Polymer Physics
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Polymer Physics
Polymer physics is the field of physics that studies polymers, their fluctuations, mechanical properties, as well as the kinetics of reactions involving degradation of polymers and polymerisation of monomers.P. Flory, ''Principles of Polymer Chemistry'', Cornell University Press, 1953. .Pierre Gilles De Gennes, ''Scaling Concepts in Polymer Physics'' CORNELL UNIVERSITY PRESS Ithaca and London, 1979M. Doi and S. F. Edwards, ''The Theory of Polymer Dynamics'' Oxford University Inc NY, 1986 While it focuses on the perspective of condensed matter physics, polymer physics was originally a branch of statistical physics. Polymer physics and polymer chemistry are also related to the field of polymer science, which is considered to be the applicative part of polymers. Polymers are large molecules and thus are very complicated for solving using a deterministic method. Yet, statistical approaches can yield results and are often pertinent, since large polymers (i.e., polymers with many ...
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Physics
Physics is the scientific study of matter, its Elementary particle, fundamental constituents, its motion and behavior through space and time, and the related entities of energy and force. "Physical science is that department of knowledge which relates to the order of nature, or, in other words, to the regular succession of events." It is one of the most fundamental scientific disciplines. "Physics is one of the most fundamental of the sciences. Scientists of all disciplines use the ideas of physics, including chemists who study the structure of molecules, paleontologists who try to reconstruct how dinosaurs walked, and climatologists who study how human activities affect the atmosphere and oceans. Physics is also the foundation of all engineering and technology. No engineer could design a flat-screen TV, an interplanetary spacecraft, or even a better mousetrap without first understanding the basic laws of physics. (...) You will come to see physics as a towering achievement of ...
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Size Exclusion Chromatography
Size-exclusion chromatography, also known as molecular sieve chromatography, is a chromatographic method in which molecules in solution are separated by their shape, and in some cases size. It is usually applied to large molecules or macromolecular complexes such as proteins and industrial polymers. Typically, when an aqueous solution is used to transport the sample through the column, the technique is known as gel filtration chromatography, versus the name gel permeation chromatography, which is used when an organic solvent is used as a mobile phase. The chromatography column is packed with fine, porous beads which are commonly composed of dextran, agarose, or polyacrylamide polymers. The pore sizes of these beads are used to estimate the dimensions of macromolecules. SEC is a widely used polymer characterization method because of its ability to provide good molar mass distribution (Mw) results for polymers. Size-exclusion chromatography (SEC) is fundamentally different from al ...
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FENE Model
In polymer physics, the finite extensible nonlinear elastic (FENE) model, also called the FENE dumbbell model, represents the dynamics of a long-chained polymer. It simplifies the chain of monomers by connecting a sequence of beads with nonlinear springs. Its direct extension the FENE-P model, is more commonly used in computational fluid dynamics to simulate turbulent flow. The P stands for the last name of physicist Anton Peterlin, who developed an important approximation of the model in 1966. The FENE-P model was introduced by Robert Byron Bird ''et al.'' in the 1980s. In 1991 the FENE-MP model (PM for modified Peterlin) was introduced and in 1988 the FENE-CR was introduced by M.D. Chilcott and J.M. Rallison. Formulation The spring force in the FENE model is given Warner's spring force, as :\textbf_i=k\frac, where R_i = , \textbf_i, , ''k'' is the spring constant and Lmax the upper limit for the length extension. Total stretching force on ''i-''th bead can be written ...
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