In the physical chemistry study of
polymer
A polymer (; Greek ''poly-'', "many" + '' -mer'', "part")
is a substance or material consisting of very large molecules called macromolecules, composed of many repeating subunits. Due to their broad spectrum of properties, both synthetic and ...
s, the end-to-end vector is the
vector
Vector most often refers to:
*Euclidean vector, a quantity with a magnitude and a direction
*Vector (epidemiology), an agent that carries and transmits an infectious pathogen into another living organism
Vector may also refer to:
Mathematic ...
that points from one end of a polymer to the other end.
If each monomer unit in a polymer is represented by a point in space, the translation vectors
connect between these points. The end-to-end vector
is the sum of these translation vectors:
:
The norm of the end-to-end vector is called the end-to-end distance.
Relation to other quantities
The
quadratic mean
In mathematics and its applications, the root mean square of a set of numbers x_i (abbreviated as RMS, or rms and denoted in formulas as either x_\mathrm or \mathrm_x) is defined as the square root of the mean square (the arithmetic mean of th ...
of the end-to-end distance
can be related to the quadratic mean of the
radius of gyration ''Radius of gyration'' or gyradius of a body about the axis of rotation is defined as the radial distance to a point which would have a moment of inertia the same as the body's actual distribution of mass, if the total mass of the body were concent ...
of a polymer by the relation:
[{{cite book, last1= Gedde , first1= Ulf W. , title= Polymer Physics , url= https://books.google.com/books?id=Iem3fC7XdnkC , year= 1995 , publisher= Springer , isbn= 0-412-62640-3 , page= 21]
:
Notes
See also
*
Freely Jointed Chain
*
Worm-like chain
The worm-like chain (WLC) model in polymer physics is used to describe the behavior of polymers that are semi-flexible: fairly stiff with successive segments pointing in roughly the same direction, and with persistence length within a few orders o ...
Polymers
Polymer physics