
A boiling chip, boiling stone, porous bit anti-bumping granule is a tiny, unevenly shaped piece of substance added to liquids to make them
boil
A boil, also called a furuncle, is a deep folliculitis, which is an infection of the hair follicle. It is most commonly caused by infection by the bacterium ''Staphylococcus aureus'', resulting in a painful swollen area on the skin caused by an ...
more calmly. Boiling chips are frequently employed in
distillation
Distillation, or classical distillation, is the process of separating the components or substances from a liquid mixture by using selective boiling and condensation, usually inside an apparatus known as a still. Dry distillation is the he ...
and heating. When a liquid becomes
superheated
A superheater is a device used to convert saturated steam or wet steam into superheated steam or dry steam. Superheated steam is used in steam turbines for electricity generation, steam engines, and in processes such as steam reforming. There are ...
, a speck of dust or a
stirring rod
A glass stirring rod, glass rod, stirring rod or stir rod is a piece of laboratory equipment used to mix chemicals. They are usually made of solid glass, about the thickness and slightly longer than a drinking straw, with rounded ends.
Structure
...
can cause violent
flash boiling. Boiling chips provide
nucleation
In thermodynamics, nucleation is the first step in the formation of either a new thermodynamic phase or structure via self-assembly or self-organization within a substance or mixture. Nucleation is typically defined to be the process that de ...
sites so the liquid boils smoothly without becoming
superheated
A superheater is a device used to convert saturated steam or wet steam into superheated steam or dry steam. Superheated steam is used in steam turbines for electricity generation, steam engines, and in processes such as steam reforming. There are ...
or
bumping.
Use
Boiling chips should not be added to liquid that is already near its
boiling point, as this could also induce flash boiling.
The structure of a boiling chip traps liquid while in use, meaning that they cannot be re-used in laboratory setups. They also don't work well under vacuum; if a solution is boiling under vacuum, it is best to constantly stir it instead.
Materials
Boiling chips are typically made of a porous material, such as
alumina,
silicon carbide
Silicon carbide (SiC), also known as carborundum (), is a hard chemical compound containing silicon and carbon. A semiconductor, it occurs in nature as the extremely rare mineral moissanite, but has been mass-produced as a powder and crystal ...
,
calcium carbonate,
calcium sulfate
Calcium sulfate (or calcium sulphate) is the inorganic compound with the formula CaSO4 and related hydrates. In the form of γ-anhydrite (the anhydrous form), it is used as a desiccant. One particular hydrate is better known as plaster of Paris, ...
,
porcelain
Porcelain () is a ceramic material made by heating substances, generally including materials such as kaolinite, in a kiln to temperatures between . The strength and translucence of porcelain, relative to other types of pottery, arises main ...
or
carbon
Carbon () is a chemical element with the symbol C and atomic number 6. It is nonmetallic and tetravalent—its atom making four electrons available to form covalent chemical bonds. It belongs to group 14 of the periodic table. Carbon makes ...
, and often have a nonreactive coating of
PTFE
Polytetrafluoroethylene (PTFE) is a synthetic fluoropolymer of tetrafluoroethylene that has numerous applications. It is one of the best-known and widely applied PFAS. The commonly known brand name of PTFE-based composition is Teflon by Chem ...
. This ensures that the boiling chips will provide effective nucleation sites, yet are
chemically inert
In chemistry, the term chemically inert is used to describe a substance that is not chemically reactive. From a thermodynamic perspective, a substance is inert, or nonlabile, if it is thermodynamically unstable (positive standard Gibbs free ener ...
. In less demanding situations, like school laboratories, pieces of broken
porcelain
Porcelain () is a ceramic material made by heating substances, generally including materials such as kaolinite, in a kiln to temperatures between . The strength and translucence of porcelain, relative to other types of pottery, arises main ...
ware or
glassware
upTypical drinkware
The list of glassware includes drinking vessels (drinkware) and tableware used to set a table for eating a meal, general glass items such as vases, and glasses used in the catering industry. It does not include laboratory glas ...
are often used.
[ (dead link 2018-08-07)]
References
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Laboratory equipment
Phase transitions