Clinozoisite is a complex

calcium Calcium is a chemical element with the symbol Ca and atomic number 20. As an alkaline earth metal, calcium is a reactive metal that forms a dark oxide-nitride layer when exposed to air. Its physical and chemical properties are most similar t ...

aluminium Aluminium (aluminum in AmE, American and CanE, Canadian English) is a chemical element with the Symbol (chemistry), symbol Al and atomic number 13. Aluminium has a density lower than those of other common metals, at approximately o ...

sorosilicate Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of minerals and make up approximately 90 percent of Earth's crust. In mineralogy, silica (silicon dioxide, ) is usually consid ...

mineral with formula: Ca₂Al₃(Si₂O₇)(SiO₄)O(OH). It forms a continuous

solid solution A solid solution, a term popularly used for metals, is a homogenous mixture of two different kinds of atoms in solid state and have a single crystal structure. Many examples can be found in metallurgy, geology, and solid-state chemistry. The wor ...

series with

epidote Epidote is a calcium aluminium iron sorosilicate mineral. Description Well developed crystals of epidote, Ca2Al2(Fe3+;Al)(SiO4)(Si2O7)O(OH), crystallizing in the monoclinic system, are of frequent occurrence: they are commonly prismatic in hab ...

by substitution of iron(III) in the aluminium (m3 site) and is also called ''aluminium epidote''. Clinothulite is a

manganese Manganese is a chemical element with the symbol Mn and atomic number 25. It is a hard, brittle, silvery metal, often found in minerals in combination with iron. Manganese is a transition metal with a multifaceted array of industrial alloy u ...

bearing variety with a pinkish hue due to substitution of Mn(III) in the aluminium site. It was originally discovered in 1896 in

East Tyrol East Tyrol, occasionally East Tirol (german: Osttirol), is an exclave of the Austrian state of Tyrol, separated from the main North Tyrol part by the short common border of Salzburg and Italian South Tyrol (''Südtirol'', it, Alto Adige). It ...

Austria Austria, , bar, Östareich officially the Republic of Austria, is a country in the southern part of Central Europe, lying in the Eastern Alps. It is a federation of nine states, one of which is the capital, Vienna, the most populous ...

, and is so-named because of its resemblance to

zoisite Zoisite, first known as saualpite, after its type locality, is a calcium aluminium hydroxy sorosilicate belonging to the epidote group of minerals. Its chemical formula is Ca2 Al3( Si O4)(Si2O7)O(O H). Zoisite occurs as prismatic, orthorhom ...

and its mono''clinic'' crystal structure. It occurs in rocks which have undergone low to medium grade

regional metamorphism Metamorphism is the transformation of existing rock (the protolith) to rock with a different mineral composition or texture. Metamorphism takes place at temperatures in excess of , and often also at elevated pressure or in the presence of ch ...

and in

contact metamorphism Metamorphism is the transformation of existing rock (the protolith) to rock with a different mineral composition or texture. Metamorphism takes place at temperatures in excess of , and often also at elevated pressure or in the presence of chem ...

of high calcium sedimentary rocks. It also occurs in

saussurite Saussurite is a mineral aggregate which is formed as a hydrothermal alteration product of plagioclase feldspar.. It appears very similar to zoisite with a green or grayish-green color, it has been used as a substitute or simulant for jade. Saussur ...

alteration of

plagioclase Plagioclase is a series of tectosilicate (framework silicate) minerals within the feldspar group. Rather than referring to a particular mineral with a specific chemical composition, plagioclase is a continuous solid solution series, more pro ...

. Jadeite bearing

pyroxene The pyroxenes (commonly abbreviated to ''Px'') are a group of important rock-forming inosilicate minerals found in many igneous and metamorphic rocks. Pyroxenes have the general formula , where X represents calcium (Ca), sodium (Na), iron (Fe II) ...

minerals have suggested Clinozoisite and paragonite are associated and derived from

lawsonite Lawsonite is a hydrous calcium aluminium sorosilicate mineral with formula CaAl2Si2O7(OH)2·H2O. Lawsonite crystallizes in the orthorhombic system in prismatic, often tabular crystals. Crystal twinning is common. It forms transparent to transluc ...

releasing

Quartz Quartz is a hard, crystalline mineral composed of silica ( silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical ...

and water via the following reaction: 4CaAl2Si2O8(H2O)2 + NaAlSi2O6 <=> 2Ca2Al3Si3O12(OH) + NaAl3Si3O10(OH)2 + SiO2 + 6H2O

References

*Nesse, William D., "Introduction to Mineralogy," (c)2000 Oxford University Press Sorosilicates Epidote group Calcium minerals Aluminium minerals Monoclinic minerals Minerals in space group 11 {{silicate-mineral-stub