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A dissipative system is a thermodynamically open system which is operating out of, and often far from,
thermodynamic equilibrium Thermodynamic equilibrium is a notion of thermodynamics with axiomatic status referring to an internal state of a single thermodynamic system, or a relation between several thermodynamic systems connected by more or less permeable or impermeable ...
in an environment with which it exchanges
energy Energy () is the physical quantity, quantitative physical property, property that is transferred to a physical body, body or to a physical system, recognizable in the performance of Work (thermodynamics), work and in the form of heat and l ...
and
matter In classical physics and general chemistry, matter is any substance that has mass and takes up space by having volume. All everyday objects that can be touched are ultimately composed of atoms, which are made up of interacting subatomic pa ...
. A
tornado A tornado is a violently rotating column of air that is in contact with the surface of Earth and a cumulonimbus cloud or, in rare cases, the base of a cumulus cloud. It is often referred to as a twister, whirlwind or cyclone, although the ...
may be thought of as a dissipative system. Dissipative systems stand in contrast to
conservative system In mathematics, a conservative system is a dynamical system which stands in contrast to a dissipative system. Roughly speaking, such systems have no friction or other mechanism to dissipate the dynamics, and thus, their phase space does not shrink o ...
s. A dissipative structure is a dissipative system that has a dynamical regime that is in some sense in a reproducible
steady state In systems theory, a system or a process is in a steady state if the variables (called state variables) which define the behavior of the system or the process are unchanging in time. In continuous time, this means that for those properties ''p' ...
. This reproducible steady state may be reached by natural evolution of the system, by artifice, or by a combination of these two.


Overview

A
dissipative In thermodynamics, dissipation is the result of an irreversible process that affects a thermodynamic system. In a dissipative process, energy ( internal, bulk flow kinetic, or system potential) transforms from an initial form to a final form, wh ...
structure is characterized by the spontaneous appearance of symmetry breaking (
anisotropy Anisotropy () is the structural property of non-uniformity in different directions, as opposed to isotropy. An anisotropic object or pattern has properties that differ according to direction of measurement. For example, many materials exhibit ve ...
) and the formation of complex, sometimes chaotic, structures where interacting particles exhibit long range correlations. Examples in everyday life include
convection Convection is single or Multiphase flow, multiphase fluid flow that occurs Spontaneous process, spontaneously through the combined effects of material property heterogeneity and body forces on a fluid, most commonly density and gravity (see buoy ...
,
turbulent flow In fluid dynamics, turbulence or turbulent flow is fluid motion characterized by Chaos theory, chaotic changes in pressure and flow velocity. It is in contrast to laminar flow, which occurs when a fluid flows in parallel layers with no disrupt ...
,
cyclone In meteorology, a cyclone () is a large air mass that rotates around a strong center of low atmospheric pressure, counterclockwise in the Northern Hemisphere and clockwise in the Southern Hemisphere as viewed from above (opposite to an ant ...
s,
hurricane A tropical cyclone is a rapidly rotating storm system with a low-pressure area, a closed low-level atmospheric circulation, strong winds, and a spiral arrangement of thunderstorms that produce heavy rain and squalls. Depending on its ...
s and
living organisms An organism is any living thing that functions as an individual. Such a definition raises more problems than it solves, not least because the concept of an individual is also difficult. Many criteria, few of them widely accepted, have been pro ...
. Less common examples include
laser A laser is a device that emits light through a process of optical amplification based on the stimulated emission of electromagnetic radiation. The word ''laser'' originated as an acronym for light amplification by stimulated emission of radi ...
s, Bénard cells,
droplet cluster Droplet cluster is a self-assembled levitating monolayer of microdroplets usually arranged into a hexagonally ordered structure over a locally heated thin (about 1 mm) layer of water. The droplet cluster is typologically similar to coll ...
, and the
Belousov–Zhabotinsky reaction A Belousov–Zhabotinsky reaction, or BZ reaction, is one of a class of reactions that serve as a classical example of non-equilibrium thermodynamics, resulting in the establishment of a nonlinear chemical oscillator. The only common element in ...
. One way of mathematically modeling a dissipative system is given in the article on ''
wandering set In dynamical systems and ergodic theory, the concept of a wandering set formalizes a certain idea of movement and mixing. When a dynamical system has a wandering set of non-zero measure, then the system is a dissipative system. This is the opposi ...
s'': it involves the action of a
group A group is a number of persons or things that are located, gathered, or classed together. Groups of people * Cultural group, a group whose members share the same cultural identity * Ethnic group, a group whose members share the same ethnic iden ...
on a
measurable set In mathematics, the concept of a measure is a generalization and formalization of geometrical measures (length, area, volume) and other common notions, such as magnitude, mass, and probability of events. These seemingly distinct concepts hav ...
. Dissipative systems can also be used as a tool to study economic systems and
complex systems A complex system is a system composed of many components that may interact with one another. Examples of complex systems are Earth's global climate, organisms, the human brain, infrastructure such as power grid, transportation or communication s ...
. For example, a dissipative system involving
self-assembly Self-assembly is a process in which a disordered system of pre-existing components forms an organized structure or pattern as a consequence of specific, local interactions among the components themselves, without external direction. When the ...
of nanowires has been used as a model to understand the relationship between entropy generation and the robustness of biological systems. The
Hopf decomposition In mathematics, the Hopf decomposition, named after Eberhard Hopf, gives a canonical decomposition of a measure space (''X'', μ) with respect to an invertible non-singular transformation ''T'':''X''→''X'', i.e. a transformation which with its i ...
states that
dynamical system In mathematics, a dynamical system is a system in which a Function (mathematics), function describes the time dependence of a Point (geometry), point in an ambient space, such as in a parametric curve. Examples include the mathematical models ...
s can be decomposed into a conservative and a dissipative part; more precisely, it states that every
measure space A measure space is a basic object of measure theory, a branch of mathematics that studies generalized notions of volumes. It contains an underlying set, the subsets of this set that are feasible for measuring (the -algebra) and the method that ...
with a non-singular transformation can be decomposed into an invariant conservative set and an invariant dissipative set.


Dissipative structures in thermodynamics

Russian-Belgian physical chemist
Ilya Prigogine Viscount Ilya Romanovich Prigogine (; ; 28 May 2003) was a Belgian physical chemist of Russian-Jewish origin, noted for his work on dissipative structures, complex systems, and irreversibility. Prigogine's work most notably earned him the 19 ...
, who coined the term ''dissipative structure,'' received the
Nobel Prize in Chemistry The Nobel Prize in Chemistry () is awarded annually by the Royal Swedish Academy of Sciences to scientists in the various fields of chemistry. It is one of the five Nobel Prizes established by the will of Alfred Nobel in 1895, awarded for outst ...
in 1977 for his pioneering work on these structures, which have dynamical regimes that can be regarded as thermodynamic steady states, and sometimes at least can be described by suitable
extremal principles in non-equilibrium thermodynamics Energy dissipation and entropy production extremal principles are ideas developed within non-equilibrium thermodynamics that attempt to predict the likely steady states and dynamical structures that a physical system might show. The search for extr ...
. In his Nobel lecture, Prigogine explains how thermodynamic systems far from equilibrium can have drastically different behavior from systems close to equilibrium. Near equilibrium, the ''local equilibrium'' hypothesis applies and typical thermodynamic quantities such as free energy and entropy can be defined locally. One can assume linear relations between the (generalized) flux and forces of the system. Two celebrated results from linear thermodynamics are the
Onsager reciprocal relations In thermodynamics, the Onsager reciprocal relations express the equality of certain ratios between flows and forces in thermodynamic systems out of equilibrium, but where a notion of local equilibrium exists. "Reciprocal relations" occur betw ...
and the principle of minimum
entropy production Entropy production (or generation) is the amount of entropy which is produced during heat process to evaluate the efficiency of the process. Short history Entropy is produced in irreversible processes. The importance of avoiding irreversible p ...
. After efforts to extend such results to systems far from equilibrium, it was found that they do not hold in this regime and opposite results were obtained. One way to rigorously analyze such systems is by studying the stability of the system far from equilibrium. Close to equilibrium, one can show the existence of a
Lyapunov function In the theory of ordinary differential equations (ODEs), Lyapunov functions, named after Aleksandr Lyapunov, are scalar functions that may be used to prove the stability of an equilibrium of an ODE. Lyapunov functions (also called Lyapunov’s ...
which ensures that the entropy tends to a stable maximum. Fluctuations are damped in the neighborhood of the fixed point and a macroscopic description suffices. However, far from equilibrium stability is no longer a universal property and can be broken. In chemical systems, this occurs with the presence of
autocatalytic In chemistry, a chemical reaction is said to be autocatalytic if one of the reaction products is also a catalyst for the same reaction. Many forms of autocatalysis are recognized.Steinfeld J.I., Francisco J.S. and Hase W.L. ''Chemical Kinetics and ...
reactions, such as in the example of the Brusselator. If the system is driven beyond a certain threshold, oscillations are no longer damped out, but may be amplified. Mathematically, this corresponds to a
Hopf bifurcation In the mathematics of dynamical systems and differential equations, a Hopf bifurcation is said to occur when varying a parameter of the system causes the set of solutions (trajectories) to change from being attracted to (or repelled by) a fixed ...
where increasing one of the parameters beyond a certain value leads to
limit cycle In mathematics, in the study of dynamical systems with two-dimensional phase space, a limit cycle is a closed trajectory in phase space having the property that at least one other trajectory spirals into it either as time approaches infinity o ...
behavior. If spatial effects are taken into account through a reaction–diffusion equation, long-range correlations and spatially ordered patterns arise, such as in the case of the
Belousov–Zhabotinsky reaction A Belousov–Zhabotinsky reaction, or BZ reaction, is one of a class of reactions that serve as a classical example of non-equilibrium thermodynamics, resulting in the establishment of a nonlinear chemical oscillator. The only common element in ...
. Systems with such dynamic states of matter that arise as the result of irreversible processes are dissipative structures. Recent research has seen reconsideration of Prigogine's ideas of dissipative structures in relation to biological systems.


Dissipative systems in control theory

Willems Willems is a patronymic surname of Dutch language, Dutch origin, equivalent to Williams (surname), Williams. In 2008, it was the 6th most common surname in Belgium (18,604 peopleand in 2007 it was the 39th most common surname in the Netherlands (17, ...
first introduced the concept of dissipativity in systems theory to describe dynamical systems by input-output properties. Considering a dynamical system described by its state x(t) , its input u(t) and its output y(t), the input-output correlation is given a supply rate w(u(t),y(t)). A system is said to be dissipative with respect to a supply rate if there exists a continuously differentiable storage function V(x(t)) such that V(0)=0, V(x(t))\ge 0 and : \dot(x(t)) \le w(u(t),y(t)). As a special case of dissipativity, a system is said to be passive if the above dissipativity inequality holds with respect to the passivity supply rate w(u(t),y(t)) = u(t)^Ty(t) . The physical interpretation is that V(x) is the energy stored in the system, whereas w(u(t),y(t)) is the energy that is supplied to the system. This notion has a strong connection with
Lyapunov stability Various types of stability may be discussed for the solutions of differential equations or difference equations describing dynamical systems. The most important type is that concerning the stability of solutions near to a point of equilibrium. ...
, where the storage functions may play, under certain conditions of controllability and observability of the dynamical system, the role of Lyapunov functions. Roughly speaking, dissipativity theory is useful for the design of feedback control laws for linear and nonlinear systems. Dissipative systems theory has been discussed by V.M. Popov, J.C. Willems, D.J. Hill, and P. Moylan. In the case of linear invariant systems, this is known as positive real transfer functions, and a fundamental tool is the so-called Kalman–Yakubovich–Popov lemma which relates the state space and the frequency domain properties of positive real systems. Dissipative systems are still an active field of research in systems and control, due to their important applications.


Quantum dissipative systems

As
quantum mechanics Quantum mechanics is the fundamental physical Scientific theory, theory that describes the behavior of matter and of light; its unusual characteristics typically occur at and below the scale of atoms. Reprinted, Addison-Wesley, 1989, It is ...
, and any classical
dynamical system In mathematics, a dynamical system is a system in which a Function (mathematics), function describes the time dependence of a Point (geometry), point in an ambient space, such as in a parametric curve. Examples include the mathematical models ...
, relies heavily on
Hamiltonian mechanics In physics, Hamiltonian mechanics is a reformulation of Lagrangian mechanics that emerged in 1833. Introduced by Sir William Rowan Hamilton, Hamiltonian mechanics replaces (generalized) velocities \dot q^i used in Lagrangian mechanics with (gener ...
for which time is reversible, these approximations are not intrinsically able to describe dissipative systems. It has been proposed that in principle, one can couple weakly the system – say, an oscillator – to a bath, i.e., an assembly of many oscillators in thermal equilibrium with a broad band spectrum, and trace (average) over the bath. This yields a
master equation In physics, chemistry, and related fields, master equations are used to describe the time evolution of a system that can be modeled as being in a probabilistic combination of states at any given time, and the switching between states is determi ...
which is a special case of a more general setting called the
Lindblad equation In quantum mechanics, the Gorini–Kossakowski–Sudarshan–Lindblad (GKSL) equation (named after Vittorio Gorini, Andrzej Kossakowski, E. C. George Sudarshan, George Sudarshan and Göran Lindblad (physicist), Göran Lindblad), master equation in ...
that is the quantum equivalent of the classical Liouville equation. The well-known form of this equation and its quantum counterpart takes time as a reversible variable over which to integrate, but the very foundations of dissipative structures imposes an irreversible and constructive role for time. Recent research has seen the quantum extension of Jeremy England's theory of dissipative adaptation (which generalizes Prigogine's ideas of dissipative structures to far-from-equilibrium statistical mechanics, as stated above).


Applications on dissipative systems of dissipative structure concept

The framework of dissipative structures as a mechanism to understand the behavior of systems in constant interexchange of energy has been successfully applied on different science fields and applications, as in optics, population dynamics and growth and chemomechanical structures.


See also

* Autocatalytic reactions and order creation *
Autopoiesis The term autopoiesis (), one of several current theories of life, refers to a system capable of producing and maintaining itself by creating its own parts. The term was introduced in the 1972 publication '' Autopoiesis and Cognition: The Realizat ...
*
Autowave Autowaves are self-supporting non-linear waves in active media (i.e. those that provide distributed energy sources). The term is generally used in processes where the waves carry relatively low energy, which is necessary for synchronization or s ...
*
Conservation equation In physics, a conservation law states that a particular measurable property of an isolated physical system does not change as the system evolves over time. Exact conservation laws include conservation of mass-energy, conservation of linear moment ...
*
Complex system A complex system is a system composed of many components that may interact with one another. Examples of complex systems are Earth's global climate, organisms, the human brain, infrastructure such as power grid, transportation or communication sy ...
*
Dynamical system In mathematics, a dynamical system is a system in which a Function (mathematics), function describes the time dependence of a Point (geometry), point in an ambient space, such as in a parametric curve. Examples include the mathematical models ...
*
Extremal principles in non-equilibrium thermodynamics Energy dissipation and entropy production extremal principles are ideas developed within non-equilibrium thermodynamics that attempt to predict the likely steady states and dynamical structures that a physical system might show. The search for extr ...
*
Information metabolism Information metabolism, sometimes referred to as informational metabolism or energetic-informational metabolism, is a psychological theory of interaction between biological organisms and their environment, developed by Polish psychiatrist Antoni K ...
*
Loschmidt's paradox In physics, Loschmidt's paradox (named for Josef Loschmidt), also known as the reversibility paradox, irreversibility paradox, or ' (), is the objection that it should not be possible to deduce an irreversible process from time-symmetric dynamics ...
*
Non-equilibrium thermodynamics Non-equilibrium thermodynamics is a branch of thermodynamics that deals with physical systems that are not in thermodynamic equilibrium but can be described in terms of macroscopic quantities (non-equilibrium state variables) that represent an ex ...
* Relational order theories *
Self-organization Self-organization, also called spontaneous order in the social sciences, is a process where some form of overall order and disorder, order arises from local interactions between parts of an initially disordered system. The process can be spont ...
* Viable system theory * Vortex engine


Notes

{{Reflist


References

* B. Brogliato, R. Lozano, B. Maschke, O. Egeland, Dissipative Systems Analysis and Control. Theory and Applications. Springer Verlag, London, 2nd Ed., 2007.
Davies, Paul ''The Cosmic Blueprint''
Simon & Schuster, New York 1989 (abridged— 1500 words) (abstract— 170 words) — self-organized structures. * Philipson, Schuster, ''Modeling by Nonlinear Differential Equations: Dissipative and Conservative Processes'', World Scientific Publishing Company 2009. * Prigogine, Ilya
''Time, structure and fluctuations''
Nobel Lecture, 8 December 1977. * J.C. Willems. Dissipative dynamical systems, part I: General theory; part II: Linear systems with quadratic supply rates. Archive for Rationale mechanics Analysis, vol.45, pp. 321–393, 1972.


External links


The dissipative systems model
The Australian National University Thermodynamic systems Systems theory Non-equilibrium thermodynamics