Cosmetic Ingredients
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Cosmetics ingredients come from a variety of sources but, unlike the ingredients of food, are often not considered by most consumers.
Cosmetics Cosmetics are substances that are intended for application to the body for cleansing, beautifying, promoting attractiveness, or altering appearance. They are mixtures of chemical compounds derived from either Natural product, natural source ...
often use vibrant
color Color (or colour in English in the Commonwealth of Nations, Commonwealth English; American and British English spelling differences#-our, -or, see spelling differences) is the visual perception based on the electromagnetic spectrum. Though co ...
s that are derived from a wide variety of sources, ranging from crushed insects to rust.Schneider, Günther ''et al'' (2005). "Skin Cosmetics" in ''Ullmann's Encyclopedia of Industrial Chemistry'', Wiley-VCH, Weinheim. Cosmetics in a variety of forms date back to early civilizations, with the need to improve ones personal appearance being an important factor in attracting a mate. Over the years the ingredients have changed dramatically as we discovered how to manufacture our own scents and cosmetic formulas. The realization of the dangers of many common ingredients also greatly affected the growing industry.
Ancient Egypt Ancient Egypt () was a cradle of civilization concentrated along the lower reaches of the Nile River in Northeast Africa. It emerged from prehistoric Egypt around 3150BC (according to conventional Egyptian chronology), when Upper and Lower E ...
ian aristocracy made use of minerals to provide colour and definition to their facial features. During the era of the Greek Empire it was common to use face paints, while
cosmetics in ancient Rome Cosmetics, first used in ancient Rome for ritual purposes,An Ancient Roman Make-up Lesson
T ...
contained
starch Starch or amylum is a polymeric carbohydrate consisting of numerous glucose units joined by glycosidic bonds. This polysaccharide is produced by most green plants for energy storage. Worldwide, it is the most common carbohydrate in human diet ...
,
olive oil Olive oil is a vegetable oil obtained by pressing whole olives (the fruit of ''Olea europaea'', a traditional Tree fruit, tree crop of the Mediterranean Basin) and extracting the oil. It is commonly used in cooking for frying foods, as a cond ...
,
beeswax Bee hive wax complex Beeswax (also known as cera alba) is a natural wax produced by honey bees of the genus ''Apis''. The wax is formed into scales by eight wax-producing glands in the abdominal segments of worker bees, which discard it in o ...
,
saffron Saffron () is a spice derived from the flower of '' Crocus sativus'', commonly known as the "saffron crocus". The vivid crimson stigma and styles, called threads, are collected and dried for use mainly as a seasoning and colouring agent ...
,
rose water Rose water, or rosewater, is a flavoured water created by steeping rose petals in water. It is typically made as a by-product during the distillation of rose petals to create rose oil for perfumes. Rose water is widely utilized to flavour cu ...
, and
lead Lead () is a chemical element; it has Chemical symbol, symbol Pb (from Latin ) and atomic number 82. It is a Heavy metal (elements), heavy metal that is density, denser than most common materials. Lead is Mohs scale, soft and Ductility, malleabl ...
.


Common ingredients

Castor oil Castor oil is a vegetable oil pressed from castor beans, the seeds of the plant ''Ricinus communis''. The seeds are 40 to 60 percent oil. It is a colourless or pale yellow liquid with a distinct taste and odor. Its boiling point is and its den ...
and its derivatives are found in many cosmetics as it is "non-comedogenic" (does not exacerbate or contribute to acne).International Castor Oil Association.
ICOA Technical Bulletins - Effect on Skin
". Accessed 27 January 2007.
Cerebroside Cerebrosides (monoglycosylceramides) are a group of glycosphingolipids which are important components of animal muscle and nerve cell membranes. They consist of a ceramide with a single sugar residue at the 1-hydroxyl moiety. The sugar residue ...
s (cells from the nervous systems of cattle or swine) were once used in some high-end skin-care products to increase moisture retention and to create a smooth skin surface, Adams, Cecil. 31 March 2000.
Does lipstick contain fish scales?
. Accessed 24 January 2007.
however the BSE controversy has put an end to this practice. In many countries colors in cosmetics are listed as numbers from the
Colour Index International Colour Index International (CI) is a reference database jointly maintained bSDC Enterprisesand the American Association of Textile Chemists and Colorists. It currently contains over 27,000 individual products listed under 13,000 Colour Index Gen ...
. The scheme covers colors used in food, personal care products, cosmetics, household products and fabric dyeing. For example,
tartrazine Tartrazine is a synthetic lemon yellow azo dye primarily used as a food coloring. It is also known as E number E102, C.I. 19140, FD&C Yellow 5, Yellow 5 Lake, Acid Yellow 23, Food Yellow 4, and trisodium 1-(4-sulfonatophenyl)-4-(4-sulfonato ...
is not normally listed as such in lipstick ingredients, but as C.I. 19140. Erythrosine will be listed as C.I. 45430, and so on. In US and Canada colors are listed as FD & C colors. Tartrazine (E102) is FD & C Yellow 5 and erythrosine (E127) is FD & C Red 3.


Visual effects

Strong red colors for eye products have been produced using the
dye Juan de Guillebon, better known by his stage name DyE, is a French musician. He is known for the music video of the single "Fantasy Fantasy is a genre of speculative fiction that involves supernatural or Magic (supernatural), magical ele ...
carmine Carmine ()also called cochineal (when it is extracted from the Cochineal, cochineal insect), cochineal extract, crimson Lake pigment, lake, or carmine lake is a pigment of a bright-red color obtained from the aluminium coordination complex, compl ...
, made from
carminic acid Carminic acid (C22H20O13) is a red glucosidal hydroxyanthrapurin that occurs naturally in some scale insects, such as the cochineal, Armenian cochineal, and Polish cochineal. The insects produce the acid as a deterrent to predators. An aluminum ...
extracted from the crushed bodies of the
cochineal The cochineal ( , ; ''Dactylopius coccus'') is a scale insect in the suborder Sternorrhyncha, from which the natural dye carmine is derived. A primarily sessility (motility), sessile parasitism, parasite native to tropical and subtropical Sout ...
insect. Carmine was once the only bright red color permitted by the FDA for use around the eye. Pearlescence, also sometimes spelled as "pearl essence", is a shine or gloss effect commonly used in a wide variety of cosmetic products. The most usual source of pearlescence is the natural
mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid substance with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. (2011): Mi ...
mica Micas ( ) are a group of silicate minerals whose outstanding physical characteristic is that individual mica crystals can easily be split into fragile elastic plates. This characteristic is described as ''perfect basal cleavage''. Mica is co ...
covered by a thin layer of
titanium dioxide Titanium dioxide, also known as titanium(IV) oxide or titania , is the inorganic compound derived from titanium with the chemical formula . When used as a pigment, it is called titanium white, Pigment White 6 (PW6), or Colour Index Internationa ...
. This coating causes
goniochromism Iridescence (also known as goniochromism) is the phenomenon of certain surfaces that appear gradually to change colour as the angle of view or the angle of illumination changes. Iridescence is caused by wave interference of light in microstruc ...
– the color appears through interference effects with the naturally translucent mica, and varying the thickness of the titanium dioxide changes the color.Weingrod, Carmi. 2005.
Three-Dimensional Color – Unlocking the Secrets of Interference Pigments
". Accessed 24 January 2007.
Alternatives exist, including the suspension of tiny flakes of a suitable material within the product, often a
wax Waxes are a diverse class of organic compounds that are lipophilic, malleable solids near ambient temperatures. They include higher alkanes and lipids, typically with melting points above about 40 °C (104 °F), melting to give lo ...
such as
glycol distearate Glycol distearate is the diester of stearic acid and ethylene glycol. It is mostly commonly encountered in personal care products and cosmetics where it is used to produce pearlescent effects as well as a moisturizer. Synthesis Glycol distearat ...
. A shimmery substance found on
fish scales A fish scale is a small rigid plate that grows out of the skin of a fish. The skin of most jawed fishes is covered with these protective scale (zoology), scales, which can also provide effective Underwater camouflage, camouflage through the us ...
, most usually obtained from
herring Herring are various species of forage fish, belonging to the Order (biology), order Clupeiformes. Herring often move in large Shoaling and schooling, schools around fishing banks and near the coast, found particularly in shallow, temperate wate ...
and one of many by-products of commercial
fish processing The term fish processing refers to the processes associated with fish and fish products between the time fish are caught or harvested, and the time the final product is delivered to the customer. Although the term refers specifically to fish, in ...
, can also be used for pearlescent effects, primarily in nail polish, but is now rarely used due to its high cost,
bismuth oxychloride Bismuth oxychloride is an inorganic compound of bismuth with the formula Bi O Cl. It is a lustrous white solid used since antiquity, notably in ancient Egypt. Light wave interference from its plate-like structure gives a pearly iridescent light r ...
flakes being used as a substitute instead.


Types of cosmetics


Facial cosmetics

The Romans and ancient
Egyptians Egyptians (, ; , ; ) are an ethnic group native to the Nile, Nile Valley in Egypt. Egyptian identity is closely tied to Geography of Egypt, geography. The population is concentrated in the Nile Valley, a small strip of cultivable land stretchi ...
used cosmetics containing mercury.


Foundation

Women of Roman Britain used a foundation made from animal fat, starch and tin oxide.
BBC News BBC News is an operational business division of the British Broadcasting Corporation (BBC) responsible for the gathering and broadcasting of news and current affairs in the UK and around the world. The department is the world's largest broad ...
. 3 November 2004.
Roman cosmetic secrets revealed
. Accessed 27 January 2007.
Today foundations come in a wide variety of formulas and finishes, most being either water, silicone, or mineral based. Foundations on today's market come in cream, liquid, pressed powder, loose powder, or mineral form. They also come in different finishes such as matte or satin depending upon the desired look.


Lipstick

Lipstick is known to have been used around 5000 years ago in ancient
Babylon Babylon ( ) was an ancient city located on the lower Euphrates river in southern Mesopotamia, within modern-day Hillah, Iraq, about south of modern-day Baghdad. Babylon functioned as the main cultural and political centre of the Akkadian-s ...
, when semi-precious jewels were crushed and applied to the lips and occasionally around the eyes.
Ancient Egypt Ancient Egypt () was a cradle of civilization concentrated along the lower reaches of the Nile River in Northeast Africa. It emerged from prehistoric Egypt around 3150BC (according to conventional Egyptian chronology), when Upper and Lower E ...
ians extracted purplish-red dye from fucus-algin, 0.01%
iodine Iodine is a chemical element; it has symbol I and atomic number 53. The heaviest of the stable halogens, it exists at standard conditions as a semi-lustrous, non-metallic solid that melts to form a deep violet liquid at , and boils to a vi ...
, and some
bromine Bromine is a chemical element; it has chemical symbol, symbol Br and atomic number 35. It is a volatile red-brown liquid at room temperature that evaporates readily to form a similarly coloured vapour. Its properties are intermediate between th ...
mannite, which resulted in serious illness.
Cleopatra Cleopatra VII Thea Philopator (; The name Cleopatra is pronounced , or sometimes in both British and American English, see and respectively. Her name was pronounced in the Greek dialect of Egypt (see Koine Greek phonology). She was ...
had her lipstick made from crushed
carmine Carmine ()also called cochineal (when it is extracted from the Cochineal, cochineal insect), cochineal extract, crimson Lake pigment, lake, or carmine lake is a pigment of a bright-red color obtained from the aluminium coordination complex, compl ...
beetles Beetles are insects that form the Taxonomic rank, order Coleoptera (), in the superorder Holometabola. Their front pair of wings are hardened into wing-cases, elytra, distinguishing them from most other insects. The Coleoptera, with about 40 ...
, which gave a deep red pigment, and ants for a base. The red color of modern lipstick can come from synthetically derived pure
iron oxide An iron oxide is a chemical compound composed of iron and oxygen. Several iron oxides are recognized. Often they are non-stoichiometric. Ferric oxyhydroxides are a related class of compounds, perhaps the best known of which is rust. Iron ...
(common iron rust), however most leading brands use the more economical synthetic colors. In the United States, every batch of synthetic dye and pigment must have a sample sent to the US FDA for testing and certification that the batch is pure and its contaminants are below the levels specified by law. Synthetic colors are listed in the ingredients as a code (e.g.: F &D red no 6) and may contain up to 10 parts per million of lead / 3 parts per million of arsenic. There is some controversy over the presence of these trace ingredients, especially since makeup worn on the lips is not just absorbed through the skin, but also swallowed with drinking and eating. Since lowering these levels would make the production and sale of practically all lipstick illegal, and since the FDA has determined that the existing levels are safe, the cosmetic industry continues to produce and sell lipstick. Typically, the pigment is crushed very finely (7 to 10
micrometres The micrometre (English in the Commonwealth of Nations, Commonwealth English as used by the International Bureau of Weights and Measures; SI symbol: μm) or micrometer (American English), also commonly known by the non-SI term micron, is a uni ...
) while being mixed with
castor oil Castor oil is a vegetable oil pressed from castor beans, the seeds of the plant ''Ricinus communis''. The seeds are 40 to 60 percent oil. It is a colourless or pale yellow liquid with a distinct taste and odor. Its boiling point is and its den ...
and is then mixed with a wax base to form a finished lipstick. Lipsticks may be sheer or dense, matte or shiny. In their thinnest and most fluid consistency they are given their own category, lipgloss.


Perfume

Islamic cultures contributed significantly in the development of western
perfume Perfume (, ) is a mixture of fragrance, fragrant essential oils or aroma compounds (fragrances), Fixative (perfumery), fixatives and solvents, usually in liquid form, used to give the human body, animals, food, objects, and living-spaces an agre ...
ry in both perfecting the extraction of fragrances through steam distillation and introducing new, raw ingredients. Both of the raw ingredients and distillation technology significantly influenced western perfumery and
scientific Science is a systematic discipline that builds and organises knowledge in the form of testable hypotheses and predictions about the universe. Modern science is typically divided into twoor threemajor branches: the natural sciences, which stu ...
developments, particularly
chemistry Chemistry is the scientific study of the properties and behavior of matter. It is a physical science within the natural sciences that studies the chemical elements that make up matter and chemical compound, compounds made of atoms, molecules a ...
. As traders, Islamic cultures such as the Arabs and Persians had wider access to different spices, herbals, and other fragrance material. In addition to trading them, many of these exotic materials were cultivated by the Muslims such that they can be successfully grown outside of their native climates. Two examples of this include jasmine, which is native to South and Southeast Asia, and various citrus, which are native to East Asia. Both of these ingredients are still highly important in modern perfumery. The
Crusaders The Crusades were a series of religious wars initiated, supported, and at times directed by the Papacy during the Middle Ages. The most prominent of these were the campaigns to the Holy Land aimed at reclaiming Jerusalem and its surrounding ...
brought
alcohol Alcohol may refer to: Common uses * Alcohol (chemistry), a class of compounds * Ethanol, one of several alcohols, commonly known as alcohol in everyday life ** Alcohol (drug), intoxicant found in alcoholic beverages ** Alcoholic beverage, an alco ...
-based perfumes back to
Europe Europe is a continent located entirely in the Northern Hemisphere and mostly in the Eastern Hemisphere. It is bordered by the Arctic Ocean to the north, the Atlantic Ocean to the west, the Mediterranean Sea to the south, and Asia to the east ...
from the Middle East in the 13th Century.Ad*Access. 1999.
Brief History of Beauty and Hygiene Products
". Accessed 27 January 2007.
The first modern perfume, made of scented oils blended in an alcohol solution, was made in 1370 at the command of Queen Elizabeth of Hungary and was known throughout Europe as Hungary Water.
France France, officially the French Republic, is a country located primarily in Western Europe. Overseas France, Its overseas regions and territories include French Guiana in South America, Saint Pierre and Miquelon in the Atlantic Ocean#North Atlan ...
quickly became the European center of perfume and cosmetic manufacture, cultivating vast amounts of flowers for their essence.


Deodorants and antiperspirants

Perfume has been used to mask body odor for many hundreds of years, but in the late 19th century the ability to reduce such odour was developed. The original active ingredient of antiperspirants was
aluminium chloride Aluminium chloride, also known as aluminium trichloride, is an inorganic compound with the formula . It forms a hexahydrate with the formula , containing six water molecules of hydration. Both the anhydrous form and the hexahydrate are col ...
but complaints of skin irritation led to the increased use of aluminium chlorohydrate as an alternative. Aluminium has been established as a
neurotoxin Neurotoxins are toxins that are destructive to nervous tissue, nerve tissue (causing neurotoxicity). Neurotoxins are an extensive class of exogenous chemical neurological insult (medical), insultsSpencer 2000 that can adversely affect function ...
and has been shown to adversely affect the
blood–brain barrier The blood–brain barrier (BBB) is a highly selective semipermeable membrane, semipermeable border of endothelium, endothelial cells that regulates the transfer of solutes and chemicals between the circulatory system and the central nervous system ...
, cause
DNA Deoxyribonucleic acid (; DNA) is a polymer composed of two polynucleotide chains that coil around each other to form a double helix. The polymer carries genetic instructions for the development, functioning, growth and reproduction of al ...
damage, and have adverse
epigenetic In biology, epigenetics is the study of changes in gene expression that happen without changes to the DNA sequence. The Greek prefix ''epi-'' (ἐπι- "over, outside of, around") in ''epigenetics'' implies features that are "on top of" or "in ...
effects. Research has shown that the aluminum salts used in antiperspirants have detrimental effects to a number of species such as non-human
primates Primates is an order of mammals, which is further divided into the strepsirrhines, which include lemurs, galagos, and lorisids; and the haplorhines, which include tarsiers and simians ( monkeys and apes). Primates arose 74–63  ...
,
mice A mouse (: mice) is a small rodent. Characteristically, mice are known to have a pointed snout, small rounded ears, a body-length scaly tail, and a high breeding rate. The best known mouse species is the common house mouse (''Mus musculus' ...
,
dog The dog (''Canis familiaris'' or ''Canis lupus familiaris'') is a domesticated descendant of the gray wolf. Also called the domestic dog, it was selectively bred from a population of wolves during the Late Pleistocene by hunter-gatherers. ...
s and others. An experiment with mice found that applying an aqueous solution of aluminum chloride to the skin resulted in "a significant increase in urine, serum, and whole brain aluminium." Other experiments on pregnant mice showed transplacental passage of aluminum chloride.


Regulation

Legislation varies from country to country but most countries have some sort of formal legislation that either restrict or prohibit certain ingredients or products. There are two main sources for cosmetics safety: the EU Cosmetics Regulation 1223/2009 and the Canadian Cosmetic Ingredient Hotlist. Regulation in the United States by the FDA is particularly weak. A new version of the EU's Cosmetics Directive was adopted by the
European Parliament The European Parliament (EP) is one of the two legislative bodies of the European Union and one of its seven institutions. Together with the Council of the European Union (known as the Council and informally as the Council of Ministers), it ...
, 24 March 2009. It includes new rules concerning the use of
nanoparticle A nanoparticle or ultrafine particle is a particle of matter 1 to 100 nanometres (nm) in diameter. The term is sometimes used for larger particles, up to 500 nm, or fibers and tubes that are less than 100 nm in only two directions. At ...
s in cosmetics and includes stricter rules on animal testing of cosmetics. In the European Union, all cosmetic products must be notified through the Cosmetic Products Notification Portal (CPNP) before being placed on the EU market. The presence of a nanomaterial in a cosmetic product must be explicitly stated in the notification to the European Commission. A list of nanomaterial cosmetics ingredients was published by the European Commission, and the European Union Observatory for
Nanomaterials Nanomaterials describe, in principle, chemical substances or materials of which a single unit is sized (in at least one dimension) between 1 and 100 nm (the usual definition of nanoscale). Nanomaterials research takes a materials science ...
(EUON) provides further information on these ingredients, including information derived from the application of the REACH regulation on chemicals. Cosmetic colorants, with the exception of hair colorants in the United States, are highly regulated. Each country or group of countries has their own regulatory agency that controls what can go into cosmetics. In the United States, the regulating body is the
Food and Drug Administration The United States Food and Drug Administration (FDA or US FDA) is a List of United States federal agencies, federal agency of the United States Department of Health and Human Services, Department of Health and Human Services. The FDA is respo ...
. Aside from color additives, cosmetic products and their ingredients are not subject to FDA regulation prior to their release into the market. It is only when a product is found to violate Federal Food, Drug, and Cosmetic Act (FD&C Act) and Fair Packaging and Labeling Act (FPLA) after its release that the FDA may start taking action against this violation. The FDA may request a recall if the company refuses to remove an unsafe product from the market, work with the Department of Justice to remove contaminated or misbranded products, request a restraining order to prevent further shipments of contaminated or misbranded products, and take action against the company violating the law. A company may use any ingredient, other than color additives and those ingredients banned from use in cosmetics through regulation, as long the completed product and its ingredients is safe, is properly labeled, and isn't contaminated or misbranded under the FD&C Act and the FPLA. FDA can and does perform inspections.


Potential dangers

The search for new ingredients and products often brings controversy, typically over ingredients whose function is unproven or disputed. There are a few potential dangers regarding the use of cosmetics. One such danger is the use of old mascara. Some mascaras contain an ingredient that breaks down to produce
formaldehyde Formaldehyde ( , ) (systematic name methanal) is an organic compound with the chemical formula and structure , more precisely . The compound is a pungent, colourless gas that polymerises spontaneously into paraformaldehyde. It is stored as ...
. The formaldehyde prevents the growth of bacteria. Aged mascara, however, may no longer be producing formaldehyde, allowing bacteria to proliferate. For this reason, it is often recommended to replace a tube of mascara every few months. In one well-known case,
Buddy Ebsen Buddy Ebsen (born Christian Ludolf Ebsen Jr.; April 2, 1908 – July 6, 2003), also known as Frank "Buddy" Ebsen, was an American actor and dancer. One of his most famous roles was as Jed Clampett in the CBS television sitcom ''The Beverly Hillb ...
was originally cast as the "Tin Man" in ''
The Wizard of Oz ''The Wizard of Oz'' is a 1939 American Musical film, musical fantasy film produced by Metro-Goldwyn-Mayer (MGM). Based on the 1900 novel ''The Wonderful Wizard of Oz'' by L. Frank Baum, it was primarily directed by Victor Fleming, who left pro ...
''. Aluminum dust was used to create a tin effect. As the result of an allergic reaction, he was hospitalized and
Jack Haley John Joseph Haley Jr. (August 10, 1898 – June 6, 1979) was an American actor, comedian, dancer, radio host, singer, drummer and vaudevillian. He was best known for his portrayal of the Tin Man and his farmhand counterpart Hickory in the 193 ...
replaced him. Aluminum dust was, instead, added to a paste.


See also

* List of cosmetic ingredients *
List of vegetable oils Vegetable oils are triglycerides extracted from plants. Some of these oils have been part of human culture for millennia. Edible vegetable oils are used in food, both in Cooking oil, cooking and as Food additive, supplements. Many oils, edible a ...
*
Palm oil Palm oil is an edible vegetable oil derived from the mesocarp (reddish pulp) of the fruit of oil palms. The oil is used in food manufacturing, in beauty products, and as biofuel. Palm oil accounted for about 36% of global oils produced from o ...
*
International Nomenclature of Cosmetic Ingredients The International Nomenclature of Cosmetic Ingredients (INCI) are the unique identifiers for cosmetic ingredients such as waxes, oils, pigments, and other chemicals that are assigned in accordance with rules established by the Personal Care P ...
(INCI) *
Testing cosmetics on animals Cosmetic testing on animals is a type of animal testing used to test the safety and hypoallergenic properties of cosmetics, cosmetic products for use by humans. Since this type of animal testing is often harmful to the animal subjects, it is o ...


References


External links


Cosmetic Safety Databasebeauty skin care products
{{DEFAULTSORT:Ingredients Of Cosmetics History of cosmetics