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Master Equation
In physics, chemistry, and related fields, master equations are used to describe the time evolution of a system that can be modeled as being in a probabilistic combination of states at any given time, and the switching between states is determined by a transition rate matrix. The equations are a set of differential equations – over time – of the probabilities that the system occupies each of the different states. The name was proposed in 1940: Introduction A master equation is a phenomenological set of first-order differential equations describing the time evolution of (usually) the probability of a system to occupy each one of a discrete set of states with regard to a continuous time variable ''t''. The most familiar form of a master equation is a matrix form: \frac = \mathbf\vec, where \vec is a column vector, and \mathbf is the matrix of connections. The way connections among states are made determines the dimension of the problem; it is either *a d-dimension ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Physics
Physics is the scientific study of matter, its Elementary particle, fundamental constituents, its motion and behavior through space and time, and the related entities of energy and force. "Physical science is that department of knowledge which relates to the order of nature, or, in other words, to the regular succession of events." It is one of the most fundamental scientific disciplines. "Physics is one of the most fundamental of the sciences. Scientists of all disciplines use the ideas of physics, including chemists who study the structure of molecules, paleontologists who try to reconstruct how dinosaurs walked, and climatologists who study how human activities affect the atmosphere and oceans. Physics is also the foundation of all engineering and technology. No engineer could design a flat-screen TV, an interplanetary spacecraft, or even a better mousetrap without first understanding the basic laws of physics. (...) You will come to see physics as a towering achievement of ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Reaction Rate
The reaction rate or rate of reaction is the speed at which a chemical reaction takes place, defined as proportional to the increase in the concentration of a product per unit time and to the decrease in the concentration of a reactant per unit time. Reaction rates can vary dramatically. For example, the oxidative rusting of iron under Earth's atmosphere is a slow reaction that can take many years, but the combustion of cellulose in a fire is a reaction that takes place in fractions of a second. For most reactions, the rate decreases as the reaction proceeds. A reaction's rate can be determined by measuring the changes in concentration over time. Chemical kinetics is the part of physical chemistry that concerns how rates of chemical reactions are measured and predicted, and how reaction-rate data can be used to deduce probable reaction mechanisms. The concepts of chemical kinetics are applied in many disciplines, such as chemical engineering, enzymology and environmental e ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Lindblad Equation
In quantum mechanics, the Gorini–Kossakowski–Sudarshan–Lindblad (GKSL) equation (named after Vittorio Gorini, Andrzej Kossakowski, E. C. George Sudarshan, George Sudarshan and Göran Lindblad (physicist), Göran Lindblad), master equation in Lindblad form, quantum Liouvillian, or Lindbladian is one of the general forms of Markov process, Markovian Quantum master equation, master equations describing open quantum systems. It generalizes the Schrödinger equation to open quantum systems; that is, systems in contacts with their surroundings. The resulting dynamics are no longer unitary, but still satisfy the property of being completely positive trace-preserving, trace-preserving and completely positive for any initial condition. The Schrödinger equation or, actually, the von Neumann equation, is a special case of the GKSL equation, which has led to some speculation that quantum mechanics may be productively extended and expanded through further application and analysis of the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Mathematical Model
A mathematical model is an abstract and concrete, abstract description of a concrete system using mathematics, mathematical concepts and language of mathematics, language. The process of developing a mathematical model is termed ''mathematical modeling''. Mathematical models are used in applied mathematics and in the natural sciences (such as physics, biology, earth science, chemistry) and engineering disciplines (such as computer science, electrical engineering), as well as in non-physical systems such as the social sciences (such as economics, psychology, sociology, political science). It can also be taught as a subject in its own right. The use of mathematical models to solve problems in business or military operations is a large part of the field of operations research. Mathematical models are also used in music, linguistics, and philosophy (for example, intensively in analytic philosophy). A model may help to explain a system and to study the effects of different components, ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Quantum Mechanics
Quantum mechanics is the fundamental physical Scientific theory, theory that describes the behavior of matter and of light; its unusual characteristics typically occur at and below the scale of atoms. Reprinted, Addison-Wesley, 1989, It is the foundation of all quantum physics, which includes quantum chemistry, quantum field theory, quantum technology, and quantum information science. Quantum mechanics can describe many systems that classical physics cannot. Classical physics can describe many aspects of nature at an ordinary (macroscopic and Microscopic scale, (optical) microscopic) scale, but is not sufficient for describing them at very small submicroscopic (atomic and subatomic) scales. Classical mechanics can be derived from quantum mechanics as an approximation that is valid at ordinary scales. Quantum systems have Bound state, bound states that are Quantization (physics), quantized to Discrete mathematics, discrete values of energy, momentum, angular momentum, and ot ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Classical Mechanics
Classical mechanics is a Theoretical physics, physical theory describing the motion of objects such as projectiles, parts of Machine (mechanical), machinery, spacecraft, planets, stars, and galaxies. The development of classical mechanics involved Scientific Revolution, substantial change in the methods and philosophy of physics. The qualifier ''classical'' distinguishes this type of mechanics from physics developed after the History of physics#20th century: birth of modern physics, revolutions in physics of the early 20th century, all of which revealed limitations in classical mechanics. The earliest formulation of classical mechanics is often referred to as Newtonian mechanics. It consists of the physical concepts based on the 17th century foundational works of Sir Isaac Newton, and the mathematical methods invented by Newton, Gottfried Wilhelm Leibniz, Leonhard Euler and others to describe the motion of Physical body, bodies under the influence of forces. Later, methods bas ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Onsager Reciprocal Relations
In thermodynamics, the Onsager reciprocal relations express the equality of certain ratios between flows and forces in thermodynamic systems out of equilibrium, but where a notion of local equilibrium exists. "Reciprocal relations" occur between different pairs of forces and flows in a variety of physical systems. For example, consider fluid systems described in terms of temperature, matter density, and pressure. In this class of systems, it is known that temperature differences lead to heat flows from the warmer to the colder parts of the system; similarly, pressure differences will lead to matter flow from high-pressure to low-pressure regions. What is remarkable is the observation that, when both pressure and temperature vary, temperature differences at constant pressure can cause matter flow (as in convection) and pressure differences at constant temperature can cause heat flow. Perhaps surprisingly, the heat flow per unit of pressure difference and the density (matter) flo ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Microscopic Reversibility
The principle of microscopic reversibility in physics and chemistry is twofold: * First, it states that the microscopic detailed dynamics of particles and fields is time-reversible because the microscopic equations of motion are symmetric with respect to inversion in time (T-symmetry); * Second, it relates to the statistical description of the kinetics of macroscopic or mesoscopic systems as an ensemble of elementary processes: collisions, elementary transitions or reactions. For these processes, the consequence of the microscopic T-symmetry is: ''Corresponding to every individual process there is a reverse process, and in a state of equilibrium the average rate of every process is equal to the average rate of its reverse process.'' History of microscopic reversibility The idea of microscopic reversibility was born together with physical kinetics. In 1872, Ludwig Boltzmann represented kinetics of gases as statistical ensemble of elementary collisions.Boltzmann, L. (1964), Lectures on ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Time Reversibility
In mathematics and physics, time-reversibility is the property (mathematics), property of a process whose governing rules remain unchanged when the direction of its sequence of actions is reversed. A deterministic process is time-reversible if the time-reversed process satisfies the same dynamic equation (other), dynamic equations as the original process; in other words, the equations are invariant (mathematics), invariant or symmetrical under a change in the Sign (mathematics), sign of time. A stochastic process is reversible if the statistical properties of the process are the same as the statistical properties for time-reversed data from the same process. Mathematics In mathematics, a dynamical system is time-reversible if the forward evolution is one-to-one function, one-to-one, so that for every state there exists a transformation (an Involution (mathematics), involution) π which gives a one-to-one mapping between the time-reversed evolution of any one state and t ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Detailed Balance
The principle of detailed balance can be used in Kinetics (physics), kinetic systems which are decomposed into elementary processes (collisions, or steps, or elementary reactions). It states that at Thermodynamic equilibrium, equilibrium, each elementary process is in equilibrium with its reverse process. History The principle of detailed balance was explicitly introduced for collisions by Ludwig Boltzmann. In 1872, he proved his H-theorem using this principle.Boltzmann, L. (1964), Lectures on gas theory, Berkeley, CA, USA: U. of California Press. The arguments in favor of this property are founded upon microscopic reversibility.Richard C. Tolman, Tolman, R. C. (1938). ''The Principles of Statistical Mechanics''. Oxford University Press, London, UK. Five years before Boltzmann, James Clerk Maxwell used the principle of detailed balance for gas kinetics with the reference to the principle of sufficient reason. He compared the idea of detailed balance with other types of balancing ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chapman–Kolmogorov Equation
In mathematics, specifically in the theory of Markovian stochastic processes in probability theory, the Chapman–Kolmogorov equation (CKE) is an identity relating the joint probability distributions of different sets of coordinates on a stochastic process. The equation was derived independently by both the British mathematician Sydney Chapman and the Russian mathematician Andrey Kolmogorov. The CKE is prominently used in recent variational Bayesian methods. Mathematical description Suppose that is an indexed collection of random variables, that is, a stochastic process. Let :p_(f_1,\ldots,f_n) be the joint probability density function of the values of the random variables ''f''1 to ''fn''. Then, the Chapman–Kolmogorov equation is :p_(f_1,\ldots,f_)=\int_^p_(f_1,\ldots,f_n)\,df_n i.e. a straightforward marginalization over the nuisance variable. (Note that nothing yet has been assumed about the temporal (or any other) ordering of the random variables—the above equatio ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Continuous-time Markov Process
A continuous-time Markov chain (CTMC) is a continuous stochastic process in which, for each state, the process will change state according to an exponential random variable and then move to a different state as specified by the probabilities of a stochastic matrix. An equivalent formulation describes the process as changing state according to the least value of a set of exponential random variables, one for each possible state it can move to, with the parameters determined by the current state. An example of a CTMC with three states \ is as follows: the process makes a transition after the amount of time specified by the holding time—an exponential random variable E_i, where ''i'' is its current state. Each random variable is independent and such that E_0\sim \text(6), E_1\sim \text(12) and E_2\sim \text(18). When a transition is to be made, the process moves according to the jump chain, a discrete-time Markov chain with stochastic matrix: :\begin 0 & \frac & \frac \\ \frac & 0 ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
