of the same element. The relative abundan ...
. Radioactive isotopes are isotopes that will decay into a different isotope. For example, 3H (
tritium Tritium () or hydrogen-3 (symbol T or H) is a rare and radioactive isotope of hydrogen with a half-life of ~12.33 years. The tritium nucleus (t, sometimes called a ''triton'') contains one proton and two neutrons, whereas the nucleus of the ...
) is a radioactive isotope of hydrogen. It decays into 3He with a
half-life Half-life is a mathematical and scientific description of exponential or gradual decay. Half-life, half life or halflife may also refer to: Film * Half-Life (film), ''Half-Life'' (film), a 2008 independent film by Jennifer Phang * ''Half Life: ...
of ~12.3 years. By comparison, stable isotopes do not undergo radioactive decay, and their fixed proportions are measured against exponentially decaying proportions of radioactive isotopes to determine the age of a substance. Radioactive isotopes are generally more useful on shorter timescales, such as investigating modern circulation of the ocean using 14C, while stable isotopes are generally more useful on longer timescales, such as investigating differences in river flow with stable strontium isotopes. These isotopes are used as tracers to study various phenomena of interest. These tracers have a certain distribution spatially, and so scientists need to deconvolve the different processes that affect these tracer distributions. One way tracer distributions are set is by conservative mixing. In conservative mixing, the amount of the tracer is conserved. An example of this is mixing two water masses with different
salinities Salinity () is the saltiness or amount of salt dissolved in a body of water, called saline water (see also soil salinity). It is usually measured in g/L or g/kg (grams of salt per liter/kilogram of water; the latter is dimensionless and equal to ...
. The salt from the saltier water mass moves to the less salty water mass, keeping the total amount of salinity constant. This way of mixing tracers is very important, giving a baseline of what value of a tracer one should expect. The value of a tracer as a point is expected to be an average value of the sources that flow into that region. Deviations from this are indicative of other processes. These can be called nonconservative mixing, where there are other processes that do not conserve the amount of tracer. An example of this is 𝛿14C. This mixes between water masses, but it also decays over time, reducing the amount of 14C in the region.


Commonly used isotopes

The most used environmental isotopes are: *
deuterium Deuterium (hydrogen-2, symbol H or D, also known as heavy hydrogen) is one of two stable isotopes of hydrogen; the other is protium, or hydrogen-1, H. The deuterium nucleus (deuteron) contains one proton and one neutron, whereas the far more c ...
*
tritium Tritium () or hydrogen-3 (symbol T or H) is a rare and radioactive isotope of hydrogen with a half-life of ~12.33 years. The tritium nucleus (t, sometimes called a ''triton'') contains one proton and two neutrons, whereas the nucleus of the ...
*
carbon-13 Carbon-13 (13C) is a natural, stable isotope of carbon with a nucleus containing six protons and seven neutrons. As one of the environmental isotopes, it makes up about 1.1% of all natural carbon on Earth. Detection by mass spectrometry A m ...
*
carbon-14 Carbon-14, C-14, C or radiocarbon, is a radioactive isotope of carbon with an atomic nucleus containing 6 protons and 8 neutrons. Its presence in organic matter is the basis of the radiocarbon dating method pioneered by Willard Libby and coll ...
*
nitrogen-15 Natural nitrogen (7N) consists of two stable isotopes: the vast majority (99.6%) of naturally occurring nitrogen is nitrogen-14, with the remainder being nitrogen-15. Thirteen radioisotopes are also known, with atomic masses ranging from 9 to 23, ...
*
oxygen-18 Oxygen-18 (, Ω) is a natural, stable isotope of oxygen and one of the environmental isotopes. is an important precursor for the production of fluorodeoxyglucose (FDG) used in positron emission tomography (PET). Generally, in the radiopharm ...
*
silicon-29 Silicon (14Si) has 25 known isotopes, with mass numbers ranging from 22 to 46. 28Si (the most abundant isotope, at 92.23%), 29Si (4.67%), and 30Si (3.1%) are stable. The longest-lived radioisotope is 32Si, which is produced by cosmic ray spallatio ...
*
chlorine-36 Chlorine-36 (36Cl) is an isotope of chlorine. Chlorine has two stable isotopes and one naturally occurring radioactive isotope, the cosmogenic isotope 36Cl. Its half-life is 301,300 ± 1,500 years. 36Cl decays primarily (98%) by beta-minus dec ...
*
isotopes of uranium Uranium (U) is a naturally occurring radioactive element (radioelement) with no stable isotopes. It has two primordial isotopes, uranium-238 and uranium-235, that have long half-lives and are found in appreciable quantity in Earth's crust. The d ...
*
isotopes of strontium The alkaline earth metal strontium (38Sr) has four stable, naturally occurring isotopes: 84Sr (0.56%), 86Sr (9.86%), 87Sr (7.0%) and 88Sr (82.58%). Its standard atomic weight is 87.62(1). Only 87Sr is radiogenic; it is produced by decay from ...


Ocean circulation

One topic that environmental isotopes are used to study is the circulation of the ocean. Treating the ocean as a box is only useful in some studies; in depth consideration of the oceans in
general circulation model A general circulation model (GCM) is a type of climate model. It employs a mathematical model of the general circulation of a planetary atmosphere or ocean. It uses the Navier–Stokes equations on a rotating sphere with thermodynamic terms for ...
s (GCMs) requires knowing how the ocean circulates. This leads to an understanding of how the oceans (along with the atmosphere) transfer heat from the tropics to the poles. This also helps deconvolve circulation effects from other phenomena that affect certain tracers such as radioactive and biological processes. Using rudimentary observation techniques, the circulation of the surface ocean can be determined. In the
Atlantic The Atlantic Ocean is the second largest of the world's five oceanic divisions, with an area of about . It covers approximately 17% of Earth's surface and about 24% of its water surface area. During the Age of Discovery, it was known for se ...
basin, surface waters flow from the south towards the north in general, while also creating gyres in the northern and southern Atlantic. In the
Pacific Ocean The Pacific Ocean is the largest and deepest of Earth's five Borders of the oceans, oceanic divisions. It extends from the Arctic Ocean in the north to the Southern Ocean, or, depending on the definition, to Antarctica in the south, and is ...
, the gyres still form, but there is comparatively very little large scale meridional (North-South) movement. For deep waters, there are two areas where density causes waters to sink into the deep ocean. These are in the North Atlantic and the Antarctic. The deep water masses formed are
North Atlantic Deep Water North Atlantic Deep Water (NADW) is a deep water mass formed in the North Atlantic Ocean. Thermohaline circulation (properly described as meridional overturning circulation) of the world's oceans involves the flow of warm surface waters from the ...
(NADW) and
Antarctic Bottom Water The Antarctic bottom water (AABW) is a type of water mass in the Southern Ocean surrounding Antarctica with temperatures ranging from −0.8 to 2 °C (35 °F) and absolute salinities from 34.6 to 35.0 g/kg. As the densest water mass of ...
(AABW). Deep waters are mixtures of these two waters, and understanding how waters are composed of these two water masses can tell us about how water masses move around in the deep ocean. This can be investigated with environmental isotopes, including 14C. 14C is predominantly produced in the upper atmosphere and from nuclear testing, with no major sources or sinks in the ocean. This 14C from the atmosphere becomes oxidized into 14CO2, allowing it to enter the surface ocean through gas transfer. This is transferred into the deep ocean through NADW and AABW. In NADW, the 𝛿14C is approximately -60‰, and in AABW, the 𝛿14C is approximately -160‰. Thus, using conservative mixing of radiocarbon, the expected amount of radiocarbon in various locations can be determined using the percent compositions of NADW and AABW at that location. This can be determined using other tracers, such as phosphate star or salinity. Deviations from this expected value are indicative of other processes that affect the delta ratio of radiocarbon, namely radioactive decay. This deviation can be converted to a time, giving the age of the water at that location. Doing this over the world's ocean can yield a circulation pattern of the ocean and the rate at which water flow through the deep ocean. Using this circulation in conjunction with the surface circulation allows scientists to understand the energy balance of the world. Warmer surface waters flow northward while colder deep waters flow southward, leading to net heat transfer towards the pole.


Paleoclimate

Isotopes are also used to study
paleoclimate Paleoclimatology ( British spelling, palaeoclimatology) is the scientific study of climates predating the invention of meteorological instruments, when no direct measurement data were available. As instrumental records only span a tiny part of ...
. This is the study of how climate was in the past, from hundreds of years ago to hundreds of thousands of years ago. The only records of these times that we have are buried in rocks,
sediment Sediment is a solid material that is transported to a new location where it is deposited. It occurs naturally and, through the processes of weathering and erosion, is broken down and subsequently sediment transport, transported by the action of ...
s, biological shells,
stalagmite A stalagmite (, ; ; ) is a type of rock formation that rises from the floor of a cave due to the accumulation of material deposited on the floor from ceiling drippings. Stalagmites are typically composed of calcium carbonate, but may consist ...
s and
stalactite A stalactite (, ; , ) is a mineral formation that hangs from the ceiling of caves, hot springs, or man-made structures such as bridges and mines. Any material that is soluble and that can be deposited as a colloid, or is in suspension (chemistry ...
s, etc. The isotope ratios in these samples were affected by the temperature, salinity, circulation of the ocean, precipitation, etc. of the climate at the time, causing a measurable change from the standards for isotope measurements. This is how climate information is encoded in these geological formations. Some of the many isotopes useful for environmental science are discussed below.


δ18O

One useful isotope for reconstructing past climates is
oxygen-18 Oxygen-18 (, Ω) is a natural, stable isotope of oxygen and one of the environmental isotopes. is an important precursor for the production of fluorodeoxyglucose (FDG) used in positron emission tomography (PET). Generally, in the radiopharm ...
. It is another stable isotope of oxygen along with
oxygen-16 Oxygen-16 (symbol: 16O or ) is a nuclide. It is a stable isotope of oxygen, with 8 neutrons and 8 protons in its nucleus, and when not ionized, 8 electrons orbiting the nucleus. Oxygen-16 has a mass of . It is the most abundant isotope of oxyg ...
, and its incorporation into
water Water is an inorganic compound with the chemical formula . It is a transparent, tasteless, odorless, and Color of water, nearly colorless chemical substance. It is the main constituent of Earth's hydrosphere and the fluids of all known liv ...
and
carbon dioxide Carbon dioxide is a chemical compound with the chemical formula . It is made up of molecules that each have one carbon atom covalent bond, covalently double bonded to two oxygen atoms. It is found in a gas state at room temperature and at norma ...
/
carbonate A carbonate is a salt of carbonic acid, (), characterized by the presence of the carbonate ion, a polyatomic ion with the formula . The word "carbonate" may also refer to a carbonate ester, an organic compound containing the carbonate group ...
molecules is strongly temperature dependent. Higher temperature implies more incorporation of oxygen-18, and vice versa. Thus, the ratio of 18O/16O can tell something about temperature. For water, the isotope ratio standard is
Vienna Standard Mean Ocean Water Vienna Standard Mean Ocean Water (VSMOW) is an isotopic standard for water, that is, a particular sample of water whose proportions of different isotopes of hydrogen and oxygen are accurately known. VSMOW is distilled from ocean water and does no ...
, and for carbonates, the standard is Pee Dee Belemnite. Using
ice core An ice core is a core sample that is typically removed from an ice sheet or a high mountain glacier A glacier (; or ) is a persistent body of dense ice, a form of rock, that is constantly moving downhill under its own weight. A glacier ...
s and sediment cores that record information about the water and shells from past times, this ratio can tell scientists about the temperature of those times. This ratio is used with ice cores to determine the temperature at the spot in the ice core. Depth in an ice core is proportional to time, and it is "wiggle-matched" with other records to determine the true time of the ice at that depth. This can be done by comparing δ18O in calcium carbonate shells in sediment cores to these records to match large scale changes in the temperature of the Earth. Once the ice cores are matched to sediment cores, highly accurate dating methods such as
U-series dating U series or U-series may refer to: Science and technology * HTC U series, Android smartphones * IdeaPad U series, Lenovo consumer laptop computers * Sony U series The Sony U series of subnotebook computers refers to two series of Sony products the ...
can be used to accurately determine the time of these events. There are some processes that mix water from different times into the same depth in the ice core, such as
firn __NOTOC__ Firn (; from Swiss German "last year's", cognate with ''before'') is partially compacted névé, a type of snow that has been left over from past seasons and has been recrystallized into a substance denser than névé. It is ice that ...
production and sloped landscape floes. Lisiecki and
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(2005) used measurements of δ18O in benthic
foraminifera Foraminifera ( ; Latin for "hole bearers"; informally called "forams") are unicellular organism, single-celled organisms, members of a phylum or class (biology), class of Rhizarian protists characterized by streaming granular Ectoplasm (cell bio ...
from 57 globally distributed deep sea sediment cores, taken as a proxy for the total global mass of glacial ice sheets, to reconstruct the climate for the past five million years. This record shows oscillations of 2-10 degrees Celsius over this time. Between 5 million and 1.2 million years ago, these oscillations had a period of 41,000 years (41 kyr), but about 1.2 million years ago the period switch to 100 kyr. These changes in global temperature match with changes in orbital parameters of the Earth's orbit around the Sun. These are called
Milankovitch cycles Milankovitch cycles describe the collective effects of changes in the Earth's movements on its climate over thousands of years. The term was coined and named after the Serbian geophysicist and astronomer Milutin Milanković. In the 1920s, he pr ...
, and these are related to
eccentricity Eccentricity or eccentric may refer to: * Eccentricity (behavior), odd behavior on the part of a person, as opposed to being "normal" Mathematics, science and technology Mathematics * Off-Centre (geometry), center, in geometry * Eccentricity (g ...
, obliquity (
axial tilt In astronomy, axial tilt, also known as obliquity, is the angle between an object's rotational axis and its orbital axis, which is the line perpendicular to its orbital plane; equivalently, it is the angle between its equatorial plane and orbita ...
), and
precession Precession is a change in the orientation of the rotational axis of a rotating body. In an appropriate reference frame it can be defined as a change in the first Euler angle, whereas the third Euler angle defines the rotation itself. In o ...
of Earth around its axis. These correspond to cycles with periods of 100 kyr, 40 kyr, and 20 kyr. δ18O can also be used to investigate smaller scale climate phenomena. Koutavas et al. (2006) used δ18O of G. ruber foraminifera to study the
El Niño–Southern Oscillation El Niño–Southern Oscillation (ENSO) is a global climate phenomenon that emerges from variation in winds and sea surface temperatures over the tropical Pacific Ocean. Those variations have an irregular pattern but do have some semblance of cyc ...
(ENSO) and it's variability through the mid-
Holocene The Holocene () is the current geologic time scale, geological epoch, beginning approximately 11,700 years ago. It follows the Last Glacial Period, which concluded with the Holocene glacial retreat. The Holocene and the preceding Pleistocene to ...
. By isolating individual foram shells, Koutavas et al. were able to obtain a spread of δ18O values at a specific depth. Because these forams live for approximately a month and that the individual forams were from many different months, clumped together in a small depth range in the coral, the variability of δ18O was able to be determined. In the eastern Pacific, where these cores were taken, the primary driver of this variability is ENSO, making this a record of ENSO variability over the core's time span. Koutavas et al. found that ENSO was much less variable in the mid Holocene (~6,000 years ago) than it is currently.


Strontium isotopes

Another set of environmental isotopes used in paleoclimate is strontium isotopes. Strontium-86 and strontium-87 are both stable isotopes of strontium, but strontium-87 is radiogenic, coming from the decay of rubidium-87. The ratio of these two isotopes depends on the concentration of rubidium-87 initially and the age of the sample, assuming that the background concentration of strontium-87 is known. This is useful because 87Rb is predominantly found in continental rocks. Particles from these rocks come into the ocean through weathering by rivers, meaning that this strontium isotope ratio is related to the weathering ion flux coming from rivers into the ocean. The background concentration in the ocean for 87Sr/86Sr is 0.709 ± 0.0012. Because the strontium ratio is recorded in sedimentary records, the oscillations of this ratio over time can be studied. These oscillations are related to the riverine input into the oceans or into the local basin. Richter and Turekian have done work on this, finding that over glacial-interglacial timescales (105 years), the 87Sr/86Sr ratio varies by 3*10−5.


Uranium and related isotopes

Uranium has many radioactive isotopes that continue emitting particles down a
decay chain In nuclear science a decay chain refers to the predictable series of radioactive disintegrations undergone by the nuclei of certain unstable chemical elements. Radioactive isotopes do not usually decay directly to stable isotopes, but rather ...
.
Uranium-235 Uranium-235 ( or U-235) is an isotope of uranium making up about 0.72% of natural uranium. Unlike the predominant isotope uranium-238, it is fissile, i.e., it can sustain a nuclear chain reaction. It is the only fissile isotope that exists in nat ...
is in one such chain, and decays into
protactinium-231 Protactinium (91Pa) has no stable isotopes. The four naturally occurring isotopes allow a standard atomic weight to be given. Thirty radioisotopes of protactinium have been characterized, ranging from 210Pa to 239Pa. The most stable isotope is 2 ...
and then into other products.
Uranium-238 Uranium-238 ( or U-238) is the most common isotope of uranium found in nature, with a relative abundance of 99%. Unlike uranium-235, it is non-fissile, which means it cannot sustain a chain reaction in a thermal-neutron reactor. However, it i ...
is in a separate chain, decaying into a series of elements, including
thorium-230 Thorium (90Th) has seven naturally occurring isotopes but none are stable. One isotope, 232Th, is ''relatively'' stable, with a half-life of 1.405×1010 years, considerably longer than the age of the Earth, and even slightly longer than the gen ...
. Both of these series end up forming lead, either
lead-207 Lead (82Pb) has four observationally stable isotopes: 204Pb, 206Pb, 207Pb, 208Pb. Lead-204 is entirely a primordial nuclide and is not a radiogenic nuclide. The three isotopes lead-206, lead-207, and lead-208 represent the ends of three decay cha ...
from uranium-235 or
lead-206 Lead (82Pb) has four observationally stable isotopes: 204Pb, 206Pb, 207Pb, 208Pb. Lead-204 is entirely a primordial nuclide and is not a radiogenic nuclide. The three isotopes lead-206, lead-207, and lead-208 represent the ends of three decay ch ...
from uranium-238. All of these decays are
alpha Alpha (uppercase , lowercase ) is the first letter of the Greek alphabet. In the system of Greek numerals, it has a value of one. Alpha is derived from the Phoenician letter ''aleph'' , whose name comes from the West Semitic word for ' ...
or
beta decay In nuclear physics, beta decay (β-decay) is a type of radioactive decay in which an atomic nucleus emits a beta particle (fast energetic electron or positron), transforming into an isobar of that nuclide. For example, beta decay of a neutron ...
s, meaning that they all follow first order rate equations of the form dN/dt=\lambda N, where λ is the half-life of the isotope in question. This makes it simple to determine the age of a sample based on the various ratios of radioactive isotopes that exist. One way uranium isotopes are used is to date rocks from millions to billions of years ago. This is through uranium-lead dating. This technique uses
zircon Zircon () is a mineral belonging to the group of nesosilicates and is a source of the metal zirconium. Its chemical name is zirconium(IV) silicate, and its corresponding chemical formula is Zr SiO4. An empirical formula showing some of th ...
samples and measures the lead content in them. Zircon incorporates uranium and thorium atoms into its
crystal structure In crystallography, crystal structure is a description of ordered arrangement of atoms, ions, or molecules in a crystalline material. Ordered structures occur from intrinsic nature of constituent particles to form symmetric patterns that repeat ...
, but strongly rejects
lead Lead () is a chemical element; it has Chemical symbol, symbol Pb (from Latin ) and atomic number 82. It is a Heavy metal (elements), heavy metal that is density, denser than most common materials. Lead is Mohs scale, soft and Ductility, malleabl ...
. Thus, the only sources of lead in a zircon crystal are through decay of uranium and thorium. Both the uranium-235 and uranium-238 series decay into an isotope of lead. The half-life of converting 235U to 207Pb is 710 million years, and the half-life of converting 238U to 206Pb is 4.47 billion years. Because of high resolution mass-spectroscopy, both chains can be used to date rocks, giving complementary information about the rocks. The large difference in half-lives makes the technique robust over long time scales, from on the order of millions of years to on the order of billions of years. Another way uranium isotopes are used in environmental science is the ratio of 231Pa/230Th. These radiogenic isotopes have different uranium parents, but have very different reactivities in the ocean. The uranium profile in the ocean is constant because uranium has a very large residence time compared to the residence time of the ocean. The decay of uranium is thus also isotropic, but the daughter isotopes react differently. Thorium is readily scavenged by particles, leading to rapid removal from the ocean into sediments. By contrast, 231Pa is not as particle-reactive, feeling the circulation of the ocean in small amounts before settling into the sediment. Thus, knowing the decay rates of both isotopes and the fractions of each uranium isotopes, the expected ratio of 231Pa/230Th can be determined, with any deviation from this value being due to circulation. Circulation leads to a higher 231Pa/230Th ratio downstream and a lower ratio upstream, with the magnitude of the deviation being related to flow rate. This technique has been used to quantify the
Atlantic Meridional Overturning Circulation The Atlantic meridional overturning circulation (AMOC) is the main ocean current system in the Atlantic Ocean.IPCC, 2021Annex VII: Glossary atthews, J.B.R., V. Möller, R. van Diemen, J.S. Fuglestvedt, V. Masson-Delmotte, C. Méndez, S. Sem ...
(AMOC) during the Last Glacial Maximum (LGM) and during abrupt climate change events in Earth's past, such as Heinrich events and Dansgaard–Oeschger event, Dansgaard-Oeschger events.


Neodymium

Neodymium isotopes are also used to determine circulation in the ocean. All of the
isotopes of neodymium Naturally occurring neodymium (60Nd) is composed of five stable isotopes, 142Nd, 143Nd, 145Nd, 146Nd and 148Nd, with 142Nd being the most abundant (27.2% natural abundance), and two long-lived radioisotopes, 144Nd and 150Nd. In all, 35 radioisotop ...
are stable on the timescales of glacial-interglacial cycles, but 143Nd is a daughter of 147Sm, a radioactive isotope in the ocean. Samarium-147 has higher concentrations in mantle rocks vs crust rocks, so areas that receive river inputs from mantle-derived rocks have higher concentrations of 147Sm and 143Nd. However, these differences are so small, the standard notation of a delta value are no blunt for it; a more precise epsilon value is used to describe variations in this ratio of neodymium isotopes. It is defined as \epsilon \ce = \left( \frac -1 \right) \times 10000 The only major sources of this in the ocean are in the North Atlantic and in the deep Pacific Ocean. Because one of the end-members is set in the interior of the ocean, this technique has the potential to tell us complementary information about paleoclimate compared to all other ocean tracers that are only set in the surface ocean.


References

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