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Chemically Inert
In chemistry, the term chemically inert is used to describe a substance that is not chemically reactive. From a thermodynamic perspective, a substance is inert, or nonlabile, if it is thermodynamically unstable (negative standard Gibbs free energy of formation) yet decomposes at a slow, or negligible rate. Most of the noble gases, which appear in the last column of the periodic table, are classified as inert (or unreactive). These elements are stable in their naturally occurring form (gaseous form) and they are called inert gases. Noble gas The noble gases (helium, neon, argon, krypton, xenon and radon) were previously known as 'inert gases' because of their perceived lack of participation in any chemical reactions. The reason for this is that their outermost electron shells (valence shells) are completely filled, so that they have little tendency to gain or lose electrons. They are said to acquire a noble gas configuration, or a full electron configuration. It is now ...
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Chemistry
Chemistry is the scientific study of the properties and behavior of matter. It is a physical science within the natural sciences that studies the chemical elements that make up matter and chemical compound, compounds made of atoms, molecules and ions: their composition, structure, properties, behavior and the changes they undergo during chemical reaction, reactions with other chemical substance, substances. Chemistry also addresses the nature of chemical bonds in chemical compounds. In the scope of its subject, chemistry occupies an intermediate position between physics and biology. It is sometimes called the central science because it provides a foundation for understanding both Basic research, basic and Applied science, applied scientific disciplines at a fundamental level. For example, chemistry explains aspects of plant growth (botany), the formation of igneous rocks (geology), how atmospheric ozone is formed and how environmental pollutants are degraded (ecology), the prop ...
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Noble Gas Compound
In chemistry, noble gas compounds are chemical compounds that include an element from the noble gases, group 8 or 18 of the periodic table. Although the noble gases are generally unreactive elements, many such compounds have been observed, particularly involving the element xenon. From the standpoint of chemistry, the noble gases may be divided into two groups: the relatively reactive krypton ( ionisation energy 14.0  eV), xenon (12.1 eV), and radon (10.7 eV) on one side, and the very unreactive argon (15.8 eV), neon (21.6 eV), and helium (24.6 eV) on the other. Consistent with this classification, Kr, Xe, and Rn form compounds that can be isolated in bulk at or near standard temperature and pressure, whereas He, Ne, Ar have been observed to form true chemical bonds using spectroscopic techniques, but only when frozen into a noble gas matrix at temperatures of or lower, in supersonic jets of noble gas, or under extremely high pressures with metal ...
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Air Sensitive
Air sensitivity is a term used, particularly in chemistry, to denote the reactivity of chemical compounds with some constituent of air. Most often, reactions occur with atmospheric oxygen (O2) or water vapor (H2O), although reactions with the other constituents of air such as carbon monoxide (CO), carbon dioxide (CO2), and nitrogen (N2) are also possible. Method A variety of air-free techniques have been developed to handle air-sensitive compounds. Two main types of equipment are gloveboxes and Schlenk lines. Glove boxes are sealed cabinets filled with an inert gas such as argon or nitrogen. Normal laboratory equipment can be set up in the glovebox, and manipulated by the use of gloves that penetrate its walls. The atmosphere can be regulated to approximately atmospheric pressure and set to be pure nitrogen or other gas with which the chemicals will not react. Chemicals and equipment can be transferred in and out via an airlock. A Schlenk line is a vacuum and inert-gas dual ...
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Ammonia
Ammonia is an inorganic chemical compound of nitrogen and hydrogen with the chemical formula, formula . A Binary compounds of hydrogen, stable binary hydride and the simplest pnictogen hydride, ammonia is a colourless gas with a distinctive pungent smell. It is widely used in fertilizers, refrigerants, explosives, cleaning agents, and is a precursor for numeous chemicals. Biologically, it is a common nitrogenous waste, and it contributes significantly to the nutritional needs of terrestrial organisms by serving as a precursor to fertilisers. Around 70% of ammonia produced industrially is used to make fertilisers in various forms and composition, such as urea and diammonium phosphate. Ammonia in pure form is also applied directly into the soil. Ammonia, either directly or indirectly, is also a building block for the synthesis of many chemicals. In many countries, it is classified as an List of extremely hazardous substances, extremely hazardous substance. Ammonia is toxic, cau ...
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Haber Process
The Haber process, also called the Haber–Bosch process, is the main industrial procedure for the ammonia production, production of ammonia. It converts atmospheric nitrogen (N2) to ammonia (NH3) by a reaction with hydrogen (H2) using finely divided iron metal as a catalyst: \ce \qquad This reaction is exothermic but disfavored in terms of entropy because four equivalents of reactant gases are converted into two equivalents of product gas. As a result, high pressures and temperatures that are not too high are needed to Le_Chatelier's_principle, drive the reaction forward. The German chemists Fritz Haber and Carl Bosch developed the process in the first decade of the 20th century, and its improved efficiency over existing methods such as the Birkeland–Eyde process, Birkeland-Eyde and Frank–Caro process, Frank-Caro processes was a major advancement in the industrial production of ammonia. The Haber process can be combined with steam reforming to produce ammonia with just ...
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Lithium Nitride
Lithium nitride is an inorganic compound with the chemical formula . It is the only stable alkali metal nitride. It is a reddish-pink solid with a high melting point. Preparation and handling Lithium nitride is prepared by direct reaction of elemental lithium with nitrogen gas: : Instead of burning lithium metal in an atmosphere of nitrogen, a solution of lithium in liquid sodium metal can be treated with . Lithium nitride is an extremely strong base, so it must be protected from moisture as it reacts violently with water to produce ammonia: : Structure and properties *''alpha''- (stable at room temperature and pressure) has an unusual crystal structure that consists of two types of layers: one layer has the composition contains 6-coordinate N centers and the other layer consists only of lithium cations. Two other forms are known: *''beta''-, formed from the ''alpha'' phase at 0.42 GPa has the sodium arsenide () structure; *''gamma''- (same structure as lithium bismuthide ) ...
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Lithium
Lithium (from , , ) is a chemical element; it has chemical symbol, symbol Li and atomic number 3. It is a soft, silvery-white alkali metal. Under standard temperature and pressure, standard conditions, it is the least dense metal and the least dense solid element. Like all alkali metals, lithium is highly reactivity (chemistry), reactive and flammable, and must be stored in vacuum, inert atmosphere, or inert liquid such as purified kerosene or mineral oil. It exhibits a metallic luster (mineralogy), luster. It corrosion, corrodes quickly in air to a dull silvery gray, then black tarnish. It does not occur freely in nature, but occurs mainly as pegmatite, pegmatitic minerals, which were once the main source of lithium. Due to its solubility as an ion, it is present in ocean water and is commonly obtained from brines. Lithium metal is isolated electrolysis, electrolytically from a mixture of lithium chloride and potassium chloride. The Atomic nucleus, nucleus of the lithiu ...
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Alkali Metal
The alkali metals consist of the chemical elements lithium (Li), sodium (Na), potassium (K),The symbols Na and K for sodium and potassium are derived from their Latin names, ''natrium'' and ''kalium''; these are still the origins of the names for the elements in some languages, such as German and Russian. rubidium (Rb), caesium (Cs), and francium (Fr). Together with hydrogen they constitute Group (periodic table)#Group names, group 1, which lies in the s-block of the periodic table. All alkali metals have their outermost electron in an s-orbital: this shared electron configuration results in their having very similar characteristic properties. Indeed, the alkali metals provide the best example of periodic trends, group trends in properties in the periodic table, with elements exhibiting well-characterised Homologous series, homologous behaviour. This family of elements is also known as the lithium family after its leading element. The alkali metals are all shiny, hardness, sof ...
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Covalent Bond
A covalent bond is a chemical bond that involves the sharing of electrons to form electron pairs between atoms. These electron pairs are known as shared pairs or bonding pairs. The stable balance of attractive and repulsive forces between atoms, when they share electrons, is known as covalent bonding. For many molecules, the sharing of electrons allows each atom to attain the equivalent of a full valence shell, corresponding to a stable electronic configuration. In organic chemistry, covalent bonding is much more common than ionic bonding. Covalent bonding also includes many kinds of interactions, including σ-bonding, π-bonding, metal-to-metal bonding, agostic interactions, bent bonds, three-center two-electron bonds and three-center four-electron bonds. The term "covalence" was introduced by Irving Langmuir in 1919, with Nevil Sidgwick using "co-valent link" in the 1920s. Merriam-Webster dates the specific phrase ''covalent bond'' to 1939, recognizing its first known ...
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Diatomic Molecule
Diatomic molecules () are molecules composed of only two atoms, of the same or different chemical elements. If a diatomic molecule consists of two atoms of the same element, such as hydrogen () or oxygen (), then it is said to be homonuclear molecule, homonuclear. Otherwise, if a diatomic molecule consists of two different atoms, such as carbon monoxide () or nitric oxide (), the molecule is said to be heteronuclear molecule, heteronuclear. The bond in a homonuclear diatomic molecule is non-polar. The only chemical elements that form stable homonuclear diatomic molecules at standard temperature and pressure (STP) (or at typical laboratory conditions of 1 bar (pressure), bar and 25 °C) are the gases hydrogen (), nitrogen (), oxygen (), fluorine (), and chlorine (), and the liquid bromine (). The noble gases (helium, neon, argon, krypton, xenon, and radon) are also gases at STP, but they are monatomic. The homonuclear diatomic gases and noble gases together are called "ele ...
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Inert Gas
An inert gas is a gas that does not readily undergo chemical reactions with other chemical substances and therefore does not readily form chemical compounds. Though inert gases have a variety of applications, they are generally used to prevent unwanted chemical reactions with the oxygen (oxidation) and moisture (hydrolysis) in the air from degrading a sample. Generally, all noble gases except oganesson (helium, neon, argon, krypton, xenon, and radon), nitrogen, and carbon dioxide are considered inert gases. The term ''inert gas'' is context-dependent because several of the inert gases, including nitrogen and carbon dioxide, can be made to react under certain conditions. Purified argon gas is the most commonly used inert gas due to its high natural abundance (78.3% N2, 1% Ar in air) and low relative cost. Unlike noble gases, an inert gas is not necessarily elemental and is often a compound gas. Like the noble gases, the tendency for non-reactivity is due to the valence, the ou ...
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