Casuarictin is an
ellagitannin
The ellagitannins are a diverse class of hydrolyzable tannins, a type of polyphenol formed primarily from the oxidative linkage of galloyl groups in 1,2,3,4,6-pentagalloyl glucose. Ellagitannins differ from gallotannins, in that their galloyl ...
, a type of hydrolysable tannin. It can be found in ''
Casuarina'' and ''
Stachyurus'' species.
[Tannins of Casuarina and Stachyurus species. I: Structures of pendunculagin, casuarictin, strictinin, casuarinin, casuariin, and stachyurin. Okuda T., Yoshida T., Ashida M. and Yazaki K., Journal of the Chemical Society, 1983, number 8, pages 1765-1772, ]
It is formed from two
hexahydroxydiphenic acid
Hexahydroxydiphenic acid is an organic compound with the formula HO)3C6HCO2Hsub>2. It is the oxidatively coupled derivative of gallic acid It is a white solid, although samples are typically brown owing to oxidation.
left, 142px, Ellagic acid ...
units and one
gallic acid
Gallic acid (also known as 3,4,5-trihydroxybenzoic acid) is a trihydroxybenzoic acid with the formula C6 H2( OH)3CO2H. It is classified as a phenolic acid. It is found in gallnuts, sumac, witch hazel, tea leaves, oak bark, and other plants ...
unit linked to a
glucose
Glucose is a simple sugar with the molecular formula . Glucose is overall the most abundant monosaccharide, a subcategory of carbohydrates. Glucose is mainly made by plants and most algae during photosynthesis from water and carbon dioxide, usi ...
molecule.
The molecule is formed from
tellimagrandin II, itself formed from
pentagalloyl glucose Pentagalloyl glucose may refer to:
* 1,2,3,4,6-Pentagalloyl-glucose
1,2,3,4,6-Pentagalloylglucose is the pentagallic acid ester of glucose. It is a gallotannin and the precursor of ellagitannins.
Pentagalloyl glucose can precipitate proteins, incl ...
via oxidation. Casuarictin is transformed into
pedunculagin via loss of a gallate group, and further into
castalagin via glucose pyranose ring opening.
Oligomers
Sanguiin H-6 is a dimer,
Lambertianin C is trimer and
lambertianin D is a tetramer of casuarictin.
References
{{Ellagitannin
Ellagitannins
Lactones