Electroceramics are a class of

ceramic A ceramic is any of the various hard, brittle, heat-resistant, and corrosion-resistant materials made by shaping and then firing an inorganic, nonmetallic material, such as clay, at a high temperature. Common examples are earthenware, porcela ...

materials used primarily for their electrical properties. While ceramics have traditionally been admired and used for their mechanical, thermal and chemical stability, their unique

electrical Electricity is the set of physical phenomena associated with the presence and motion of matter possessing an electric charge. Electricity is related to magnetism, both being part of the phenomenon of electromagnetism, as described by Maxwel ...

optical Optics is the branch of physics that studies the behaviour and properties of light, including its interactions with matter and the construction of instruments that use or detect it. Optics usually describes the behaviour of visible, ultravio ...

and

magnetic Magnetism is the class of physical attributes that occur through a magnetic field, which allows objects to attract or repel each other. Because both electric currents and magnetic moments of elementary particles give rise to a magnetic field, m ...

properties have become of increasing importance in many key technologies including communications, energy conversion and storage, electronics and automation. Such materials are now classified under ''electroceramics'', as distinguished from other functional ceramics such as advanced structural ceramics. Historically, developments in the various subclasses of electroceramics have paralleled the growth of new technologies. Examples include: ferroelectrics - high dielectric

capacitor In electrical engineering, a capacitor is a device that stores electrical energy by accumulating electric charges on two closely spaced surfaces that are insulated from each other. The capacitor was originally known as the condenser, a term st ...

s, non-volatile memories; ferrites - data and information storage; solid electrolytes - energy storage and conversion;

piezoelectric Piezoelectricity (, ) is the electric charge that accumulates in certain solid materials—such as crystals, certain ceramics, and biological matter such as bone, DNA, and various proteins—in response to applied stress (mechanics), mechanical s ...

s - sonar; semiconducting oxides -

environmental monitoring Environmental monitoring is the processes and activities that are done to characterize and describe the state of the environment. It is used in the preparation of environmental impact assessments, and in many circumstances in which human activit ...

. Recent advances in these areas are described in th
Journal of Electroceramics

Dielectric ceramics

Dielectric In electromagnetism, a dielectric (or dielectric medium) is an Insulator (electricity), electrical insulator that can be Polarisability, polarised by an applied electric field. When a dielectric material is placed in an electric field, electric ...

materials used for construction of ceramic

capacitors In electrical engineering, a capacitor is a device that stores electrical energy by accumulating electric charges on two closely spaced surfaces that are insulated from each other. The capacitor was originally known as the condenser, a term st ...

include: Lead Zirconate titanate (PZT),

Barium titanate Barium titanate (BTO) is an inorganic compound with chemical formula BaTiO3. It is the barium salt of metatitanic acid. Barium titanate appears white as a powder and is transparent when prepared as large crystals. It is a Ferroelectricity, ferroe ...

(BT),

strontium titanate Strontium titanate is an oxide of strontium and titanium with the chemical formula strontium, Srtitanium, Tioxygen, O3. At room temperature, it is a centrosymmetric paraelectricity, paraelectric material with a Perovskite (structure), perovskite st ...

(ST),

calcium titanate Calcium titanate is an inorganic compound with the chemical formula Ca Ti O3. As a mineral, it is called perovskite, named after Russian mineralogist, Lev Perovski (1792–1856). It is a colourless, diamagnetic solid, although the mineral is of ...

(CT), magnesium titanate (MT), calcium magnesium titanate (CMT), zinc titanate (ZT), lanthanum titanate (LT), and neodymium titanate (NT), barium zirconate (BZ), calcium zirconate (CZ), lead magnesium niobate (PMN), lead zinc niobate (PZN),

lithium niobate Lithium niobate () is a synthetic salt consisting of niobium, lithium Lithium (from , , ) is a chemical element; it has chemical symbol, symbol Li and atomic number 3. It is a soft, silvery-white alkali metal. Under standard temperatur ...

(LN), barium stannate (BS), calcium stannate (CS), magnesium aluminium silicate, magnesium silicate, barium tantalate,

titanium dioxide Titanium dioxide, also known as titanium(IV) oxide or titania , is the inorganic compound derived from titanium with the chemical formula . When used as a pigment, it is called titanium white, Pigment White 6 (PW6), or Colour Index Internationa ...

, niobium oxide,

zirconia Zirconium dioxide (), sometimes known as zirconia (not to be confused with zirconium silicate or zircon), is a white crystalline oxide of zirconium. Its most naturally occurring form, with a monoclinic crystalline structure, is the mineral ba ...

silica Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , commonly found in nature as quartz. In many parts of the world, silica is the major constituent of sand. Silica is one of the most complex and abundant f ...

sapphire Sapphire is a precious gemstone, a variety of the mineral corundum, consisting of aluminium oxide () with trace amounts of elements such as iron, titanium, cobalt, lead, chromium, vanadium, magnesium, boron, and silicon. The name ''sapphire ...

beryllium oxide Beryllium oxide (BeO), also known as beryllia, is an inorganic compound with the formula BeO. This colourless solid is an electrical insulator with a higher thermal conductivity than any other non-metal except diamond, and exceeds that of most met ...

, and zirconium tin titanate Some piezoelectric materials can be used as well; the EIA Class 2 dielectrics are based on mixtures rich on

barium titanate Barium titanate (BTO) is an inorganic compound with chemical formula BaTiO3. It is the barium salt of metatitanic acid. Barium titanate appears white as a powder and is transparent when prepared as large crystals. It is a Ferroelectricity, ferroe ...

. In turn, EIA Class 1 dielectrics contain little or no barium titanate.

Electronically conductive ceramics

Indium tin oxide Indium tin oxide (ITO) is a ternary composition of indium, tin and oxygen in varying proportions. Depending on the oxygen content, it can be described as either a ceramic or an alloy. Indium tin oxide is typically encountered as an oxygen-saturate ...

(ITO), lanthanum-doped strontium titanate (SLT), yttrium-doped strontium titanate (SYT)

Fast ion conductor ceramics

Yttria-stabilized zirconia Yttria-stabilized zirconia (YSZ) is a ceramic in which the cubic crystal structure of zirconium dioxide is made stable at room temperature by an addition of yttrium oxide. These oxides are commonly called "zirconia" ( Zr O2) and "yttria" ( Y2 O3 ...

(YSZ), gadolinium-doped ceria (GDC), lanthanum strontium gallate magnesite(LSGM), beta alumina, beta alumina

Piezoelectric and ferroelectric ceramics

Commercially used piezoceramic is primarily

lead zirconate titanate Lead zirconate titanate, also called lead zirconium titanate and commonly abbreviated as PZT, is an inorganic compound with the chemical formula . It is a ceramic perovskite material that shows a marked piezoelectric effect, meaning that the comp ...

(PZT).

(BT),

(ST),

quartz Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The Atom, atoms are linked in a continuous framework of SiO4 silicon–oxygen Tetrahedral molecular geometry, tetrahedra, with each oxygen being shared between two tet ...

, and others are also used. See :Piezoelectric materials.

Magnetic ceramics

Ferrites Ferrite may refer to: * Ferrite (iron), one of the allotropes of iron that is stable at room temperature and pressure, α-Fe * Ferrite (magnet), a ferromagnetic ceramic material See also * * Ferrite bead, a component placed on the end of a data c ...

including

iron(III) oxide Iron(III) oxide or ferric oxide is the inorganic compound with the formula . It occurs in nature as the mineral hematite, which serves as the primary source of iron for the steel industry. It is also known as red iron oxide, especially when use ...

and

strontium carbonate Strontium carbonate (SrCO3) is the carbonate salt of strontium that has the appearance of a white or grey powder. It occurs in nature as the mineral strontianite. Chemical properties Strontium carbonate is a white, odorless, tasteless powder ...

display magnetic properties. Lanthanum strontium manganite exhibits colossal magnetoresistance.

References

The Electroceramics and Crystal Physics Group at MIT
{{Authority control Materials science Ceramic materials Condensed matter physics