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Chemical Agent Identification Sets (CAIS), known by several other names, were sets of glass vials or bottles that contained small amounts of chemical agents. They were employed by all branches of the
United States Armed Forces The United States Armed Forces are the military forces of the United States. The armed forces consists of six service branches: the Army, Marine Corps, Navy, Air Force, Space Force, and Coast Guard. The president of the United States is ...
from 1928-1969 for the purpose of training in detection, handling and familiarization with
chemical warfare Chemical warfare (CW) involves using the toxic properties of chemical substances as weapons. This type of warfare is distinct from nuclear warfare, biological warfare and radiological warfare, which together make up CBRN, the military a ...
. Most CAIS were destroyed in the 1980s but the U.S. Army Chemical Materials Agency still occasionally demilitarizes CAIS that are found buried.


History


Nomenclature

Throughout the military's use of CAIS they were known by several different common names aside from Chemical Agent Identification Sets. The other names were: Toxic Gas Sets, Chemical Agent Identification Training Sets, Instructional War Gas Identification Sets, Detonation War Gas Identification Sets, and Instructional Gas Identification Replacement Sets.


General history

CAIS were used by all branches of the
United States military The United States Armed Forces are the military forces of the United States. The armed forces consists of six service branches: the Army, Marine Corps, Navy, Air Force, Space Force, and Coast Guard. The president of the United States is ...
for training in detection, handling and familiarization with chemical warfare agents between the 1930s and 1960s. The U.S. Army used CAIS to train its soldiers from 1928 until 1969. During this time period more than 100,000 CAIS units were produced by all branches of the military. CAIS were declared obsolete in 1971 and systematically recalled from military installations during two operations. The first recall operation, Operation Set Consolidation I (SETCON I), was in 1978; SETCON II followed on in 1980.


Specifications

Chemical Agent Identification Sets were small glass vials, ampules or bottles which contained small amounts of chemical warfare agents or
industrial chemical The chemical industry comprises the companies that produce industrial chemicals. Central to the modern world economy, it converts raw materials ( oil, natural gas, air, water, metals, and minerals) into more than 70,000 different products ...
s. Each set contained more than two dozen glass ampules, each ampule contained about 100 milliliters of chemical agent. There were three subsets of CAIS, distributed in 18 different set configurations. These subsets included bottles of
sulfur mustard Mustard gas or sulfur mustard is a chemical compound belonging to a family of cytotoxic and blister agents known as mustard agents. The name ''mustard gas'' is technically incorrect: the substance, when dispersed, is often not actually a gas, b ...
used to purposely contaminate equipment or terrain for
decontamination Decontamination (sometimes abbreviated as decon, dcon, or decontam) is the process of removing contaminants on an object or area, including chemicals, micro-organisms or radioactive substances. This may be achieved by chemical reaction, disinfect ...
training.Meacham, Kim.
Removal and Destruction of Chemical Agent Identification Sets At Fort Benning
, Environmental Branch, Engineering and Support Center,
United States Army Corps of Engineers , colors = , anniversaries = 16 June (Organization Day) , battles = , battles_label = Wars , website = , commander1 = ...
, via
Defence Science and Technology Laboratory The Defence Science and Technology Laboratory (Dstl) is an executive agency of the Ministry of Defence of the United Kingdom. Its stated purpose is "to maximise the impact of science and technology for the defence and security of the UK". The a ...
(Great Britain). p. 3. accessed December 9, 2008.
Another type of CAIS were known as "sniff sets" and were used to train soldiers to recognize the color and odor of chemical agents. Used indoors, the sniff sets contained agent-impregnated charcoal and agent simulants; they contained very little actual chemical warfare agent.Meacham, Kim.
Removal and Destruction of Chemical Agent Identification Sets At Fort Benning
, Environmental Branch, Engineering and Support Center,
United States Army Corps of Engineers , colors = , anniversaries = 16 June (Organization Day) , battles = , battles_label = Wars , website = , commander1 = ...
, via
Defence Science and Technology Laboratory The Defence Science and Technology Laboratory (Dstl) is an executive agency of the Ministry of Defence of the United Kingdom. Its stated purpose is "to maximise the impact of science and technology for the defence and security of the UK". The a ...
(Great Britain), accessed December 9, 2008.


Chemical agents

Each of the CAIS held between one and five different chemical agents. The agents used in CAIS were
phosgene Phosgene is the organic chemical compound with the formula COCl2. It is a toxic, colorless gas; in low concentrations, its musty odor resembles that of freshly cut hay or grass. Phosgene is a valued and important industrial building block, es ...
,
adamsite Adamsite or DM is an organic compound; technically, an arsenical diphenylaminechlorarsine, that can be used as a riot control agent. DM belongs to the group of chemical warfare agents known as vomiting agents or sneeze gases. First synthesized i ...
,
lewisite Lewisite (L) (A-243) is an organoarsenic compound. It was once manufactured in the U.S., Japan, Germany and the Soviet Union for use as a Chemical warfare, chemical weapon, acting as a vesicant (blister agent) and lung irritant. Although the substa ...
,
cyanogen chloride Cyanogen chloride is a highly toxic chemical compound with the formula CNCl. This linear, triatomic pseudohalogen is an easily condensed colorless gas. More commonly encountered in the laboratory is the related compound cyanogen bromide, a room-t ...
,
chloroacetophenone Phenacyl chloride, also commonly known as chloroacetophenone, is a substituted acetophenone. It is a useful building block in organic chemistry. Apart from that, it has been historically used as a riot control agent, where it is designated CN. It ...
,
sarin Sarin (NATO designation GB G-series, "B"">Nerve_agent#G-series.html" ;"title="hort for Nerve agent#G-series">G-series, "B" is an extremely toxic synthetic organophosphorus compound.nitrogen mustard Nitrogen mustards are cytotoxic organic compounds with the chloroethylamine (Cl(CH2)2NR2) functional group. Although originally produced as chemical warfare agents, they were the first chemotherapeutic agents for treatment of cancer. Nitrogen ...
, sulfur mustard and
chloropicrin Chloropicrin, also known as PS and nitrochloroform, is a chemical compound currently used as a broad-spectrum antimicrobial, fungicide, herbicide, insecticide, and nematicide. It was used as a poison gas in World War I. Its chemical structural for ...
. In addition, triphosgene, a phosgene simulant, and ethyl malonate, a tabun simulant were also used. Sarin was the only
nerve agent Nerve agents, sometimes also called nerve gases, are a class of organic chemicals that disrupt the mechanisms by which nerves transfer messages to organs. The disruption is caused by the blocking of acetylcholinesterase (AChE), an enzyme that ...
used in CAIS.Committee on Review and Evaluation of the Army Non-Stockpile Chemical Materiel Disposal Program,
U.S. National Research Council The National Academies of Sciences, Engineering, and Medicine (also known as NASEM or the National Academies) are the collective scientific national academy of the United States. The name is used interchangeably in two senses: (1) as an umbrell ...
. ''Disposal of Chemical Agent Identification Sets'',
Google Books
, p. 14-15, National Academies Press, 1999, ().


Disposal programs

Following the recall operations of the late 1970s and early 1980s, 21,400 CAIS were sent to
Rocky Mountain Arsenal The Rocky Mountain Arsenal was a United States chemical weapons manufacturing center located in the Denver Metropolitan Area in Commerce City, Colorado. The site was completed December 1942, operated by the United States Army throughout the lat ...
where they were destroyed by
incineration Incineration is a waste treatment process that involves the combustion of substances contained in waste materials. Industrial plants for waste incineration are commonly referred to as waste-to-energy facilities. Incineration and other hig ...
. The destroyed CAIS represented the entire stockpile then in storage.Chemical Agent Identification Sets
", Fact Sheet, U.S. Army Chemical Materials Agency, accessed December 9, 2008.
This initial disposal took place from May–October 1979 and again from May 1981-December 1982.Mauroni, Albert J. ''Chemical Demilitarization: Public Policy Aspects'',
Google Books
, Greenwood Publishing Group, 2003, pp. 43-44, ().
Though the stockpile of CAIS were destroyed decades ago, there remained the problem of what to do with CAIS found buried underground. Most of the other 80,000 or so CAIS were used during training but some were disposed of, the primary method of disposal was burial. The U.S. Army Chemical Materials Agency was assigned the task of destroying CAIS as they were found, usually through ongoing construction projects.Single CAIS Access and Neutralization System
", Fact Sheet, U.S. Army Chemical Materials Agency, accessed December 9, 2008.
Most parts of the CAIS can be disposed of as hazardous waste, but the concentrated mustard agent must be neutralized before it is shipped. The Single CAIS Access and Neutralization System (SCANS) is a handheld container for safely mixing the mustard agent with a neutralizing agent.


References


External links


U.S. Army Chemical Materials Agency
Non-Stockpile Chemical Materiel Project (NSCMP) {{U.S. chemical weapons Chemical warfare Military equipment of the United States