Chlorophyllide A Reductase
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Chlorophyllide ''a'' reductase (), also known as COR, is an
enzyme An enzyme () is a protein that acts as a biological catalyst by accelerating chemical reactions. The molecules upon which enzymes may act are called substrate (chemistry), substrates, and the enzyme converts the substrates into different mol ...
with
systematic name A systematic name is a name given in a systematic way to one unique group, organism, object or chemical substance, out of a specific population or collection. Systematic names are usually part of a nomenclature. A semisystematic name or semitrivi ...
''bacteriochlorophyllide-a:ferredoxin 7,8-oxidoreductase''. It catalyses the following
chemical reaction A chemical reaction is a process that leads to the chemistry, chemical transformation of one set of chemical substances to another. When chemical reactions occur, the atoms are rearranged and the reaction is accompanied by an Gibbs free energy, ...
: chlorophyllide ''a'' + 2 reduced
ferredoxin Ferredoxins (from Latin ''ferrum'': iron + redox, often abbreviated "fd") are iron–sulfur proteins that mediate electron transfer in a range of metabolic reactions. The term "ferredoxin" was coined by D.C. Wharton of the DuPont Co. and applied t ...
+ ATP + H2O + 2 H+ \rightleftharpoons 3-deacetyl 3-vinylbacteriochlorophyllide ''a'' + 2 oxidized ferredoxin + ADP + phosphate substrate Substrate may refer to: Physical layers *Substrate (biology), the natural environment in which an organism lives, or the surface or medium on which an organism grows or is attached ** Substrate (aquatic environment), the earthy material that exi ...
and product of the enzyme"> Chlorophyllide a.svg, Chlorophyllide ''a'' Bacteriochlorophyllide a.png, Bacteriochlorophyllide ''a'' (R=H). The product of COR retains the
vinyl group In organic chemistry, a vinyl group (abbr. Vi; IUPAC name: ethenyl group) is a functional group with the formula . It is the ethylene (IUPAC name: ethene) molecule () with one fewer hydrogen atom. The name is also used for any compound contai ...
of the substrate in place of the
acetyl group In organic chemistry, an acetyl group is a functional group denoted by the chemical formula and the structure . It is sometimes represented by the symbol Ac (not to be confused with the element actinium). In IUPAC nomenclature, an acetyl grou ...
shown This reduction (with ''trans'' stereochemistry) of the pyrrole ring B gives the characteristic 18-electron aromatic system that distinguishes
bacteriochlorophyll Bacteriochlorophylls (BChl) are photosynthetic pigments that occur in various phototrophic bacteria. They were discovered by C. B. van Niel in 1932. They are related to chlorophylls, which are the primary pigments in plants, algae, and cyanobacte ...
s from
chlorophyll Chlorophyll is any of several related green pigments found in cyanobacteria and in the chloroplasts of algae and plants. Its name is derived from the Greek words (, "pale green") and (, "leaf"). Chlorophyll allows plants to absorb energy ...
s, which retain the
chlorin In organic chemistry, chlorins are tetrapyrrole pigments that are partially hydrogenation, hydrogenated porphyrins. The parent chlorin is an unstable compound which undergoes air oxidation to porphine. The name chlorin derives from chlorophyll. ...
system of chlorophyllide ''a''. This enzyme is present in
purple bacteria Purple bacteria or purple photosynthetic bacteria are Gram-negative proteobacteria that are phototrophic, capable of producing their own food via photosynthesis. They are pigmented with bacteriochlorophyll ''a'' or ''b'', together with various ...
such as ''
Rhodobacter capsulatus ''Rhodobacter capsulatus'' is a species of purple bacteria, a group of bacteria that can obtain energy through photosynthesis. Its name is derived from the Latin adjective "capsulatus" ("with a chest", "encapsulated"), itself derived Latin noun ...
'' and ''
Rhodobacter sphaeroides ''Rhodobacter sphaeroides'' is a kind of purple bacterium; a group of bacteria that can obtain energy through photosynthesis. Its best growth conditions are anaerobic phototrophy ( photoheterotrophic and photoautotrophic) and aerobic chemoh ...
'', and
Pseudomonadota Pseudomonadota (synonym "Proteobacteria") is a major phylum of gram-negative bacteria. Currently, they are considered the predominant phylum within the domain of bacteria. They are naturally found as pathogenic and free-living (non- parasitic) ...
. It is a component of the
biosynthetic pathway In biochemistry, a metabolic pathway is a linked series of chemical reactions occurring within a cell. The reactants, products, and intermediates of an enzymatic reaction are known as metabolites, which are modified by a sequence of chemical re ...
to bacteriochlorophylls.


See also

* Biosynthesis of bacteriochlorophylls


References

EC 1.3.7 {{1.3-enzyme-stub