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Carl Paul Gottfried von Linde (11 June 1842 – 16 November 1934) was a German scientist, engineer, and businessman. He discovered the refrigeration cycle and invented the first industrial-scale air separation and gas liquefaction processes, which led to the first reliable and efficient compressed-ammonia
refrigerator A refrigerator, commonly shortened to fridge, is a commercial and home appliance consisting of a thermal insulation, thermally insulated compartment and a heat pump (mechanical, electronic or chemical) that transfers heat from its inside to ...
in 1876. Linde was the founder of the company now known as Linde plc but formerly known (variously) as the Linde division of Union Carbide, Linde, Linde Air Products, Praxair, and others. This company is the world's largest producer of industrial gases and ushered in the creation of the global
supply chain A supply chain is a complex logistics system that consists of facilities that convert raw materials into finished products and distribute them to end consumers or end customers, while supply chain management deals with the flow of goods in distri ...
for
industrial gas Industrial gases are the gaseous materials that are Manufacturing, manufactured for use in Industrial sector, industry. The principal gases provided are nitrogen, oxygen, carbon dioxide, argon, hydrogen, helium and acetylene, although many other ...
es. Linde was a member of scientific and engineering associations, including being on the board of trustees of the Physikalisch-Technische Reichsanstalt and the
Bavarian Academy of Sciences and Humanities The Bavarian Academy of Sciences and Humanities () is an independent public institution, located in Munich. It appoints scholars whose research has contributed considerably to the increase of knowledge within their subject. The general goal of th ...
. He was
knight A knight is a person granted an honorary title of a knighthood by a head of state (including the pope) or representative for service to the monarch, the church, or the country, especially in a military capacity. The concept of a knighthood ...
ed in 1897 as Ritter von Linde.


Biography


Early years

Born in ,
Bavaria Bavaria, officially the Free State of Bavaria, is a States of Germany, state in the southeast of Germany. With an area of , it is the list of German states by area, largest German state by land area, comprising approximately 1/5 of the total l ...
as the son of a German-born minister and a Swedish mother, he was expected to follow in his father's footsteps but took another direction entirely. Von Linde's family moved to
Munich Munich is the capital and most populous city of Bavaria, Germany. As of 30 November 2024, its population was 1,604,384, making it the third-largest city in Germany after Berlin and Hamburg. Munich is the largest city in Germany that is no ...
in 1854, and eight years later he started a course in engineering at the Swiss Federal Institute of Technology in Zürich, Switzerland, where his teachers included
Rudolf Clausius Rudolf Julius Emanuel Clausius (; 2 January 1822 – 24 August 1888) was a German physicist and mathematician and is considered one of the central founding fathers of the science of thermodynamics. By his restatement of Sadi Carnot's principle ...
, Gustav Zeuner and Franz Reuleaux. In 1864, he was expelled before graduating for participating in a student protest, but Reuleaux found him a position as an apprentice at the Kottern cotton-spinning plant in Kempten. Linde stayed only a short time before moving first to Borsig in
Berlin Berlin ( ; ) is the Capital of Germany, capital and largest city of Germany, by both area and List of cities in Germany by population, population. With 3.7 million inhabitants, it has the List of cities in the European Union by population withi ...
and then to the new Krauss locomotive factory in
Munich Munich is the capital and most populous city of Bavaria, Germany. As of 30 November 2024, its population was 1,604,384, making it the third-largest city in Germany after Berlin and Hamburg. Munich is the largest city in Germany that is no ...
, where he worked as head of the technical department. Von Linde married Helene Grimm in September 1866; their marriage lasted 53 years and they had six children. In 1868 Linde learned of a new university opening in Munich (the ''
Technische Hochschule A ''Technische Hochschule'' (, plural: ''Technische Hochschulen'', abbreviated ''TH'') is a type of university focusing on engineering sciences in Germany. Previously, it also existed in Austria, Switzerland, the Netherlands (), and Finland (, ) ...
'') and immediately applied for a job as a lecturer; he was accepted—at the age of 26—for the position. He became a full professor of mechanical engineering in 1872, and set up an engineering lab where students such as
Rudolf Diesel Rudolf Christian Karl Diesel (, ; 18 March 1858 – 29 September 1913) was a German inventor and mechanical engineer who invented the Diesel engine, which burns Diesel fuel; both are named after him. Early life and education Diesel was born on 1 ...
studied.


Middle years

In 1870 and 1871, Linde published articles in the ''Bavarian Industry and Trade Journal'' describing his research findings in the area of
refrigeration Refrigeration is any of various types of cooling of a space, substance, or system to lower and/or maintain its temperature below the ambient one (while the removed heat is ejected to a place of higher temperature).IIR International Dictionary of ...
. Linde's first refrigeration plants were commercially successful, and development began to take up increasing amounts of his time. In 1879, he gave up his professorship and founded the ''Gesellschaft für Lindes Eismaschinen Aktiengesellschaft'' ("Linde's Ice Machine Company"), now ''Linde plc'', in
Wiesbaden Wiesbaden (; ) is the capital of the German state of Hesse, and the second-largest Hessian city after Frankfurt am Main. With around 283,000 inhabitants, it is List of cities in Germany by population, Germany's 24th-largest city. Wiesbaden form ...
, Germany. After a slow start in a difficult German economy, business picked up quickly in the 1880s. The efficient new refrigeration technology offered big benefits to the breweries, and by 1890 Linde had sold 747 machines. In addition to the breweries, other uses for the new technology were found in slaughterhouses and cold storage facilities all over Europe. In 1888, Linde moved back to Munich where he took up his professorship once more but was soon back at work developing new refrigeration cycles. In 1892, an order from the Guinness brewery in
Dublin Dublin is the capital and largest city of Republic of Ireland, Ireland. Situated on Dublin Bay at the mouth of the River Liffey, it is in the Provinces of Ireland, province of Leinster, and is bordered on the south by the Dublin Mountains, pa ...
for a
carbon dioxide Carbon dioxide is a chemical compound with the chemical formula . It is made up of molecules that each have one carbon atom covalent bond, covalently double bonded to two oxygen atoms. It is found in a gas state at room temperature and at norma ...
liquefaction plant drove Linde's research into the area of low-temperature refrigeration, and in 1894 he started work on a process for the liquefaction of air. In 1895, Linde first achieved success, and filed for
patent A patent is a type of intellectual property that gives its owner the legal right to exclude others from making, using, or selling an invention for a limited period of time in exchange for publishing an sufficiency of disclosure, enabling discl ...
protection of his process (not approved in the US until 1903). In 1901, Linde began work on a technique to obtain pure
oxygen Oxygen is a chemical element; it has chemical symbol, symbol O and atomic number 8. It is a member of the chalcogen group (periodic table), group in the periodic table, a highly reactivity (chemistry), reactive nonmetal (chemistry), non ...
and
nitrogen Nitrogen is a chemical element; it has Symbol (chemistry), symbol N and atomic number 7. Nitrogen is a Nonmetal (chemistry), nonmetal and the lightest member of pnictogen, group 15 of the periodic table, often called the Pnictogen, pnictogens. ...
based on the
fractional distillation Fractional distillation is the separation of a mixture into its component parts, or fractions. Chemical compounds are separated by heating them to a temperature at which one or more fractions of the mixture will vaporize. It uses distillation ...
of liquefied air. By 1910, coworkers including Carl's son Friedrich had developed the ''Linde double-column'' process, variants of which are still in common use today. After a decade, Linde withdrew from managerial activities to refocus on research, and in 1895 he succeeded in liquefying air by first compressing it and then letting it expand rapidly, thereby cooling it. He then obtained oxygen and nitrogen from the liquid air by slow warming. In the early days of oxygen production, the biggest use by far for the gas was the
oxyacetylene torch file:Brennschneiden.svg, Principle of burn cutting Oxy-fuel welding (commonly called oxyacetylene welding, oxy welding, or gas welding in the United States) and oxy-fuel cutting are processes that use fuel gases (or liquid fuels such as gasolin ...
, invented in
France France, officially the French Republic, is a country located primarily in Western Europe. Overseas France, Its overseas regions and territories include French Guiana in South America, Saint Pierre and Miquelon in the Atlantic Ocean#North Atlan ...
in 1903, which revolutionized metal cutting and
welding Welding is a fabrication (metal), fabrication process that joins materials, usually metals or thermoplastics, primarily by using high temperature to melting, melt the parts together and allow them to cool, causing Fusion welding, fusion. Co ...
in the construction of ships,
skyscraper A skyscraper is a tall continuously habitable building having multiple floors. Most modern sources define skyscrapers as being at least or in height, though there is no universally accepted definition, other than being very tall high-rise bui ...
s, and other iron and steel structures. In 1897, Linde was appointed to the Order of Merit of the Bavarian Crown and ennobled in accordance with its statutes. In addition to Linde's technical and engineering abilities, he was a successful entrepreneur. He formed many successful partnerships in Germany and internationally, working effectively to exploit the value of his patents and knowledge through licensing arrangements. In 1906, Linde negotiated a stake in Brin's Oxygen Company, renamed The BOC Group. in exchange for rights to Linde's patents in the UK and other countries, and held a board position until 1914. Linde also formed the Linde Air Products Company in the USA in 1907, a company that passed through US Government control to Union Carbide in the 1940s and on to form Praxair. In 2005 ''Linde, plc'' bought the BOC Group, and in 2019 ''Linde plc'' merged with Praxair, thus combining all three companies founded by Linde.


Later years and death

From around 1910, Linde started transferring responsibility for the company's operation to his sons Friedrich and Richard and to his son-in-law Rudolf Wucherer. He continued with supervisory board and advisory duties until his death. Carl von Linde died in Munich in November 1934 at the age of 92.


Key inventions

Linde's first refrigeration system used
dimethyl ether Dimethyl ether (DME; also known as methoxymethane) is the organic compound with the formula CH3OCH3, (sometimes ambiguously simplified to C2H6O as it is an isomer of ethanol). The simplest ether, it is a colorless gas that is a useful precursor ...
as the refrigerant and was built by ''Maschinenfabrik Augsburg'' (now MAN AG) for the Spaten Brewery in 1873. He quickly moved on to develop more reliable
ammonia Ammonia is an inorganic chemical compound of nitrogen and hydrogen with the chemical formula, formula . A Binary compounds of hydrogen, stable binary hydride and the simplest pnictogen hydride, ammonia is a colourless gas with a distinctive pu ...
-based cycles. These were early examples of vapor-compression refrigeration machines, and ammonia is still in wide use as a
refrigerant A refrigerant is a working fluid used in the cooling, heating, or reverse cooling/heating cycles of air conditioning systems and heat pumps, where they undergo a repeated phase transition from a liquid to a gas and back again. Refrigerants are ...
in industrial applications. His apparatus for the liquefaction of air combined the cooling effect achieved by allowing a compressed gas to expand (the
Joule–Thomson effect In thermodynamics, the Joule–Thomson effect (also known as the Joule–Kelvin effect or Kelvin–Joule effect) describes the temperature change of a Real gas, ''real'' gas or liquid (as differentiated from an ideal gas) when it is expanding; ty ...
first observed by James Prescott Joule and
Lord Kelvin William Thomson, 1st Baron Kelvin (26 June 182417 December 1907), was a British mathematician, Mathematical physics, mathematical physicist and engineer. Born in Belfast, he was the Professor of Natural Philosophy (Glasgow), professor of Natur ...
) with a counter-current heat exchange technique that used the cold air produced by expansion to chill ambient air entering the apparatus. Over a period of time this effect gradually cooled the apparatus and air within it to the point of liquefaction. Linde followed development of air liquefaction equipment with equipment that also separated air into its constituent parts using distillation processes. Linde's inventions and developments spurred development in many areas of
cryogenics In physics, cryogenics is the production and behaviour of materials at very low temperatures. The 13th International Institute of Refrigeration's (IIR) International Congress of Refrigeration (held in Washington, DC in 1971) endorsed a universa ...
,
physics Physics is the scientific study of matter, its Elementary particle, fundamental constituents, its motion and behavior through space and time, and the related entities of energy and force. "Physical science is that department of knowledge whi ...
,
chemistry Chemistry is the scientific study of the properties and behavior of matter. It is a physical science within the natural sciences that studies the chemical elements that make up matter and chemical compound, compounds made of atoms, molecules a ...
and
engineering Engineering is the practice of using natural science, mathematics, and the engineering design process to Problem solving#Engineering, solve problems within technology, increase efficiency and productivity, and improve Systems engineering, s ...
.


Patents


CH10704
– 31 January 1896 – ''Gasverflüssigungs-maschine (Machine for the liquefaction of gas)'' (in German) – Switzerland
GB189512528
– 16 May 1896 – ''Process and Apparatus for Liquefying Gases or Gaseous Mixtures, and for Producing Cold, more particularly applicable for Separating Oxygen from Atmospheric Air'' – UK * – 12 May 1903 – ''Linde oxygen process'' – US * – 12 May 1903 – ''Equipment for Linde oxygen process'' – US * – 25 July 1905 – ''Equipment for Linde oxygen and nitrogen process'' – US


Awards

*
Wilhelm Exner Medal The Wilhelm Exner Medal has been awarded by the Austrian Industry Association, (ÖGV), for excellence in research and science since 1921. The medal is dedicated to Wilhelm Exner (1840–1931), former president of the Association, who initialize ...
, 1922


See also

* Air separation * Cryogenic nitrogen plant *
Industrial gas Industrial gases are the gaseous materials that are Manufacturing, manufactured for use in Industrial sector, industry. The principal gases provided are nitrogen, oxygen, carbon dioxide, argon, hydrogen, helium and acetylene, although many other ...
* Timeline of low-temperature technology * German inventors and discoverers


References


Further reading

* Carl von Linde: "''Aus meinem Leben und von meiner Arbeit''" (Memoirs: "From my life and about my work"), first published 1916, reprinted by
Springer Springer or springers may refer to: Publishers * Springer Science+Business Media, aka Springer International Publishing, a worldwide publishing group founded in 1842 in Germany formerly known as Springer-Verlag. ** Springer Nature, a multinationa ...
1984, . *


External links

*
Linde AG
' (Homepage) * {{DEFAULTSORT:Linde, Carl von 1842 births 1934 deaths Burials at Munich Waldfriedhof ETH Zurich alumni German company founders German industrialists German chemical industry businesspeople 19th-century German businesspeople 20th-century German businesspeople German mechanical engineers Engineers from Bavaria 19th-century German inventors Industrial gases People from the Kingdom of Bavaria People from Kulmbach (district) Academic staff of the Technical University of Munich Werner von Siemens Ring laureates Recipients of the Pour le Mérite (civil class) Linde plc people