Cibachrome
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Ilfochrome (also commonly known as Cibachrome) is a
dye destruction Dye destruction or dye bleach is a photographic printing process, in which dyes embedded in the paper are bleached (destroyed) in processing. Because the dyes are fully formed in the paper prior to processing, they may be formulated with few constr ...
positive-to-positive photographic process used for the reproduction of film transparencies on
photographic paper Photographic paper is a coated paper, paper coated with a light-sensitive chemical, used for making photographic prints. When photographic paper is exposed to light, it captures a latent image that is then Photographic developer, developed to form ...
. The prints are made on a dimensionally stable
polyester Polyester is a category of polymers that contain one or two ester linkages in every repeat unit of their main chain. As a specific material, it most commonly refers to a type called polyethylene terephthalate (PET). Polyesters include some natura ...
base as opposed to traditional paper base. Since it uses 13 layers of
azo dye Azo dyes are organic compounds bearing the functional group R−N=N−R′, in which R and R′ are usually aryl and substituted aryl groups. They are a commercially important family of azo compounds, i.e. compounds containing the C−N=N−C l ...
s sealed in a polyester base, the print will not fade, discolour, or deteriorate for an extended time. Accelerated aging tests conducted by Henry Wilhelm rated the process as producing prints which, framed under glass, would last for 29 years before color shifts could be detected. Characteristics of Ilfochrome prints are image clarity, color purity, and being an archival process able to produce critical accuracy to the original transparency.


History

Dr. Bela Gaspar created
Gasparcolor Gasparcolor was a color motion picture film system, developed in Berlin in 1933 by the Hungarian chemist Béla Gáspár, ( Oraviczabánya, Transylvania, Kingdom of Hungary 1898–1973). It used a subtractive 3-color process on a single film st ...
, the dye bleach process upon which the Cibachrome process was originally based. It was considered vital to the war effort in the 1940s. Gaspar turned down many offers to sell the rights to his process and after he died, Paul Dreyfus, who was the chemist and technician for Gaspar, went to work for CIBA AG. When the patents ran out, he developed the process for Cibachrome. (Frozen Moments - Richard C. Miller) In the 1960s, the Cibachrome process was originally engineered by the
Ciba Geigy Novartis AG is a Swiss multinational pharmaceutical corporation based in Basel, Switzerland. Novartis is one of the largest pharmaceutical companies in the world and was the eighth largest by revenue in 2024. Novartis manufactures the drugs c ...
Corporation of
Switzerland Switzerland, officially the Swiss Confederation, is a landlocked country located in west-central Europe. It is bordered by Italy to the south, France to the west, Germany to the north, and Austria and Liechtenstein to the east. Switzerland ...
. Ciba acquired Ilford in 1969, and sold it to
International Paper The International Paper Company is an American pulp and paper company, the largest such company in the world. It has approximately 39,000 employees, and is headquartered in Memphis, Tennessee. History The company was incorporated January 31 ...
in 1989; in 1992 the product was renamed to "Ilfochrome". Colloquially, however the process is still referred to as "Cibachrome". Before 2004 Ilford Ltd had two main manufacturing sites: Mobberley in the UK, where most traditional products were made, and
Fribourg or is the capital of the Cantons of Switzerland, Swiss canton of Canton of Fribourg, Fribourg and district of Sarine (district), La Sarine. Located on both sides of the river Saane/Sarine, on the Swiss Plateau, it is a major economic, adminis ...
(Freiburg) in Switzerland, where Ilfochrome and Ilfocolor papers were made, as well as the inkjet papers. The UK side was subject to a management buyout, and the Swiss operation (
Ilford Imaging Switzerland GmbH Ilford is a large town in East London, England, northeast of Charing Cross. Part of the London Borough of Redbridge, Ilford is within the ceremonial county of Greater London. It had a population of 168,168 in 2011, compared to 303,858 for the ...
) was sold to the Japanese Oji paper group in 2005 and to Paradigm Global Partners LLP in 2010. The Swiss plant retained the Ilford name, while the UK operation was inaugurated under the name HARMAN, taken from the name of the founder of the original Britannia Works. Ilford Photo HARMAN Technology Ltd can still use the Ilford brandname and logo under license on previously existing products, while new products will carry the Harman name. In 2012, Ilford announced its final production run of Ilfochrome Classic in response to declining market demand attributed to the expanding popularity of digital image making.


Advantages

The composition of the
emulsion An emulsion is a mixture of two or more liquids that are normally Miscibility, immiscible (unmixable or unblendable) owing to liquid-liquid phase separation. Emulsions are part of a more general class of two-phase systems of matter called colloi ...
used in Ilfochrome prints is responsible for color purity, image clarity, and archival permanence.
Azo dye Azo dyes are organic compounds bearing the functional group R−N=N−R′, in which R and R′ are usually aryl and substituted aryl groups. They are a commercially important family of azo compounds, i.e. compounds containing the C−N=N−C l ...
s, which provide stable vivid colors, are embedded in the Ilfochrome emulsion and bleached out in processing. Since the dyes are in the emulsion rather than formed from couplers in the chemistry, the image is also much sharper and clearer because the dyes create an anti-light-scattering layer which keeps the image from being diffused when viewed. As the azo dyes are far more stable than
chromogenic In chemistry, the term chromogen refers to a colourless (or faintly coloured) chemical compound that can be converted by chemical reaction into a compound which can be described as "coloured" (a chromophore). There is no universally agreed definiti ...
dyes, prints made by this process are of archival quality and galleries and art collectors report they do not fade in normal light.


Use directly in camera

An alternative use of Ilfochrome was for image capture directly inside a
large format Large format photography refers to any imaging format of or larger. Large format is larger than "medium format", the or size of Hasselblad, Mamiya, Rollei, Kowa, and Pentax cameras (using 120 film, 120- and 220-roll film), and much la ...
or ultra large format camera. This created a unique original positive photograph, in which the subject is reversed left-right unless a mirror or prism was used in front of the camera lens. A much longer exposure was required than with sheet films or
plates Plate may refer to: Cooking * Plate (dishware), broad, mainly flat vessel commonly used to serve food * Plates, tableware, dishes or dishware used for setting a table, serving food and dining * Plate, the content of such a plate (for example: ...
designed for use in a camera. The procedure thus resembled the slow
daguerreotype Daguerreotype was the first publicly available photography, photographic process, widely used during the 1840s and 1850s. "Daguerreotype" also refers to an image created through this process. Invented by Louis Daguerre and introduced worldwid ...
and
ambrotype The ambrotype, also known as a collodion positive in the UK, is a positive photograph on glass made by a variant of the wet plate collodion process. As a cheaper alternative to the French daguerreotype, ambrotypes came to replace them. Like a ...
direct positive black-and-white processes used in the 1850s.


Sources

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References


External links

{{Commons category, Ilfochrome
Ilford Official Website


Photographic film processes International Paper