Chloryl Tetraperchloratoaurate
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Chloryl tetraperchloratoaurate is an inorganic chemical compound with the formula consisting of the
chloryl In chemistry, chloryl refers to a triatomic cation with chemical formula . This species has the same general structure as chlorite () but it is electronically different, with chlorine having a +5 oxidation state (rather than the +3 of chlorite). ...
cation and a tetraperchloratoaurate(III) anion. It is an orange solid that readily hydrolyzes in air.


Production and reactions

Chloryl tetraperchloratoaurate is produced by the oxidation of
gold Gold is a chemical element; it has chemical symbol Au (from Latin ) and atomic number 79. In its pure form, it is a brightness, bright, slightly orange-yellow, dense, soft, malleable, and ductile metal. Chemically, gold is a transition metal ...
metal,
gold(III) chloride Gold(III) chloride, traditionally called auric chloride, is an inorganic compound of gold and chlorine with the molecular formula . The "III" in the name indicates that the gold has an oxidation state of +3, typical for many gold compounds. It ...
, or
chloroauric acid Chloroauric acid is an inorganic compound with the chemical formula . It forms hydrates . Both the trihydrate and tetrahydrate are known. Both are orange-yellow solids consisting of the planar anion. Often chloroauric acid is handled as a solutio ...
by
dichlorine hexoxide Dichlorine hexoxide is the chemical compound with the molecular formula or , which is correct for its gaseous state. However, in liquid or solid form, this chlorine oxide ionizes into the dark red ionic compound chloryl perchlorate or dioxochlor ...
: : A production of gold(III) perchlorate is attempted by heating this compound, but it instead forms an oxy-perchlorato derivative.


References

{{perchlorates Gold(III) compounds Perchlorates chloryl compounds