Calcsilicates
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The Canaveilles Group is the basal
metasediment In geology, metasedimentary rock is a type of metamorphic rock. Such a rock was first formed through the deposition and solidification of sediment Sediment is a solid material that is transported to a new location where it is deposited. It occu ...
ary succession of late
Neoproterozoic The Neoproterozoic Era is the last of the three geologic eras of the Proterozoic geologic eon, eon, spanning from 1 billion to 538.8 million years ago, and is the last era of the Precambrian "supereon". It is preceded by the Mesoproterozoic era an ...
and
Cambrian The Cambrian ( ) is the first geological period of the Paleozoic Era, and the Phanerozoic Eon. The Cambrian lasted 51.95 million years from the end of the preceding Ediacaran period 538.8 Ma (million years ago) to the beginning of the Ordov ...
age outcropping in the
Pyrenees The Pyrenees are a mountain range straddling the border of France and Spain. They extend nearly from their union with the Cantabrian Mountains to Cap de Creus on the Mediterranean coast, reaching a maximum elevation of at the peak of Aneto. ...
.


Etymology

The Canaveilles Group, sometimes also called ''Canaveilles Series'', was named after its type locality
Canaveilles Canaveilles (; ) is a commune in the Pyrénées-Orientales department in southern France. Geography Canaveilles is located in the canton of Les Pyrénées catalanes and in the arrondissement of Prades. Olette-Canaveilles-les-Bains station has ...
, a small town in the
French French may refer to: * Something of, from, or related to France ** French language, which originated in France ** French people, a nation and ethnic group ** French cuisine, cooking traditions and practices Arts and media * The French (band), ...
department
Pyrénées-Orientales Pyrénées-Orientales (; ; ; ), also known as Northern Catalonia, is a departments of France, department of the Regions of France, region of Occitania (administrative region), Occitania, Southern France, adjacent to the northern Spain, Spanish ...
.


Geographical occurrence

The areal distribution of the Canaveilles Group centers on the eastern
Pyrenees The Pyrenees are a mountain range straddling the border of France and Spain. They extend nearly from their union with the Cantabrian Mountains to Cap de Creus on the Mediterranean coast, reaching a maximum elevation of at the peak of Aneto. ...
. Further north in the
Montagne Noire The Montagne Noire (; , known as the 'Black Mountain' in English) is a mountain range in central southern France. It is located at the southwestern end of the Massif Central at the juncture of the Tarn, Hérault and Aude departments. Its highe ...
, the southernmost promontory of the Massif Central, a comparable succession occurs, the la Salvetat-Saint-Pons Series. The Upper Alcudian of the
Iberia The Iberian Peninsula ( ), also known as Iberia, is a peninsula in south-western Europe. Mostly separated from the rest of the European landmass by the Pyrenees, it includes the territories of peninsular Spain and Continental Portugal, compri ...
n peninsula also displays great similarities with the Canaveilles Group. The group's main area of distribution focusses on the type locality and the surroundings of Mount Canigou. Yet the group can also be encountered in the Cadí nappe on the
Spanish Spanish might refer to: * Items from or related to Spain: **Spaniards are a nation and ethnic group indigenous to Spain **Spanish language, spoken in Spain and many countries in the Americas **Spanish cuisine **Spanish history **Spanish culture ...
side of the Pyrenees.


Stratigraphy


Main sequence

At its type locality the marine Canaveilles Group reaches a thickness of 3000 meters, otherwise its thickness varies between 2000 and 4000 meters. On Mount Canigou the group's base overlies leptynitic, so-called “transitional
gneiss Gneiss (pronounced ) is a common and widely distributed type of metamorphic rock. It is formed by high-temperature and high-pressure metamorphic processes acting on formations composed of igneous or sedimentary rocks. This rock is formed under p ...
es” with underlying
augen gneiss Gneiss (pronounced ) is a common and widely distributed type of metamorphic rock. It is formed by high-temperature and high-pressure metamorphic processes acting on formations composed of igneous or sedimentary rocks. This rock is formed under p ...
es. The group's age reaches back to the
Ediacarian The Ediacaran ( ) is a geological period of the Neoproterozoic Era that spans 96 million years from the end of the Cryogenian Period at 635 Mya to the beginning of the Cambrian Period at 538.8 Mya. It is the last period of the Proterozoic Eon ...
, to about 580 million years. Essentially the group consists of
shale Shale is a fine-grained, clastic sedimentary rock formed from mud that is a mix of flakes of Clay mineral, clay minerals (hydrous aluminium phyllosilicates, e.g., Kaolinite, kaolin, aluminium, Al2Silicon, Si2Oxygen, O5(hydroxide, OH)4) and tiny f ...
s (with subordinate
black shale Shale is a fine-grained, clastic sedimentary rock formed from mud that is a mix of flakes of clay minerals (hydrous aluminium phyllosilicates, e.g., kaolin, Al2 Si2 O5( OH)4) and tiny fragments (silt-sized particles) of other minerals, especiall ...
s) and
greywacke Greywacke or graywacke ( ) is a variety of sandstone generally characterized by its hardness (6–7 on Mohs scale), dark color, and Sorting (sediment), poorly sorted angular grains of quartz, feldspar, and small rock fragments or sand-size Lith ...
s, intercalated are
carbonate A carbonate is a salt of carbonic acid, (), characterized by the presence of the carbonate ion, a polyatomic ion with the formula . The word "carbonate" may also refer to a carbonate ester, an organic compound containing the carbonate group ...
s and
rhyodacite Rhyodacite is a volcanic rock intermediate in composition between dacite and rhyolite. It is the extrusive equivalent of those plutonic rocks that are intermediate in composition between monzogranite and granodiorite. Rhyodacites form from rapid ...
s. In the Cadí nappe
archeocyathid Archaeocyatha (), 'ancient cups') is a taxon of extinct, sessile, reef-building marine sponges that lived in warm tropical and subtropical waters during the Cambrian Period. It is believed that the centre of the Archaeocyatha origin is now locate ...
-bearing
limestone Limestone is a type of carbonate rock, carbonate sedimentary rock which is the main source of the material Lime (material), lime. It is composed mostly of the minerals calcite and aragonite, which are different Polymorphism (materials science) ...
s occur during the lower Cambrian. With the onset of the middle Cambrian the Canaveilles Group is replaced by the lower metamorphic (
greenschist facies Greenschists are metamorphic rocks that formed under the lowest temperatures and pressures usually produced by regional metamorphism, typically and 2–10 kilobars (). Greenschists commonly have an abundance of green minerals such as chlorite, ...
conditions, chlorite zone), flyschoid
Jujols Group Jujols (; ) is a Communes of France, commune in the Pyrénées-Orientales Departments of France, department in southern France. Geography Jujols is located in the canton of Les Pyrénées catalanes and in the arrondissement of Prades. Gover ...
, to be more specific by its basal formation, the
olistostrome An olistostrome is a sedimentary deposit composed of a chaotic mass of heterogeneous material, such as blocks and mud, known as olistoliths, that accumulates as a semifluid body by submarine (geology), submarine gravity sliding or Slump (geology ...
-rich ''Tregurà Formation''.


Carbonate interlayers

Within its schists the Canaveilles Group contains at its type locality four carbonate interlayers which have been metamorphosed to
marble Marble is a metamorphic rock consisting of carbonate minerals (most commonly calcite (CaCO3) or Dolomite (mineral), dolomite (CaMg(CO3)2) that have recrystallized under the influence of heat and pressure. It has a crystalline texture, and is ty ...
s and calc schists (from top to bottom): * calcsilicates * calcareous marbles *
dolomitic Dolomite () is an anhydrous carbonate mineral composed of calcium magnesium carbonate, ideally The term is also used for a sedimentary carbonate rock composed mostly of the mineral dolomite (see Dolomite (rock)). An alternative name sometimes ...
marbles * basal calcareous marbles


Basal calcareous marbles

Intercalated at the base of the group are about 150 meters of calcareous marbles ( fr. ''marbres de base''). They include five layers of calcareous marble of sometimes massive habit and a layer of impure marbles that has formed from calcarenites. Within the last layer there are gneissic bands reaching ten centimeters and more in thickness; they are composed of calcsilicates and probably represent
marl Marl is an earthy material rich in carbonate minerals, Clay minerals, clays, and silt. When Lithification, hardened into rock, this becomes marlstone. It is formed in marine or freshwater environments, often through the activities of algae. M ...
y horizons.


Dolomitic marbles

The fine-grained, grey to cream coloured dolomitic marbles develop the mineral
chondrodite Chondrodite is a nesosilicate mineral with formula . Although it is a fairly rare mineral, it is the most frequently encountered member of the humite group of minerals. It is formed in hydrothermal deposits from locally metamorphosed dolomite ...
. In some layers also
clinochlore The chlorites are the group of phyllosilicate minerals common in low-grade metamorphic rocks and in altered igneous rocks. Greenschist, formed by metamorphism of basalt or other low-silica volcanic rock, typically contains significant amounts ...
and
phlogopite Phlogopite is a yellow, greenish, or reddish-brown member of the mica family of phyllosilicates. It is also known as magnesium mica. Phlogopite is the magnesium endmember of the biotite solid solution series, with the chemical formula KMg3AlSi3 ...
appear. Intercalated between the dolomitic marbles and the overlying calcareous marbles are layers of
quartzite Quartzite is a hard, non- foliated metamorphic rock that was originally pure quartz sandstone.Essentials of Geology, 3rd Edition, Stephen Marshak, p 182 Sandstone is converted into quartzite through heating and pressure usually related to tecton ...
and greywackes.


Calcareous marbles

The white, sometimes also greyish calcareous marbles are banded. They display a great variability in thickness. Their normal thickness of about 20 meters can increase in places up to 180 meters. These pronounced variations in thickness indicate a
reef A reef is a ridge or shoal of rock, coral, or similar relatively stable material lying beneath the surface of a natural body of water. Many reefs result from natural, abiotic component, abiotic (non-living) processes such as deposition (geol ...
al origin of the marbles, most likely as
bioherm A reef knoll is a landform that comprises an immense pile of calcareous material that had previously accumulated on an ancient sea floor. Reef knolls are geological remnants of reefs and other organic concentrations of calcareous organisms. Reef kn ...
s.


Calcsilicates

The very fine-grained calcsilicates have a gneissose appearance. They originated from very
potassium Potassium is a chemical element; it has Symbol (chemistry), symbol K (from Neo-Latin ) and atomic number19. It is a silvery white metal that is soft enough to easily cut with a knife. Potassium metal reacts rapidly with atmospheric oxygen to ...
-rich marbles. They can take on the character of multicoloured (mainly light and greenish colours), banded
hornfels Hornfels is the group name for a set of Metamorphism#Contact .28thermal.29, contact metamorphic rocks that have been baked and hardened by the heat of Intrusive rock, intrusive igneous masses and have been rendered massive, hard, splintery, and in ...
. They contain the minerals
diopside Diopside is a monoclinic pyroxene mineral with composition . It forms complete solid solution series with hedenbergite () and augite, and partial solid solutions with orthopyroxene and pigeonite. It forms variably colored, but typically dull ...
,
tremolite Tremolite is a member of the amphibole group of silicate minerals with composition Ca2(Mg5.0-4.5Fe2+0.0-0.5)Si8O22(OH)2. Tremolite forms by metamorphism of sediments rich in dolomite and quartz, and occurs in two distinct forms, crystals and fib ...
,
clinozoisite Clinozoisite is a complex calcium aluminium sorosilicate mineral with formula: Ca2Al3(Si2O7)(SiO4)O(OH). It forms a continuous solid solution series with epidote by substitution of iron(III) in the aluminium (m3 site) and is also called ''aluminiu ...
, basic
plagioclase Plagioclase ( ) is a series of Silicate minerals#Tectosilicates, tectosilicate (framework silicate) minerals within the feldspar group. Rather than referring to a particular mineral with a specific chemical composition, plagioclase is a continu ...
,
microcline Microcline (KAlSi3O8) is an important igneous rock-forming tectosilicate mineral. It is a potassium-rich alkali feldspar. Microcline typically contains minor amounts of sodium. It is common in granite and pegmatites. Microcline forms during s ...
and microscopic
biotite Biotite is a common group of phyllosilicate minerals within the mica group, with the approximate chemical formula . It is primarily a solid-solution series between the iron- endmember annite, and the magnesium-endmember phlogopite; more al ...
. At the type locality these calcsilicates form ''sandy calcschists''.


Rhyodacites

The original rhyodacites (or rhyodacitic
tuff Tuff is a type of rock made of volcanic ash ejected from a vent during a volcanic eruption. Following ejection and deposition, the ash is lithified into a solid rock. Rock that contains greater than 75% ash is considered tuff, while rock co ...
s) have been metamorphosed to fine-grained leptynites. Stratigraphically they usually follow after the basal calcareous marbles, but occasionally they can be found somewhat higher above the calcareous marbles.
Radiometric age dating Radiometric dating, radioactive dating or radioisotope dating is a technique which is used to date materials such as rocks or carbon, in which trace radioactive impurities were selectively incorporated when they were formed. The method compares ...
on these rhyodacites yielded 581 million years supporting the Ediacarian age of the Canaveilles Group.


Depositional environment

Most likely the Canaveilles Group was deposited during the interval end-Neoproterozoic to lower Cambrian at the northern edge of
Gondwana Gondwana ( ; ) was a large landmass, sometimes referred to as a supercontinent. The remnants of Gondwana make up around two-thirds of today's continental area, including South America, Africa, Antarctica, Australia (continent), Australia, Zea ...
. The sediments are of marine origin and probably were left behind on the continental margin. Possible bioherms within the carbonaceous intercalations and the archeocyathid reefs in the Cadí Nappe point at shelf or shelf edge deposits with some incorporated reefal complexes. The rhyodacites probably were associated with an
island arc Island arcs are long archipelago, chains of active volcanoes with intense earthquake, seismic activity found along convergent boundary, convergent plate tectonics, tectonic plate boundaries. Most island arcs originate on oceanic crust and have re ...
, so it is possible that the Canaveilles Group was sedimented in a
backarc The back-arc region is the area behind a volcanic arc. In island volcanic arcs, it consists of back-arc basins of oceanic crust with abyssal depths, which may be separated by remnant arcs, similar to island arcs. In continental arcs, the back-ar ...
position. This finds support in the group's close relationship with the Alcudian of central Iberia, a 15 kilometer! thick, strongly subsident Neoproterozoic sedimentary succession formed along a transform fault traversing the active northern margin of Gondwana.


Metamorphism

During the
Variscan orogeny The Variscan orogeny, or Hercynian orogeny, was a geologic mountain-building event caused by Late Paleozoic continental collision between Euramerica (Laurussia) and Gondwana to form the supercontinent of Pangaea. Nomenclature The name ''Varis ...
in the
Pennsylvanian Pennsylvanian may refer to: * A person or thing from Pennsylvania * Pennsylvanian (geology) The Pennsylvanian ( , also known as Upper Carboniferous or Late Carboniferous) is, on the International Commission on Stratigraphy, ICS geologic timesc ...
about 310 million years ago the sediments of the Canaveilles Group were
metamorphosed Metamorphic rocks arise from the transformation of existing rock to new types of rock in a process called metamorphism. The original rock (protolith) is subjected to temperatures greater than and, often, elevated pressure of or more, causi ...
under mesozonal conditions (
amphibolite facies Amphibolite () is a metamorphic rock that contains amphibole, especially hornblende and actinolite, as well as plagioclase feldspar, but with little or no quartz. It is typically dark-colored and dense, with a weakly foliated or schistose (fl ...
). The original shales transformed into
mica schist Schist ( ) is a medium-grained metamorphic rock generally derived from fine-grained sedimentary rock, like shale. It shows pronounced ''schistosity'' (named for the rock). This means that the rock is composed of mineral grains easily seen with a l ...
s of the ''cordierite, andalusite and sillimanite zone'' in the lower part of the section, higher up they only converted to
greenschist facies Greenschists are metamorphic rocks that formed under the lowest temperatures and pressures usually produced by regional metamorphism, typically and 2–10 kilobars (). Greenschists commonly have an abundance of green minerals such as chlorite, ...
phyllite Phyllite ( ) is a type of foliation (geology), foliated metamorphic rock formed from slate that is further metamorphosed so that very fine grained white mica achieves a preferred orientation.Stephen Marshak ''Essentials of Geology'', 3rd ed. I ...
s of the ''biotite zone''. The carbonaceous intercalations became marbles and calcsilicates. Close to the contact with the “transitional gneiss” first the
andalusite Andalusite is an aluminium nesosilicate mineral with the chemical formula Al2SiO5. This mineral was called andalousite by Delamétherie, who thought it came from Andalusia, Spain. It soon became clear that it was a locality error, and that the sp ...
isograd __NOTOC__ An isograd is a concept used in the study of metamorphic rocks. The metamorphic grade of such a rock is a rough measure of the degree of metamorphism it has undergone, as characterised by the presence of certain index minerals. An isogr ...
is reached, followed by the
cordierite Cordierite (mineralogy) or iolite (gemology) is a magnesium iron aluminium cyclosilicate. Iron is almost always present, and a solid solution exists between Mg-rich cordierite and Fe-rich sekaninaite with a series formula: to . A high-tempera ...
isograd. This indicates a magmatic origin of the gneisses formed from intrusive
granitoid A granitoid is a broad term referring to a diverse group of coarse-grained igneous rocks that are widely distributed across the globe, covering a significant portion of the Earth's exposed surface and constituting a large part of the continental ...
s.


Magmatism

The sedimentary succession of the Canaveilles Group often is crosscut by dikes of two-mica granite and associated
pegmatite A pegmatite is an igneous rock showing a very coarse texture, with large interlocking crystals usually greater in size than and sometimes greater than . Most pegmatites are composed of quartz, feldspar, and mica, having a similar silicic c ...
s. These dikes form part of the deep-seated Canigou granite. They intrude mainly the basal calcareous marbles and the dolomitic marbles, but can also be found higher up-section. In the lower section
diorite Diorite ( ) is an intrusive rock, intrusive igneous rock formed by the slow cooling underground of magma (molten rock) that has a moderate content of silica and a relatively low content of alkali metals. It is Intermediate composition, inter ...
s and
quartz diorite Quartz diorite is an igneous, plutonic ( intrusive) rock, of felsic composition, with phaneritic texture. Feldspar is present as plagioclase (typically oligoclase or andesine) with 10% or less potassium feldspar. Quartz is present at between 5 an ...
s sometimes occur. All these granitoid intrusions developed after the formation of the nappe structures towards the end of the Variscan orogeny.


Structural development

During the Variscan orogeny the Canaveilles Group was not only metamorphosed but also strongly deformed. In the Canigou Massif the group's metasediments together with the gneisses and the augengneisses were folded into a gigantic flat-lying isoclinal fold. Due to shearing in the fold limbs two nappe units formed which were later deformed plastically (internal folding) and buckled anticlinally. Upon reaching the brittle regime the continuing shortening led to
thrusting Thrust is a reaction force described quantitatively by Newton's third law. When a system expels or accelerates mass in one direction, the accelerated mass will cause a force of equal magnitude but opposite direction to be applied to that syst ...
and backthrusting (especially along the south side of Mount Canigou). Since several revisions of the intrusion age of the orthogneisses now all find a lower Ordovician age of 474 million years for the last crystallisation on
zircon Zircon () is a mineral belonging to the group of nesosilicates and is a source of the metal zirconium. Its chemical name is zirconium(IV) silicate, and its corresponding chemical formula is Zr SiO4. An empirical formula showing some of th ...
s, the concept of a Cadomian basement has become highly questionable. This also casts doubts on the presumed isoclinal fold structure, yet the nappes and later deformations rest established. A further consequence of the intrusive character of the orthogneisses resides in the fact, that the underlying paragneisses, once considered to be also of Cadomian age, now have to be attributed to the Canaveilles Group. Most likely these metagreywackes only have undergone a higher degree of metamorphism.Laumonier, B., Autran, A., Barbey, P., Cheilletz, A., Baudin, T., Cocherie, A. & Guerrot, C. (2004). Conséquences de l'absence de socle cadomien sur l'âge et la signification des séries pré-varisques (anté-Ordovicien supérieur) du sud de la France (Pyrénées, Montagne Noire). Bull. Soc. géol. Fr., 175, n° 6, pp. 643-655


References


Sources

* Jaffrezo, M. (1977). Pyrénées Orientales Corbières. Guides géologiques régionaux. Masson. {{ISBN, 2-225-47290-4 Geologic groups of Europe Geologic formations of France Geologic formations of Spain Pyrenees