Boiling Chips
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A boiling chip, boiling stone, or porous bit anti-bumping granule is a tiny, unevenly shaped piece of substance added to liquids to make them
boil A boil, also called a furuncle, is a deep folliculitis, which is an infection of the hair follicle. It is most commonly caused by infection by the bacterium ''Staphylococcus aureus'', resulting in a painful swollen area on the skin caused by ...
more calmly. Boiling chips are frequently employed in
distillation Distillation, also classical distillation, is the process of separating the component substances of a liquid mixture of two or more chemically discrete substances; the separation process is realized by way of the selective boiling of the mixt ...
and heating. When a liquid becomes superheated, a speck of dust or a stirring rod can cause violent flash boiling. Boiling chips provide
nucleation In thermodynamics, nucleation is the first step in the formation of either a new Phase (matter), thermodynamic phase or Crystal structure, structure via self-assembly or self-organization within a substance or mixture. Nucleation is typically def ...
sites so the liquid boils smoothly without becoming superheated or bumping.


Use

Boiling chips should not be added to liquid that is already near its
boiling point The boiling point of a substance is the temperature at which the vapor pressure of a liquid equals the pressure surrounding the liquid and the liquid changes into a vapor. The boiling point of a liquid varies depending upon the surrounding envi ...
, as this could also induce flash boiling. Boiling chips should not be used when cooking unless they are suitable for food-grade applications. The structure of a boiling chip traps liquid while in use, meaning that they cannot be re-used in laboratory setups. They also don't work well under vacuum; if a solution is boiling under vacuum, it is best to constantly stir it instead.


Materials

Boiling chips are typically made of a porous material, such as
alumina Aluminium oxide (or aluminium(III) oxide) is a chemical compound of aluminium and oxygen with the chemical formula . It is the most commonly occurring of several aluminium oxides, and specifically identified as aluminium oxide. It is commonly ...
,
silicon carbide Silicon carbide (SiC), also known as carborundum (), is a hard chemical compound containing silicon and carbon. A wide bandgap semiconductor, it occurs in nature as the extremely rare mineral moissanite, but has been mass-produced as a powder a ...
,
calcium carbonate Calcium carbonate is a chemical compound with the chemical formula . It is a common substance found in Rock (geology), rocks as the minerals calcite and aragonite, most notably in chalk and limestone, eggshells, gastropod shells, shellfish skel ...
,
calcium sulfate Calcium sulfate (or calcium sulphate) is an inorganic salt with the chemical formula . It occurs in several hydrated forms; the anhydrous state (known as anhydrite) is a white crystalline solid often found in evaporite deposits. Its dihydrate ...
,
porcelain Porcelain (), also called china, is a ceramic material made by heating Industrial mineral, raw materials, generally including kaolinite, in a kiln to temperatures between . The greater strength and translucence of porcelain, relative to oth ...
or
carbon Carbon () is a chemical element; it has chemical symbol, symbol C and atomic number 6. It is nonmetallic and tetravalence, tetravalent—meaning that its atoms are able to form up to four covalent bonds due to its valence shell exhibiting 4 ...
, and often have a nonreactive coating of
PTFE Polytetrafluoroethylene (PTFE) is a synthetic fluoropolymer of tetrafluoroethylene, and has numerous applications because it is chemically inert. The commonly known brand name of PTFE-based composition is Teflon by Chemours, a spin-off fro ...
. This ensures that the boiling chips will provide effective nucleation sites, yet are
chemically inert In chemistry, the term chemically inert is used to describe a substance that is not chemically reactive. From a thermodynamic perspective, a substance is inert, or nonlabile, if it is thermodynamically unstable (negative standard Gibbs free en ...
. In less demanding situations, like school laboratories, pieces of broken
porcelain Porcelain (), also called china, is a ceramic material made by heating Industrial mineral, raw materials, generally including kaolinite, in a kiln to temperatures between . The greater strength and translucence of porcelain, relative to oth ...
ware or
glassware upTypical drinkware. This list of glassware includes drinking vessels (drinkware), tableware used to set a table for eating a meal and generally glass items such as vases, and glasses used in the catering industry. It does not include laboratory ...
are often used. (dead link 2018-08-07)


References

{{reflist Laboratory equipment Phase transitions